• Title/Summary/Keyword: Borosilicate Glass

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Phase Separation of Matrix Glasses and Precipitation Characteristics of CuCl Nanocrystals in CuCl Doped Borosilicate Glasses for Nonlinear Optical Application (CuCl 미립자 분산 붕괴산염계 비선형 광학유리에서 매질유리의 상분리와 CuCl 미립자의 석출 특성)

  • 윤영권;한원택
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.886-896
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    • 1997
  • To investigate an effect of phase separation on precipitation characteristics of CuCl nanocrystals in CuCl doped nonlinear optical glasses, borosilicate glass systems with 9 different compositions with ~2wt% of CuCl were selected and CuCl doped glasses were prepared by melting and precipitation method. Microstructural properties of the CuCl doped glasses were analyzed by optical absorption spectroscopy, acid elution test, TEM, and EDXS. While phase separation did not occur in Glass A~D, interconnected and droplet microstructures due to phase separation were found in Glass E, F and Glass G~I, respectively. In the particular composition of the matrix glasses in this study, the precipitation of the CuCl particles was observed in the phase separable glasses, not in phase non-separable glasses. The CuCl particles were precipitated in both silica-rich phase region and boronrich phase region of the glass matrix. In the case of 7.7Na2O-36.6B2O3-52.7SiO2(mole%) glass, the larger CuCl particles than those in the silica-rich phase region were observed in the boron-rich phase region.

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Etching Characteristics of Er-doped Sodium Borosilicate Glass Film Fabricated by Aerosol Flame Deposition Method (Aerosol Flame Deposition 법에 의해 제조된 Er 첨가 Soldium Borosilicate 유리박막의 식각 특성에 관한 연구)

  • 박강희;정형곤;이정우;이형종;박현수;문종하
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.946-953
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    • 1999
  • The etching characteristics of Er-doped sodium borosilicate glass film for the planar optical waveguides were investigated using reactive ion etching. The etch rate decreased as the pressure in creased but increased as the RF power increased. The etch rate increased as the flow rate C2F gas and the amount of O2 addition increased but decreased over critical point (C2F6 7,5 accm O2 20%) The etch rate was 180${\AA}$/min under C2F6 7.5 sccm O2 20% RF power 270 W, pressure 150 mTorr. With this optimum etching condition and subsequent heat treatment at 975$^{\circ}C$ for 30 minutes planar optical waveguides having improved sidewall roughness were fabricated successfully.

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Characterization of Sodium Borosilicate Glasses Containing Fluorides and Properties of Sintered Composites with Alumina

  • Ryu, Bong-Ki
    • The Korean Journal of Ceramics
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    • v.1 no.2
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    • pp.96-100
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    • 1995
  • Recently, alumina/glass composites have been applied as a substrate material for hybrid IC and LSI multi-chip packaging. In this study, the characterization of sodium borosilicate glasses containing NaF and $AlF_3$ and the preparation of the resulted glass/alumina composites have been examined and the effect of the addition of fluorides on the thermal. and dielectric properties of the sintered composites have been studied. The sintering temperature of specimens was lowered by about 100-$150^{\circ}C$ by the addition of fluorine compared with the specimens without fluorine. The specimens containing fluorine showed slightly lower dielectric constants than those of the specimens without fluorine.

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A study on the breakdown characteristics of power p-n junction device using field limiting ring and side insulator wall (전계제한테와 측면 유리 절연막 사용한 전력용 p-n 접합 소자의 항복 특성 연구)

  • 허창수;추은상
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.3
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    • pp.386-392
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    • 1996
  • Zinc-Borosilicate is used as a side insulator wall to make high breakdown voltage with one Field Limiting Ring in a power p-n junction device in simulation. It is known that surface charge density can be yield at the interface of Zinc-Borosilicate glass / silicon system. When the glass is used as a side insulator wall, surface charge varied potential distribution and breakdown voltage is improved 1090 V under the same structure.The breakdown voltage under varying the surface charge density has a limit value. When the epitaxial thickness is varied, the position of FLR doesn't influence to the breakdown characteristic not only under non punch-through structure but also under punch-through structure. (author). 7 refs., 12 figs., 2 tabs.

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Preparation of Borosilicate Foamed Glass Body with Sound Absorption Characteristics by the Recycling Waste Liquid Crystal Display Glass (폐 LCD 유리를 이용한 흡음특성을 갖는 붕규산유리발포체 제조)

  • Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.612-619
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    • 2016
  • In this research, an alumino-borosilicate foamed glass with sound absorption property was prepared using the waste borosilicate glass obtained from the recycling process of waste liquid crystal display (LCD) panel. A 100 g of pulverized waste borosilicate glass with the particle size of under 325 mesh, was mixed with 0.3 g (wt/wt) of graphite, each 1.5 g (wt/wt) of $Na_2CO_3$, $Na_2SO_4$ and $CaCO_3$ as a foaming agent, and 6.0 g (wt/wt) of $H_3BO_3$ and 3.0 g (wt/wt) of $Al_2O_3$ as a pore control agent. Following mixture was under the foaming process for 20 minutes at a foaming temperature of $950^{\circ}C$. The result yielded the foaming agent with 45% of the opened porosity and 0.5-0.7 of the sound absorbing coefficient. This alumino-borosilicate foamed glass with the sound absorption property showed excellent physical and mechanical properties such as density of $0.21g/cm^3$, bending strength of $55N/cm^2$ and compression strength of $298N/cm^2$ which can be ideally used as sound absorption materials with heat-resisting and chemical-resisting property.

Microwave Dielectric Properties of $0.7Ca(Li_{1/4}Nb_{3/4})O_3-0.3CaTiO_3$ Ceramics Added with zinc-borosilicate Glass Frit (Zinc-borosilicate Glass Frit 첨가에 따른 $0.7Ca(Li_{1/4}Nb_{3/4})O_3-0.3CaTiO_3$ 세라믹스의 마이크로파 유전 특성)

  • Yoon, Sang-Ok;Kim, Kwan-Soo;Jo, Tae-Hyun;Oh, Chang-Yong;Kim, Chan-Hang;Shim, Sang-Heung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.371-374
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    • 2004
  • 저온동시 소성용(low temperature co-fired ceramics, LTCC) 마이크로파 유전체을 만들기 위해 $Ca(Li_{1/4}Nb_{3/4})O_3$ 마이크로파 유전체 세라믹스에 zinc-borosililcate glass를 첨가하여 소결 특성과 마이크로파 유전 특성을 조사하였다. $Ca(Li_{1/4}Nb_{3/4})O_3$$0.7Ca(Li_{1/4}Nb_{3/4})O_3-0.3CaTiO_3$에 zinc-borosilicate를 $5{\sim}30wt%$ 첨가하여 소결한 결과 $875{\sim}925^{\circ}C$에서 동시 소성이 가능한 것으로 확인되었으며 zinc-borosilicate glass의 함량이 증가할수록 저온에서 소성이 가능하였지만 과량의 액상과 2차상이 형성되면서 유전율과 품질계수가 저하되는 경향을 나타내었다. $Ca(Li_{1/4}Nb_{3/4})O_3$에 5wt%의 zinc-borosilicate를 첨가하여 $900^{\circ}C$에서 소성한 결과 가장 우수한 유전 특성$(\epsilon_r=17.45,\;Q{\times}f_0=5487)$을 나타내었고, 유전율을 높이기 위해 $CaTiO_3$를 0.3mol% 첨가한 $0.7Ca(Li_{1/4}Nb_{3/4})O_3-0.3CaTiO_3$에 10wt%의 zinc-borosilicate를 첨가하여 $925^{\circ}C$에서 소성한 결과 가장 우수한 유전특성$(\epsilon_r=44.92,\;Q{\times}f_0=5567)$을 나타내었다.

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Microwave Dielectric Properties of Ca(Li1/4Nb3/4)O3-CaTiO3 Ceramics added with Zinc-borosilicate Glass Frit (Zinc-borosilicate Glass Frit 첨가에 따른 Ca(Li1/4Nb3/4)O3-CaTiO3 세라믹스의 마이크로파 유전 특성)

  • Yoon Sang-Ok;Kim Kwan-Soo;Jo Tae-Hyun;Shim Sang-Heung;Park Jong-Guk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.524-530
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    • 2006
  • $xCa(Li_{1/4}Nb_{3/4})O_{3}-(1-x)CaTiO_{3}$ ceramics were sintered under the presence of zinc-borosilicate(ZBS) glass and resultant microwave dielectric properties were investigated with a view to applying the composition to low-temperature co-fired ceramic(LTCC) technology. The addition of $5{\sim}15wt%$ ZBS glass ensured successful sintering below $900\;^{\circ}C$. In general, increased addition of ZBS glass increased sinterability but it decreased the quality factor($Q{\times}f_{0}$) significantly due to the formation of an excessive liquid and second phases. As for the addition of $CaTiO_3$, the dielectric constant(${\epsilon}_r$) and temperature coefficient of resonant frequency(${\tau}_f$) increased, while the quality factor($Q{\times}f_{0}$) did not show an apparent change. The sintered $0.9Ca(Li_{1/4}Nb_{3/4})O_{3}-0.1CaTiO_{3}$ specimen at $900\;^{\circ}C$ with 10 wt% ZBS glass demonstrated 39.6 in dielectric constant(${\epsilon}_r$), 4,400 in quality factor$(Q{\times}f_{0}),\;and\;-11ppm/^{\circ}C$ in temperature coefficient of resonant frequency(${\tau}_f$).

Fabrication of Soda Borosilicate Class-Coated Electrostatic Chucks (소다붕규산염유리 도포형 정전척의 제조)

  • 방재철
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.1
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    • pp.49-52
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    • 2002
  • This study demonstrated the feasibility of tape casting method to fabricate soda borosilicate glass-coated stainless steel electrostatic chucks(ESC) for low temperature semiconductor processes. Glass coating on the stainless steel substrate was 125 $\mu\textrm{m}$ thick. The adhesion of glass coating was found to be excellent such that it was able to withstand temperature cycling to over $300^{\circ}C$ without cracking and delamination. The electrostatic clamping pressure generally followed the theoretical voltage-squared curve except at elevated temperatures and high applied voltages. The deviations at elevated temperatures and high applied voltages are due to increased leakage current as the electrical resistivity of glass coating drops.

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Long-term leach rates of simulated borosilicate waste glasses under a repository condition (처분환경조건에서 모의 방사성폐기물 붕규산유리고화체의 장기침출률)

  • 전관식;김승수;최종원
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.41-46
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    • 2003
  • To understand the long-term leach behavior of a borosilicate Waste glass in a repository, the leaching experiment with three kinds of simulated borosilicate waste glasses has been carried out since the middle of 1997. The five years results indicate that a boron would be applied as an indicator of a long-term leaching of their borosilicate waste glasses and that their long-term leach rates have a tendency to be close to about 0.03g/$m^2$-day even though their compositions and their ratios of the surface area to the volume of leachate are different.

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