• 제목/요약/키워드: Boron analysis

검색결과 264건 처리시간 0.019초

CURRENT RESEARCH ON ACCELERATOR-BASED BORON NEUTRON CAPTURE THERAPY IN KOREA

  • Kim, Jong-Kyung;Kim, Kyung-O
    • Nuclear Engineering and Technology
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    • 제41권4호
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    • pp.531-544
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    • 2009
  • This paper is intended to provide key issues and current research outcomes on accelerator-based Boron Neutron Capture Therapy (BNCT). Accelerator-based neutron sources are efficient to provide epithermal neutron beams for BNCT; hence, much research, worldwide, has focused on the development of components crucial for its realization: neutron-producing targets and cooling equipment, beam-shaping assemblies, and treatment planning systems. Proton beams of 2.5 MeV incident on lithium target results in high yield of neutrons at relatively low energies. Cooling equipment based on submerged jet impingement and micro-channels provide for viable heat removal options. Insofar as beam-shaping assemblies are concerned, moderators containing fluorine or magnesium have the best performance in terms of neutron accumulation in the epithermal energy range during the slowing-down from the high energies. NCT_Plan and SERA systems, which are popular dose distribution analysis tools for BNCT, contain all the required features (i.e., image reconstruction, dose calculations, etc.). However, detailed studies of these systems remain to be done for accurate dose evaluation. Advanced research centered on accelerator-based BNCT is active in Korea as evidenced by the latest research at Hanyang University. There, a new target system and a beam-shaping assembly have been constructed. The performance of these components has been evaluated through comparisons of experimental measurements with simulations. In addition, a new patient-specific treatment planning system, BTPS, has been developed to calculate the deposited dose and radiation flux in human tissue. It is based on MCNPX, and it facilitates BNCT efficient planning based via a user-friendly Graphical User Interface (GUI).

계면활성제 수용액에 의해 재생된 활성탄 촉매의 탈질 성능 ($DeNO_{x}$ Performance of Activated Carbon Catalysts Regenerated by Surfactant Solution)

  • 박혜민;박영권;전종기
    • Korean Chemical Engineering Research
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    • 제49권6호
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    • pp.739-744
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    • 2011
  • 선택적환원 반응용 활성탄 촉매는 액정디스플레이 제조 공정에서 배출되는 붕소를 포함하는 배가스 중의 $NO_x$를 제거하는데 사용되는데, 붕소가 촉매의 세공을 막거나 활성점에 침적되어 촉매 비활성화가 발생하게 된다. 폐촉매는 다양한 계면활성제를 포함하는 수용액 중에서의 세정, 건조 및 소성에 의해 재생이 가능하였다. 세정 과정의 조건, 계면 활성제 종류, 소성 조건 등을 변화시키면서 재생 전과 후의 폐촉매의 물리화학적 성능 비교를 위하여 질소 흡착 실험, ICP에 의한 원소 분석을 수행하였다. 암모니아를 사용하는 선택적환원 반응은 고정층 촉매 반응기를 사용하여 $120^{\circ}C$에서 수행하였다. $90^{\circ}C$의 수용액에서 비이온 계면활성제를 사용하여 세정하고, 질소 분위기에서 $550^{\circ}C$에서 소성하여 재생한 활성탄 촉매는 붕소가 가장 많이 제거되어 신규 활성탄과 유사한 수준의 표면적과 $NO_x$ 제거 효율을 회복하였다.

Carbon-coated boron using low-cost naphthalene for substantial enhancement of Jc in MgB2 superconductor

  • Ranot, Mahipal;Shinde, K.P.;Oh, Y.S.;Kang, S.H.;Jang, S.H.;Hwang, D.Y.;Chung, K.C.
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권3호
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    • pp.40-43
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    • 2017
  • Carbon coating approach is used to prepare carbon-doped $MgB_2$ bulk samples using low-cost naphthalene ($C_{10}H_8$) as a carbon source. The coating of carbon (C) on boron (B) powders was achieved by direct pyrolysis of naphthalene at $120^{\circ}C$ and then the C-coated B powders were mixed well with appropriate amount of Mg by solid state reaction method. X-ray diffraction analysis revealed that there is a noticeable shift in (100) and (110) Bragg reflections towards higher angles, while no shift was observed in (002) reflections for $MgB_2$ doped with carbon. As compared to un-doped $MgB_2$, a systematic enhancement in $J_c(H)$ properties with increasing carbon doping level was observed for naphthalene-derived C-doped $MgB_2$ samples. The substantial enhancement in $J_c$ is most likely due to the incorporation of C into $MgB_2$ lattice and the reduction in crystallite size, as evidenced by the increase in the FWHM values for doped samples.

단결정 태양전지의 단락 및 개방 시 노광에 의한 초기 출력저하 비교 분석 (Analysis and comparison of initial performance degradation for single crystalline silicon solar cell under open and short circuit)

  • 정태희;김태범;신준오;윤나리;우성철;강기환;안형근;한득영
    • 한국태양에너지학회 논문집
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    • 제30권6호
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    • pp.16-21
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    • 2010
  • It is well-known that Boron-doped Cz Si solar cells suffer light-induced degradation due to boron-oxygen defect which is responsible of a reduction in lifetime and hence efficiency. In this paper, we assume that PV solar cell has been connected with variable load to account the real operating condition and it shows different light-induced degradation of Si solar cell. To evaluate the effect of light-induced degradation for solar cell with various load, Single crystalline solar cells are connected with open and short circuits during light exposure. Isc-Voc curve evaluate light induced degradation of solar cells and the reason is explained as a change for serial resistance. From the results, Electrical characteristics of solar cells show better performance under short circuit conditions, after light exposure.

유도결합 플라즈마와 이중관 반응기를 이용하여 제조한 보론-도핑된 결정질 실리콘 나노입자의 합성 (Synthesis of Boron-doped Crystalline Si Nanoparticles Synthesized by Using Inductive Coupled Plasma and Double Tube Reactor)

  • 정천영;구정분;장보윤;이진석;김준수;한문희
    • 한국전기전자재료학회논문지
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    • 제27권10호
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    • pp.662-667
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    • 2014
  • B-doped Si nanoparticles were synthesized by using inductive coupled plasma and specially designed double tube reactor, and their microstructures were investigated. 0~10 sccm of $B_2H_6$ gas was injected during the synthesis of Si nanoparticles from $SiH_4$ gas. Highly crystalline Si nanoparticles were synthesized, and their crystallinity did not change with increase of $B_2H_6$ flow rates. From SEM measurement, their particle sizes were approximately 30 nm regardless of $B_2H_6$ flow rates. From SIMS analysis, almost saturation of B in Si nanoparticles was detected only when 1 sccm of $B_2H_6$ was injected. When $B_2H_6$ flow rate exceeded 5 sccm, higher concentration of B than solubility limit was detected even if any secondary phase was not detected in XRD or HR-TEM results. Due to their high electronic conductivity, those heavily B-doped Si nanoparticles can be a potential candidate for an active material in Li-ion battery anode.

실리콘에 도핑된 붕소의 정량분석에 대한 공동분석연구 (RRT Study for the Quantitative Analysis of Boron in Silicon)

  • 김경중;김현경;문대원;홍태은;정칠성;김이경;김재남;임철호;김정호
    • 한국진공학회지
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    • 제11권4호
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    • pp.218-224
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    • 2002
  • 반도체 박막의 분석에서 중요한 분석 대상의 하나인 미량 불순물의 정량분석을 위한 표준절차를 확립하고 그에 필요한 인증표준물질의 개발하였으며 이를 이용하여 국내공동분석을 실시하였다. 공동분석에 사용된 붕소가 균질하게 도핑된 박막 인증표준물질과 분석시편은 이온빔 스퍼터증착법에 의해 제작하였으며, 가장 정량적이고 감도가 높은 ICP-MS를 이용한 동위원소희석법으로 인증하였다. 이러한 인증표준물질과 SIMS에 의한 실리콘 내 의 붕소의 정량분석에 대해 이미 확립되어 있는 국제표준절차인 ISO/DIS-14237에 의거하여 국내 공동 분석을 시행하였는데, 이번의 공동분석에서 얻어진 붕소농도의 전체 평균값이 ICP-MS에 의한 인증치에 약 2% 정도의 오차를 보여주고 있어 분석의 정확성이 확인되었다.

Analysis of the CREOLE experiment on the reactivity temperature coefficient of the UO2 light water moderated lattices using Monte Carlo transport calculations and ENDF/B-VII.1 nuclear data library

  • El Ouahdani, S.;Erradi, L.;Boukhal, H.;Chakir, E.;El Bardouni, T.;Boulaich, Y.;Ahmed, A.
    • Nuclear Engineering and Technology
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    • 제52권6호
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    • pp.1120-1130
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    • 2020
  • The CREOLE experiment performed In the EOLE critical facility located In the Nuclear Center of CADARACHE - CEA have allowed us to get interesting and complete experimental information on the temperature effects in the light water reactor lattices. To analyze these experiments with accuracy an elaborate calculation scheme using the Monte Carlo method implemented in the MCNP6.1 code and the ENDF/B-VII.1 cross section library has been developed. We have used the ENDF/B-VII.1 data provided with the MCNP6.1.1 version in ACE format and the Makxsf utility to handle the data in the specific temperatures not available in the MCNP6.1.1 original library. The main purpose of this analysis is the qualification of the ENDF/B-VII.1 nuclear data for the prediction of the Reactivity Temperature Coefficient while ensuring the ability of the MCNP6.1 system to model such a complex experiment as CREOLE. We have analyzed the case of UO2 lattice with 1166 ppm of boron in ordinary water moderator in specified temperatures. A detailed comparison of the calculated effective multiplication factors with the reference ones [1] in room temperature presented in this work shows a good agreement demonstrating the validation of our 3D calculation model. The discrepancies between calculations and the differential measurements of the Reactivity Temperature Coefficient for the analyzed configuration are relatively small: the maximum discrepancy doesn't exceed 1,1 pcm/℃. In addition to the analysis of direct differential measurements of the reactivity temperature coefficient performed in the poisoned UO2 lattice configuration, we have also analyzed integral measurements in UO2 clean lattice configuration using equivalency of the integral temperature reactivity worth with the driver core fuel reactivity worth and soluble boron reactivity worth. In this case both of the ENDF/B-VII.1 and JENDL.4 libraries were used in our analysis and the obtained results are very similar.

다관원통형 열교환기의 파울링 해석기법 개발 연구 (A Study on the Development of Fouling Analysis Technique for Shell-and-Tube Heat Exchangers)

  • 황경모;진태은
    • 대한기계학회논문집B
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    • 제28권2호
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    • pp.167-173
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    • 2004
  • Fouling of heat exchangers is generated by water-borne deposits, commonly known as foulants including particulate matter from the air, migrated corrosion produces; silt, clays, and sand suspended in water; organic contaminants; and boron based deposits in plants. The fouling is known to interfere with normal flow characteristics and reduce thermal efficiencies of heat exchangers. This paper describes the fouling analysis technique developed in this study which can analyze the thermal performance for heat exchangers and estimate the future fouling variations. To develop the fouling analysis technique fur heat exchangers, fouling factor was introduced based on the ASME O&M codes and TEMA standards. For the purpose or verifying the fouling analysis technique, the routing analyses were performed for four heat exchangers in several nuclear power plants; two residual heat removal heat exchangers of the residual heat removal system and two component cooling water heat exchangers of the component cooling water system.

보강재로 보수된 균열평판의 파괴역학적 해석(II)-분리 영향에 대한 연구- (Fracture Mechanics Analysis of Cracked Plate Repaired by Patch(II) - The Analysis of Debonding Effect -)

  • 정기현;양원호;조명래
    • 대한기계학회논문집A
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    • 제24권9호
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    • pp.2246-2251
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    • 2000
  • Adhesive bonding repair methods has been used for a number of decades for construction of damaged structures. In order to evaluate the life of cracked aging aircraft structures, the repair technique which uses adhesively bonded boron/epoxy composite patches is being widely considered as a cost-effective and reliable method. But, this repair method contains many shortcomings. One of these shortcomings, debonding is major issue. When the adhesive shear stress increases, debonding is caused at the end of patch and plate interface. And this debonding is another defect except cracks propagation. In this paper, we assess safety at the cracked AI-plate repaired by Br/Epoxy composite patch. Firstly, from the view of fracture mechanics, reduction of stress intensity factors is determined by the variety of patch feature. Secondly, using the elastic analysis and finite element analysis, the distribution of adhesive shear stresses is acquired. Finally, The problem of how to optimize the geometric configurations of the patch has been discussed.

The DISNY facility for sub-cooled flow boiling performance analysis of CRUD deposited zirconium alloy cladding under pressurized water reactor condition: Design, construction, and operation

  • Ji Yong Kim;Yunju Lee;Ji Hyun Kim;In Cheol Bang
    • Nuclear Engineering and Technology
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    • 제55권9호
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    • pp.3164-3182
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    • 2023
  • The CRUD on the fuel cladding under the pressurized water reactor (PWR) operating condition causes several issues. The CRUD can act as thermal resistance and increases the local cladding temperature which accelerate the corrosion process. The hideout of boron inside the CRUD results in axial offset anomaly and reduces the plant's shutdown margin. Recently, there are efforts to revise the acceptance criteria of emergency core cooling systems (ECCS), and additionally require the modeling of the thermal resistance effect of the CRUD during the performance analysis. There is an urgent need for the evaluation of the effect of the CRUD deposition on the cladding heat transfer under PWR operating conditions, but the experimental database is very limited. The experimental facility called DISNY was designed and constructed to analyze the CRUD-related multi-physical phenomena, and the performance analysis of the constructed DISNY facility was conducted. The thermal-hydraulic and water chemistry conditions to simulate the CRUD growth under PWR operating conditions were established. The design characteristics and feasibility of the DISNY facility were validated by the MARS-KS code analysis and separate performance tests. In the current study, detailed design features, design validation results, and future utilization plans of the proposed DISNY facility are presented.