• Title/Summary/Keyword: Bond order

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Development of Bond Strength Model for FRP Plates Using Back-Propagation Algorithm (역전파 학습 알고리즘을 이용한 콘크리트와 부착된 FRP 판의 부착강도 모델 개발)

  • Park, Do-Kyong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.2
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    • pp.133-144
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    • 2006
  • In order to catch out such Bond Strength, the preceding researchers had ever examined the Bond Strength of FRP Plate through their experimentations by setting up of various fluent. However, since the experiment for research on such Bond Strength takes much of expenditure for equipment structure and time-consuming, also difficult to carry out, it is conducting limitedly. This Study purposes to develop the most suitable Artificial Neural Network Model by application of various Neural Network Model and Algorithm to the adhering experiment data of the preceding researchers. Output Layer of Artificial Neural Network Model, and Input Layer of Bond Strength were performed the learning by selection as the variable of the thickness, width, adhered length, the modulus of elasticity, tensile strength, and the compressive strength of concrete, tensile strength, width, respectively. The developed Artificial Neural Network Model has applied Back-Propagation, and its error was learnt to be converged within the range of 0.001. Besides, the process for generalization has dissolved the problem of Over-Fitting in the way of more generalized method by introduction of Bayesian Technique. The verification on the developed Model was executed by comparison with the resulted value of Bond Strength made by the other preceding researchers which was never been utilized to the learning as yet.

Determination of Reactivities by MO Theory (XIII). MO Studies on Nonlinear Hammett Correlation of Benzyl Systems (MO 理論에 依한 反應性의 決定 (第13報). 벤질系의 非線型 Hammett 關係에 관한 分子軌道論的 硏究)

  • Ikchoon Lee;Keun Bae Rhyu;Byung Choon Lee
    • Journal of the Korean Chemical Society
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    • v.23 no.5
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    • pp.277-285
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    • 1979
  • CNDO/2 calculations on $XC_6H_4CH_2Cl,\;where\;X = H,\;p-CH_3,\;p-NH_2\;and\;p-NO_2$, and on benzyl radicals, cations and anions have been carried out in order to investigate nonlinear Hammett behavior. Main conclusions reached are: 1. Benzyl chloride exhibits borderline behavior due to ${\sigma}-{\pi}$ conjugation between C-Cl bond and the ring-system. 2. The extent of mutual conjugation can be judged by $\pi$-charge and bond alternation and interfrontier level separation narrowing effects. 3.The electron donating para substituent reduces the HOMO AO coefficient of the benzylic carbon, while the electron withdrawing para substituent reduces the LUMO AO coefficient of the benzylic carbon.

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A Study on the Stress Corrosion Cracking Behaviors for Weld Joint of Steel with Various pH Values in Synthetic Sea Water (인공해수의 pH에 따른 강 용접부의 응력 부식균열거동에 관한 연구)

  • 유효선;나의균;정세희
    • Journal of Welding and Joining
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    • v.13 no.1
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    • pp.78-88
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    • 1995
  • This paper was performed to study the utility of the SP(small punch) test and the AE(acoustic emission) test in the evaluation of SCC(stress corrosion cracking) susceptibility for parent metal and bond line of HT80 steel-weld joint by SAW(submerged arc welding) with the various pH values. The loading rate used was 3*10$^{-4}$ mm/min and the corrosive environment used was synthetic sea water during the SP test and the AE test. According to the test results, the SCC susceptibility of the parent metal was increased in the order of pH6.0, pH8.2 and pH10.0. On the other hand, the bond line showed almost the same high SCC susceptibility in all pH concentrations. Synthetically, from the results of the SCC susceptibility, the macro- and micro-SEM observation, the microfracture behaviors by AE test and the relationship between SCC susceptibility and displacement at incipient failure, .delta.$_{i.f-AE}$, it can be concluded that the SP test and the AE test are the good test methods to evaluate the SCC susceptibility for parent metal and bond line of the weld joint with the change of environmental factors.

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A Study on the Shear Bond Strength of Resin Artificial Tooth Depending on Repair Techniques (레진 인공치아의 재부착 방법에 따른 전단결합강도에 관한 연구)

  • Kim, Ik-Jung;Lee, Jong-Hyuk;Cho, In-Ho
    • Journal of Dental Rehabilitation and Applied Science
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    • v.21 no.2
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    • pp.143-151
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    • 2005
  • The purpose of this study was to evaluate the most effective method for repairing the exfoliated resin teeth. The specimens were divided into five groups according to repair method and presence of retention holes. The groups were as follows Group1 : Control group Group2 : Sprinkle method with no retention holes Group3 : Sprinkle method with retention holes Group4 : Flask method with no retention holes Group5 : Flask method with retention holes The results were as follows. 1. According to shear bond strength, the value decreased in the order of group1, group5, group3, group2, group4 and there were significant difference between, each group except between group1 and groups5, group2 and group3, group2 and group4(p < 0.05). 2. According to observations of the exfoliation surface, group2 and 4 showed more failure in the denture base resin and repair resin interface, but in group1, 3 and 5 there were more mixed failures. From the results above, there were no significant difference between repair methods without retention holes. But when comparing groups with retention holes, the flask method showed significantly improved results compared to the sprinkle method. Especially, group5 showed similar results as the control group.

Customer Level Classification Model Using Ordinal Multiclass Support Vector Machines

  • Kim, Kyoung-Jae;Ahn, Hyun-Chul
    • Asia pacific journal of information systems
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    • v.20 no.2
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    • pp.23-37
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    • 2010
  • Conventional Support Vector Machines (SVMs) have been utilized as classifiers for binary classification problems. However, certain real world problems, including corporate bond rating, cannot be addressed by binary classifiers because these are multi-class problems. For this reason, numerous studies have attempted to transform the original SVM into a multiclass classifier. These studies, however, have only considered nominal classification problems. Thus, these approaches have been limited by the existence of multiclass classification problems where classes are not nominal but ordinal in real world, such as corporate bond rating and multiclass customer classification. In this study, we adopt a novel multiclass SVM which can address ordinal classification problems using ordinal pairwise partitioning (OPP). The proposed model in our study may use fewer classifiers, but it classifies more accurately because it considers the characteristics of the order of the classes. Although it can be applied to all kinds of ordinal multiclass classification problems, most prior studies have applied it to finance area like bond rating. Thus, this study applies it to a real world customer level classification case for implementing customer relationship management. The result shows that the ordinal multiclass SVM model may also be effective for customer level classification.

Design and Performance Measurement of a Genetic Algorithm-based Group Classification Method : The Case of Bond Rating (유전 알고리듬 기반 집단분류기법의 개발과 성과평가 : 채권등급 평가를 중심으로)

  • Min, Jae-H.;Jeong, Chul-Woo
    • Journal of the Korean Operations Research and Management Science Society
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    • v.32 no.1
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    • pp.61-75
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    • 2007
  • The purpose of this paper is to develop a new group classification method based on genetic algorithm and to com-pare its prediction performance with those of existing methods in the area of bond rating. To serve this purpose, we conduct various experiments with pilot and general models. Specifically, we first conduct experiments employing two pilot models : the one searching for the cluster center of each group and the other one searching for both the cluster center and the attribute weights in order to maximize classification accuracy. The results from the pilot experiments show that the performance of the latter in terms of classification accuracy ratio is higher than that of the former which provides the rationale of searching for both the cluster center of each group and the attribute weights to improve classification accuracy. With this lesson in mind, we design two generalized models employing genetic algorithm : the one is to maximize the classification accuracy and the other one is to minimize the total misclassification cost. We compare the performance of these two models with those of existing statistical and artificial intelligent models such as MDA, ANN, and Decision Tree, and conclude that the genetic algorithm-based group classification method that we propose in this paper significantly outperforms the other methods in respect of classification accuracy ratio as well as misclassification cost.

Study About Measurement of Interfacial Bonding Strength of STS/Al Clad sheet by Blanking Process (블랭킹 공정을 이용한 STS/Al 클래드 판재의 계면 접합력 측정에 관한 연구)

  • Kim, T.H.;Lee, K.S.;Kim, J.H.;Moon, Y.H.;Lee, Y.S.;Yoon, E.Y.
    • Transactions of Materials Processing
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    • v.27 no.5
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    • pp.267-275
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    • 2018
  • The clad sheet material is produced by a roll-bonding process of one or more materials with different properties. Good formability of clad sheet material is an essential property in to deform a clad metal sheet into a part or component. Performance of the clad sheet material largely depends on interfacial bond strength between different materials. In this study, interfacial bond strength of STS/Al clad sheet was analyzed by varying experimental parameters using a blanking process. Experimental parameters are the punching speed, clearance, and stacking order of plate materials. In addition, blanking test results were compared with bond strengths measured by the T-peel test, that analyzes interface bonding strength of the standard clad sheet. The blanking process was analyzed by the finite element method under the sticking condition of interface of different materials, and experimental results and analysis results were compared.

A study on the cracking mechanism of the welded parts in steel structures for the use of low temperature and high pressure (저온, 고압력용 강재 구조물의 용접부균열 발생과 그 대책에 관한 연구)

  • 김영식;배차헌;구자영
    • Journal of Advanced Marine Engineering and Technology
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    • v.9 no.4
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    • pp.328-338
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    • 1985
  • When the low temperature service steels are used as materials for welded structure, some problems-brittleness and weld cracking, etc.-occur in welded part due to the change of mechanical and metallurgical characteristics resulted from the thermal cycle during the welding procedure. In this study, the experiments were conducted to investigate the change of mechanical and metallurgical characteristics of the welded part for the low temperature and high pressure service steels. Moreover, the Static and Dynamic Implant Test Method was introduced to this study in order to find out the mechnism of weld cracking. In addition, the fracture toughnesses of welded bond were inspected under the various low temperature environments. Main results obtained are as follows; 1) The effect of the hydrogen on the fatigue characteristics of the weld bond can be estimated by the new self-contrived Dynamic Implant Test equipment. 2) The fine micro-structure and low hardness in the heat affected zone can be obtained by the small heat input multi-pass welding. 3) The susceptibility of the delayed cracking is largely affected by the condition of used electrode. 4) The transition temperature of the fracture surface in weld bond appears to be higher 20 .deg. C than that in base metal.

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Development of Newly Formulated High-strength Wash Primer for Membrane LNG Carrier (멤브레인형 LNG 운반선용 고강도 워시프라이머 개발)

  • Song, Eun-Ha;Lee, Sung-Kyun;Chung, Mong-Kyu;Baek, Kwang-Ki
    • Special Issue of the Society of Naval Architects of Korea
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    • 2007.09a
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    • pp.48-56
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    • 2007
  • Wash primer was applied to cargo tank of Membrane-LNG Carrier (M-LNGC) for corrosion resistance and high bond-strength with the mastic. However, a lack of bond-strength verification at high thickness wash primer coating resulted in strict coating thickness control. Therefore wash primer was controlled below DFT(Dry Film Thickness) $30{\mu}m$. In order to develop the wash primer satisfying GTT (GAZ TRANSPORTAION TECHNIGAZ) standard even at high thickness, we evaluated coating properties such as wash primer/mastic bond-strength, corrosion resistance, as well as workability for the newly formulated wash primer materials. The newly formulated wash primer had high bonding-strength to mastic even at high thickness and had proper corrosion resistance and workability suitable to yard condition.

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Characteristic Effects of 4,5-Disubstituted Pyridazin-3-one Derivatives with Various Functional Groups: Ab initio Study

  • Yoon, Yong-Jin;Koo, In-Sun;Park, Jong-Keun
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1363-1370
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    • 2007
  • The geometrical structures of pyridazin-3-one derivatives (4,5-dihalopyridazin-3-one and 4-halo-5- alkoxypyridazin-3-one) with various functional and substituent groups were fully optimized using the ab initio Hartree-Fock (HF) and second order Moller-Plesset perturbation (MP2) methods. At the N2-, C4-, and C5- positions on the pyridazin-3-one rings, the structural and electronic features pertaining to the variations of the functional and substituent groups were analyzed, respectively. The trends in the variation of the bond lengths, atomic charges, and energetics (relative energy, binding energy) of the derivatives induced by changing the electron donating functional groups (X1 = OMe, OEt) to electron withdrawing groups (X1 = Cl, NO2) were examined. The variations of the bond lengths, atomic charges, and binding energies with the electron withdrawing strength of the substituent groups (Y = Me → F) were also investigated.