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Determination of nickel and cadmium in fish, canned tuna, black tea, and human urine samples after extraction by a novel quinoline thioacetamide functionalized magnetite/graphene oxide nanocomposite

  • Naghibzadeh, Leila;Manoochehri, Mahboobeh
    • Carbon letters
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    • v.26
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    • pp.43-50
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    • 2018
  • In this research, a novel and efficient quinoline thioacetamide functionalized magnetic graphene oxide composite ($GO@Fe_3O_4@QTA$) was synthesized and utilized for dispersive magnetic solid phase preconcentration of Cd(II) and Ni(II) ions in urine and various food samples. A number of diverse methods were employed for characterization of the new nanosorbent. The design of experiments approach and response surface methodology were applied to monitor and find the parameters that affect the extraction performance. After sorption and elution steps, the concentrations of target analytes were measured by employing FAAS. The highest extraction performance was achieved under the following experimental conditions: pH, 5.8; sorption time, 6.0 min; $GO@Fe_3O_4@QTA$ amount, 17 mg; 2.4 mL $1.1mol\;L^{-l}$ $HNO_3$ solution as the eluent and elution time, 13.0 min. The detection limit is 0.02 and $0.2ng\;mL^{-1}$ for Cd(II), and Ni(II) ions, respectively. The accuracy of the new method was investigated by analyzing two certified reference materials (sea food mix, Seronorm LOT NO 2525 urine powder). The interfering study revealed that there are no interferences from commonly occurring ions on the extractability of target ions. Finally, the new method was satisfactorily employed for rapid extraction and determination of target ions in urine and various food samples.

A Study of Tradition Formation and Characteristic of Korean Ottchil Painting (한국 칠화(漆畵)의 전통 형성과 특징 연구)

  • Lim, Seung Taek
    • Journal of the Korea Furniture Society
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    • v.26 no.1
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    • pp.31-50
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    • 2015
  • This study analyzes traditional form and figurative characteristics of Ottchil Painting based on objective relics about long lasted Ottchil Painting and related literature as our country's national culture. Study range is among Lolang (Nangnang), Three Kingdom Dynastys (Koguryo, Baekje and Shilla), Unified Shilla Dynasty, Koryo Dynasty, Joseon Dynasty, Modern times and Contemporary. The method of study is after theoretical consideration of Ottchil Painting through related literature, adduced figurative characteristics of related Ottchil Painting by time period with case-study methods such as excavated relics and historical basis. Ottchil Painting consists of color, which is derived from Ottchil mixed with a mineral pigment of powder and various patterns and drawings using different techniques. The methods of Ottchil Painting are Myohoi, Yanggam, Gakhoik, Younma, Balsoa and Toiso. The techniques of Ottchil Painting of our country is established by splendid and unique for about 1,600 years revolved around Myochilchaehoi technique and Myoyuchaehoi technique started at Unified Shill a Daynasty and through Koryo, Joseon Dynasty, Modern times and Contemporary. Also, such this Ottchil Painting form of red in the inside and black in the outside, which is wood based, the rest is bamboo sheath and framework from Geonchil based and the figurative characteristics presented the traditional Patterns of Lotus, Phoenix, arabesque, bird, animal, cloud, marble and letter with red Ottchil, yellow Ottchil, or five colors Ottchil.

Electromagnetic-wave Shielding by Nano Particles-contained Glass Fiber Reinforced Composite Materials (나노입자 첨가 유리섬유강화 복합재료의 전자기파 차폐특성)

  • 정우균;안성훈;원명식
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1331-1334
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    • 2004
  • The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties or from structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites), was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz~12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test showed little shielding effect.

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The Effect of Additive to Corrosion Resistance of Heavy Anti-Corrosive Paint (중방식 도료의 내식성에 미치는 첨가제의 영향)

  • Moon, Kyung-Man;Cho, Hwang-Rae;Lee, Myung-Hoon;Kim, Hyun-Myung;Lee, In-Won;Chun, Ho-Hwan
    • Journal of Ocean Engineering and Technology
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    • v.21 no.3 s.76
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    • pp.65-70
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    • 2007
  • There are many kinds of protection methods for marine structures, with varyingeconomical and environmental advantages. The coating protection method is being widely used in both continental and marine structures. In this study, by adding some additives, such as Zn powder(Zn), carbon black(CB) to epoxy anti-corrosive paint, the effect on the corrosion resistance was investigated throughan electrochemical method. The additive of Zn(20)+CB(10) showed the lowest passivity current density. Polarization resistance in both cyclic voltammogram and impedance measurement of an additive of Zn(20)+CB(10) was also the largest value, compared to other additives. Furthermore, rusting and bubbling was not observed on the surface of the test specimen with the additive of Zn(20)+CB(10), compared to other specimens. It is suggested that the corrosion resistance of the anti-corrosive paint can be improved by using some additives.

Comparative Study of Make-up and Hair Styling Cultures of the King Jeongjo and the Edo Period (정조시대와 에도시대(江戶時代)의 화장문화(化粧文化)와 수발문화(鬚髮文化)의 비교 연구)

  • Kim, Min-Kyung
    • Korean Journal of Human Ecology
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    • v.18 no.1
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    • pp.189-200
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    • 2009
  • In the Edo period speaking of hair culture, common women wore decorative pigtail ribbons on the right, and twisted from side to side their tressed hair in such a manner as ungeunmeori and traemeori. Instead of gachae, common women used gogae made of their own hair, ungeunmeori on forehead, or jjokjinmeori at the back of head. During the Edo period, people women naturally exposed their necklines as a way of exposing their faces in the aesthetically ceremonial act of wearing make-up. As for lipsticks, they rouged extracts from red petals of safflowers mainly on their lips, and sometimes on their cheeks by blending this with white powder. Samurai families disliked women who wore thick lip makeup. In the latter period, women painted their necklines or foreheads black, applied a small amount of rouge on their cheeks thinly or thickly, and colored a reddish color into their fingernails by using petals and leaves of balsam flowers. Despite the chronological and spatial proximity of the King Jeongjo period and the Edo period, it was found that there were no similarities between two countries' cosmetic cultures. Moreover, it was discovered that current TV dramas were being produced, even not based on historical evidence in the Jeongjo period.

A study on the Polymer surface treatment of GF-filter bag for collection of fine Particle like carbon black (카본블랙류 미세입자 포집을 위한 유리섬유 필터백의 고분자 표면처리에 관한 연구)

  • Lee, B.;Choi, H.L.;Moon, C.K.
    • Journal of Power System Engineering
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    • v.12 no.3
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    • pp.55-59
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    • 2008
  • In this paper, we have investigated on collection efficiency of fine particle of glass fiber-filter bag according to the surface treatment. The solution consisted of polytetrafluoroethylene(teflon), graphite powder, silicon resin and water was used as a basic surface treatment agent. Tensile strength of glass filter-bag increased with up to 3hrs and then decreased with surface treatment time. Tensile strength and initial modulus of the glass fiber-filter bag treated by iodine after basic surface treatment for 3hrs were lower than those of basic surface treatment for 3hrs, however collection efficiency and fracture strain were higher than those of basic surface treatment for 3hrs. Glass fiber-filter bag with lower initial modulus and more strain will be extend the durable period and the one treated by iodine after basic surface treatment 3or 3hrs is expected high collection efficiency of fine particle. This method makes it possible to manufacture glass fiber-filter bag of the optimum condition.

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Studies on Quality Evaluation of Pepper(Piper nigrum L.) (후추의 품질평가에 관한 연구)

  • Park, Wan-Kyu;Yoon, Jong-Hoon;Choi, Chun-Un
    • Korean Journal of Food Science and Technology
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    • v.23 no.1
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    • pp.15-18
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    • 1991
  • Physical and chemical qualifies of 13 kinds of pepper imported from South-East Asian countries and Brazil were investigated. These included length and weight of berry, and color of the powder, and the contents of light berry, acid insoluble ash, piperine and volatile oil. While physical qualities of Sarawak special, Sarawak brown and Indian TGEB were the best(berries were larger and weightier, and the content of light berry was lower), those of Lampong ASTA and Lampong FAQ were relatively not good. In the other hand, chemical qualifies of Lampong ASTA, Lampong FAO and Indian TGEB were the best. In terms of color, all the samples were almost similar but that of Sarawak peppers were slightly lighter than the others.

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Characteristics on the forms of the Eye Brow over the Ages - Focusing on the western women - (서구 여성의 시대적 변천에 따른 눈썹형태의 특징)

  • Lee Sang-Eun;Shin Ji-Hyun
    • Journal of the Korea Fashion and Costume Design Association
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    • v.7 no.1
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    • pp.77-84
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    • 2005
  • The purpose of this study is to know on the changes characteristics of eye brow forms of the wester women. A facial image which people recognize contents on changes of image according to various eye brow changes on the face. Various changes of image were seen by length, angle and thickness of eye brow types. The ancient Egyptians used antimony powder to blacken their brows huge black lines. In medieval times, women shaved both their eye brows and their hairlines to give a pure look. The early nineteenth century, brows were untweezed and natural. In the 1920s, when women started paying attention to their faces and their freedom, brows were tweezed, narrowed. In the 1930s, the idealized faces of Jean Harlow, Marlene Dietrich and Greta Garbo - narrow tracery of drawn on brows. The eyebrows is filled various shape of the 1950s. In the 1970s, the Disco Decade of Dreadful tastes, women were at their tweezers again, manicuring their brows. Brooke Shields's natural-looking brow would be an example of the 1980s. In the 1990s, the eyebrow designed by superstar makeup artists who determined the look of fashion model and screen star.

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Catalytic oxidation kinetics of iron-containing carbon particles generated from diesel-sprayed hydrogen-air diffusion flame (디젤-분무 수소-공기 확산화염에서 생성된 철-함유 탄소입자의 촉매 산화반응 특성)

  • Kim, Yongho;Kim, Yong-Tae;Kim, Soo Hyung;Lee, Donggeun
    • Particle and aerosol research
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    • v.4 no.2
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    • pp.51-67
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    • 2008
  • In this study, we devoted to kinetic measurement of the catalytic oxidation of iron-containing flame soot particles and better understanding the role of catalytic particles on carbon oxidation in particular at low temperature, targeting on autothermal regeneration of diesel particulate filter by diesel exhaust gas. Carbon-based Fe-containing particles generated by spraying ferrocene-doped diesel fuel in an oxy-hydrogen flame are tested and compared with a commercial carbon black powder for thermogravimetric analysis (TGA), secondary ion mass spectrometry (SIMS), Fourier-transform infrared spectroscopy (FTIR), Induced coupled plasma-Atomic emission spectroscopy (ICP-AES), and High-resolution transmission electron microscopy (HR-TEM). As a result, we found that a small amount of the ferrocene addition led to significant reductions in a on-set temperature and an activation energy of the carbon oxidation as well. An oxygenated surface complex forming at the particle surface could be thought as active species that would be readily consumed in particular at low temperature.

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The Study on Dress through Rehabilitation (실물제작을 통한 의상 연구)

  • 김문숙
    • Journal of the Korean Society of Costume
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    • v.29
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    • pp.117-126
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    • 1996
  • As the current stage of the fashion begins to follow the styles of the past the study on the past costume is getting more importance and as the methodolgy of the study the accu-rately approached study through the rehabili-tation of the past cosume is more needed than the simple rearrangement of the historical documents. By this methodology this study can be positioned as a re-creation activity. The results of the study are as follows. 1) Style: The general silhouette is the style to emphasize the waist and to widen skirt at the lower part of the body. The front shows hourglass silhouette but the side shows S-line silhouette. The dress is two-piece composed of bodice and skirt. 2) Color and Fabric: The main color is dull powder blue end the sub color is ivory. The dress is made of wool crepe and cotton and partly silk crepe satin and taffeta. 3) Pattern and sewing: The dress is combined with lining and fabrics, The patterns. or overbodice. The skirt is gored skirt. The skirt is gored skirt. The dress has various effect not only to decorate but also to conceal seams support hemlines nd affect the depth and length of front panel. 4) Datail: The braid black velvet ribbon frill and tucks in bodice skirt sleeves front panel collar cuffs are repeatedly used to dec-orate the dress. Finally the 1902-3 day dress has the characteristics of transitional stag in which the chatacteristics of the costume of 1900s and the remnants of the characteristics of the pre-vious costume style and shows the charac-teristics of day dress well in terms of the style color and fabric pattern and sewing and detail.

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