• Title/Summary/Keyword: Bond order

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Effect of Tension-Test Temperature on Fracture Behavior and Mechanical Properties in STS/Al/Cu Clad Materials (STS/Al/Cu 클래드재의 파괴거동 및 기계적 물성에 미치는 인장시험 온도의 영향)

  • Bae, Dong-Hyun;Choi, Young-Jun;Chung, Won-Sub;Bae, Dong-Su;Cho, Young-Rae
    • Korean Journal of Metals and Materials
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    • v.47 no.12
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    • pp.811-818
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    • 2009
  • In order to meet increasingly complex and rigorous technical specifications, extensive effort has been devoted to fabricate clad materials with multi-layered metal plates. In this study, novel stainless steel/aluminum/copper (STS/Al/Cu) three-ply clad materials were fabricated by a hot rolling process for cookware applications. The effect of the testing temperature on the mechanical properties of the clad materials and on each component metal was investigated during the tensile tests. The interface properties of the clad materials were also examined by optical microscopy (OM) and an electron probe micro-analyzer (EPMA). The best mechanical and interfacial properties for a warm working process were found in a sample annealed at a temperature of $300^{\circ}C$. For the sample annealed at $400^{\circ}C$, the results of the tensile test indicated that interface delamination occurred only in the region of the Al/Cu interfaces. This was due to the formation of the thick and brittle intermetallic compound of $Al_2Cu$ in the Al/Cu interface. In contrast, no interface delamination was observed in the STS/Al interface, most likely due to its strong bond strength.

New constitutive models for non linear analysis of high strength fibrous reinforced concrete slabs

  • Yaseen, Ahmed Asaad;Abdul-Razzak, Ayad A.
    • Structural Engineering and Mechanics
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    • v.82 no.1
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    • pp.121-131
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    • 2022
  • The main goal of this study is to prepare a program for analyzing High Strength Steel Fibrous Reinforced Concrete (HSSFRC) slabs and predict the response and strength of the slab instead of preparing a prototype and testing it in the laboratory. For this purpose, new equations are proposed to represent the material properties of High Strength Steel Fibrous Reinforced Concrete. The proposed equations obtained from performing regression analysis on many experimental results using statistical programs. The finite element method is adopted for non-linear analysis of the slabs. The eight-node "Serendipity element" (3 DoF) is chosen to represent the concrete. The layered approach is adopted for concrete elements and the steel reinforcement is represented by a smeared layer. The compression properties of the concrete are modeled by a work hardening plasticity approach and the yield condition is determined depending on the first two stress invariants. A tensile strength criterion is adopted in order to estimate the cracks propagation. many experimental results for testing slabs are compared with the numerical results of the present study and a good agreement is achieved regarding load-deflection curves and crack pattern. The response of the load deflection curve is slightly stiff at the beginning because the creep effect is not considered in this study and for assuming perfect bond between the steel reinforcement and the concrete, however, a great agreement is achieved between the ultimate load from the present study and experimental results. For the models of the tension stiffening and cracked shear modulus, the value of Bg and Bt (Where Bg and Bt are the curvature factor for the cracked shear modulus and tension stiffening models respectively) equal to 0.005 give good results compared with experimental result.

Development of Sealing Technology for Far-Infrared Multispectral ZnS Using Chalcogenide Glass Material

  • Soyoung Kim;Jung-Hwan In;Karam Han;Yoon Hee Nam;Seon Hoon Kim;Ju Hyeon Choi
    • Korean Journal of Materials Research
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    • v.32 no.12
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    • pp.515-521
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    • 2022
  • Various types of optical materials and devices used in special environments must satisfy durability and optical properties. In order to improve the durability of zinc sulfide multispectral (MS ZnS) substrates with transmission wavelengths from visible to infrared, Ge-Sb-Se-based chalcogenide glass was used as a sealing material to bond the MS ZnS substrates. Wetting tests of the Ge-Sb-Se-based chalcogenide glass were conducted to analyze flowability as a function of temperature, by considering the glass transition temperature (Tg) and softening temperature (Ts). In the wetting test, the viscous flow of the chalcogenide glass sample was analyzed according to the temperature. After placing the chalcogenide glass disk between MS ZnS substrates (20 × 30 mm), the sealing test was performed at a temperature of 485 ℃ for 60 min. Notably, it was found that the Ge-Sb-Se-based chalcogenide glass sealed the MS ZnS substrates well. After the MS ZnS substrates were sealed with chalcogenide glass, they showed a transmission of 55 % over 3~12 ㎛. The tensile strength of the sealed MS ZnS substrates with Ge-Sb-Se-based chalcogenide glass was analyzed by applying a maximum load of about 240 N, confirming its suitability as a sealing material in the far infrared range.

Expansion Ratio and Ultimate Load of Pulse-Discharge Bulbed Anchors (펄스방전 그라운드 앵커의 확공특성 및 극한인발력에 관한 연구)

  • Kim, Nak-Kyung;Kim, Sung-Kyu;Joo, Yong-Sun;Seo, Hyo-Kyun;Kim, Sun-Ju
    • Journal of the Korean Geotechnical Society
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    • v.25 no.7
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    • pp.5-10
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    • 2009
  • The ground anchor is not usually used in soft clay and loose sand, because the pullout resistance of anchors can not be guaranteed. However, there is a method to increase the capacity of anchors using electric discharge geotechnical technologies, which are also known as pulse discharge and electric-spark technologies. The pulse-discharge anchor has a bulbed (or underreamed) bond length that is expanded by high voltage electrokinetic pulse energy. 24 anchors were installed in the weathered soil and sandy clay at the Geotechnical Experimentation Site at Sungkyunkwan University in Suwon, Korea. In this study, in order to define a relation between expansion rate of the anchor diameter and ultimate load, anchor load tests were carried out in accordance with testing procedures by AASHTO (AASHTO 1990) and FHWA (Weatheb 1998). And then several anchors were exhumed to measure the diameter of the pulse discharge anchors.

Fracture Mechanical Characterization of Bi-material Interface for the Prediction of Load Bearing Capacity of Composite-Steel Bonded Joints (복합재료-탄소강 접착제 결합 조인트의 하중지지 능력 예측을 위한 이종 재료 접합 계면의 파괴 역학적 분석)

  • Kim, Won-Seok;Shin, Kum-Chel;Lee, Jung-Ju
    • Composites Research
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    • v.19 no.4
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    • pp.15-22
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    • 2006
  • One of the primary factors limiting the application of composite-metal adhesively bonded joints in structural design is the lack of a good evaluation tool for the interfacial strength to predict the load bearing capacity of boned joints. In this paper composite-steel adhesion strength is evaluated in terms of stress intensity factor and fracture toughness of the interface corner. The load bearing capacity of double lap joints, fabricated by co-cured bonding of composite-steel adherends has been determined using fracture mechanical analysis. Bi-material interface comer stress singularity and its order are presented. Finally stress intensities and fracture toughness of the wedge shape bi-material interface corner are determined. Double lap joint failure locus and its mixed mode crack propagation criterion on $K_1-K_{11}$ plane have been developed by tension tests with different bond lengths.

Synthesis and Characterization of Magnetic Cellulose Powder from Sawdust Waste

  • Heru SURYANTO;Uun YANUHAR;Husni Wahyu WIJAYA;Joseph Selvi BINOJ;Azlin Fazlina OSMAN;Poppy PUSPITASARI;Jibril MAULANA;Nico Rahman CAESAR;Fajar NUSANTARA;Komarudin KOMARUDIN
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.5
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    • pp.504-523
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    • 2024
  • Timber industry waste is being examined for cellulose manufacturing to give important benefits. The study's goal is to investigate the properties of cellulose powder derived from sawdust waste after it has been reinforced with ferrous-ferric oxide nanoparticles (Fe3O4-NPs). Sawdust cellulose powder was produced from Sengon (Albizia chinensis) wood waste in this study. The crushed sawdust waste is handled with alkalization and bleaching. Cellulose powder is then reinforced with Fe3O4-NPs at 10 wt.%, 20 wt.%, and 30 wt.%. The magnetic cellulose powder was analysed by X-ray diffraction, Fourier Transform Infrared, scanning electron microscopy morphology, magnetic vibrating sample magnetometer, Brunauer-Emmett teller, and adsorption tests for Methylene Blue and Congo Red dyes. Structure study identifies sawdust as cellulose 1β, with peaks at 14°, 16°, and 22° diffraction angles. The addition of Fe3O4-NPs reduces the crystalline index of sawdust cellulose powder from 68.50% to 63.38%, and functional group bond analysis revealed many peak shifts indicating a change in the chemical bonds of magnetic cellulose powder. Incorporating Fe3O4-NPs into sawdust cellulose powder confers magnetic and superparamagnetic properties to the sawdust cellulose. Similarly, the surface texture of magnetic cellulose seems rougher as the surface area increases. These parameters imply a 31.8% increase in Congo Red adsorption, using adsorption kinetics based on the pseudo-first-order model.

Fabrication and Mechanical Properties of Carbon Fiber Reinforced Polymer Composites with Functionalized Graphene Nanoplatelets (기능기화 된 그래핀 나노플레이틀릿이 첨가 된 탄소섬유 강화 고분자 복합소재의 제조 및 기계적 특성 연구)

  • Cha, Jaemin;Kim, Jun Hui;Ryu, Ho Jin;Hong, Soon H.
    • Composites Research
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    • v.30 no.5
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    • pp.316-322
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    • 2017
  • Carbon fiber is a material with excellent mechanical, electrical and thermal properties, which is widely used as a composite material made of a polymer matrix. However, this composite material has a weak point of interlaminar delamination due to weak interfacial bond with polymer matrix compared with high strength and elasticity of carbon fiber. In order to solve this problem, it is essential to use reinforcements. Due to excellent mechanical properties, graphene have been expected to have large improvement in physical properties as a reinforcing material. However, the aggregation of graphene and the weak interfacial bonding have resulted in failure to properly implement reinforcement effect. In order to solve this problems, dispersibility will be improved. In this study, functionalization of graphene nanoplatelet was proceeded with melamine and mixed with epoxy polymer matrix. The carbon fiber reinforced polymer composites were fabricated using the prepared graphene nanoplatelet/epoxy and flexural properties and interlaminar shear strength were measured. As a result, it was confirmed that the dispersibility of graphene nanoplatelet was improved and the mechanical properties of the composite material were increased.

Determinants of Capital Structure in KOSDAQ Firms (코스닥 기업의 자본구조 결정요인: 동태적 자본구조 모형을 중심으로)

  • Son, Seung-Tae;Lee, Yoon-Goo
    • The Korean Journal of Financial Management
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    • v.24 no.1
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    • pp.109-147
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    • 2007
  • According to the perspective of capital structure theory, we analyzed the dynamism of the capital structure determinants by using panel data of 244 KOSDAQ firms based on two-step GMM system methodology suggested by Blundell Bond(1998). This dynamic methodology had not been used to analyse capital structure determinants in Korea. In the dynamic model of capital structure, profit had negative effect on the book leverage and market leverage, which meant supporting pecking order theory. Growth opportunity (MBR) affected negatively to the market leverage. For the determinants of leverage, earnings volatility had significantly positive effect on KOSDAQ 50 firms. KOSDAQ and KOSDAQ 50 firms had the target leverage. The adjustment speed in KOSDAQ firms was 0.4958 on the book leverage, it was faster than in KOSDAQ 50 firm's 0.2863 on the book leverage and the adjustment speeds for the market leverage were 0.7651 for KOSDAQ firms and 0.5643 for KOSDAQ 50 firms. There was difference in adjustment cost between KOSDAQ firms and KOSDAQ 50 firms.

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Evaluate the Suitability of MC3T3 Cells to Antibacterial Ag-30CaO·70SiO2 Gel (항균성 Ag-30CaO·70SiO2 Gel의 MC3T3 세포적합성에 관한 연구)

  • Yoon, Geum-Jae;Ryu, Jae-Kyung;An, Eung-Mo;Kim, Yun-Jong;Kim, Taik-Nam;Noh, In-Sup;Cho, Sung-Beck
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.671-676
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    • 2014
  • It is known that bones get damaged by accidents and aging. Since the discovery of Bioglass, various kinds of ceramics have been also found to bond to living bone; some of these ceramics are already being clinically used as bone-repairing materials. In the present study, antibacterial calcium silicate gel ($Ag-30CaO{\cdot}70SiO_2$ gel) was prepared by sol-gel method in order to control the microstructure, which is related to the dissolution rate and induction period of apatite formation in body environment. In addition, biological $Ag-30CaO{\cdot}70SiO_2$ is tested. This was done to impart antimicrobial activity to the $30CaO{\cdot}70SiO_2$. Ag ion was added during sol-gel synthesis to replace the $H_2O$ added during the making of the $30CaO{\cdot}70SiO_2$ gel, which has silver solutions of various concentration. After the sol-gel process, 1N-$HNO_3$ solution was used to wash the gel when synthesizing the gel, in order to maintain the porous structure and remove PEG, water soluble polymers. Then, the apatite forming ability of the sol-gel derived CaO-$SiO_2$ gels was investigated using simulated body fluid (SBF), which had almost the same ion concentration as that of human blood plasma. The gels were analyzed by FT-IR spectroscopy, SEM observation, XRD, and fluorescent microscopy. The apatite was successfully created even after washing the gel; apatite is present in an amorphous state, and was found to affect the concentration of the Ag ion in cells in MC3T3 live & dead assay results. From these results, it is suggested that a good material that can be used to repair defects of nature bone is $Ag-30CaO{\cdot}70SiO_2$ gel.

Application of In-Situ Mixing Hydration Accelerator on Polymer Modified Concrete for Bonded Concrete Overlay (접착식 콘크리트 덧씌우기를 위한 초속경화 첨가재 현장 혼합 폴리머 개질 콘크리트의 적용성 연구)

  • Kim, Young Kyu;Hong, Seong Jae;Lee, Seung Woo
    • International Journal of Highway Engineering
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    • v.17 no.3
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    • pp.85-95
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    • 2015
  • PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS : Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS : It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.