• 제목/요약/키워드: Bond Properties

검색결과 1,128건 처리시간 0.034초

Influence of 10-MDP concentration on the adhesion and physical properties of self-adhesive resin cements

  • Shibuya, Kazuhiko;Ohara, Naoko;Ono, Serina;Matsuzaki, Kumiko;Yoshiyama, Masahiro
    • Restorative Dentistry and Endodontics
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    • 제44권4호
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    • pp.45.1-45.10
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    • 2019
  • Objectives: Self-adhesive resin cements contain functional monomers that enable them to adhere to the tooth structure without a separate adhesive or etchant. One of the most stable functional monomers used for chemical bonding to calcium in hydroxyapatite is 10-methacryloyloxydecyl dihydrogen phosphate (10-MDP). The aim of this study was to evaluate the influence of the10-MDP concentration on the bond strength and physical properties of self-adhesive resin cements. Materials and Methods: We used experimental resin cements containing 3 different concentrations of 10-MDP: 3.3 wt% (RC1), 6.6 wt% (RC2), or 9.9 wt% (RC3). The micro-tensile bond strength of each resin cement to dentin and a hybrid resin block (Estenia C&B, Kuraray Noritake Dental) was measured, and the fractured surface morphology was analyzed. Further, the flexural strength of the resin cements was measured using the three-point bending test. The water sorption and solubility of the cements following 30 days of immersion in water were measured. Results: The bond strength of RC2 was significantly higher than that of RC1. There was no significant difference between the bond strength of RC2 and that of RC3. The water sorption of RC3 was higher than that of any other cement. There were no significant differences in the three-point bending strength or water solubility among all three types of cements. Conclusions: Within the limitations of this study, it is suggested that 6.6 wt% 10-MDP showed superior properties than 3.3 wt% or 9.9 wt% 10-MDP in self-adhesive resin cement.

불소유리 전색재와 일반 레진계 전색재의 전단결합강도에 관한 비교연구 (A COMPARISON OF THE SHEAR BOND STRENGTHS BETWEEN CONVENTIONAL COMPOSITE SEALANTS AND FLUORIDE-RELEASING SEALANTS)

  • 김신;정태성
    • 대한소아치과학회지
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    • 제27권1호
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    • pp.85-89
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    • 2000
  • 치면열구 전색재가 교합면 열구우식의 억제에 예방효과를 보임은 이미 잘 알려져 있다. 최근에 들어서는 치면열구 전색재가 불소를 유리하도록 성분적인 첨가를 하려는 시도가 있었고, 여러 제품이 현재 이러한 특징을 가지고 시판되고 있다. 그러나, 불소를 유리하는 장점은 가졌으나, 물성의 저하가 초래되지는 않았을지 에 대한 의문을 가질 수 있다. 본 연구에서는 일반 레진계 전색재, 불소유리 전색재, GI계 전색재 등 4종의 치면열구 전색재의 유지력을 전단결합강도를 측정으로 비교 분석하여 다음과 같은 결론을 얻었다. 1. 레진계 전색재인 Helioseal과 Teethmate-A가 불소유리 레진계 전색재인 Teethmate-F에 비해 전단결합강도가 약간 크게 나타나기는 하였으나, 유의한 차는 없었다(p>0.05). 2. GI계 전색재인 Fuji III의 전단결합강도는 레진계 전색재에 비해 상당히 낮았다(p<0.05). 3. 위 실험결과에서처럼 레진계 전색재에서 우식예방효과를 증대시킬 목적으로 불소를 포함시켰을 때, 전색재의 유지력에 큰 영향을 미치지는 않는 것으로 생각되었다.

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부착특성을 고려한 휨모멘트-곡률 관계에 관한 연구 (Study on the Relationships of Bending Moment-Corvature Based on Bond Property)

  • 장일영
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1991년도 봄 학술발표회 논문집
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    • pp.81-85
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    • 1991
  • The object of this study is to propose the bending moment-curvature relationships based on the bond properties between concrete and steel for noncraking zone, and evaluate the flexural displacement of reinforced concrete members. The bond-slip relationship and the strain hardening effect of steel were taken into account in order to evaluate the spacing of the cracks and the curvature distribution. Calculated curvature distribution along the longitudinal axis was transformed into equivalent curvature distribution. The flexural displacement was calculated by means of double intergral of the equivalent curvature. Calculated values are in good agreement with the experimental data.

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XRD 분석과 FTIR 분석에 의한 비정질 박막의 특성 연구 (Characteristic Properties of Organic Thin Film Surface on Si Semiconductor)

  • 오데레사
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.112-113
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    • 2007
  • $SiO_2$ 절연 박막위에 희석된 PMMA 유기물을 처리하였다. 유기물 처리량에 따른 $SiO_2$ 박막의 $620{\sim}1100\;cm^{-1}$ 영역의 FTIR 스펙트라를 분석한 결과 0.3~0.7%로 PMMA 처리된 박막에서 친핵성 반응이 밀어나는 것을 확인하였으며, 친핵성 반응이 일어나는 박막들에서 누설전류가 적었으며, 절연특성이 우수한 것을 확인하였다.

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Ab initio Electronic Structure Calculations of $O_2$ Using Coupled Cluster Approaches and Many-Body Perturbation Theory

  • Yoon Sup Lee;Sang Yeon Lee
    • Bulletin of the Korean Chemical Society
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    • 제12권2호
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    • pp.211-213
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    • 1991
  • The ground state of the oxygen molecule is calculated by various methods of coupled cluster approaches and many body perturbation theory using a double zeta plus polarization basis set and the UHF reference state. All the methods employed are capable of describing the oxygen molecule near the equilibrium bond length and the separated atom, but do not correctly depict the breaking of the multiple bond. For this basis set, including more correlations does not necessarily improve the agreement with experiment for molecular properties such as bond lengths and dissociation energies.

Structural lightweight concrete containing expanded poly-styrene beads; Engineering properties

  • Vakhshouri, Behnam
    • Steel and Composite Structures
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    • 제34권4호
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    • pp.581-597
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    • 2020
  • Light-Weight Concrete containing Expanded Poly-Styrene Beads (EPS-LWC) is an approved structural and non-structural material characterized by a considerably lower density and higher structural efficiency, compared to concrete containing ordinary aggregates. The experimental campaign carried out in this project provides new information on the mechanical properties of structural EPS-LWC, with reference to the strength and tension (by splitting and in bending), the modulus of elasticity, the stress-strain curve in unconfined compression, the absorbed energy under compression and reinforcement-concrete bond. The properties measured at seven ages since casting, from 3 days to 91 days, in order to investigate their in-time evolution. Mathematical relationships are formulated as well, between the previous properties and time, since casting. The dependence of the compressive strength on the other mechanical properties of EPS-LWC is also described through an empirical relationship, which is shown to fit satisfactorily the experimental results.

Effect of Heat Treatment Method on Properties of ZnO Thin Films Deposited by RF Magnetron Sputtering

  • Kim, Deok Kyu
    • Applied Science and Convergence Technology
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    • 제26권2호
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    • pp.30-33
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    • 2017
  • ZnO thin films which were deposited by RF magnetron sputtering system were annealed by furnace and insitu heat treatment methods. We investigated the effect of heat treatment method on physical properties of ZnO thin films. The structural and optical properties of ZnO thin films were improved by heat treatment. Through the annealing treatment of ZnO film by furnace, the good crystallinity and ultraviolet emission were obtained. These results are attributed to the improved formation of Zn-O bond in ZnO thin film annealed at by furnace. We confirm that the formation of Zn-O bond plays an important role in obtaining the excellent structural and optical properties of ZnO thin films.

Nd-Fe-B-Co계 급냉리본과 Bond 자석의 자기적 성질 (Magenetic Properties of Nd-Fe-B-Co-based Melt-spun Ribbons an dTheir Bonded Magents)

  • 강계명;강기원;오영민;송진태
    • 한국재료학회지
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    • 제3권2호
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    • pp.175-184
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    • 1993
  • Nd-Fe-B계에 Co와 Al을 첨가한 자석합금을 진공유도용해로에서 제조하여 이들 합금을 단롤법으로 melt-spun시켜 급냉리본을 얻었다. 제작된 급냉리본의 냉각속도에 따른 자기적 성질의 변화를 조사하였고, 최적의 급냉속도에서 제작된 리본을 파쇄하여 resin bond 자석을 제조하였으며, 이들 급냉리본 및 bond자석의 자기적 성질, 미세구조, 결정구조에 관하여 연구, 조사하였다. 이들 급냉리본의 자기적 성질은 급냉속도에 따라 크게 변하였으며 20m/sec전후에서 최적의 자기적 성질을 보였다. 이때의 급냉리본의 미세조직은 Nd-rich의 입계상이 미세한 N$d_2$F$e_14$B결정립을 둘러싼 cell 형의 구조였으며, 특히 Al이 2.1at%첨가된 리본시료에서는 iHc=15.5KOe, Br=7.8KG, (BH)max=8.5MGOe의 자기적 성질을 나타내었다. 최적의 급냉속도에서 제작된 리본을 polyamide resin과 2.5wt%의 비율로 혼합하여 상온에서 성형, 결합시켜 제작한 bond자석에서 보다 현저히 향상되었으며 유지시간이 8분인 경우 iHc=10.8KOe, Br=7.3KG, (BH)max=8.0MGOe의 값을 가졌다. 한편, 자구구조는 maze pattern이 주로 관찰되어 자화용이축인 C축이 배열되었으며 bond자석에서보다 hot-press 자석에서 자구폭이 보다 작았다.

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비선형 유한요소법에 의한 에폭시 피막된 철근의 부착에 관한 연구 (Bond Strength Evaluation of Epoxy-Coated Reinforcement using Nonlinear Finite Element Analysis)

  • 최완철
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1991년도 봄 학술발표회 논문집
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    • pp.65-68
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    • 1991
  • Finite element analysis is used to study the role of interfacial properties on the bond strength of reinforcing steel to concrete. Specifically, the role played by epoxy coatings on the failure of standard beam-end specimens is explored. Experimental results show that epoxy coatings reduce bond strength, but that the effect is dependent on the bar size and the deformation pattern. The finite element model for the beam-end specimen includes representations for the deformed steel bar, the concrete, and the interfacial material. The interface elements can be varied to match the stiffness and friction properties of the interfacial material. Cracking within the concrete is represented using Hillerborg's ficticious crack model. The model is used to study important aspects or behavior observed in the tests and to provide an explanation for the effect of the various test parameters.

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Effects of Species on the Isocyanate-bonded Flakeboard Properties

  • Kwon, Jin Heon
    • Journal of the Korean Wood Science and Technology
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    • 제35권5호
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    • pp.38-45
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    • 2007
  • Flakeboards made from ring- and drum-cut flakes of Douglas-fir, hemlock, red lauan and kapur using two kinds of resin levels were evaluated for the selected properties according to flake thickness. The pH and buffering capacity of four species were determined. Those of kapur were extremely different from the other three species. These pH and buffering capacity values result in the poor internal bond strength of kapur flakeboard. The internal bond strength was affected significantly by flake thickness, resin content and species. MOR and MOE in bending strength were maximized at medium drum-cut flake thickness. Screw holding strength was not consistent for flake thickness, but it was influenced by species. Thickness swelling and water absorption of Douglas-fir and hemlock flakeboard were minimized at medium drum-cut flake thickness.