• Title/Summary/Keyword: C/N0

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Hydrogeneted Amorphous Carbon Nitride Films on Si(100) Deposited by DC Saddle Field Plasma Enhanced Chemical Vapor Deposition ($N_2/CH_4$가스비에 따른 Hydrogenated Amorphous Carbon Nitride 박막의 특성)

  • 장홍규;김근식;황보상우;이연승;황정남;유영조;김효근
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.242-247
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    • 1998
  • Hydrogenated amorphous carbon nitride[a-C:H(N)] films were deposited on p-type Si(100) at room temperature with bias voltage of 200 V by DC saddle-field plasma-enhanced chemical vapor deposition. Effects of the ratio of $N_2$ to $CH_4$($N_2/CH_4$), in the range of 0 and 4 on such properties as optical properties, microstucture, relative fraction of nitrogen and carbon, etc. of the films have been investigated. The thickness of the a-C:H(N) film was abruptly decreased with the addition of nitrogen, but at $N_2/CH_4$>0.5, the thickness of the film gradually decreased with the increase of the $N_2/CH_4$. The ratio of N to C(N/C) of the films was saturated at 0.25 with the increase of $N_2CH_4$. N-H, C≡N bonds of the films increased but C-H bond decreased with the increase of $N_2CH_4$.Optical band gap energy of the film decreased from 2.53 eV at the ratio of $N_2CH_4$=4.

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Phase and Microstructure of SiC-AlN Ceramics Prepared by Pressureless Sintering (상압소결에 의하여 제조된 SiC-AlN 세라믹스의 상 및 미세구조)

  • Choi, Woong;Lee, Jong-Kook;Cho, Duk-Ho;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1308-1314
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    • 1995
  • Changes in phase and microstructure were investigated in the SiC-AlN ceramics prepared by pressureless sintering using yttrium aluminum garnet (YAG) as a sintering aid at 200$0^{\circ}C$ and 210$0^{\circ}C$. The SiC/AlN ratio made a remarkable difference in densification, phase relations and the morphology of grains. In the AlN-rich composition, major phase was 2H and microstructure was composed of the densified equiaxed grains irrespective of the sintering temperatures. While those sintered at 200$0^{\circ}C$ were porous with major phase being 3C, the rod-like and the equiaxed grains were coexisted when sintered at 210$0^{\circ}C$ in the SiC-rich composition.

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AN ERDŐS-KO-RADO THEOREM FOR MINIMAL COVERS

  • Ku, Cheng Yeaw;Wong, Kok Bin
    • Bulletin of the Korean Mathematical Society
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    • v.54 no.3
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    • pp.875-894
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    • 2017
  • Let $[n]=\{1,2,{\ldots},n\}$. A set ${\mathbf{A}}=\{A_1,A_2,{\ldots},A_l\}$ is a minimal cover of [n] if ${\cup}_{1{\leq}i{\leq}l}A_i=[n]$ and $$\bigcup_{{1{\leq}i{\leq}l,}\\{i{\neq}j_0}}A_i{\neq}[n]\text{ for all }j_0{\in}[l]$$. Let ${\mathcal{C}}(n)$ denote the collection of all minimal covers of [n], and write $C_n={\mid}{\mathcal{C}}(n){\mid}$. Let ${\mathbf{A}}{\in}{\mathcal{C}}(n)$. An element $u{\in}[n]$ is critical in ${\mathbf{A}}$ if it appears exactly once in ${\mathbf{A}}$. Two minimal covers ${\mathbf{A}},{\mathbf{B}}{\in}{\mathcal{C}}(n)$ are said to be restricted t-intersecting if they share at least t sets each containing an element which is critical in both ${\mathbf{A}}$ and ${\mathbf{B}}$. A family ${\mathcal{A}}{\subseteq}{\mathcal{C}}(n)$ is said to be restricted t-intersecting if every pair of distinct elements in ${\mathcal{A}}$ are restricted t-intersecting. In this paper, we prove that there exists a constant $n_0=n_0(t)$ depending on t, such that for all $n{\geq}n_0$, if ${\mathcal{A}}{\subseteq}{\mathcal{C}}(n)$ is restricted t-intersecting, then ${\mid}{\mathcal{A}}{\mid}{\leq}{\mathcal{C}}_{n-t}$. Moreover, the bound is attained if and only if ${\mathcal{A}}$ is isomorphic to the family ${\mathcal{D}}_0(t)$ consisting of all minimal covers which contain the singleton parts $\{1\},{\ldots},\{t\}$. A similar result also holds for restricted r-cross intersecting families of minimal covers.

Denitrification of Synthetic Wastewater in Submerged Biofilter (침지식 여과조를 이용한 합성 폐수의 탈질화)

  • 오승용;조재윤;김인배
    • Journal of Aquaculture
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    • v.10 no.3
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    • pp.335-346
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    • 1997
  • Denitrification is one of the important processes of removing nitrate from in recirculating aquaculture systems. And this process is affected by many factors such as external organic carbon sources, hydraulic retention time (HRT), COD/NO3--N (C:N) ratio, etc. However, not many studies were done for the optimum conditions of denitrification in the recirculation system for aquaculture. Therefore, this study was conducted to find out the optimum removal condition of NO3--N using submerged denitrification biofilter. The combinations of two external organic carbon sources (glucose and methanol), two HRT (4 and 8-hour) and four differnent C : N ratios (3, 4, 5, 6) were tested. The removal efficiencies of NO3--N and total inorganic nitrogen (TIM) at 8-hour HRT were better than those at 4-hour's (P<0.05). The maximum removal efficiency of NO3--N by methanol (97.8%) was achieved at HRT and C : N ratio were 8-hour and 4.0 respectively. The efficiencies of methanol for the removal of NO3--N and TIN were always better than those of glucose (P<0.05). The maximum removal efficiencies of total inorgainc nitrogen (TIN) were gained at C : N ration of 5.0. The maximum removel efficiencies of TIN using methanol and glucose were 96.9% and 71.5% respectively. Anaerobic condition which is necessary for denitrification process was not made until the 8-hour HRT and higher C : N ratio (5.0). Removal of NO3--N at 4-hour HRT and C : N ration lower than 5.0 were inhibited by oxygen and/or low quantity of external organic carbon. Removal efficiencies of NO3--N were also inhibited by high C : N (6.0) ratio when HRT was 8-hour.

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AN EVALUATION FORMULA FOR A GENERALIZED CONDITIONAL EXPECTATION WITH TRANSLATION THEOREMS OVER PATHS

  • Cho, Dong Hyun
    • Journal of the Korean Mathematical Society
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    • v.57 no.2
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    • pp.451-470
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    • 2020
  • Let C[0, T] denote an analogue of Wiener space, the space of real-valued continuous functions on the interval [0, T]. For a partition 0 = t0 < t1 < ⋯ < tn < tn+1 = T of [0, T], define Xn : C[0, T] → ℝn+1 by Xn(x) = (x(t0), x(t1), …, x(tn)). In this paper we derive a simple evaluation formula for Radon-Nikodym derivatives similar to the conditional expectations of functions on C[0, T] with the conditioning function Xn which has a drift and does not contain the present position of paths. As applications of the formula with Xn, we evaluate the Radon-Nikodym derivatives of the functions ∫0T[x(t)]mdλ(t)(m∈ℕ) and [∫0Tx(t)dλ(t)]2 on C[0, T], where λ is a complex-valued Borel measure on [0, T]. Finally we derive two translation theorems for the Radon-Nikodym derivatives of the functions on C[0, T].

The Crystal and Molecular Structure of Sulfadiazine (Sulfadiazine의 結晶 및 分子構造)

  • Shin Hyun So;Ihn Gwon Shik;Kim Hoon Sup;Koo Chung Hoe
    • Journal of the Korean Chemical Society
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    • v.18 no.5
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    • pp.329-340
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    • 1974
  • Sulfadiazine, $C_{10}H_{10}N_4O_2S$, forms monoclinic crystals of space group $P21}c$ from a mixture of acetone and ethanol with $a=13.71{\pm}0.04,\;b=5.84{\pm}0.03,\;c=15.11{\pm}0.05{\AA},\;{\beta}=115.0{\pm}0.3^{\circ}$, and four molecules per cell. Three dimensional photographic data were collected with $CuK\alpha$ radiation. The structure was determined using Patterson and Fourier synthesis methods and refined by block diagonal least-squares methods with isotropic thermal parameter for all non-hydrogen atoms. The final R value was 0.15 for the 1517 observed independent reflections. The dihedral angle between the planes through the benzene ring and the pyrimidine ring is $76^{\circ}$. The conformational angle formed by the projection of the S-C(5) bond with that of N(1)-C(1) where the projection is taken along the S-N(1) bond is $77^{\circ}$. The imino nitrogen atom, N(1), and pyrimidine nitrogen atom, N(3), form intermolecular $N-H{\cdots}N$ hydrogen bond between the molecules related by center of symmetry. Amino nitrogen atom, N(4), forms two intermolecular $N-H{\cdots}O$ hydrogen bonds, with O(1) and O(2) atoms of different molecules separated by b. A two dimensional network of hydrogen bonds form infinite molecular sheets parallel to the (100) plane. Adjacent sheets are bound together by van der Waals forces.

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A Study on Vitamin C Content of Nutrition Emphasized Products (영양강조표시제품 중 비타민 C 함량 조사)

  • Jeong, Da-un;Lee, Heon-Ok;Kim, Young-Kyoung;Om, Ae-Son
    • Korean Journal of Community Nutrition
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    • v.21 no.6
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    • pp.574-579
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    • 2016
  • Objectives: Vitamin C has various functions such as antioxidative effect and supporting absorption of iron (Fe). Aim of this present study was to provide vitamin C nutrition information and to briefly evaluate absorption interaction of vitamin C and Fe content of vitamin C emphasized products. Methods: Vitamin C emphasized foods including beverages, cereal, snacks, chocolate products, other cocoa products, and sugary products were examined by HPLC. Fe contents in samples after dry-ashing were examined by ICP. Results: Vitamin C content ranges in various products tested were the following: beverages (n=11) $20.15{\pm}0.08{\sim}845.41{\pm}6.07mg$, cereal (n=11) $52.50{\pm}0.23{\sim}262.50{\pm}0.07mg$, snacks (n=1) $50.00{\pm}0.25mg$, chocolate products (n=1) $311.73{\pm}2.44mg$, other cocoa products (n=1) $311.73{\pm}2.44mg$, other sugary products (n=2) $52.50{\pm}0.23{\sim}262.50{\pm}0.07mg$. Vitamin C (n=27) analysis values ranged from 82 to 450% of the labeled value. Vitamin C content in vitamin C emphasized food (n=6) was estimated 7.7 times~56.6 times more than Fe content. Conclusions: Analyzed samples ranged more than 80% of the labeled value in vitamin C emphasized products, which complied with food labeling regulation. But, beverages (n=3), cereal (n=4), chocolate products (n=1) were 2 times more than the labeled value. To provide accurate nutrition information, food manufactures should supervise nutrition labeling and understand the interactions between nutrients. Also, consumer should decide about the adequate amount of nutrient intake by thoroughly checking nutrition labeling.

Effect of Fatty Acid Profiles on Sensory Properties of Beef Evaluated by Korean and Australian Consumer Groups

  • Cho, Soo-Hyun;Kim, Jae-Hee;Kim, Jin-Hyoung;Park, Beom-Young;Hwang, In-Ho;Lee, Jong-Moon;Seong, Pil-Nam;Kim, Dong-Hun
    • Food Science and Biotechnology
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    • v.17 no.3
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    • pp.495-500
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    • 2008
  • This study assessed the role of fatty acids on beef preference of 2 consumer groups from South Korea and Australia. Three muscles (longissimus dorsi, triceps brachii, and semimembranosus) were obtained from 36 carcasses (18 Hanwoo steers and 18 Angus steers) and the cooked beef samples were evaluated by 1,080 consumers (720 Korean consumer panels and 360 Australian consumer panels). The cluster analysis showed that the Korean consumers had more significant relationship with fatty acid composition of beef than that of the Australian consumers when evaluated Australian Angus beef Only C20:5(n-3), and C22:5(n-3) affected preference clustering for Australian consumers; while saturated (C16:0 and C 18:0) as well as unsaturated fatty acids [C16:1(n-7), C18:2(n-6), C18:3(n-3), C20:3(n-6), C20:4(n-6), C20:5(n-3), C22:4(n-6), C22:5(n-3)] affected preference clustering for Korean consumers (p<0.05). In the discriminant analysis of Korean consumer's preference clustering, C20:5(n-3) was a significant fatty acid for Australian Angus beef while the C20:4(n-6) and C 18:0 for Korean Hanwoo beef to evaluate the palatability (p<0.05). Therefore, fatty acid compositions impact Korean consumer's preference of beef.

Comparison of Chlorine, Chlorine Dioxide and Ozone as Disinfectants in Drinking Water (정수소독공정에 이용되는 염소, 이산화염소, 오존 소독제의 비교, 고찰에 관한 연구)

  • Lee, Yoon-Jin;Lee, Sun-Jong;Lee, Dong-Chan;Kim, Hyun;Lee, Hwan;Lee, Cheol-Hyo;Nam, Sang-Ho
    • Journal of Environmental Health Sciences
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    • v.28 no.3
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    • pp.1-8
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    • 2002
  • The experiments for the characterization of inactivation were performed in a series of batch processes with the total coliform as a general indicator organism based on chlorine, chlorine dioxide and ozone as disinfectants. The water sam-ples were taken from the outlet of settling basin in a conventional surface water treatment system that is provided with the raw water drawn from the mid-stream of the Han River. The inactivation of total coliform was experimentally ana-lyzed for the dose of disinfectant contact time, pH, Temperature and DOC. The nearly 2.4,3.0,3.9 log inactivation of total coliform killed by injecting 1 mか1 at 5 minutes for chlorine, chlorine dioxide and ozone. For the inactivation of 99.9%(3 log), Disinfectants required were 1.70, 1.00 and 0.60 mか1 for chlorine, chlorine dioxide and ozone, respec-tively. The higher the pH is, the poorer the disinfections effects are in the range of pH 6-9 by using chlorine and ozone. But the irfluence of pH value on killing effects of chlorine dioxide is weak. The parameters estimated by the models of Chick-Watson, Hom, and Selleck from our experimental data obtained for chlorine are: log(N/ $N_{0}$ )=-0.16 CT with n= 1, log(N/ $N_{0}$ )=-0.71 $C^{0.87}$T with n$\neq$1, for Chicks-Watson model, log (N/ $N_{0}$ )= -1.87 $C^{0.47}$ $T^{0.36}$ for Hom model. For chlorine dioxide are: log(N/ $N_{0}$ )= -1.53 CT with n = 1, log(N/ $N_{0}$ )= -2.29 $C^{0.94}$T with n$\neq$1,, for Chicks-Watson model, log(N/ $N_{0}$ )= -3.64 $C^{0.43}$ $T^{0.24}$ for Hom model and for ozone are: log(N/ $N_{0}$ )= -2.59 CT with n = 1, log(N/ $N_{0}$ )= -2.28 $C^{0.36}$T with n$\neq$1, for Chicks-Watson model, log(N/ $N_{0}$ )= -4.53 $C^{0.26}$ $T^{0.19}$ for Hom model.19/ for Hom model.

The Solvent-Independent Structure of 6-(2-pyridyl)-3, 5-hexadiyn-1-ol (6-(2-pyridyl)-3, 5-hexadiyn-1-ol의 용매 비의존 분자구조)

  • 서일환;이진호
    • Korean Journal of Crystallography
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    • v.6 no.1
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    • pp.36-42
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    • 1995
  • Two types of single crystals of the title compound [6-(2-pyridyl)-3, 5-hexadiyn-ol, PyHxD] were obtained by solution of n-hexane/CH2C12 and n-hexane/Et2O, and their molecular conformations are proved identical in spite of different of space groups; C22H18N2O2 (I), Mr=343.70, Monoclinic, Pa, a=14.595(2), b=5.413(2), c=12.218(2)Å, β=96.86(1)°, V=958.3Å3, Z=2, Dx=1.19 Mgm-3, λ(MoKα)=0.71069Å, μ=0.072mm-1, F(000)=360.0, T=292K, R=0.104 for 756 unique observed reflections. An asymmetric unit contains a dimer connected by two N-H…O intermolecular hydrogen bonds. C11H9NO (II), Mr=171.85, Monoclinic, P21/a, a=14.611(2), b=5.423(6), c=12.191(2)Å, β=96.89(1)°, V=959.0Å3, Z=4, Dx=1.19 Mgm-3, λ(MoKα)=0.71069Å, μ=0.072mm-1, F(000)=360.0, T=293K, R=0.066 for 824 unique observed reflection. The structural asymmetric unit contains a molecule, but two N-H…O hydrogen bonds related by controsymmetry make the molecules form a dimer. In both structure, the dihedral angle between the planar pyridyl ring and the plane defined by C(10)-C(11)-O connected by linear diyne chain is approximately normal, and the molecules are stacked along b-axis with the unit repeat of b-axis.

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