• Elastomers and Composites
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• 제38권2호
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• pp.167-174
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• 2003

Thermoplastic vulcanizates (TPV) or dynamic vulcanizates are thermoplastic elastomers produced by simultaneous mixing and crosslinking of a rubber and a thermoplastic. The objective of the present work is to investigate the effects of different types of peroxides as curing agents on the properties of PP/EPDM TPVs. The mechanical properties change significantly with the chemical nature of the peroxides and the extent of crosslinking at a fixed PP/EPDM blend ratio. The tensile strength of the TPVs obtained with the various peroxides can be related to the solubility parameters of the polymers and of the peroxides. The Young's modulus of the peroxide-cured TPVs can be correlated with the delta torque values of equivalent thermoset EPDM vulcanizates, corresponding to the crosslinking efficiencies of the peroxides.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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• pp.193-196
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• 2004

The objective of in this study makes investigation into the characteristics of concrete as to properties and blended ratio of crushed aggregates through experimental researches. In this research observed crushed quality characteristic of crushed aggregates that is produced in representative stony mountains of Busan suburbs (Yang-san, Kim-hea, Jin-hea). And wished to investigate the quality change and characteristics of concrete with variation of blend ratio of crushed sand(50, 60, 70, 80, 90, $100\%$). Measured the air contents and slump to investigate properties of fresh concrete, and unit weight and compressive strength in age of 7, 28, 60, 90 days to investigate properties of hardened concrete.

• 한국의류학회지
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• 제34권3호
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• pp.448-458
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• 2010

Kenaf has a rigid and rough touch that inhibits the use of it as a textile material; therefore, this study developed a novel textile material using kenaf. Kenaf and cotton were blended in the ratio of 3:7 and manufactured as 20' spun yarn that was compared to 20's spun yarn made of 100% cotton. Both kenaf/cotton-blended and 100% cotton spun yarn were constructed as plain woven and knitted fabrics. Four kinds of fabrics were prepared as follows. Plain kenaf/cotton-woven fabrics, plain cotton-woven fabrics, kenaf/cotton jersey, and cotton jersey. A cellulase washing process was carried out to reduce the character of kenaf/cotton-blended fabrics, rigid, and rough touch. All fabrics were pretreated with NaOH. NaOH at the concentrations of 0, 0.25, 1.25, and 2.25mol/L, and cellulase at concentrations of 0, 1, 3 and 5g/L were used since the pretreatment of NaOH has a higher efficiency of weight loss than $Na_2CO_3,\;K2CO_3$ and Triton X-100. The ratio of weight loss, tensile strength, stiffness, drape property, and surface appearance were measured in order to evaluate the efficiency of the washing treatment on fabrics. Kenaf/cotton-blended fabrics exhibited more rigid and rough features than cotton fabrics. A cotton jersey showed significant differences in the degree of stiffness and drape properties. When all fabrics were treated with 1.25mol/L of NaOH and 3g/L of cellulase, kenaf/cotton-blended fabrics showed a higher retention ratio of tensile strength than cotton fabrics after washing despite the increased weight l08s of kenaf-blended fabrics compared to cotton fabrics. The ratio of weight loss for all fabrics was well correlated with flexibility. The washing treatment process made woven fabrics more flexible than knitted fabrics, because the stiffness of woven fabrics made the rubbing actions stronger. Kenaf/cotton-blended fabrics showed a significantly higher ratio of weight loss and more reduction in stiffness than cotton fabrics after the washing treatment. This might be due to the lack of cohesiveness and easy elimination from fabrics. The drape property of kenaf-blended fabrics was superior to cotton fabrics.

• 폴리머
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• 제25권5호
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• pp.707-718
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• 2001

폴리프로필렌 (PP)은 낮은 밀도, 우수한 내열성, 내화학성, 가공성과 더불어 재활용이 용이한 플라스틱이다. 하지만 폴리프로필렌의 발포에 대한 연구는 그리 많지 않다. 본 연구에서는 화학적 발포제를 사용하여 발포 폴리프로필렌을 만들고자 하였다. 폴리프로필렌의 가공온도에서 유동성과 발포체의 유연성을 높이기 위해 에틸렌/옥텐 공중합체 (mPE)를 폴리프로필렌에 용융 블렌드하였다. 발포에 앞서 발포체의 발포배율과 셀구조에 미치는 상분리 거동의 영향을 알기 위해 PP/mPE 블렌드 상분리 거동을 조사하였다. PP/mPE 블렌드의 강 거동은 블렌드 조성과 mixing torque ratio, 그리고 mixing rpm에 영향을 받았다. PP 기질에 mPE가 분산상으로 존재하는 블렌드를 발포시켰을 때 높은 배율과 안정한 셀 구조를 가지는 발포체를 얻을 수 있었다.

• Carbon letters
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• 제25권
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• pp.78-83
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• 2018

Pyrolyzed fuel oil (PFO) and coal tar was blended in the feedstock to produce pitch via thermal reaction. The blended feedstock and produced pitch were characterized to investigate the effect of the blending ratio. In the feedstock analysis, coal tar exhibited a distinct distribution in its boiling point related to the number of aromatic rings and showed higher Conradson carbon residue and aromaticity values of 26.6% and 0.67%, respectively, compared with PFO. The pitch yield changed with the blending ratio, while the softening point of the produced pitch was determined by the PFO ratio in the blends. On the other hand, the carbon yield increased with increasing coal tar ratio in the blends. This phenomenon indicated that the formation of aliphatic bridges in PFO may occur during the thermal reaction, resulting in an increased softening point. In addition, it was confirmed that the molecular weight distribution of the produced pitch was associated with the predominant feedstock in the blend.

• 대한기계학회논문집B
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• 제37권5호
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• pp.473-479
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• 2013

본 연구에서는 천연가스 70%, 수소 30%의 조성비를 가진 HCNG연료와 천연가스를 각각 대형천연가스엔진에 공급하여 실험을 수행하였다. 고압축비의 수소-천연가스(HCNG)엔진의 배기특성을 살펴보기 위하여 부분부하조건에서 공기과잉률 변화에 따른 각 연료의 배출가스를 분석하였다. 실험결과 압축비가 증가함에 따라 열효율이 향상되었으며 그로인해 $CO_2$ 배출량은 감소하였다. 낮은 배기가스온도에 의하여 산화가 활발히 이루어지 못해 CO의 배출량이 증가하였다. 동일한 공기과잉률에서 압축비가 증가하면 $NO_x$의 배출량이 증가하였다. 하지만 ${\lambda}$=1.9이상의 영역에서는 MBT 점화시기가 동일해지기 때문에 압축비의 영향을 받지 않았다.

• 대한기계학회논문집B
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• 제37권4호
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• pp.387-394
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• 2013

온실가스인 $CO_2$ 배출을 줄이기 위한 연료로서 고효율 연소의 특성을 갖는 수소-천연가스 혼합연료(HCNG)가 유력한 미래 대체연료로서 주목받고 있다. 일반적으로 엔진에서의 압축비 상승은 효율 향상 및 이산화탄소 배출 저감을 위한 방법 중의 하나로서 HCNG 엔진에서도 고압축비의 적용이 효과적일 수 있으나, 수소의 높은 연소 속도 및 화염 온도로 인한 조기착화, 노킹 등의 이상연소는 엔진 부품의 파손 및 출력 저하를 초래할 수 있다. 본 연구는 HCNG 엔진에서 압축비를 변경하여 엔진 성능 및 노킹 특성을 분석하는데 목적이 있다. 기존의 CNG 엔진에 CNG 및 HCNG 연료를 적용하여 공기과잉률의 변화에 따른 연소 특성을 분석하고, 압축비 변경 후 엔진의 성능에 미치는 영향을 파악하였다.

• 대한기계학회논문집B
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• 제27권11호
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• pp.1548-1562
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• 2003

This paper is the first of several companion papers which compare the methods of Air-fuel ratio determination. There are many methods which calculate Air-Fuel ratio from exhaust emission. Most of them are based on the simple chemical equations, which use balance of atom, and the error of the calculation is negligible as far as the instrumentation accuracy is guaranteed. They assume homogeneous mixture and complete combustion to the extent of oxygen availability. Because of these simple assumptions, they cannot offer the information about the fuel distribution state and the malfunction of instrument. For these limitations, Eltinge offered new one based on stricter mathematical model. This result coincides with the others very well and gives more information about the mixture state and instrumentation. Consequently this might be a general solution for Air-fuel ratio determination and exhaust composition. The objects of the calculation, however, were not commercial fuels except gasoline and the compensation method of unburned hydrocarbon was not appropriate to recent analyzer. Moreover he did not consider the fuel which contains oxygen, such as methanol, ethanol and blend of gasoline-alcohol. In this paper, Eltinge chart is expanded to the arbitrary fuel composition as the reference exhaust compositions for the purpose of further discussions about Air-fuel ratio determination methods and the charts fur gasoline, diesel, methanol, M85, liquefied petroleum gas(LPG), natural gas(NG), propane, butane are illustrated.

• 동력기계공학회지
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• 제19권3호
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• pp.16-21
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• 2015

Nitrous oxide($N_2O$) concentration in the atmosphere has been constantly increased by the human activities with industrial growth after the industrial revolution. One of factors to increase $N_2O$ concentration in the atmosphere is the $N_2O$ emission caused by the combustion of marine fuel. Especially, a sulfur component included in marine fuel oils is known as increasing the $N_2O$ formation in diesel combustion. Form this point of view, $N_2O$ emission from a ship is not negligible. On the other hand, Exhaust gas recirculation(EGR) that have thermal, chemical and dilution effect is effective method for reducing the NOx emission. In this study, an author investigated $N_2O$ reduction by using EGR on a direct injection diesel engine. The test engine was a 4-stroke diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of the engine was a fixed load of 75%. The experimental oil was a blend-fuel that were adjusted with sulfur ratio of 3.5%, and EGR ratio of 0%, 10%, 20% and 30%. In conclusion, diesel fuel that contained 3.5% sulfur component increased $SO_2$ emission in exhaust gas, and increment of EGR ratio reduced NO emission. Moreover, $N_2O$ emission was decreased as over 50% at EGR ratio of 10% and reduced 100% at EGR ratio of 30% compared with $N_2O$ emission of 0% EGR ratio.

• 한국건설순환자원학회논문집
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• 제6권1호
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• pp.25-35
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• 2018

본 연구에서는 카올린과 플라이애시의 두 종류의 결합재를 혼합하여 알칼리 활성화시킨 후, 경화체의 강도 및 미세구조 분석을 수행하였다. 이를 위해, 경화된 시험체에 대해 압축강도, X선 회절분석(XRD), 열중량(TG) 분석 및 SEM/EDS 분석을 실시하였다. 카올린-플라이애시 혼합 결합재는 카올린 혼합에 관계없이 모든 경화체에 대해서 재령에 따라 압축강도가 증가하는 경향을 나타냈으며, 플라이애시 중량에 대한 카올린의 혼합비가 증가할수록 압축강도는 낮아지는 것으로 나타났다. XRD 분석 결과에서는 제작된 모든 시험체에 대해서 플라이애시 및 카올린의 원재료에 함유된 구성광물 이외에 새로운 결정질 물질 형성은 확인되지 않았지만, 이에 반해 TG 분석에서는 모든 시험체 내에서 N-A-S-H gel이 반응생성물로 형성된 것을 알 수 있었다. 모든 시험체들의 내부는 대체적으로 치밀하지 않은 것으로 나타났으며, 카올린 치환율에 따른 강도 발현의 차이가 있음에도 불구하고, 내부의 조직구조에서 뚜렷한 차이는 없는 것으로 나타났다. 본 연구에서 보여준 반응생성물의 Si/Al가 낮을수록 시험체의 강도가 상대적으로 높은, Si/Al와 강도와의 상관관계에 따라, 반응생성물의 Si/Al가 낮도록, 즉 사용되는 결합재의 $Al_2O_3$의 용해도를 높일 수 있는 화학적 첨가제가 고려된다면, 카올린-플라이애시 혼합 결합재의 강도 개선 효과를 기대할 수 있을 것으로 판단된다.