• Structural Engineering and Mechanics
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• v.75 no.1
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• pp.123-131
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• 2020

The bond performance of glass fibre reinforced polymer (GFRP) bars and that of steel bars embedded in Alkali Activated Cement (AAC) concrete are analysed and compared using pull-out specimens. The bond failure modes, the average bond strength and the free end bond stress-slip curves are used for comparison. Tepfers' concrete ring model is used to further analyse the splitting failure in ribbed steel bar and GFRP bar specimens. The angle the bond forces make with the bar axis was calculated and used for comparing bond behaviour of ribbed steel bar and GFRP bars in AAC concrete. The results showed that bond failure mode plays a significant role in the comparison of the average bond stress of the specimens at failure. In case of pull-out failure mode, specimens with ribbed steel bars showed a higher bond strength while specimens with GFRP bars showed a higher bond stress in case of splitting failure mode. Comparison of the bond stress-slip curves of ribbed steel bars and GFRP bars depicted that the constant bond stress region at the peak is much smaller in case of GFRP bars than ribbed steel bars indicating a basic bond mechanism difference in GFRP and ribbed steel bars.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.104-107
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• 2004

The crack widths of reinforced concrete flexural members are influenced by repetitive fatigue loadings. The bond stress-slip relation is necessary to estimate these crack widths realistically. The purpose of the present study is, therefore, to propose a realistic model for bond stress-slip relation under repeated loading. To this end, several series of tests were conducted to explore the bond-slip behavior under repeated loadings. Three different bond stress levels with various number of load cycles were considered in the tests. The present tests indicate that the bond strength and the slip at peak bond stress are not influenced much by repeated loading if bond failure does not occur. However, the values of loaded slip and residual slip increase with the increase of load cycles. The bond stress after repeated loading approaches the ultimate bond stress under monotonic loading and the increase of bond stress after repeated loading becomes sharper as the number of repeated loads increases. The bond stress-slip relation after repeated loading was derived as a function of residual slip, bond stress level, and the number of load cycles. The models for slip and residual slip were also derived from the present test data. The number of cycles to bond slip failure was derived on the basis of safe fatigue criterion, i.e. maximum slip criterion at ultimate bond stress.

• Steel and Composite Structures
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• v.38 no.5
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• pp.563-582
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• 2021

The present study experimentally and analytically investigated the push-out behaviour of H-shaped steel section embedded in ultrahigh-performance fibre-reinforced concrete (UHPFRC). The effect of significant parameters such as the concrete types, fibre content, embedded steel length, transverse reinforcement ratio and concrete cover on the bond stress, development of bond stress along the embedded length and failure mechanism has been reported. The test results show that the bond slip behaviour of steel-UHPFRC is different from the bond slip behaviour of steel-normal concrete and steel-high strength concrete. The bond-slip curves of steel-normal concrete and steel-high strength concrete exhibit brittle behaviour, and the bond strength decreases rapidly after reaching the peak load, with a residual bond strength of approximately one-half of the peak bond strength. The bond-slip curves of steel-UHPFRC show an obvious ductility, which exhibits a unique displacement pseudoplastic effect. The residual bond strength can still reach from 80% to 90% of the peak bond strength. Compared to steel-normal concrete, the transverse confinement of stirrups has a limited effect on the bond strength in the steel-UHPFRC substrate, but a higher stirrup ratio can improve cracking resistance. The experimental campaign quantifies the local bond stress development and finds that the strain distribution in steel follows an exponential rule along the steel embedded length. Based on the theory of mean bond and local bond stress, the present study proposes empirical approaches to predict the ultimate and residual bond resistance with satisfactory precision. The research findings serve to explain the interface bond mechanism between UHPFRC and steel, which is significant for the design of steel-UHPFRC composite structures and verify the feasibility of eliminating longitudinal rebars and stirrups by using UHPFRC in composite columns.

• Asia-Pacific Journal of Business
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• v.11 no.1
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• pp.45-60
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• 2020

Recently, ESG bond issuance has been gradually spreading to banks and non-financial private companies in Korea. However, the Korean ESG bond market is still in its infancy in terms of size, diversity and investor base compared to the global ESG bond market. In other words, ESG bonds are rapidly forming in the global market, but are still in the formation stage in the domestic market, and various policy and practical measures such as system, incentives, and infrastructure are needed to activate them. In this paper, we examine the domestic and international status of ESG bonds in relation to responsible investment. In addition, this paper explores specific measures to revitalize the domestic ESG bond market in four aspects: establishing ESG bond standards, procedures and regulations, increasing ESG bond investment demand, increasing ESG bond issuance, building market infrastructure and market efforts. This study is expected to contribute to the development of the domestic ESG bond market and responsible investment.

• The Journal of Asian Finance, Economics and Business
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• v.9 no.3
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• pp.181-193
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• 2022

This paper seeks to investigate major macroeconomic factors and bond yield interactions in Thai bond markets, with the goal of forecasting future bond yields. This study examines the best predictive yields for future bond yields at different maturities of 1-, 3-, 5-, 7-, and 10-years using time series data of economic indicators covering the period from 1998 to 2020. The empirical findings support the hypothesis that macroeconomic factors influence bond yield fluctuations. In terms of forecasting future bond yields, static predictions reveal that in most cases, the BVAR model offers the best predictivity of bond rates at various maturities. Furthermore, the BVAR model has the best performance in dynamic rolling-window, forecasting bond yields with various maturities for 2-, 4-, and 8-quarters. The findings of this study imply that the BVAR model forecasts future yields more accurately and consistently than other competitive models. Our research could help policymakers and investors predict bond yield changes, which could be important in macroeconomic policy development.

• Journal of the korean academy of Pediatric Dentistry
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• v.34 no.4
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• pp.560-568
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• 2007

This study was performed to compare the shear bond strength of primary enamel & dentin treated by AQ Bond $Plus^{TM}$ and G $Bond^{TM}$, recently developed 6th generation dentin bonding system, to that of Single $Bond^{TM}$ being widely used. Also by observing the resin tag under scanning electron microscope, Resin tags of each material were also observed under scanning electron microscope and compared to one another. The possibility of clinical application of All-in-One system which has an advantage to reduce chair-time for children with difficult behavior pattern was evaluated. The results obtained are as follows: 1. No statistically significant difference between groups was found in shear bond strength of primary enamel. 2. In primary dentin, the shear bond strength of AQ Bond $Plus^{TM}$ was $1.15\;{\pm}\;0.37\;MPa$, G $Bond^{TM}$ was $1.69\;{\pm}\;0.74\;MPa$ and Single $Bond^{TM}$ was $0.56\;{\pm}\;0.11\;MPa$. There were no statistical difference between AQ Bond $Plus^{TM}$ and G $Bond^{TM}$ and between G $Bond^{TM}$ and Single $Bond^{TM}$, whereas statistically significant difference was found between AQ Bond $Plus^{TM}$ and Single $Bond^{TM}$. 3. Under scanning electron microscope, resin tags observed in AQ Bond $Plus^{TM}$ and G $Bond^{TM}$ were very weak and tangled while strong and thick tags were shown with many lateral branches in Single $Bond^{TM}$. The result of the present study coupled with the advantages of less working time over the previous generation suggests that All-in-One system might be effectively used in adhesive dental procedures for primary teeth.

• Restorative Dentistry and Endodontics
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• v.45 no.3
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• pp.36.1-36.10
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• 2020

Objectives: This study aims to assess the effect of universal adhesives pretreatment on the bond strength of resin-modified glass ionomer cement to dentin. Materials and Methods: Fifty caries-free human third molars were employed. The teeth were randomly assigned into five groups (n = 10) based on dentin surface pretreatments: Single Bond Universal (3M Oral Care), Gluma Bond Universal (Heraeus Kulzer), Prime&Bond Elect (Dentsply), Cavity Conditioner (GC) and control (no surface treatment). After Fuji II LC (GC) was bonded to the dentin surfaces, the specimens were stored for 7 days at 37℃. The specimens were segmented into microspecimens, and the microspecimens were subjugated to microtensile bond strength testing (1.0 mm/min). The modes of failure analyzed using a stereomicroscope and scanning electron microscopy. Data were statistically analyzed with one-way analysis of variance and Duncan tests (p = 0.05). Results: The surface pretreatments with the universal adhesives and conditioner increased the bond strength of Fuji II LC to dentin (p < 0.05). Single Bond Universal and Gluma Bond Universal provided higher bond strength to Fuji II LC than Cavity Conditioner (p < 0.05). The bond strengths obtained from Prime&Bond Elect and Cavity Conditioner were not statistically different (p > 0.05). Conclusions: The universal adhesives and polyacrylic acid conditioner could increase the bond strength of resin-modified glass ionomer cement (RMGIC) to dentin. The use of universal adhesives before the application of RMGIC may be more beneficial in improving bond strength.

• Restorative Dentistry and Endodontics
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• v.21 no.1
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• pp.280-288
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• 1996

The purpose of this study was to assess comparatively the shear bond strength on dentin of four dentin bonding agents used in conjunction with light-curing composite resins. Clearfil New Bond, Scotchbond Multipurpose Dentin Adhesive, All-Bond 2 and X-R Bond were applicated on labial dentin surfaces just below dentin - enamel juction of bovine incisor teeth. After shear bond strength testing with the universal testing machine, the bonding interface of the specimens were observed under light stereomicroscope. Following results were obtained. 1. The shear bond strength was high in the order of B,C,D,A and group B Scotchbond Multipurpose Dentine Adhesive revealed greater bond strength than Clearfil New Bond and X-R Bond. (p<.001) 2. When using ANOVA and Duncan's multiple range test, there were statistical differences among the four groups, except between group Band C,group D and A. 3. There was no relationship between mode of failure and shear bond strength.

• Journal of the Korean Chemical Society
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• v.16 no.2
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• pp.59-63
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• 1972

In connection with two electron binding energy of each bond of saturated hydrocarbons, C-C bond fission and hydrogen abstraction from C-H bond are discussed by means of two center Huckel method. A beautiful correlation could be noticed between the observed bond dissociation energy and the calculated bond energy except for n-butane. Bond dissociation energies between C-C bond were also related to C-C bond fission. We could also find a very close relation between the relative easiness of hydrogen abstraction and the calculated binding energy of C-H bond. In other words, C-H bonds of tertiary hydrogen have been noticed as most weakely bonded and hence the tertiary hydrogen would most easily from the paraffins. In addition, the C-H binding energy is discussed applying ionic character of C-H bond which is derived from its dipole moment (0.4D)

• The Journal of Advanced Prosthodontics
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• v.5 no.3
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• pp.305-311
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• 2013

PURPOSE. Over the past years, the adhesion of fiber posts luted with simplified adhesive systems has been a matter of great interest. The aim of this study was to assess the post retentive potential of a self-adhesive resin cement using different adhesive systems to compare the push-out bond strengths of fiber posts. MATERIALS AND METHODS. The post spaces of 56 mandibular premolar roots were prepared and divided into 4 experimental groups and further divided into 2 subgroups according to testing time (n=7). The fiber posts (Rely X Fiber Post) were luted with a self-adhesive resin cement (RelyX Unicem) and one of the following adhesive systems: no adhesive, a total-etch adhesive resin (Single Bond), a two-step self-etch adhesive resin (Clearfil SE Bond) and a one-step self-etch adhesive resin (Clearfil S3 Bond). Each root was cut horizontally, and 1.5 mm thick six root segments were prepared. Push-out tests were performed after one week or three months (0.5 mm/min). Statistical analysis were performed with three-way ANOVA (${\alpha}$=.05). RESULTS. Cervical root segments showed higher bond strength values than middle segments. Adhesive application increased the bond strength. For one week group, the total-etch adhesive resin Single Bond showed higher bond strength than the self-adhesive resin cement RelyX Unicem applied without adhesive resin at middle region. For 3 months group, the two-step self-etch adhesive resin Clearfil SE Bond showed the highest bond strength for both regions. Regarding the time considered, Clearfil SE Bond 3 months group showed higher bond strength values than one week group. CONCLUSION. Using the adhesive resins in combination with the self-adhesive resin cement improves the bond strengths. The bond strength values of two-step self-etch adhesive resin Clearfil SE Bond improved as time passes.