• Title/Summary/Keyword: Bleached

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Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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Effect of Fluoride Treatment after Bleaching with Hydrogen Peroxide exposed to Plasma Arc (고농도 과산화수소와 플라즈마 아크를 이용한 미백 치료에 있어서 불소의 효과)

  • Chung, Sun-Young;Lee, Young-Eun;Ahn, Sang-Hun;Yang, Hae-Young;Jeon, Eun-Suk;Choi, Youn-Hee;Song, Keun-Bae
    • Journal of dental hygiene science
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    • v.11 no.4
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    • pp.375-380
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    • 2011
  • This study evaluated whether fluoride treatment can affect recovery of the irregularity of enamel surface after tooth whitening with a high concentration of hydrogen peroxide (HP) activated by plasma arc light. A total of 36 bovine teeth stained with coke were used in this experiment. The specimens were classified into following three groups (two different commercial plasma arc groups and a control group without light curing source): (1) 35% HP gel only, (2): 35% HP gel and Plasma arc A, and (3) 35% HP gel and Plasma arc B. To measure color changes and surface morphologies before and after the bleaching, colorimeter and scanning electron microscopy were used, respectively. When the specimens were bleached with hydrogen peroxide and plasma arc lights, the bleaching effect was greater than when only hydrogen peroxide gels were used (Kruskal-Wallis test, p<0.05). In addition, plasma arc B showed the more color changes than plasma arc A (Bonferroni post-hoc test, p<0.05). The surfaces of the teeth treated with fluoride gel after the whitening treatment came to be smooth. Therefore, the results of this study suggested that the fluoride application for patients who got tooth whitening therapy with a high concentration of hydrogen peroxide gels activated by plasma arc light will be effective to recover rough enamel surfaces.

Bleachability of Hemp Bast Fiber by Chlorine Dioxide (이산화염소 표백조건에 따른 삼 인피섬유의 표백효과)

  • Kim, Jun-Kyu;Choi, Kyoung-Hwa;Seo, Jin-Ho;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.109-114
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    • 2015
  • In this study, the effects of chlorine dioxide (D) bleaching conditions on the delignification of hemp bast fiber were elucidated. Chlorine dioxide bleaching was carried out through three stages (DED) and five stages (DEDED), respectively. Applied amounts of chlorine dioxide at $D_1$ and $D_2$ stages were varied to find the optimum bleaching condition. It was found that the optical properties of its handsheet as well as the delignification of hemp bast fiber increased as the concentration of chlorine dioxide at $D_1$ stage increased. It was also notable that the bleachability of the DEDED bleaching stages was slightly more effective than that of the DED bleaching stages. The burst index of the handsheets made with bleached hemp bast fiber was higher than that of the unbleached samples, but the burst index of these samples decreased as their delignification increased. These results indicated that the higher concentration of chlorine dioxide at $D_1$ stage was major factor to improve the bleaching efficiency of hemp bast fiber.

Fold Cracking of High Grammage Coated Paper Depending on Pulp Composition and Structure of Base Paper (도공원지의 원료 조성 및 구조에 따른 고평량 도공지의 접힘 터짐)

  • Sim, Kyujeong;Youn, Hye Jung;Oh, Kyudeok;Lee, Hak Lae;Yeu, Seung Uk;Lee, Yong Min
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.38-45
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    • 2015
  • Fold cracking is one of quality troubles of coated papers. In this study, the fold cracking of high grammage ($250g/m^2$) coated paper made with the different pulp composition and layer structure of base paper was investigated. The single layered, high grammage base paper was prepared by mixing of hardwood and softwood bleached kraft pulp fibers with the different ratios. The high grammage coated paper showed the higher fold cracking than low grammage coated paper because of the increase in thickness. The increase in the content of softwood pulp fibers reduced the fold cracking in the case of high grammage coated paper. When the creasing process was conducted before folding process, the fold cracking of coated paper decreased. By manufacturing the base paper with multiply structure, the fold cracking of coated paper could be reduced significantly, especially when the BCTMP and OCC were used as a middle layer and the creasing process was carried out. The delamination of layers in base paper affected the fold cracking positively.

Effects of Oil Refining Processes on Oxidative Stability and Antioxidative Substances of Sesame Oil (정제공정이 참기름의 항산화 물질과 산화 안정성에 미치는 영향)

  • Han, Jin-Suk;Moon, Soo-Yeun;Ahn, Seung-Yo
    • Korean Journal of Food Science and Technology
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    • v.29 no.1
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    • pp.15-20
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    • 1997
  • Changes in antioxidative substances-sesamol, sesamin and sesamolin - and mineral contents of sesame oil during refining processes have been studied to investigate the oxidative stability of oils during the storage at $70^{\circ}C$. Fe, Cu, Mg and Zn were nearly removed from the oil by the degumming process. During storage, the changes of total volatile contents in crude and degummed sesame oil were not noticeable but those in alkali-refined and deodorized sesame oil were increased at early period of the storage. The increases of hexanal and pentanal were most noticeable and their concentration was increased markedly in alkali-refined, bleached and deodorized sesame oil at early period of the storage. During refining processes and storage, sesamin was relatively stable but the content of sesamolin was decreased. The content of sesamol was decreased until alkali-refining process but increased during a bleaching process. The content of sesamolin tended to decrease with increasing of sesamol during storage.

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Changes of BCTMP Fibers and Handsheets Properties by the Treatment of LB DES at Different Molar Ratios (상이한 몰 비율의 LB 공융용매 처리에 따른 BCTMP 섬유 및 수초지 특성의 변화)

  • Choi, Kyoung-Hwa;Nam, Yun-Seok;Lee, Myoung-Ku;Ryu, Jeong-Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.75-81
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    • 2016
  • This study was conducted to investigate the effects of deep eutectic solvent (DES) treatment on BCTMP fibers and handsheets properties. DES was prepared using lactic acid and betaine (LB), and the molar ratio of these two components mixtures was controlled to 2:1 (LB 2:1) and 5:1 (LB 5:1). As results, 2% of BCTMP pulp (o.d. weight) was extracted when it was treated by LB 5:1 at $50^{\circ}C$ for 12 hours, stirring constantly at 120 rpm. In contrast, lignin was not extracted when BCTMP was mildly treated by the LB DES mixed with 50% of distilled water at the reacting condition of temperature $60^{\circ}C$ for 2 hours using water bath. These results indicate that conditioned water content and adequate reaction time are needed to achieve effective extraction of lignin. It was also found that stiffening of cellulose fiber due to the mild treatment of LB DES to BCTMP fiber leads to the increase of paper bulk without the loss of strength.

Modeling and Optimizing Brightness Development in Peroxide Bleaching of Thermomechanical Pulp

  • Wang, Li-Jun;Park, Kyoung-Hwa;Yoon, Byung-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.5
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    • pp.86-94
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    • 1999
  • Alkaline peroxide bleaching of chemi-mechanical pulp is a very complicated system where various process factors affect the bleacing performance and pulp properties. Traditional onefactor-at a time method is ineffective and costly infinding the optimal bleaching conditions. In this study, statistical experimental design and multiple regression method wre used to investigated the interactions among various bleaching factors and to find out the possbile maximal brightness development during one stage alkaline peroxide bleacing of TMP. The TMP was made from 10% Korean red pine and 90% Korean spruce and had an initial brightness of 54.5% ISO. the TMP was pretreated with EDTA(0.5% on O.D. pulp, 3% pulp consistency, 30$^{\circ}C$ for 60 minutes) and bleached in a 2 L Mark V Quantum Reactor at 750 rmp, 7.5% of bleaching consistency and with 0.05% magnesium sulfate addition. The ranges of chemical factors studied , based on oven-ried pulp, were 1-5% for hydrogen peroxide, 1-4% for sodium hydroxide and 1-4% for sodium silicate. The rages of reaction temperature and time were 50-90$^{\circ}C$ and 40-180minutes respectively. Interactions of hydrogen peroxide with alkali , time with temperature ature, alkali with time and silicate with temperature were found to be significant which means that hydrogen peroxide bleaching will be favored at stable concentration of perhydroxyl ion, relatively short time and low temperature, and high level of silicate. Mathematical model which has good predictability for target brightness in one stage peroxide bleaching can also be established easily. Base ion the model, maximal brightness of 70% ISO was found to at 50$^{\circ}C$ and 50 minutes by chemical additions of 5% for hydrogen peroxide, 3.2-3.4% for sodium hydroxide and 4% for silicate based on O.D. pulp. However, this result might not be suitable for situation where furnishes are different from ours, or different pretreatment is used, or bleaching carried out at different pulp consistency. In these cases it will be good to re-investigate the process by a similar methodology as was used in this study.

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Antibacterial Function of Fabrics Dyed with Extract from Chamaecyparis obtusa Leaves against Methicillin-resistant Staphylococcus aureus (편백나무 잎 추출액을 이용한 천연염색포의 항생제 내성균주에 대한 항균성)

  • Choi, Na Young;Kim, Ji-Hee
    • Fashion & Textile Research Journal
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    • v.19 no.3
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    • pp.331-336
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    • 2017
  • Bacteria exist everywhere and continuously come into contact with daily surroundings and humans. Super bacterium methicillin-resistant Staphylococcus aureus, resistant to methicillin, has recently appeared. The morbidity and rate of death associated with super bacteria infection has increased. This study investigated the antibacterial activity of fabrics naturally dyed with Chamaecyparis obtusa leaves extract against methicillin-resistant Staphylococcus aureus. Fabrics were left for 15 min in a natural dyeing solution prepared by extraction from C. obtusa leaves using 11.3% (o.w.f) with a fixed liquor ratio of 1:22 at $40^{\circ}C$. The dyeing process was conducted using three different mordants; subsequently, the K/S value of the dyed fabrics increased in the order of None < Cu < Fe < Al. The color fastness property of the fabrics to washing, dry-cleaning, and rubbing was found to be excellent and ranked in the 4-5 grade. The color fastness to light of natural dyeing is low in most cases and has the problem that the dye color soon becomes bleached. Yet, in most cases cloth dyed with retinispora leaves, the color fastnezz to light was good with a third to fourth grade. Non-mordant fabrics, aluminum mordants, and copper mordants also showed better antibacterial properties (99.9% reduction) against methicillin-resistant Staphylococcus aureus, compared to the control fabrics. The dyed fabrics showed the same antibacterial activity even after three washes. The results highlight the strong potential of fabrics naturally dyed with C. obtusa-extract as a medicinal material with excellent antibacterial function against methicillin-resistant Staphylococcus aureus.

Evaluation on the Lightning Breakdown Voltages of Palm Oil and Coconut Oil under Non-Uniform Field at Small Gap Distances

  • Thien, Yee Von;Azis, Norhafiz;Jasni, Jasronita;Kadir, Mohd Zainal Abidin Ab;Yunus, Robiah;Ishak, Mohd Taufiq;Yaakub, Zaini
    • Journal of Electrical Engineering and Technology
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    • v.11 no.1
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    • pp.184-191
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    • 2016
  • In recent years, there are a number of studies that have been carried out to explore the alternative for Mineral Oil (MO) as dielectric insulating fluid in transformers due to the increasing tight regulation on safety and environment. Vegetable oils have been identified as suitable candidate since it is biodegradable, non-toxic and high flash/fire points which ensure more in-service safety. Among the types of vegetable oils considered for transformers application are Palm Oil (PO) and Coconut Oil (CO). This paper presents an experimental study on the lightning breakdown voltages of PO and CO under non-uniform electric field based on needle-sphere electrodes configuration at 3 small gap distances. The type of PO used in this study is Refined Bleached and Deodorized Palm Oil (RBDPO) Olein. The main focus of this study is to examine the lightning breakdown performance of RBDPO and CO under different test conditions and assess its suitability as dielectric insulating fluid in transformers. The effect of voltage polarities (positive and negative) and testing methods (rising-voltage, up-and-down and multiple-voltage) were investigated. The data obtained from all tests were analysed by Weibull distribution in order to determine the withstand voltages for each type of oils. It was found that the breakdown voltages of RBDPO and CO are comparable with MO under positive lightning impulse. Under negative lightning impulse, the breakdown voltage of MO is slightly higher than RBDPO and CO. There is no significant effect of testing methods and voltage polarities on lightning breakdown voltages of RBDPO and CO. Based on the statistical analysis, it is found that the breakdown voltages of RBDPO and CO at 1% probability are slightly lower than MO.

Bleaching of Kraft Pulp with Lignin - Degrading Enzymes

  • Harazono, Koich;Kondo, Ryuichrto;Sakai, Kokki
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.2
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    • pp.83-90
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    • 1997
  • An unbleached hardwood kraft pulp was bleached in vitro with partially purified manganese peroxidase (MnP) from the fungus Phanerochaete sordida YK-624 without the addition of MnSO$_4$ in the presence of oxalate, malonate or gluconate known as manganese chelator, When the pulp was treated without the addition of MnSO$_4$, the pulp brightness increased by about 10 points in the presence of 2 mM oxalate, but the brightness did not significantly increase in the presence of 50 mM malonate. Residual MnP activity decreased faster during the bleaching with MnP without MnSO$_4$ in the presence of malonate than in the presence of oxalate. Oxalate reduced MnO$_2$ which already existed in the pulp or was produced from $Mn^{2+}$ by oxidation with MnP and thus supplied $Mn^{2+}$ to the MnP system. Thus, bleaching of hardwood kraft pulp with MnP, using manganese originally existing in the pulp, became possible in the presence of oxalate, a good manganese chelator and reducing reagent. Properties of partially purified MnPs from liquid cultures of white rot fungi, Ganoderma sp. YK-505, Phanerochaete sordida YK-624 and Phanerochaete chrysosporium were compared. MnP from Ganoderma sp. YK-505 was superior to MnPs from P. sordida YK-624 and P. chrysosporium in stabilities against high temperature and high concentration of $H_2O$$_2$. The MnP from Ganoderma sp. YK-505 differed in pH-activity profile from other MnPs. These data suggest that MnP from Ganoderma sp. YK-505 has different structure from those of other fungi. Bleaching of hardwood kraft pulp using the MnP from ganoderma sp. YK-505 is now in progress.

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