• Title/Summary/Keyword: Bond order

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A simple plane-strain solution for functionally graded multilayered isotropic cylinders

  • Pan, E.;Roy, A.K.
    • Structural Engineering and Mechanics
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    • v.24 no.6
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    • pp.727-740
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    • 2006
  • A simple plane-strain solution is derived in this paper for the functionally graded multilayered isotropic elastic cylinder under static deformation. The solution is obtained using method of separation of variables and is expressed in terms of the summation of the Fourier series in the circumferential direction. While the solution for order n = 0 corresponds to the axisymmetric deformation, that for n = 2 includes the special deformation frequently utilized in the upper and lower bounds analysis. Numerical results for a three-phase cylinder with a middle functionally graded layer are presented for both axisymmetric (n = 0) and general (n = 2) deformations, under either the traction or displacement boundary conditions on the surface of the layered cylinder. The solution to the general deformation case (n = 2) is further utilized for the first time to find the upper and lower bounds of the effective shear modulus of the layered cylinder with a functionally graded middle layer. These results could be useful in the future study of cylindrical composites where FGMs and/or multilayers are involved.

Molecular Dynamics Simulation for the Mechanical Properties of CNT/Polymer Nanocomposites (분자동역학 시뮬레이션을 이용한 나노튜브/고분자 나노복합재의 물성 해석)

  • Yang, Seung-Hwa;Cho, Maeg-Hyo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.2 s.257
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    • pp.237-244
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    • 2007
  • In order to obtain mechanical properties of CNT/Polymer nano-composites, molecular dynamics simulation is performed. Overall system was modeled as a flexible unit cell in which carbon nanotubes are embedded into a polyethylene matrix for N $\sigma$ T ensemble simulation. COMPASS force field was chosen to describe inter and intra molecular potential and bulk effect was achieved via periodic boundary conditions. In CNT-polymer interface, only Lennard-Jones non-bond potential was considered. Using Parrinello-Rahman fluctuation method, mechanical properties of orthotropic nano-composites under various temperatures were successfully obtained. Also, we investigated thermal behavior of the short CNT reinforced nanocomposites system with predicting glass transition temperature.

The Solvent Effects on the Formation of Polyynes by Laser Ablation

  • Park, Young-Eun;Shin, Seung-Keun;Park, Seung-Min
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2439-2442
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    • 2012
  • In order to explore the effects of the solvent on the formation rate of polyynes, we investigated the absorption spectra of polyynes obtained by laser ablation of a graphite target in different solvents at 1064 nm. Polyynes so produced were confirmed by the Raman band around $2200cm^{-1}$ which corresponds to the carbon triple bonds. The production of polyynes by laser ablation turned out to be significantly affected by the ratio of the hydrogen and carbon atoms in the solvent molecule. No clear correlations were observed in the formation of polyynes for other properties of the solvent such bond dissociation energy, thermal conductivity, and total mass of hydrogen atoms per volume of solvent.

Determination of Reactivity by MO Theory (VIII). PMO Interpretation for Photocyclodehydrogenation of o-Terphenyl-type compounds (화학반응성의 분자궤도론적 연구 (제8보). o-Terphenyl 형 화합물의 광학적탈수소 고리화 반응에 대한 섭동분자궤도론적 해석)

  • Ikchoon Lee;Bonsu Lee
    • Journal of the Korean Chemical Society
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    • v.20 no.2
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    • pp.136-140
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    • 1976
  • The photocyclodehydrogenation reaction of o-terphenyl type compounds has been interpreted with perturbational molecular orbital theory. Results show that the mobile bond order for the first excited state is a good reactivity index and this approach is also consistent with the orbital symmetry conservation rule of Woodward and Hoffmann.

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Structural and magnetic study of electron- and proton-irradiated graphite tiles

  • Kweon, Jin-Jung;Lee, Kyu-Won;Park, Jun-Kue;Jeon, Gi-Wan;Kim, Hyo-Jung;Lee, Cheol-Eui;Noh, S.J.;Kim, H.S.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2011.12a
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    • pp.55-56
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    • 2011
  • We have carried out spectroscopic studies on the physical properties of graphite tiles modified by electron and proton irradiation. While increase in local order was observed in the electron-irradiated sample, structural disorder and amorphization were revealed in the proton-irradiated sample, with considerably decreased electrical conductivity. Besides, C-OH bond with a sp3 configuration was identified in the proton-irradiated sample, apparently giving rise to a narrow ESR peak ascribed to localized spins.

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Development of Polymeric Drugs Utilizing Dithiocarbamate Chitosan: Formation and Antimicrobial Activities of Dithiocarbamate Chitosan-Ca(II)-Tetracycline Complex (Dithiocarbamate Chitosan을 Matrix로 이용한 고분자 약물의 개발 : Dithiocarbamate Chitosan-Ca(II)-Tetracycline Complex 의 생성 및 항균성)

  • 김윤택;김영미;한석규;정연진;유종호
    • YAKHAK HOEJI
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    • v.39 no.1
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    • pp.48-54
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    • 1995
  • Coupling of tetracycline(Tc) to dithiocarbamate chitosan(DTCC) via chelate bond was investigated varying reaction time, concentration, temperature, pH, and Ca(II)/Tc ratio. The amount of Tc bound to matrix increased to give a maximum and decreased as the reaction proceeded. The degree and rate of dissociation of Tc complex were affected by the reaction temperature, and pH. By running the reaction at low temperature and pH, the degree of dissociation was greatly diminished. Properties of drug-release from DTCC-Ca(II)-Tc complex were studied by batch- and flow-method and release of Tc and CA(II) by flow method followed nearly zero-order. DTCC-Ca(II)-Tc showed very prolonged antimicrobial activity compared to that of free Tc.

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Development of Ultra-Clean Aligning/Mounting Process of FED Spacers using Electrostatic Bonding (정전 열 접합을 이용한 FED 스페이서의 초청정 정렬/탑재 공정 개발)

  • Ju, Byeong-Kwon;Kang, Moon-Sik;Lee, Yun-Hi
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.11
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    • pp.635-639
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    • 2000
  • In this paper, a new idea about ultra-clean aligning and mounting method of FED spacers was introduced. The glass-to -glass electrostatic bonding process was employed in order to bond the micro-structures of spacers to black matrix area formed on an FED anode substrate. It is possible to get adhesive-free bonding interface and well-aligned spacer array on an FED anode substrate with a ${\pm}5{\mu}m$ accuracy. Finally, I inch-sized FED panel was demonstrated to make sure of its applicability to FED panel fabrication.

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Surge Voltage Distribution at the Different Bonding Practice During a Direct Lightning Stroke to Building (건물의 직격뢰시 본딩 방식에 따른 서지 진압 분포)

  • Lee, Jae-Bok;Chang, Sug-Hun;Myung, Sung-Ho;Cho, Yuen-Gue
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.57 no.4
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    • pp.444-450
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    • 2008
  • There are several ways to bond to building grounding systems for reducing GPR(ground potential rise) and EMI resulting from power system faults or lightning stroke to building. In order to verify effective bonding practice, the GPR and voltage of equipment due to the direct stroke to building are calculated with ATP-EMTP model for transformer, transmission line and MOV(Metal oxide varistor). The simulated model shows a satisfactory accuracy compared with experimental result for the $8/20{\mu}s$ simulated current pulse. It is observed that separate grounding can cause dangerous voltage to the building equipment and the performance of surge protective device can improve when it is installed to the protected equipment in distance as short as possible.

Electrochemical Properties of Carbonized Phenol Resin (탄화된 페놀레진의 전기화학적 성질)

  • 김한주;박종은;홍지숙;류부형;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.629-632
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    • 1999
  • For replacing Li metal ai Lithium ton Bakery(LIB) system. we used carbon powder material which prepared by pyrolysis of phenol resin as starting material. It became amorphous carbon by pyrolysis through it\`s self condensation by thermal treatment. Amorphous carbon can be doped with Li intercalation and deintercalation because it has wide interlayer. however it has a problem with structural destroy causing weak carbon-carbon bond. So. we used ZnCl$_2$ as the pore-forming agent. This inorganic salt used together with the resin serves not only as the pore-forming agent to form open pores, which grow Into a three-dimensional network structure in the cured material, foul also as the microstructure-controlling agent to form a loose structure dope with bulky dopants. We analyzed SEM in order to find to different of structure. and can calculate distance of interlayer. CV test showed oxidation and reduction

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Analysis of Transmission Infrared Laser Bonding for Polymer Micro Devices (폴리머 마이크로 장치에 대한 레이저 투과 마이크로 접합)

  • Kim, Joo-Han;Shin, Ki-Hoon
    • Journal of Welding and Joining
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    • v.23 no.5
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    • pp.55-60
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    • 2005
  • A precise bonding technique, transmission laser bonding using energy transfer, for polymer micro devices is presented. The irradiated IR laser beam passes through the transparent part and absorbed on the opaque part. The absorbed energy is converted into heat and bonding takes place. In order to optimize the bonding quality, the temperature profile on the interface must be obtained. Using optical measurements of the both plates, the absorbed energy can be calculated. At the wavelength of 1100nm $87.5\%$ of incident laser energy was used for bonding process from the calculation. A heat transfer model was applied for obtaining the transient temperature profile. It was found that with the power of 29.5 mW, the interface begins to melt and bond each other in 3 sec and it is in a good agreement with experiment results. The transmission IR laser bonding has a potential in the local precise bonding in MEMS or Lab-on-a-chip applications.