• Title/Summary/Keyword: Boron analysis

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Optical Probing of Electronic Interaction between Graphene and Hexagonal Boron Nitride (hBN)

  • Ahn, Gwanghyun;Kim, Hye Ri;Ko, Taeg Yeoung;Choi, Kyoungjun;Watanabe, Kenji;Taniguchi, Takashi;Hong, Byung Hee;Ryu, Sunmin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.213-213
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    • 2013
  • Even weak van der Waals (vdW) adhesion between two-dimensional solids may perturbtheir various materials properties owing to their low dimensionality. Although the electronic structure of graphene has been predicted to be modified by the vdW interaction with other materials, its optical characterization has not been successful. In this report, we demonstrate that Raman spectroscopy can be utilized to detect a few % decrease in the Fermi velocity ($v_F$) of graphene caused by the vdW interaction with underlying hexagonal boron nitride (hBN). Our study also establishes Raman spectroscopic analysis which enables separation of the effects by the vdW interaction from those by mechanical strain or extra charge carriers. The analysis reveals that spectral features of graphene on hBN are mainly affected by change in vF and mechanical strain, but not by charge doping unlike graphene supported on $SiO_2$ substrates. Graphene on hBN was also found to be less susceptible to thermally induced hole doping.

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Thermal Decomposition Behavior of Boron-Potassium Nitrate (BKNO3) by TGA (열중량분석법에 의한 Boron-Potassium Nitrate(BKNO3)의 열분해 특성 연구)

  • Go, Cheongah;Kim, Junhyung;Park, Youngchul;Moon, Youngtaek;Seo, Taeseok;Ryu, Byungtae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.2
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    • pp.104-110
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    • 2019
  • The thermal decomposition characteristics of boron-potassium nitrate ($BKNO_3$) were investigated by non-isothermal thermal gravimetric analysis (TGA). Two steps of mass loss were observed in the temperature range between room temperature and $600^{\circ}C$. Kinetic parameters of the thermal decompositions were evaluated from the measured TGA curves using the AKTS Thermokinetics Software. For the first step of mass loss ($220-360^{\circ}C$) corresponding to the thermal decomposition process of the binder (Laminac/Lupersol), the activation energy is in the range of approximately 120-270 kJ/mol when evaluated by Friedman's iso-conversional method, while the value of activation energy varies in the range of approximately 150-400 kJ/mol during the second step process ($360-550^{\circ}C$).

Development of Automobile One-piece Lower-Arm Part by Thermo-Mechanical Coupled Analysis (열-소성 연계 해석을 이용한 자동차 로어암 부품 개발)

  • Son, H.S.;Kim, H.G.;Choi, B.K.;Cho, Y.R.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.218-221
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    • 2008
  • Hot Press Forming (HPF), an advanced sheet forming method in which a high strength part can be produced by forming at high temperature and rapid cooling in dies, is one of the most successful forming process in producing components with complex geometric shape, high strength and a minimum of springback. In order to obtain effectively and accurately numerical finite element simulations of the actual HPF process, the flow stress of a boron steel in the austenitic state at elevated temperatures has been investigated with Gleeble system. To evaluate the formability of the thermo- mechanical material characteristics in the HPF process, the FLDo defined at the lowest point in the forming limit diagrams of a boron steel has been investigated. In addition, the simulation results of thermo-mechanical coupled analysis of an automobile one-piece lower-arm part are compared with the experimental ones to confirm the validity of the proposed simulations.

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Nonlinear Finite Element Crash Analysis of Guardrail Structures Using Supports Made of Composite Materials (복합재 지주를 적용한 가드레일 구조체의 비선형 유한요소 충돌 해석)

  • Kim, Gyu-Dong;Lee, Sang-Youl
    • Composites Research
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    • v.29 no.6
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    • pp.363-368
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    • 2016
  • This study performed a nonlinear finite element crash analysis of guardrail structures using supports made of composite materials. In this study, we used a new [0/90/90/0] laminated Boron fiber composite for resisting the crash effects. Based on the improved ground-structure interaction model, appropriate ground properties to the support were determined. In particular, the complex crash mechanism of guardrails was studied using various parameters. The parametric studies are focused on the various effects of car crash on the structural performance and thickness of supports. The numerical results for various parameters are verified by comparing those using existing steel materials.

Design of cooling channel in hot press forming process of Boron Steel (보론강 고온 성형 공정의 냉각 채널 설계)

  • Hong, S.M.;Ryu, S.Y.;Park, J.K.;Yoon, S.J.;Kim, K.J.;Kim, H.Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.367-370
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    • 2009
  • Recently, ultra high strength products can be manufactured by the hot press forming process of Boron steel in automotive and electronics industries. In order to get high strength, the hot press forming should be accompanied by quenching process inducing phase transformation. In the study, the heat conductive die and the cooling channel were designed by the numerical simulation and the effect of three different parameters were determined to improve cooling characteristics.

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Evaluation of Elastic Properties of Anisotropic Cylindrical Tubes Using an Ultrasonic Resonance Scattering Spectroscopy

  • Kim, Jin-Yeon;Li, Zheng
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.6
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    • pp.548-557
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    • 2010
  • An ultrasonic resonance scattering spectroscopy technique is developed and applied for reconstructing elastic constants of a transversely isotropic cylindrical component. Immersion ultrasonic measurements are performed on tube samples made from a boron/aluminum composite material to obtain resonance frequencies and dispersion curves of different guided wave modes propagating in the tube. Theoretical analysis on the acoustic resonance scattering from a transversely isotropic cylindrical tube is also performed, from which complete backscattering and resonance scattering spectra and theoretical dispersion curves are calculated. A sensitive change of the dispersion curves to the elastic properties of the composite tube is observed for both normal and oblique incidences; this is exploited for a systematic evaluation of damage and elastic constants of the composite tube samples. The elastic constants of two boron/aluminum composite tube samples manufactured under different conditions are reconstructed through an optimization procedure in which the residual between the experimental and theoretical phase velocities (dispersion curves) is minimized.

Mechanical Property of Liquid Phase Diffusion Bonded Joint of Rene80/B/Rene80 (Rene 80/B/Rene 80 액상 확산접합부의 기계적 성질)

  • 정재필;강춘식
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.125-133
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    • 1995
  • Rene80 superalloy was liquid phase diffusion bonded by using pure boron (B) as an insert material. As a basic study for the possibility of practical application of this bonding method, hardness and high temperature tensile strength of the bonded joint and metallurgical analysis were investigated. As experimental results, hardness of the bonded joint was homogenized after bonding and the tensile strength at 1144K was obtained to 90% of that of base metal. But there were some problems to be improved also, that means the joint was hardened after bonding due to increase of B content and elongation was much lower than that of base metal. Flat area and (Mo, Cr, W) boride, which should be harmful for bonding strength, were observed on the fractured surface of the tensile tested specimen.

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The Analysis of p-MOSFET Performance Degradation due to BF2 Dose Loss Phenomena

  • Lee, Jun-Ha;Lee, Hoong-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.1
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    • pp.1-5
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    • 2005
  • Continued scaling of MOS devices requires the formation of the ultra shallow and very heavily doped junction. The simulation and experiment results show that the degradation of pMOS performance in logic and SRAM pMOS devices due to the excessive diffusion of the tail and a large amount of dose loss in the extension region. This problem comes from the high-temperature long-time deposition process for forming the spacer and the presence of fluorine which diffuses quickly to the $Si/SiO_{2}$ interface with boron pairing. We have studied the method to improve the pMOS performance that includes the low-energy boron implantation, spike annealing and device structure design using TCAD simulation.

Two-dimensional Redistribution of Impurity considering Thermal Oxidation in silicon using BEM (BEM을 이용하여 열산화를 고려한 실리콘 내에서 불순물의 2차원 재분포에 관한 연구)

  • Kim, Hun;Hwang, Ho-Jung
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.370-374
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    • 1988
  • This paper is concerned with the investigation of the impurity redistribution process in a two step diffusion. In integrated circuit technology, two step boron diffusion involving a deposition step followed by a drive-in step in commonly encounted. The drive-in process is usually performed in oxidizing atmosphere resulting in redistribution of impurity (boron) within the semiconductor. This paper proposes a new numerical analysis method; Bounary Element Method to determine impurity profile at the arbitrary point in domain by its coordinate and boundary value.

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Processing of $Si_3N_4/SiC$ and Boron-Modified Nanocomposites Via Ceramic Precursor Route

  • Lee, Hyung-Bock;Rajiv S. Mishra;Matt J. Gasch;Han, Young-Hwan;Amiya K. Mukherjee
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.245-249
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    • 2000
  • Consolidation of amorphous powders is emerging as a route for synthesis of high strength composite materials. Diffusion processes necessary for consolidation are expected to be more rapid in amorphous state(SRO) than in the crystalline state(LRO). A new synthesis technique of exploiting polymeric ceramic precursors(polysilazane and polyborosilazane) is derived for Si$_3$N$_4$/SiC and boron-modified nanocomposites for extremely high temperature applications up to 200$0^{\circ}C$. The characterization methods include thermal analysis of DTA, and XRD, NMR, TEM, after pyrolysis, as a function of time and temperature.

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