• Journal of Korea Soil Environment Society
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• v.1 no.2
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• pp.15-21
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• 1996

Effects of acid deposition on the acidification of surface water over a short term period were studied during June~October, 1995. A reservoir located in Chunchon, Kangwondo was selected for this study because this reservoir had received little man-made pollutants. Geological survey within the study area was carried out and the pH of a small and shallow stream flowing from the mountain valley down to the reservoir was monitored. Rainfall was measured by using a rain gauge and the precipitation was collected by automatic precipitation sampler. During the study period, rain pH was in the range of 3.81~5.77 with an average of 4.8. The EC was in the range of 5~189$\mu$S/cm with an average of 10.6$\mu$S/cm. ionic composition of the rainfall showed that of the anions, deposition of ${SO_4}^{2-}$, was highest with 3,119.7 kg/$\textrm{km}^2$, and it was $NH^{4+}$ with 1,053.2kg/$\textrm{km}^2$ for cations. The surface water pHs were maintained neutral or weak basic representing little evidence of acidification regardless of the acidic rainfall pH. Every time of sampling, however, the pHs exhibited increasing tendency as elevation of measuring site of the stream became lowered, which indicated the impacts of acid-base reactions by acidic or basic substances during travel of water downstream. This result suggested the necessity of further research to determine the respective buffering capacity of soil and underlying rocks.

• Journal of Environmental Science International
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• v.33 no.5
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• pp.323-332
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• 2024

Circulating hydroponic cultivation has the advantage of reducing soil and water pollution problems caused by discharge of fertilizer components because the nutrient solution is reused. However, cyclic hydroponic cultivation has a low biological buffering capacity and can cause outbreaks of infectious root pathogens. Therefore, it is necessary to develop technologies or disinfection systems to control them. This study used dielectric barrier discharge plasma, which generates various persistent oxidants, to treat Fusarium oxysporum f. sp., a pathogen that causes wilt disease. Batch and intermittent continuous inactivation experiments were conducted, and the results showed that the total residual oxidant was persistent in intermittent plasma treatment at intervals of 2-3 days, and F. oxysporum was treated efficiently. Intermittent plasma treatment did not inhibit the growth of tomatoes.

• Korean Journal of Soil Science and Fertilizer
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• v.16 no.1
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• pp.42-49
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• 1983

In order to find out the possibility of predicting fertilizer K requirement from the K supplying capacity of soil, the relative K activity ratio, Kas/kai, the potential buffering capacity of $K^+$ ($PBC^k$ ; the liner regression coefficient) and its activity ratio ($AR^k_o$ ; $^{k+}$/${\sqrt{Ca^{+2}+Mg^{+2}}}$ in mol/l) at ${\delta}K$ = O, in the Q/I relationships of Beckett(1964), were determined for the soils before flooding and the samples taken at heading stage of transplanted rice in pot experiment. These parameters assumed as the K supplying capacity of soils were subjected for the investigation through correlation stady between themselves and other factors such as grain yield or the amounts of $K_2O$ uptake by rice plant at harvest. The results may be summarized as follows; 1. The potassium supplying power of the flooded soil was considered to be ruled by the amounts of exchangeable K before flooding, since there was little change in exchangeable K concentration from no-exchangeable K during the incubation periods of 67 days. 2. The $PBC^k$ values, in soils before flooding were 0.027, 0.014 and 0.009, where as the $AR^k_o{\times}10^{-3}$ values were 9.1, 7.6, and 15.4, respectively, in clay, loamy and sandy loam soils. 3. The $PBC^k$ values, determined in the soil samples taken at heading stage, varied little compared with the values of orignal soil, regardless of those different fertilizer treatments and textures, showing the possibility of using them as a factor for the improvement of soil to increase the efficiency of fertilizer K. 4. The significant yield responses to potassium fertilizer application were observed wherever the $AR^k_o$ values in soil at heading stage drop down to the original $AR^k_o$ values, regardless of any levels of fertilizer application. 5. The higher correlations between the gain yield or the amounts of $K_2O$ uptake and by the use of both soil factors of $PBC^k$ and $AR^k_o$ at heading stage were observed compared with the use of any single factor. 6. The Kas/Kai value in the soil, estimated prior to the experiment, had high possitive correlation with the $AR^k_o$ determined in the soil at heading stage and could be used as a soil factor for predicting potassium fertilizer requirement.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.5
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• pp.329-335
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• 2004

Acid deposition in forest adjacent to the industrial complexes causes soil acidification resulting in the leaching of cations, decreases of buffering capacity and increases of toxic metal concentrations such as Al, Fe, Mn and Cu in soil solution. Changes of nutrient availability equilibria by acid deposition have been known to retard the growth of pine trees. Objective of this research was to assess the critical ratios of Ca/Al and Mg/Al limiting the growth of Pinus thunbergii in the hydroponic culture. The Ca concentration and Ca/Al ratio in stalks of pine tree were increased as increasing Ca/Al molar ratio in the nutrient solution, but were not changed when the Ca/Al molar ratio was adjusted to greater than 1. Growth of Pinus thunbergii was inhibited at the Ca/Al molar ratio lower than l due to the Ca deficiency. The molar ratios of Ca/Al in the needles of Pinus thunbergii showed the similar tendency with the stalks. This indicated that Ca/Al molar ratio of 1 in the growth media was the critical level limiting the growth of Pinus thunbergii. Concentration of Mg and Mg/Al molar ratios in the stalks of pine tree were increased as increasing Mg/Al molar ratio in nutrient solution. Molar ratios of Mg/Al in the needles were increased as increasing Mg/Al ratios in nutrient solution up to 0.83, which was the critical level limiting the growth of Pinus thunbergii.

• Geomechanics and Engineering
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• v.7 no.2
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• pp.183-200
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• 2014

The expansivity of clayey soils is a complicated phenomenon which may affect the stability of geotechnical structures and geo-environmental projects. In all common factors for the monitoring of soil expansion, less attention is given to anion type of pore space solutions. Therefore, this paper is concerned with the impact of various concentrations of different inorganic salts including NaCl, $Na_2SO_4$, and $Na_2CO_3$ on the macro and microstructure behavior of the expandable smectite clay. Comparison of the responses of the smectite/NaCl and smectite/$Na_2SO_4$ mixtures indicates that the effect of anion valance on the soil engineering properties is not very pronounced, regardless of the electrolyte concentration. However, at presence of carbonate as potential determining ions (PDIs) the swelling power increases up to 1.5 times compared to sulfate or chloride ions. The samples with $Na_2CO_3$ are also more deformable and show lower osmotic compressibility than the other mixtures. This demonstrates that the barrier performance of smectite greatly decreases in case of anions with the non-specific adsorption (e.g., $Cl^-$ and $SO{_4}^{2-}$) as the salinity of solution increases. Based on the results of the X-ray diffraction and sedimentation tests, the high soil volumetric changes upon exposure to carbonate is attributed to an increase in the repulsive forces between smectite basic unit layers due to the PDI effect of $CO{_3}^{2-}$ and increasing the pH level which enhance the buffering capacity of smectite. The study concluded that the nature of anion through its influence on the re-arrangement of soil microstructure and osmotic phenomena governs the hydro-mechanical parameters of expansive clays. It seems not coinciding with the double layer theory of the Gouy-Chapman double layer model.

• Korean Journal of Soil Science and Fertilizer
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• v.4 no.2
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• pp.149-154
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• 1971

To elucidate the effects of calcium carbonate applied under upland and flooded conditions on the changes of soil pH, an incubation study of a soil was carried out. The experiment was conducted under the conditions with and without ground rice straw application. The results of the experiment are summarized as follows: 1. The incubation under the upland moisture condition after the application of calcium carbonate raised soil pH as high as calcium hydroxide did, whereas incubation with calos treatment under the flooded condition showed a low pH. 2. Reduction of a soil brought about by the application of ground rice straw has a significant effect on the rise of soil pH. The high pH of a soil thus brought about or raised by the use of lime is gradually reduced as the accumulation of bicarbonate ions and carbon dioxide increases in the soil solution. It may, however, be possible to keep the high pH of a flooded soil by practicing intermittent drainage or cultivation which reduces the content of bicarbonate and $CO_2$ pressure in soil solution. 3. Carbonate and bicarbonate salts which may be produced in flooded and reduced soil increases the buffering capacity of the soil.

• Journal of Korean Society of Forest Science
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• v.79 no.4
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• pp.376-387
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• 1990

A research effort has been made to determine soil buffer capacity in forest soils nearby urban and industrialized regions. Buffer capacities of soils from four regions were measured by different pH levels of artificial acid precipitation. The following conclusions have been drawn in response to the overall research objectives. Soil Suffer capacity was the highest in Kangwondo followed by Uisan, Yeochon and Seoul when simulated acid precipitation were treated at the level of pH 3.0-5.7. With the acid precipitation treatment below pH 2.0 level, however, the capacity dropped seriously with no significant differences between the regions. In Kangwondo region soils weathered from granite and limestone showed significant differences in the buffer capacities. Soil collected in Seoul and Ulsean revealed that the capacities tended to increase with the distance from the pollution sources when treated at pH 3.0, 4.5 and 5.7 level of acid precipitation. The major mechanism of soil buffer observed during simulated acid precipitation experiment was canon exchange for Kangwondo forest soils. In Seoul region canon exchange also played an important role in soil buffering under artificial acid precipitation between 3.0 and 5.7 pH levels, yet under pH 2.0 level aluminum and silicate hydrolysis. In Ulsan canon exchange was a msjor determinant for the buffer capacity above pH 4.5 level, between pH 3.0-4.5 aluminum hydrolysis and below pH 3.0 aluminum and silicate hydrolysis. In Yeochon silicate hydrolysis led buffer capacity above pH 4.5 and below pH 4.5 aluminum hydrolysis.

• Korean Journal of Soil Science and Fertilizer
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• v.30 no.1
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• pp.56-61
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• 1997

A study was carried out to find out the basic information in physical properties for selection and manufacturing the good seedling media through the analysis of the physical properties, such as particle size, water retention and three phases of the major horticultural substrates. Easily available water(EAW), the water contents between 1kPa and 5kPa water potental, was highest in peatmoss with 39%, and perlite 34.0%, vermiculite 16.9%, but the values of osmunda and bark were lower than 4.8%. Water buffering capacity(WBC), the water content between 5kPa and 10kPa, was 6.1% in peatmoss and 2.3% in vermiculite but it was lower than 1.0% in other substrates. To adjust the suitable range of water potential at crossing point of water and air curves to 1.5~2.5kPa, more finer materials were needed in osmunda and bark, and more coarser materials must be added to peatmoss, perlite and vermiculite. Water potentials of substrates in saturated pot condition were equivalent to 2.2kPa in peatmoss and others were ranged in 1.0kPa to 4.3kPa of water potential in pressure chamber.

• Korean Journal of Environmental Agriculture
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• v.26 no.3
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• pp.259-266
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• 2007

Enormous amount of zeolite by-products as a fine powder have been produced while manufacturing commercial zeolite products. Granulation of the zeolite by-products is necessary in order for them to be recycled as soil conditioners or absorbent for various environmental contaminants due to the limitations inherent from their physical properties. We granulated the zeolite powders using Portland cement as a cementing agent and characterized the physical and chemical properties of the granulated zeolite product. The experimental natural zeolite had a Si/Al ratio of 4.8 and CEC of 68.1 $cmol_c\;kg^{-1}$. The X-ray diffractometry (XRD) revealed that clinoptilolite and mordenite were the major minerals of natural zeolite. Smectite, feldspar and quartz also existed as secondary minerals. Optimum conditions of granulated zeolite production occurred when natural zeolite was mixed with Portland cement at a 4:1 ratio and granulated using the extruder, left to harden for one month at $25^{\circ}C$ and treated at $400^{\circ}C$ for 3 hours. The wide spectra of XRD revealed that the granulated zeolite had amorphous oxide minerals. The alkali- or thermal-treated natural zeolite exhibited pH-dependent charge properties. The major minerals of the granulated zeolite were clinoptilolite, mordenite and tobermorite. The buffering capacity and charge density of the granulated zeolite were greater than those of natural zeolite.

• Economic and Environmental Geology
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• v.54 no.4
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• pp.409-425
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• 2021

Carbon dioxide has been known to be a typical greenhouse gas causing global warming, and a number of efforts have been proposed to reduce its concentration in the atmosphere. Among them, carbon dioxide capture and storage (CCS) has been taken into great account to accomplish the target reduction of carbon dioxide. In order to commercialize the CCS, its safety should be secured. In particular, if the stored carbon dioxide is leaked in the arable land, serious problems could come up in terms of crop growth. This study was conducted to investigate the effect of carbon dioxide leaked from storage sites on soil fertility. The leakage of carbon dioxide was simulated using the facility of its artificial injection into soils in the laboratory. Several soil chemical properties, such as pH, cation exchange capacity, electrical conductivity, the concentrations of exchangeable cations, nitrogen (N) (total-N, nitrate-N, and ammonia-N), phosphorus (P) (total-P and available-P), sulfur (S) (total-S and available-S), available-boron (B), and the contents of soil organic matter, were monitored as indicators of soil fertility during the period of artificial injection of carbon dioxide. Two kinds of soils, such as non-cultivated and cultivated soils, were compared in the artificial injection tests, and the latter included maize- and soybean-cultivated soils. The non-cultivated soil (NCS) was sandy soil of 42.6% porosity, the maize-cultivated soil (MCS) and soybean-cultivated soil (SCS) were loamy sand having 46.8% and 48.0% of porosities, respectively. The artificial injection facility had six columns: one was for the control without carbon dioxide injection, and the other five columns were used for the injections tests. Total injection periods for NCS and MCS/SCS were 60 and 70 days, respectively, and artificial rainfall events were simulated using one pore volume after the 12-day injection for the NCS and the 14-day injection for the MCS/SCS. After each rainfall event, the soil fertility indicators were measured for soil and leachate solution, and they were compared before and after the injection of carbon dioxide. The results indicate that the residual concentrations of exchangeable cations, total-N, total-P, the content of soil organic matter, and electrical conductivity were not likely to be affected by the injection of carbon dioxide. However, the residual concentrations of nitrate-N, ammonia-N, available-P, available-S, and available-B tended to decrease after the carbon dioxide injection, indicating that soil fertility might be reduced. Meanwhile, soil pH did not seem to be influenced due to the buffering capacity of soils, but it is speculated that a long-term leakage of carbon dioxide might bring about soil acidification.