• 제목/요약/키워드: Bulk diffusion

검색결과 186건 처리시간 0.023초

Effect of Deformation Temperature on Crystal Texture Formation in Hot Deformed Nanocrystalline SmCo5 Permanent Magnets

  • Ma, Q.;Yue, M.;Lv, W.C.;Zhang, H.G.;Yuan, X.K.;Zhang, D.T.;Zhang, X.F.;Zhang, J.X.;Gao, X.X.
    • Journal of Magnetics
    • /
    • 제21권1호
    • /
    • pp.25-28
    • /
    • 2016
  • In the present study, bulk anisotropic nanocrystalline $SmCo_5$ magnets were prepared by hot deformation. The effect of deformation temperature on the texture and magnetic properties are presented, based on which the mechanism of plastic deformation and texture formation during the hot deformation process is discussed. Our analyses reveal that deformation temperature is one of the most important parameters that determine the texture of $SmCo_5$ grains. We suggest that diffusion creep plastic deformation occurs during hot deformation, which is very sensitive to the energy gain provided by an increase in temperature.

Analysis of In/Ga Inter-Diffusion Effect on the Thermodynamical Properties of InAs Quantum Dot

  • Abdellatif, M.H.;Song, Jin Dong;Lee, Donghan;Jang, Yudong
    • Applied Science and Convergence Technology
    • /
    • 제25권6호
    • /
    • pp.158-161
    • /
    • 2016
  • Debye temperature is an important thermodynamical factor in quantum dots (QDs); it can be used to determine the degree of homogeneity of a QD structure as well as to study the interdiffusion mechanism during growth. Direct estimation of the Debye temperature can be obtained using the Varshni relation. The Varshni relation is an empirical formula that can interpret the change of emission energy with temperature as a result of phonon interaction. On the other hand, phonons energy can be calculated using the Fan Expression. The Fan expression and Varshni relation are considered equivalent at a temperature higher than Debye temperature for InAs quantum dot. We investigated InAs quantum dot optically, the photoluminescence spectra and peak position dependency on temperature has been discussed. We applied a mathematical treatment using Fan expression, and the Varshni relation to obtain the Debye temperature and the phonon energy for InAs quantum dots sample. Debye temperature increase about double compared to bulk crystal. We concluded that the In/Ga interdiffusion during growth played a major role in altering the quantum dot thermodynamical parameters.

초미세 결정립을 가지는 몰리브덴의 제조 및 기계적 특성 (Fabrication of Ultra Fine Grained Molybdenum and Mechanical Properties)

  • 김세훈;서영익;김대건;석명진;김영도
    • 한국분말재료학회지
    • /
    • 제17권3호
    • /
    • pp.235-241
    • /
    • 2010
  • Mo nanopowder was synthesized by ball-milling and subsequent hydrogen-reduction of $MoO_3$ powder. To fabricate ultra fine grained molybdenum, two-step sintering and spark plasma sintering process were employed. The grain size of specimen by two-step sintering and spark plasma sintering was around $0.6\;{\mu}m$ and $0.4\;{\mu}m$, respectively. Mechanical properties of ultra fine grained Mo with relative density of above 90% were significantly improved at room and high temperatures comparing to commercial bulk Mo of 99% relative density. This result was mainly explained by the grain size refinement due to diffusion-controlled sintering.

Fabrication of Superjunction Trench Gate Power MOSFETs Using BSG-Doped Deep Trench of p-Pillar

  • Kim, Sang Gi;Park, Hoon Soo;Na, Kyoung Il;Yoo, Seong Wook;Won, Jongil;Koo, Jin Gun;Chai, Sang Hoon;Park, Hyung-Moo;Yang, Yil Suk;Lee, Jin Ho
    • ETRI Journal
    • /
    • 제35권4호
    • /
    • pp.632-637
    • /
    • 2013
  • In this paper, we propose a superjunction trench gate MOSFET (SJ TGMOSFET) fabricated through a simple p-pillar forming process using deep trench and boron silicate glass doping process technology to reduce the process complexity. Throughout the various boron doping experiments, as well as the process simulations, we optimize the process conditions related with the p-pillar depth, lateral boron doping concentration, and diffusion temperature. Compared with a conventional TGMOSFET, the potential of the SJ TGMOSFET is more uniformly distributed and widely spread in the bulk region of the n-drift layer due to the trenched p-pillar. The measured breakdown voltage of the SJ TGMOSFET is at least 28% more than that of a conventional device.

Strategic coating of NdFeB magnets with Dy to improve the coercivity of permanent magnets

  • Ucar, Huseyin;Parker, David S.;Nlebedim, I.C.;McCallum, R.W.;McCall, S.K.;Parans Paranthaman, M.
    • Advances in materials Research
    • /
    • 제4권4호
    • /
    • pp.227-233
    • /
    • 2015
  • We present a method, supported by theoretical analysis, for optimizing the usage of the critical rare earth element dysprosium in $Nd_2Fe_{14}B$ (NdFeB)-based permanent magnets. In this method, we use Dy selectively in locations such as magnet edges and faces, where demagnetization factors are largest, rather than uniformly throughout the bulk sample. A200 nm thick Dy film was sputtered onto a commercial N-38, NdFeB magnets with a thickness of 3 mm and post-annealed at temperatures from $600-700^{\circ}C$. Magnets displayed enhanced coercivities after post-annealing and as much as a 5 % increase in the energy product, while requiring a total Dy content of 0.06 wt. % - a small fraction of that used in the commercial grade Dy-NdFeB magnets. By assuming all Dy diffused into NdFeB magnets, the improvement in energy product corresponds to a saving of over 1% Dy (critical element). Magnets manufactured using this technique will therefore be higher performing which would potentially broaden the application space of these magnets in the traction motors of hybrid and pure electric vehicles, and wind generators.

화장품용 미분체 혼합공정에서의 분산특성 연구 (A Study of Mixing Characteristics for Cosmetic Pine Powder)

  • 이종옥;송건응
    • 대한화장품학회지
    • /
    • 제19권1호
    • /
    • pp.85-107
    • /
    • 1993
  • 화장품에 사용되는 미분체의 혼합특성을 알기 위하여 화장품용 미분체 혼합기인 ribbon mixer, powder mixer micropulverizer, fine impact mill에 미립자, 구상 및 판상의 형태를 가진 bulk powders를 혼합시간을 변화 시키면서 혼합하는 실험을 하였다. 혼합분체의 혼합정도를 평가하기 위하여 산화철을 tracer로 사용하였으며, 원료 및 혼합물의 particle size distribution, specific surface area, density 및 표면색상을 측정하였다. 미분체 혼합물의 혼합시간과 표면색상변화, 입도분포 및 비표면적과의 사이에 대수적 1차 상관관계가 성립되었고, 색상의 변화로부터 혼합정도를 평가할 수 있는 간단한 식을 도출하였다. 사용된 혼합기에 대해 혼합기구별 modelling과 혼합에 따른 입도 분포 및 비표면적의 변화로부터 혼합기 impellar tip에서의 linear velocity별 혼합기는 대류혼합, 전단혼합 및 확산혼합으로 분류되었다.

  • PDF

티타늄과 티타늄 알루니마이드 합금에서 황의 표면석출 (Surface Segregation of Sulfur in Ti and ti-Aluminide Alloys)

  • 이원식;이재희
    • 한국진공학회지
    • /
    • 제5권1호
    • /
    • pp.39-47
    • /
    • 1996
  • The segregation of S in electrotransport-purified polycrystaline $\alpha$-Ti and Ti-aluminide alloys has been studied by Auger electron spectroscopy(AES), Ion scattering spectroscopy(ISS) and Secondary ion mass spectrometry(SIMS) in the temperature range extending from 20 to $1000^{\circ}C$. The chemisorbed oxygen and carbon on Ti were observed to disappear at T>$400^{\circ}C$ after which the S signal increased to levels approaching 0.5 monolayer. At lower temperatures the presence of the surface oxygen and carbon appeared to inhibit the segregation, presumably because there were no available surfaces sites for the S emerging from the bulk. The activation energy for the S segregation in pure polycrystaline Ti was determined to be 16.7 kcal/mol, which, when compared to S segretation from single-crystal Ti, is quite small and suggests grain boundary or defect diffusion segregation kinetics. In the Ti-aluminide alloys, the presence of Al appeared to enhance the retention of surface oxygen which, in turn, substantially reduced the S segretation. The $\gamma$ alloy, with its high Al content, exhibited the greatest retention of surface oxygen and the smallest quantity of the S segregation(T$\simeq1000^{\circ}C$).

  • PDF

A Simple Mlodel for Dispersion in the Stable Boundary Layer

  • Sung-Dae Kang;Fuj
    • 한국환경과학회지
    • /
    • 제1권1호
    • /
    • pp.35-43
    • /
    • 1992
  • Handling the emergency problems such as Chemobyl accident require real time prediction of pollutants dispersion. One-point real time sounding at pollutant source and simple model including turbulent-radiation process are very important to predict dispersion at real time. The stability categories obtained by one-dimensional numerical model (including PBL dynamics and radiative process) are good agreement with observational data (Golder, 1972). Therefore, the meteorological parameters (thermal, moisture and momentum fluxes; sensible and latent heat; Monin-Obukhov length and bulk Richardson number; vertical diffusion coefficient and TKE; mixing height) calculated by this model will be useful to understand the structure of stable boundary layer and to handling the emergency problems such as dangerous gasses accident. Especially, this simple model has strong merit for practical dispersion models which require turbulence process but does not takes long time to real predictions. According to the results of this model, the urban area has stronger vertical dispersion and weaker horizontal dispersion than rural area during daytime in summer season. The maximum stability class of urban area and rural area are "A" and "B" at 14 LST, respectively. After 20 LST, both urban and rural area have weak vertical dispersion, but they have strong horizontal dispersion. Generally, the urban area have larger radius of horizontal dispersion than rural area. Considering the resolution and time consuming problems of three dimensional grid model, one-dimensional model with one-point real sounding have strong merit for practical dispersion model.al dispersion model.

  • PDF

Simulation of Capacitively Coupled RF Plasma; Effect of Secondary Electron Emission - Formation of Electron Shock Wave

  • Park, Seung-Kyu;Kim, Heon-Chang
    • 반도체디스플레이기술학회지
    • /
    • 제8권3호
    • /
    • pp.31-37
    • /
    • 2009
  • This paper presents one and two dimensional simulation results with discontinuous features (shocks) of capacitively coupled rf plasmas. The model consists of the first two and three moments of the Boltzmann equation for the ion and electron fluids respectively, coupled to Poisson's equation for the self-consistent electric field. The local field and drift-diffusion approximations are not employed, and as a result the charged species conservation equations are hyperbolic in nature. Hyperbolic equations may develop discontinuous solutions even if their initial conditions are smooth. Indeed, in this work, secondary electron emission is shown to produce transient electron shock waves. These shocks form at the boundary between the cathodic sheath (CS) and the quasi-neutral (QN) bulk region. In the CS, the electrons emitted from the electrode are accelerated to supersonic velocities due to the large electric field. On the other hand, in the QN the electric field is not significant and electrons have small directed velocities. Therefore, at the transition between these regions, the electron fluid decelerates from a supersonic to a subsonic velocity in the direction of flow and a jump in the electron velocity develops. The presented numerical results are consistent with both experimental observations and kinetic simulations.

  • PDF

기계적 합금화에 의해 제조된 Ti5Si3 분말의 전기방전소결 특성 연구 (Characteristic Studies on Electro-Discharge-Sintering of Ti5Si3 Powder Synthesized by Mechanical Alloying)

  • 천연욱;조유정;강태주;김정열;박준식;변창섭;이상호;이원희
    • 대한금속재료학회지
    • /
    • 제47권10호
    • /
    • pp.660-666
    • /
    • 2009
  • The consolidation of mechanical alloyed $Ti_5Si_3$ powder by electro-discharge-sintering has been investigated. A single pulse of 2.5 to 8.0 kJ/0.34 g was applied to each powder mixture using 300 and $450{\mu}F$ capacitors. A bulk-like solid with $Ti_5Si_3$ phase has been successfully fabricated by the discharge with an input energy of more than 2.5 kJ in less than $160{\mu}sec$. Micro-Vickers hardness was found to be higher than 1350, which is significantly higher than that of a conventional high temperature sintered sample. The formation of $Ti_5Si_3$ and consolidation occurred through a fast solid state diffusion reaction.