• Title/Summary/Keyword: C-C Coupling

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The Shear Strength and Deformability of R/C Coupling Beams using Strut-and-Tie Models (스트럿-타이 모델을 이용한 철근 콘크리트 연결보의 전단강도와 변형능력)

  • Jang, Sang-Ki;Hong, Sung-Gul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.349-352
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    • 2004
  • In this study, a strut-and-tie models for the coupling beam based on deformations are presented. To design shear-dominated R/C coupling beams, it is important to consider shear strength deterioration with required deformations. This study proposes the method of estimating shear strength of the reinforced concrete coupling beams. The proposed method determines the strain states from target displacements based on the nonlinear truss analysis. The estimated horizontal strain of beam is then used in calculating the strength of the diagonal strut with compatibility conditions. The deterioration of shear strength of the coupling beam depends on the strength degradation of struts due to plastic deformations.

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Surface Modification of Glass Fiber for Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료용 유리섬유의 표면개질)

  • 임경범;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.5
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    • pp.206-212
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    • 2003
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, glass surface was treated by plasma to examine the effect of dry interface treatment without coupling agent. It was identified that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

Thermal Stability and High Exchange Coupling Field of Bottom Type IrMn-Pinned Spin Valve (Bottom형 IrMn 스핀밸브 박막의 열적안정성과 높은 교환결합력)

  • Hwang, J.Y.;Kim, M.Y.;Rhee, J.R.
    • Journal of the Korean Magnetics Society
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    • v.12 no.2
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    • pp.64-67
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    • 2002
  • IrMn pinned spin valve (SV) films with stacks of Ta/NiFe/IrMn/CoFe/Cu/CoFe/NiFe/Ta were prepared by dc sputtering onto thermally oxidized Si (111) substrates at room temperature under a magnetic field of about 100 Oe. The annealing cycle number and temperature dependence of exchange coupling field (H$_{ex}$), magnetoresistance (MR) ratio, and coercivity (H$_{c}$) were investigated. By optimizing the process of deposition and post thermal annealing condition, we obtained the IrMn based SV films with MR ratio of 3.6%, H$_{ex}$ of 1180 Oe for the pinned layer. The H$_{ex}$ is stabilized after the second annealing cycle and it is thought that this SV reveals high thermal stability. The H$_{ex}$ maintained its strength of 600 Oe in operation up to 24$0^{\circ}C$ and decreased monotonically to zero at 27$0^{\circ}C$.

Effect of weak interlayer coupling on critical fluctuation in high $T_c$ superconductors

  • Kim, Jin-Tae;Kang, W.N.;Chung, S.H.;Ha, D.H.;Yoo, K.H.;Kim, M.S.;Lee, Sung-Ik;Park, Y.K.;Park, J.C.
    • Progress in Superconductivity
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    • v.1 no.1
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    • pp.1-8
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    • 1999
  • The magnetization and/or resistivity of high $T_c$ superconductors ($YBa_2Cu_3O_{7-\delta}$(YBCO) single crystal, $Bi_2Sr_2CaCu_2O_8$ (Bi-2212) single crystal, $Tl_2Ba_2CaCu_2O_8$ (Tl-2212) film, $HgBa_2Ca_2Cu_3O_8$ (Hg-1223) film) have been measured as a function of magnetic field H and temperature T. The extracted fluctuation part of the magnetization and conductivity exhibits a critical behavior consistent with the three-dimensional XY model. The dynamic critical exponent z does not sensitively vary with a type of the superconductors. The value of z ranges from 1.5 to $1.8{\pm}0.1$. However, the static critical exponent ${\nu}$ is the most largely increased in Tl-2212 that has a weaker interlayer coupling strength than YBCO; the value of ${\nu}$ is 0.669, 0.909, 1.19, and 1.338 for YBCO, Bi-2212, Hg-1223, and Tl-2212 respectively. The results indicate that the weak interlayer coupling along the c-axis of high $T_c$ superconductors near $T_c$ does not influence the dynamic critical exponent z (the same value of superfluid $^4He$), but significantly increases the static critical exponent ${\nu}$.

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Junction Size Dependence of Magnetic and Magnetotransport Properties in MTJs (자기터널절합에서 자기 및 자기저항의 접합크기 의존성)

  • Sankaranarayanan, V.K.;Hu, Yong-kang;Kim, Cheol-Gi;Kim, Chong-Oh;Lee, Hee-bok
    • Korean Journal of Materials Research
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    • v.13 no.6
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    • pp.369-373
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    • 2003
  • Magneto-optic Kerr Effect(MOKE), AFM and magnetoresistance measurements have been carried out on as-deposited and annealed Magnetic Tunnel Junctions(MTJs) with junction sizes 180, 250, 320 and 380 $\mu\textrm{m}$ in order to investigate the correlation among interlayer exchange coupling, surface roughness and junction size. Relatively irregular variations of coercivity $H_{c}$ (∼17.5 Oe) and interlayer exchange coupling $H_{E}$ (∼17.5 Oe) are observed over the junction in as-deposited sample prepared by DC magnetron sputtering. After annealing at $200^{\circ}C$, $H_{c}$ decreases to 15 Oe, while $H_{ E}$ increases to 20 Oe with smooth local variation. $H_{E}$ shows very good correlation with surface roughness across the junction in agreement with Neel's orange peel coupling. The increasing slope per $\mu\textrm{m}$ of normalized $H_{c}$ and $H_{E}$ are same near junction edge along free-layer direction irrespective of junction size, giving relatively uniform $H_{c}$ and $H_{ E}$ for wider junction size. Thickness profiles of the junctions measured with $\alpha$-step show increasingly flat top surface for larger junctions, indicating better uniformity for large. junctions in agreement with the normalized$ H_{c}$ and H$/_{E}$ curves. TMR ratios also increase with increasing junction size, indicating improvement for larger uniform junctions.

Effect of fiber-matrix adhesion on the fracture behavior of a carbon fiber reinforced thermoplastic-modified epoxy matrix

  • Carrillo-Escalante, H.J.;Alvarez-Castillo, A.;Valadez-Gonzalez, A.;Herrera-Franco, P. J.
    • Carbon letters
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    • v.19
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    • pp.47-56
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    • 2016
  • In this study, the fracture behavior of a thermoplastic-modified epoxy resin reinforced with continuous carbon fibers for two levels of fiber-matrix adhesion was performed. A carbon fiber with commercial sizing was used and also treated with a known silane, (3-glycidoxy propyl trimethoxysilane) coupling agent. Toughness was determined using the double cantilever test, together with surface analysis after failure using scanning electron microscope. The presence of polysulfone particles improved the fracture behavior of the composite, but fiber-matrix adhesion seemed to play a very important role in the performance of the composite material. There appeared to be a synergy between the matrix modifier and the fiber-matrix adhesion coupling agent.

Synthesis of Graphene Oxide Based CuOx Nanocomposites and Application for C-N Cross Coupling Reaction

  • Choi, Jong Hoon;Park, Joon B.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.176.1-176.1
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    • 2014
  • Graphene has attracted an increasing attention due to its extraordinary electronic, mechanical, and thermal properties. Especially, the two dimensional (2D) sheet of graphene with an extremely high surface to volume ratio has a great potential in the preparation of multifunctional nanomaterials, as 2D supports to host metal nanoparticles (NPs). Copper oxide is widely used in various areas as antifouling paint, p-type semiconductor, dry cell batteries, and catalysts. Although the copper oxide(II) has been well known for efficient catalyst in C-N cross-coupling reaction, copper oxide(I) has not been highlighted. In this research, CuO and Cu2O nanoparticles (NPs) dispersed on the surface of grapehene oxide (GO) have been synthesized by impregnation method and their morphological and electronic structures have been systemically investigated using TEM, XRD, and XAFS. We demonstrate that both CuO and Cu2O on graphene presents efficient catalytic performance toward C-N cross coupling reaction. The detailed structural difference between CuO and Cu2O NPs and their effect on catalytic performance are discussed.

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Graphene Based Cu Oxide Nanocomposites for C-N Cross Coupling Reaction

  • Choi, Jong Hoon;Park, Joon B.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.138.2-138.2
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    • 2013
  • Copper oxide is a multi-functional material being used in various research areas including catalysis, electrochemical materials, oxidizing agents etc. Among these areas, we have synthesized and utilized graphene based copper oxide nanocomposites (CuOx/Graphene) for the catalytic applications (C-N cross coupling reaction). Briefly, Cu precursors were anchored on the graphite oxide(GO) sheets being exfoliated and oxidized from graphite powder. Two different crystalline structures of Cu2O and CuO on graphene and GO were prepared by annealing them in Ar and O2 environments, respectively. The morphological and electronic structures were systemically investigated using FT-IR, XRD, XPS, XAFS, and TEM. Here, we demonstrate that the catalytic performance was found to depend on oxidative states and morphological structures of CuOx graphene nanocomposites. The relationship between the structure of copper oxides and catalytic efficiency toward C-N cross coupling reaction will be discussed.

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Effect of Calcining Temperature on Planr Coupling Factor and Resonance Characteristics of PZT (하소온도가 PZT의 Kp와 공진특성에 미치는 영향)

  • 정수태;이우일;조상희
    • Journal of the Korean Ceramic Society
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    • v.22 no.1
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    • pp.47-52
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    • 1985
  • The effect of calcining temperature on planar coupling factor Kp resonance and antiresonance frequency of $Pb(Z_{0.53}Ti_{0.47})O_3$ doped with $Nb_2O_5$ has been investigated. The calcining temperature ranged from $700^{\circ}C$ to 110$0^{\circ}C$ The calcining temperature affected on antiresonance frequency more strongly than the resonance frequency. Therefore the Kp was almost entirely dependent upon the antiresonance frequency. The p and antiresonance frequency of the sample in creased with the calcining temperature reaching a maximum at about 90$0^{\circ}C$ When a poling electric field of 35KV/cm was applied to the sample calcined at 90$0^{\circ}C$ and sintered for two hours at 120$0^{\circ}C$ Kp attained a maximum value of 0.64 which is in good agreement with the results of other investigators.

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