• 한국위험물학회지
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• 제6권2호
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• pp.95-104
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• 2018

Gas-liquid bubble column reactors are extensively used in industrial processes. A detailed knowledge of bubble size distribution is needed for determining the mass transfer in gas-liquid film. Experimental data on bubble size distribution and liquid-side mass transfer coefficient($k_L$) were used to calculate the estimated time to saturation in bubble column reactor. Also, the gas flux was evaluated to the liquid-side mass transfer coefficient($k_L$) and solubility data for hydrogen sulfide($H_2S$) and chlorine($Cl_2$) absorption into water. Simulation results show that $H_2S$ absorption time to 50 % of saturation concentrations are 611 sec and 1,329 sec when bubble diameters are 0.5 mm and 4.5 mm, while absorbing 1 % $H_2S$ gas. In case of $Cl_2$, absorption time range 657 to 1,400 sec when bubble size range 0.5 mm to 4.5 mm, while absorbing 1 % $Cl_2$ gas. Calculated simulation results can be used in the design of emergency relief bubble reactors.

• 설비공학논문집
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• 제13권9호
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• pp.878-887
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• 2001

Experimental investigation has been carried out to examine the operating characteristics of a bubble pump for diffusion absorption refrigerator. The effects of heat input and delivery height on generation rate of refrigerant vapor and circulation rate of solution have been investigated. as a result heat input and delivery height increase, circulation rate of solution increases. And the smaller the tube diameter, the larger the circulation rate of solution. Pumping ratio increases to a critical point and then decrease with the increase of heat input, and it increases with the increase in delivery height. In this paper, Marcus's analytical theory was also examined. It was found that the Marcus\`s analytical theory of a bubble pump was not appropriate for a bubble pump using ammonia aqueous solution as a working fluid.

• 설비공학논문집
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• 제18권7호
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• pp.556-562
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• 2006

The objectives of this paper are to analyze simultaneous heat and mass transfer performance for a plate type bubble absorber with binary nanofluids numerically and to investigate the effects of binary nanofluids and surfactants on the size of the bubble absorber. The effective absorption ratio represents the effect of binary nanofluids and surfactants on the absorption performance. The kinds and concentrations of nano-particles and surfactants are considered as the key parameters. The results show that the addition of surfactants can reduce the size of absorber up to 74.4%, the application of binary nanofluids does the size up to 63.6%. Combination of binary nanofluids and surfactants can reduce the size of absorber up to 77.4%.

• 설비공학논문집
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• 제17권4호
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• pp.312-317
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• 2005

The objectives of this paper are to study the absorption characteristics of $NH_3$ bubbles in the binary nanofluids and to quantify the effects of surfactants and nano-particles on the bubble absorption performance. 2-Ethyl-1-Hexanol, n-Octanol, and 2-Octanol are used as the surfactants and nano-sized $Al_{2}O_3$ and Cu particles are added to make the binary nanofluids into $NH_3/H_{2}O$ solution. The concentration of $NH_3$ solution ($x_s$), the concentration of surfactants ($x_{SA}$), and the mass fraction of nano-particles ($w_{np}$) are considered as key parameters. The experimented ranges of $x_s,\;x_{SA},\;and\;w_{np}$ are $0{\sim}17.92\%,\;0{\sim}1,500\;ppm\;and\;0{\sim}0.2\%$, respectively. The absorption rates are calculated by measuring initial and final weights of test section and exposed time. In addition, the bubble absorption processes are visualized using the shadow graphic method. The results show that the absorption performance is significantly enhanced up to 4 times by adding the surfactants and up to 3 times in the binary nanofluids.

• International Journal of Air-Conditioning and Refrigeration
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• 제14권4호
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• pp.131-137
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• 2006

The absorber in which heat and mass transfer phenomena occur simultaneously is one of the most critical components in the absorption system. It has the most significant influence on the performance and the size of the absorption system. During the absorption process, heat and mass transfer resistances exist in both liquid and vapor regions, so that the heat transfer mode should be carefully selected to reduce them. The objective of this paper is to review the previous papers analysing mathematical models of simultaneous heat and mass transfer phenomena during the absorption process. The most conventional working fluids ($H_2O$LiBr and $NH_3/H_2O$) are considered and the most common absorption modes (falling film and bubble mode) are dealt with in this review.

• 설비공학논문집
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• 제16권3호
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• pp.287-292
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• 2004

An experimental investigation was carried out to study the performance of a bubble pump for the diffusion absorption refrigerating system. Ammonia was used as the refrigerant and the helium was charged in order to balance the pressure between the low and high pressure side. As experimental variables, the concentration of ammonia charged into system, heat input, and the pressure of helium were selected. Experimental results show that the generation rate of ammonia vapor and the circulation rate of diluted ammonia solution were increased as the heat input increases, but the ratio of the solution to vapor flow rate was decreased. The generation rate of refrigerant vapor and the circulation rate of diluted ammonia solution increased as the system pressure decreased. Finally under the condition of 25 bars, the concentration of rich ammonia solution was not affected by the generation rate of ammonia vapor and the circulation of diluted ammonia solution.

• 청정기술
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• 제7권4호
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• pp.273-280
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• 2001

흡수기는 흡수식 열펌프 시스템에서 중요한 구성요소일 뿐만 아니라 흡수기의 성능은 전체 시스템에 중요한 영향을 미친다. 본 연구에서는 기포분사형 흡수기에서의 암모니아기체의 흡수열의 효과적 제거를 위한 냉각수 방향으로의 열전달에 대해 실험적 연구를 수행하였다. 흡수기에 유입되는 암모니아 기체의 유속, 암모니아 수용액의 유속, 농도, 온도, 흡수기의 지름, 높이, 기체와 용액의 유입 방향등 여러 가지 변수에 대하여 열전달 성능의 특성을 살펴본 결과, 기체의 주입량, 용액의 주입량 증가는 열전달 성능 향상에 기여하며, 용액의 온도나 농도의 상승은 열전달 성능에 방해요소로 작용하였으며 흐름방향이 향류인 경우 열전달 성능에 향상이 있었다. 본 실험의 데이터를 이용하여 상관관계식을 유도하여 열전달에 대한 복잡한 관계를 일반화 하였다.

• Environmental Engineering Research
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• 제19권4호
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• pp.345-354
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• 2014

In this paper, effects of physical configurations and operating conditions on bubble column performance were analyzed in terms of bubble hydrodynamic and mass transfer parameters. Bubble column with 3 different dimensions and 7 gas diffusers (single / multiple orifice and rigid / flexible orifice) were applied. High speed camera and image analysis program were used for analyzing the bubble hydrodynamic parameters. The local liquid-side mass transfer coefficient ($k_L$) was estimated from the volumetric mass transfer coefficient ($k_La$) and the interfacial area (a), which was deduced from the bubble diameter ($D_B$) and the terminal bubble rising velocity ($U_B$). The result showed that the values of kLa and a increased with the superficial gas velocity (Vg) and the size of bubble column. Influences of gas diffuser physical property (orifice size, thickness and orifice number) can be proven on the generated bubble size and the mass transfer performance in bubble column. Concerning the variation of $k_L$ coefficients with bubble size, 3 zones (Zone A, B and C) can be observed. For Zone A and Zone C, a good agreement between the experimental and the predicted $K_L$ coefficients was obtained (average difference of ${\pm}15%$), whereas the inaccuracy result (of ${\pm}40%$) was found in Zone B. To enhance the high $k_La$ coefficient and absorption efficiency in bubble column, it was unnecessary to generate numerous fine bubbles at high superficial gas velocity since it causes high power consumption with the great decrease of $k_L$ coefficients.

• Composites Research
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• 제32권2호
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• pp.90-95
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• 2019

LNG 운반선의 슬로싱 충격하중은 LNG 화물창 내 단열시스템의 파손을 야기하는 주원인이다. 단열시스템의 파손은 LNG 화물창 내 극저온을 유지시키는 데 치명적으로 작용하게 된다. 극저온을 유지하기 위해서는 단열재료의 성능 강화가 가장 전형적인 방법이다. 일반적으로 LNG 화물창 내의 단열재료는 폴리우레탄 폼과 플라이우드, 이 두 재료를 접합시키기 위한 접착제가 사용된다. 본 연구에서는 단열시스템에 채용되는 단열재료를 강화하기 위한 일환으로 글라스 버블/에폭시 복합수지를 제작하여 충격 하중이 작용할 때 재료의 흡수에너지를 향상시켰다. 실험 시나리오는 글라스버블의 첨가량, 온도의 영향성을 분석하기 위한 상온 및 극저온 환경을 고려하여 자유낙하 실험을 수행하였다. 실험 결과는 글라스 버블 첨가량이 20 wt.%에 도달할 경우 극저온 흡수에너지가 최대의 성능이 나타나는 것을 확인하였다. 반면에 상온 흡수에너지는 첨가량 0 wt.%에서 최대 성능을 보였다. 글라스버블/에폭시 수지의 혼합성능의 경우 첨가량이 20 wt.%가 되면 교반성능 저하로 인하여 응집현상이 발생하여, 접착성능이 떨어질 것으로 판단된다.

• 천문학논총
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• 제30권2호
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• pp.89-91
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• 2015

Observed spectra of stars around the Sun have indicated that the Sun is located in a gas cavity, extending to 100pc. This gas cavity is called the "Local Bubble". The density of the interstellar medium (ISM) in the local bubble is about one tenth that of the average for the ISM in the Milky Way. Furthermore, some structures such as gas planes and strings in the local bubble are probably the result of supernovae. These, due to their low temperatures, can not be observed in the visible and infrared. The only way to do so is to measure the spectra of nearby stars so that the light of stars passing through the local bubble is absorbed by existing gas and the resulting spectral lines from absorption can be measured. In this study, we use binary stars to trace the local bubble structures through lines such as the Na I Doublet. First, we determined the observed spectral lines of stars by HARPS and FEROS echelle spectrographs. Then, we made synthetic spectra with the ATLAS9 code. Finally, the difference between the observational and synthetic spectra confirms the existence of the Na I Doublet in the local ISM.