• Korean Journal of Soil Science and Fertilizer
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• v.9 no.2
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• pp.65-70
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• 1976

The effect of leaf spray ($80{\ell}$ of 100 times diluted solution per 10a) of three liquid complex fertilizers (Compresal 1 and 2. and 3P) on rice (var, Minehikari) at 10 days before and after heading and 20 days after heading in a farmer's field was investigated by yield components and flag leaf analysis. 1. Leaf spray significantly increased filled grain ratio (at 10% level) and harvest index (at 5% level) suggesting significant yeild increase in uniform field condition. 2. Phosphorus content of flag leaf was in deficient range and increased by leaf spray while iron content was decreased indicating that liquid complex fertilizer supplied phosphorus which ratards iron translocation to the upper leaves. 3. Higher manganese content in flag leaf by leaf spray (significant at 5% level) suggests that phosphorus stimulates manganese translocation to the upper leaves resulting in favorable Fe/Mn balance. 4. Nitrogen concentration in flag leaf was in the insufficient range suggesting that nitrogen in liquid complex fertilzer had to be a nitrogen supply source. 5. In flag leaf calcium concentration was increased by leaf spray but that of boron and zinc was decreased.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.251-251
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• 2016

For several decades, industrial processes consume a huge amount of raw water for various objects that consequently results in the generation of large amounts of wastewater. Wastewaters are consisting of complex mixture of different inorganic and organic compounds and some of them can be toxic, hazardous and hard to degrade. These effluents are mainly treated by conventional technologies such are aerobic and anaerobic treatment and chemical coagulation. But, these processes are not suitable for eliminating all hazardous chemical compounds form wastewater and generate a large amount of toxic sludge. Therefore, other processes have been studied and applied together with these techniques to enhance purification results. These include photocatalysis, absorption, advanced oxidation processes, and ozonation, but also have their own drawbacks. In recent years, electrochemical techniques have received attention as wastewater treatment process that could be show higher purification results. Among them, boron doped diamond (BDD) attract attention as electrochemical electrode due to good chemical and electrochemical stability, long lifetime and wide potential window that necessary properties for anode electrode. So, there are many researches about high quality BDD on Nb, Ta, W and Si substrates, but, their application in effluents treatment is not suitable due to high cost of metal and low conductivity of Si. To solve these problems, Ti has been candidate as substrate in consideration of cost and property. But there are adhesion issues that must be overcome to apply Ti as BDD substrate. Al, Cu, Ti and Nb thin films were deposited on Ti substrate to improve adhesion between substrate and BDD thin film. In this paper, BDD films were deposited by hot filament chemical vapor deposition (HF-CVD) method. Prior to deposition, cleaning processes were conducted in acetone, ethanol, and isopropyl alcohol (IPA) using sonification machine for 7 min, respectively. And metal layer with the thickness of 200 nm were deposited by DC magnetron sputtering (DCMS). To analyze microstructure X-ray diffraction (XRD, Bruker gads) and field emission scanning electron microscopy (FE-SEM, Hitachi) were used. It is confirmed that metal layer was effective to adhesion property and improved electrode property. Electrochemical measurements were carried out in a three electrode electrochemical cell containing a 0.5 % H2SO4 in deionized water. As a result, it is confirmed that metal inter layer heavily effect on BDD property by improving adhesion property due to suppressing formation of titanium carbide.

• Nuclear Engineering and Technology
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• v.52 no.6
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• pp.1120-1130
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• 2020

The CREOLE experiment performed In the EOLE critical facility located In the Nuclear Center of CADARACHE - CEA have allowed us to get interesting and complete experimental information on the temperature effects in the light water reactor lattices. To analyze these experiments with accuracy an elaborate calculation scheme using the Monte Carlo method implemented in the MCNP6.1 code and the ENDF/B-VII.1 cross section library has been developed. We have used the ENDF/B-VII.1 data provided with the MCNP6.1.1 version in ACE format and the Makxsf utility to handle the data in the specific temperatures not available in the MCNP6.1.1 original library. The main purpose of this analysis is the qualification of the ENDF/B-VII.1 nuclear data for the prediction of the Reactivity Temperature Coefficient while ensuring the ability of the MCNP6.1 system to model such a complex experiment as CREOLE. We have analyzed the case of UO₂ lattice with 1166 ppm of boron in ordinary water moderator in specified temperatures. A detailed comparison of the calculated effective multiplication factors with the reference ones [1] in room temperature presented in this work shows a good agreement demonstrating the validation of our 3D calculation model. The discrepancies between calculations and the differential measurements of the Reactivity Temperature Coefficient for the analyzed configuration are relatively small: the maximum discrepancy doesn't exceed 1,1 pcm/℃. In addition to the analysis of direct differential measurements of the reactivity temperature coefficient performed in the poisoned UO₂ lattice configuration, we have also analyzed integral measurements in UO₂ clean lattice configuration using equivalency of the integral temperature reactivity worth with the driver core fuel reactivity worth and soluble boron reactivity worth. In this case both of the ENDF/B-VII.1 and JENDL.4 libraries were used in our analysis and the obtained results are very similar.

• Journal of The Korean Society of Grassland and Forage Science
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• v.7 no.1
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• pp.63-69
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• 1987

This field experiment was undertaken to assess the effectiveness of magnesium- and boronenriched complex fertilizer ($N-P_2O_5-K_2O-MgO-B_2O_3$ : 8-25-7-3-0.2) compared with some straight fertilizers on the hilly pasture establishment. This second part was concerned with the changes in the forage yields, yield components, botanical and chemical compositions in a mixed grassclover sward (orchardgrass, tall fescue, Kentucky bluegrass, and ladino clover). The results from a two-year experiment are summarized as follows: 1. Dry matter yields of whole mixed forages were significantly reduced in control by 54.5% and the NK-plot ($P_o$ by 35.0%, compared with the normal NPK-plots. 2. The yields of oversown grasses were significantly reduced in control by 79.7% and the NKplot ($P_o$) by 52.196, compared with the normal NPK applications. At the normal NPK applications, the oversown grasses were lowest in the yields when provided with double superphosphate with no significant differences. The yields of weeds were not significantly influenced by the treatments. 3. The significant differences in the legume yields (relative yield, %) were laid in the follow. ing increasing order; complex fertilizer (178.5%) > NPK-fused superphosphate (139.5%) > NPK-double superphosphate (100.0%) = control > NK (51.1%). The legume yield was much more depressed in the NK-plot ($P_o$) than in control ($N_oP_oK_o$). 4. The rate of oversown grasses and whole forages were increased by the normal NPK applications, showing little difference among the kinds of fertilizers. It was recognized that the application of complex fertilizer contributed to the increasing of legume rate in the mixed sward. This contribution turned out to be due to the rather enhanced performance and yield-increase of legume, compared with the straight fertilizers. 5. With the NK-treatment ($P_o$) the P concentration in mixed forages dropped below the critical level (0.2%). The Mg concentrations in mixed forages were lower in all the plots than the critical level (0.2%). Therefore, a sufficient amount of Mg was desirably to be applied It is recommended that, in relation to its effectiveness and simplification of fertilizer application, the application of this complex fertilizer for pasture establishment be carried out. The change of the constituent ratio of complex fertilizer to the standard of "8 - 15-20 - 7 - 5-10 - 0.2" considering the need of sufficient Mg supply and the continuous accumulation of P in the top-surface soil is possibly recommended.commended.

• Journal of the Korean Chemical Society
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• v.40 no.1
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• pp.11-19
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• 1996

The cationic polymerization of energetic substituted oxetanes which have pendant energetic group such as azido and nitrato are investigated theoretically, using semiempirical HF/3-21G, MINDO/3, MNDO and AM1 method. The stereo- and electronic structure of binary molecular complex composed of energetic substituted oxetane and boron trifluoride can be explain by molecular orbital theory. The reactivity of propagation in the copolymerization of oxetanes can be presented by the positive charge on carbon(C2) atom of oxetane and energy level of the lowest unoccupied molecular orbital(LUMO) of propagating species of oxetanes. The reactivity ratios for copolymerization of oxetanes are a random copolymer-zation which is agree with MO calculated and experimental results. The relative equlibrium concentration of cyclic oxonium and open carbenium ions is found to be a major determinant of mechanism, owing to the rapid equilibrium of these cation forms and the expectation based on calculation that in the prepolymer propagation step, SN1 mechanism will be at least as fast as that for SN2 mechanism.

• Journal of the Korean Chemical Society
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• v.27 no.6
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• pp.411-418
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• 1983

The effects of existing anions in hydrofluoric acid solutions, $F^-$ and $HF_2$on the extraction of methylene blue-$BF_4^-$ ion-pair into 1,2-dichloroethane have been investigated by spectrophotometry. The absorbance of the extracted ion-pair is found to be independent of $F^-$ion up to $10^{-2}$ molar concentration, which implies that $F^-$ion dose not directly interfere with the extraction. However, $HF_2^-$ ion competes with $BF_4^-$ion for methylene blue and the extraction constant for methylene blue-H$F_2$ion-pair is calculated to be 8.5 at $25^{\circ}C$.

• Journal of the Mineralogical Society of Korea
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• v.18 no.3 s.45
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• pp.227-236
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• 2005

Hydrothermal tourmaline occurs as aggregates or dissemination in the diaspore nodule from an aluminum-rich clay deposit, Milyang, southeastern Korea. Most crystals of tourmaline show complex textures that are finely zoned. The fine-scale chemical zonation of hydrothermal tourmaline reflects the fluctuation conditions that would be expected from fluid mixing in open systems. Oscillatory chemical zoning in tourmaline formed and showed similar patterns, regardless of its crystallographic directions. Mg was enriched in the early stage of crystal growth while Fe was enriched in the later stage, with fluctuations of the ratio of Fe to Mg. Chemical analysis, BSE images, and X-ray compositional maps confirm that the oscillatory Boning in tourmaline is exclusively controlled by the variations of Fe and Mg contents, but the contribution of boron to the zonation is insignificant. The fact that tourmaline altered to diaspore and dickite indicates that tourmaline was unstable with respect to these aluminous minerals as the B, Fe, and Mg activities decreased. Therefore, the aluminum activity may control the stability of tourmaline in the hydrothermal system.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.6
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• pp.666-670
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• 2015

Competition among anion species in solution for same sorption sites and soil surface can be of major significance in determining the effective mobility of any potentially adsorbing species. Major soil anion species include $OH^-$, $F^-$, $Cl^-$, $HCO_3{^-}$, $CO_3{^-}$, $NO_3{^-}$, $SO_4{^{2-}}$, and $PO_4{^{3-}}$. And some micro nutrients such as boron and molybdenum exist as $H_2BO_3{^-}$ and $MoO_4{^{2-}}$, as do some heavy metals such as chrome and arsenic as $CrO_4{^{2-}}$ and $HAsO_4{^{2-}}$. Pesticides such as 2,4,5-T and 2,4-D also exist as anions. Many anion species are retained by more complex mechanisms than the simple electrostatic attractions involved in most cation adsorption reactions. In binary system composed of two anions, the adsorption of one anion is influenced by the other anion due to the competition for the available and limited binding sites in soil constituents. The specifically adsorbed anions may compete more effectively for sorption sites than that of nonspecifically adsorbed anion. In this study, we aim to evaluate the mathematical models to determine the magnitude of concentration variations in adsorption due to competitive interactions between anions introduced to a system in binary mixtures.

• Journal of The Korean Society of Grassland and Forage Science
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• v.11 no.4
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• pp.244-251
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• 1991

This study was undertaken to assess the effectiveness of magnesium-and boron-enriched complex fertilizer(CF, N-P$_2$O$_{5}$-K$_2$O-MgO-B$_2$O$_3$: 14-10-12-3-0.2) on the maintenance and management of hilly pasture. The effectiveness of CF was compared to those of some straight fertilizers (SF). This first part of the study was concerned with the soil chemical properties and the mutural balances of mineral nutrients in the soils of a mixed grass-clover and a pure grass swards. The results of a two-year field experiment are summarized as follows: 1. The Mg contents in the soils of the CF plots were higher than those of the SF plots. On the other hand, the Ca contents were higher in the SF plots than in the CF plots. The contents of Mg and Ca, and CEC, except K, in both the CF and SF plots were considerably below the optimum levels. At the normal application rate of NPK, the contents of available P$_2$O$_{5}$ were close to the optimum level in both the CF and SF plots. 2. The contents of exchangeable Mg were lower than the K contents in soils of all the plots. At the normal application rate of NPK, the Mg contents in the CF plots, but not in the SF plots, were close to the critical level for general crops (0.29me Mg/100g soil). The Mg contents in soils of all the plots, however, were considerably below the critical level for pasture forages and grazing cows (0.41me/100g). 3. Considering the desirable base saturation level of soil, the saturation levels of Ca and Mg were insufficient in both the CF and SF plots. The saturation levels of Mg in the CF plots, however, were relatively good compared with the SF plots. The equivalent ratios or Mg/K, Ca/Mg. Ca:Mg:K, and %Mg of CEC in soils were generally unfavorable in all the plots. These ratios of the CF plots, however, were relatively better than those of the SF plots. 4. Considering the contents of exchangeable Ca and Mg in soils, it is suggested that the application of slaked magnesium lime as a soil amelioration might be desirable for the fundamental increment of those contents at pasture establishment.

• Journal of The Korean Society of Grassland and Forage Science
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• v.11 no.4
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• pp.252-257
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• 1991

In a two-year's field experiment, the effectiveness of magnesium-and boron-enriched complex fertilizer (CF, N-P$_2$O$_{5}$-K$_2$O-MgO-B$_2$O$_3$: 14-10-12-3-0.2) on the maintenance and management of hilly pasture was studied. The effects of CF and some straight fertilizers (SF) on forage yields, yield components, and chemical compositions were compared in a mixed grass-clover (orchardgrass, tall fescue, kentucky bluegrass, and ladino clover) and a pure grass (orchardgrass) swards. The results are summarized as follows: 1. Considerably higher average dry matter yields were obtained in the CF plots than in the SF plots. In the mixed sward, the yields of whole mixed forages were inclosed by 10.8-14.5%, grasses by 11%, and legume by 21.5-31.0% by the use of the CF over the use of SF. In the pure grass sward, the yield of grasses was increased by 7.0-21.8%. 2. The rates of yield increase due to the application of CF were dependent on such factors as types of sward (pure or mixed), application rates of NPK, and forage species. The increase of forage yields due to the CF was greater at the normal rate of NPK application than at lower application rate, and in legume forage than in grass forage. 3. The crude fiber, crude fat and NFE contents of forages were not significantly changed by different treatments. However, the forage of CF plot at the normal application rate of NPK contained relatively higher amount of crude protein and crude fat compared with the forages of other plots. 4. There were no significant differences in the contents of mineral nutrients in forages among the different treatments. In spite of the application of Mg-enriched CF, the contents of Mg in soils and forages were below the optimum level.