• Analytical Science and Technology
• /
• v.20 no.5
• /
• pp.448-451
• /
• 2007

A new bis(dicyclohexylammonium) chromate dihydrate complex, $[(C_6H_{11})_2NH_2]_2[CrO_4]{\cdot}2H_2O$, (I), has been synthesized and its structure analyzed by FT-IR, EDS, elemental analysis, ICP-AES, and single crystal X-ray diffraction methods. The Cr(VI) complex (I) is tetragonal system, I${\bar{4}}$2d space group with a = 12.5196(1), b = 12.5196(1), c = $17.3796(3){\AA}$, a = ${\beta}$ = ${\gamma}$ = $90^{\circ}$, V = $2724.09(6){\AA}^3$, Z = 4. The crystal structure of complex (I) consists of tetrahedral chromate $[CrO_4]^{2-}$ anion, two organic dicyclohexylammonium $[(C_6H_{11})_2NH_2]^+$ cations and two lattice water molecules. The chromate anion and protonated dicyclohexylammonium cation is mainly constructed through the ionic bond. The cyclohexylammonium rings of the dicyclohexylammonium cation take the chair form and vertical configuration with each other. The N-H${\cdot}$O and O-H${\cdot}$O hydrogen bond networks between the $N_{dicyclohexylammonium}$, $O_{water}$ and $O_{chromate}$ atom lead to self-assembled molecular conformation and stabilize the crystal structure.

• Structural Engineering and Mechanics
• /
• v.67 no.4
• /
• pp.391-401
• /
• 2018

Locally available Stainless Steel Wire Mesh (SSWM) bonded on a concrete surface with an epoxy resin is explored as an alternative method for the torsional strengthening of Reinforced Concrete (RC) beam in the present study. An experiment is conducted to understand the behavior of RC beams strengthened with a different configuration of SSWM wrapping subjected to pure torsion. The experimental investigation comprises of testing fourteen RC beams with cross section of $150mm{\times}150mm$ and length 1300 mm. The beams are reinforced with 4-10 mm diameter longitudinal bars and 2 leg-8 mm diameter stirrups at 150 mm c/c. Two beams without SSWM strengthening are used as control specimens and twelve beams are externally strengthened by six different SSWM wrapping configurations. The torsional moment and twist at first crack and at an ultimate stage as well as torque-twist behavior of SSWM strengthened specimens are compared with control specimens. Also the failure modes of the beams are observed. The rectangular beams strengthened with corner and diagonal strip wrapping configuration exhibited better enhancement in torsional capacity compared to other wrapping configurations. The numerical simulation of SSWM strengthened RC beam under pure torsion is carried out using finite element based software ABAQUS. Results of nonlinear finite element analysis are found in good agreement with experimental results.

• Journal of Electrochemical Science and Technology
• /
• v.15 no.3
• /
• pp.421-426
• /
• 2024

Ru dye (Z-907) is a crucial photosensitizing material in dye-sensitized solar cells (DSSCs). To enhance the utilization of Ru dye's photosensitizing properties in bulk heterojunction solar cells, a method was developed to synthesize phenyl-C61-butyric acid methyl ester (PCBM) nanoparticles that are chemically linked to Ru dye. PCBM contains a methoxy (-OCH₃) group, whereas Ru dye incorporates a carboxyl group (-COOH) within its molecular structure. By exploiting these complementary functional groups, a successful bond between Ru dye and PCBM was established through an anhydride functional group. The coupling of PCBM with Ru dye results in a modification of the energy levels, yielding lower LUMO (3.8 eV) and HOMO (6.1 eV) levels, compared with the LUMO (3.0 eV) and HOMO (5.2 eV) levels of Ru dye alone. This configuration potentially facilitates efficient electron transfer from Ru dye to PCBM, alongside promoting hole transfer from Ru dye to the conducting polymer. Consequently, the bulk heterojunction solar cells incorporating this Ru dye-PCBM configuration demonstrate superior performance, with an open circuit voltage (V_oc) of 0.62 V, short circuit current (J_sc) of 0.63 mA cm^-2, fill factor (FF) of 65.6%, and a photovoltaic conversion efficiency (η) of 0.25%.

• Nuclear Engineering and Technology
• /
• v.11 no.1
• /
• pp.1-20
• /
• 1979

Neutron inelastic scattering studies on polycrystalline hydrates, NaBr-2$H_2O$ and BaCl$_2$-2$H_2O$ have been performed to observe librational modes. Assuming all observed peaks are from the $H_2O$ librational origin, the weighted frequency distribution functions are obtained by eliminating the contributions from the higher order processes. All of theoretical frequencies obtained using FG matrix method are dus to highly mixed modes, and therefore the modes identified as significant $H_2O$ librationat modes from their large potential energy distributions are assigned to the observed peaks. The H-bond interactions are estimated using a modified Lippincott Schroeder potential function, and the applicability of the potential function to the H-bond with highly bent or bifurcated configuration is examined on the basis of the shape of $H_2O$ librational potential energies. Some discussions are given on the usefulness of introducing O-H…Y bending terms in addition to the H…Y stretching in similar frequency calculation in order to obtain more information on the nature of H-bond. Also the purity and symmetry properties of the $H_2O$ librational modes are discussed using group theoretical analyses.

• Restorative Dentistry and Endodontics
• /
• v.33 no.5
• /
• pp.472-480
• /
• 2008

This study was conducted to evaluate the influence of the C-factor on the bond strength of a 6th generation self-etching system by measuring the microtensile bond strength of four types of restorations classified by different C-factors with an identical depth of dentin. Eighty human molars were divided into four experimental groups, each of which had a C-factor of 0.25, 2, 3 or 4. Each group was then further divided into four subgroups based on the adhesive and composite resin used. The adhesives used for this study were AQ Bond Plus (Sun Medical, Japan) and XenoIII (DENTSPLY, Germany). And composite resins used were fantasists (Sun Medical, Japan) and Ceram-X mono (DENTSPLY, Germany). The results were then analyzed using one-way ANOVA, a Tukey's test, and a Pearson's correlation test and were as follows. 1. There was no significant difference among C-factor groups with the exception of groups of Xeno III and Ceram-X mono (p<0.05). 2. There was no significant difference between any of the adhesives and composite resins in groups with C-factor 0.25, 2 and 4. 3. There was no correlation between the change in C-factor and microtensile bond strength in the Fantasista groups. It was concluded that the C-factor of cavities does not have a significant effect on the microtensile bond strength of the restorations when cavities of the same depth of dentin are restored using composite resin in conjunction with the 6th generation self-etching system.

• Proceedings of the Korea Concrete Institute Conference
• /
• 1998.10a
• /
• pp.589-596
• /
• 1998

Experimental studies are investigated for RC column retrofitting under cyclic load. Design considerations are jacketing of steel plate of carbon fiber with epoxy bonding, use of unbonded plate, additional concrete grouting, ratio of additional longitudinal steel reinforcement and longitudinal configuration of additional ties. Investigated results are 1) jacketing and additional reinforcements are effective for strengthening, 2) use of additional grouting is less effective with respect to increased section. Future studies are needed to evaluate the requirements about additional reinforcements for member stress level, 3) bond between original and additional grout concrete.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2003.06a
• /
• pp.848-851
• /
• 2003

In this paper, a separating system for used CRT recycling is presented. Depend on manufacturer CRTs has small differences in dimension for the same model, but the dimensions of the panel are nearly same. To simplifying configuration of the system, we developed CRT fixing pallets for every model of CRT. The height of cutting position for every model of CRT will be same. The cutting machine has two rotating arm and use metal-bond type diamond cutting wheel. Instead of water, two vortex tube type air-coolers are used for the cooling of cutter. Workers in recycling factory are generally old people. Therefore, control program should be easy to use and operate. Thus we developed GUI with very simple interface.

• Archives of Pharmacal Research
• /
• v.21 no.3
• /
• pp.338-343
• /
• 1998

$2^1$-Fluorohexopyranosyl nucleosides 1a and 1b which contained a bioisosteric double bond and a fluorine were synthesized in 12 steps, starting from D-galactose. During diethylaminosulfur trifluoride (DAST) fluorination, retention of stereochemistry was observed through the participation of methoxy or chloro group at the 6-posiition of the purine base. The final nucleosides 1a and 1b were found to be inactive against HIV-1 and HSV-1,2.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2000.10a
• /
• pp.21-24
• /
• 2000

Traction motors driven by several type inverters have been subjected to increasing demands for higher operating temperature, more demands for duty cycles, higher starting current, frequent voltage transients and finally severe environmental exposure. For applications to inverter duty, traction motors needs a special insulation system, which has characteristics of increased bond strength, lower operating temperature and higher turn-to-tum insulation. Also it needs major contributors to insulation life and reliability of motors, which more considered by temperature, voltage, frequency, rise time, pulse configuration, wire thickness and insulation materials. In this paper, to evaluate of reliability and expected life, it is analyzed the several stresses and their degradation mechanism on insulation system of AC traction motor.

• Structural Engineering and Mechanics
• /
• v.43 no.5
• /
• pp.623-636
• /
• 2012

The aim of the current work is to describe the flexural behaviour of simply supported concrete beams with tension reinforcement spliced at mid-span. The parameters included in the study were the type of the concrete, the splice length and the configuration of the hooked splice. Fifteen beams were cast using an ordinary concrete mix and two fiber reinforced concrete mixes incorporating steel and polypropylene fibers. Each concrete mix was used to cast five beams with continuous, spliced and hooked spliced tension steel bars. A test beam was reinforced on the tension side with two 12 mm bars and the splice length was 20 and 40 times the bar diameter. The hooked bars were spliced along 20 times the bar diameter and provided with 45-degree and 90-degree hooks. The test results in terms of cracking and ultimate loads, cracking patterns, ductility, and failure modes are reported. The results demonstrated the consequences due to short splices and the improvement in the structural behaviour due to the use of hooks and the confinement provided by the steel and polypropylene fibers.