• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1034-1042
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• 2012

This study was performed by using an LFR (laminar flow reactor), which can be used to carry out different types of research on coal. In this study, an LFR was used to analyze coal flames, tar and soot yields, and structures of chars for two coals depending on their volatile content. The results show that the volatile content and oxygen concentration have a significant effect on the length and width of the soot cloud and that the length and width of the cloud under combustion conditions are less than those under a pyrolysis atmosphere. At sampling heights until 50 mm, the tar and soot yields of Berau (sub-bituminous) coal, which contains a large amount of volatile matter, are less than those of Glencore A.P. (bituminous) coal because tar is oxidized by the intrinsic oxygen component of coal and by radicals such as OH-. On the other hand, at sampling heights above 50 mm, the tar and soot yields of Berau coal are higher than those of Glencore A.P. coal by reacted residual volatile matter, tar and light gas in char and flame. With above results, it is confirmed that the volatile matter content and the intrinsic oxygen component in a coal are significant parameters for length and width of the soot cloud and yields of the soot. In addition, the B.E.T. results and the images of samples (SEM) obtained from the particle separation system of the sampling probe support the above results pertaining to the yields; the results also confirm the pore development on the char surface caused by devolatilization.

• Korean Journal of Soil Science and Fertilizer
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• v.25 no.3
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• pp.249-254
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• 1992

This research was conducted to investigate the effects of fly ash applications on growth and yield parameters of corn (Zea mays L.), and soil chemical properties. Corn height at silking stage, and height and dry matter ratio at harvesting stage were enhanced by applications of fly ashes derived from bituminous coal and anthracite, respectively. Effects of fly ash treatment on growth parameters of corn were varied with kinds and levels of fly ash application and growth periods, but relatively small without revealing a major negative effect as compared to the control. Yield of corn was increased by applying fly ash of anthracite origin, but other yield components were not influenced negatively by fly ash treatment. Soil total carbon contents, cation exchange capacity, and phosphorus contents of soils sampled after harvest of corn were significantly increased by fly ash treatment, although there were slightly different effects according to kinds and levels of fly ash application. Exchangeable cations of soils were varied within an experimental error range. Phosphorus taken up by corn was enhanced by treating fly ash of the bituminous coal to the soil and there were a positive correlation between phosphorus uptake and soil Phosphorus level. Cation uptake by corn was changed a little, but no significant reduction was observed in cation uptake due to fly ash treatment. It seems to be difficult to figure out the mechanism of fly ash effects on growth and nutrient uptake by corn with one year field experiment, however treatment of fly ash enhanced some parameters of growth and yield, and nutrient uptake by corn without revealing any major negative effects. To determine the value of fly ash as a fertilizer source, continuous researches under various soil and crop conditions were considered to be necessary.

• Korean Chemical Engineering Research
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• v.49 no.3
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• pp.372-380
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• 2011

Char gasification is affected by operating conditions such as reaction temperature, reactants gas partial pressure, total system pressure and particle size in addition to chemical composition and physical structure of char. The aim of the present work was to characterize the effect of coal particle size on $CO_{2}$ gasification of chars prepared from two different types of bituminous coals at different reaction temperatures(1,000-$1,400{^{\circ}C}$). Lab scale experiments were carried out at atmospheric pressure in a fixed reactor where heat was supplied into a sample of char particles. When a flow of $CO_{2}$(40 vol%) was delivered into the reactor, the char reacted with $CO_{2}$ and was transformed into CO. Carbon conversion of the char was measured using a real time gas analyzer having NDIR CO/$CO_{2}$ sensor. The results showed that the gasification reactivity increased as the particle size decreased for a given temperature. The sensitivity of the reactivity to particle size became higher as the temperature increases. The size effects became remarkably prominent at higher temperatures and became a little prominent for lower reactivity coal. The particle size and coal type also affected reaction models. The shrinking core model described better for lower reactivity coal, whereas the volume reaction model described better for higher reactivity coal.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.2
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• pp.75-84
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• 2018

In this study, the analysis of torrefaction products was carried out for fueling of sewage sludge. The mixed samples were composed as follows : 50% of sewage sludge and 50% of rice husk and CR(Coffee Residue). In this experiment, the reaction time(30min, 60min) and temperature($200^{\circ}C$, $250^{\circ}C$, $300^{\circ}C$) were expressed as a single variable using SF(Severity Factor). As a result, it was confirmed that as the SF increased, the heating value and fuel ratio increased, but the CI(Combustibility Index) decreased. The heating value was similarly increased as CR(Coffee Residue) and SF increased. The fuel ratio range of mixed samples was equal to that of lignite(0.5~1.0) in case of SF lower than 6.19 and that of bituminous coal(1.0~1.8) in case of SF higher than 7.36 or above. The CI showed a stable range(3,000~5,500kcal/kg) in low SF as the content of mixed samples contained more rice husk than CR.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.1
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• pp.24-34
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• 2015

Domestic companies supplying electricity must increase obligatory duty to use renewable energy annually. If not met with obligatory allotment, the electricity-supply companies must pay RPS (Renewable Portfolio Standards) penalty. Although the power plants using a pulverizing coal firing boiler could co-fire up to around 3 per cent with wood pellets mixed in with coal feedstock without any major equipment revamps, they recorded only about 60 per cent fulfillment of RPS. Consequently, USD 46 million of RPS penalty was imposed on the six power supplying subsidiaries of GENCOs in 2014. One of the solutions to reduce the RPS penalty is that the power supply companies adopt the co-firing of torrefied lignocellulosic biomass in coal plants, which may contribute to the use of over 30 per cent of torrefied biomass mixed with bituminous coals. Extra binder was required to form pellets using torrefied biomass such as wood chips, PKS (Palm Kernel Shell) and EFB (Empty Fruit Bunch). Instead of corn starch, 30, 50 and 70 per cent of Larix saw dusts were respectively added to the torrefied feedstocks such as Pinus densiflora chips, PKS and EFB. The addition of saw dusts led to the decrease of the calorific values of the pellets but the forming ability of the pelletizer was exceedingly improved. Another advantage from the addition of saw dusts stemmed from the reduction of ash contents of the pellets. Finally, it was confirmed that torrefied oil palm biomass such as PKS and EFB could be valuable feedstocks in making pellets through improved binding ability.

• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.147-163
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• 2015

Chemical and mineralogical properties of coal ash samples from the nine thermal power plants of Korea were investigated to acquire basic data for estimating the potential of rare metal recovery. Chemical compositions of coal ash were consistent with those of average shale and foreign coal ashes. However, there were small differences between the metal contents of domestic anthracitic and imported bituminous coal ashes. Unburned coal particles were much abundant in the ash of domestic anthracitic coal. Chalcophile elements were relatively enriched in the fly ash compared to bottom ash. Silicate glass was the major component of coal ash with minor minerals such as quartz, illite (muscovite), mullite, magnetite, lime, and anhydrite. Al and Si were the major components of the glass with varying contents of Ca, Fe, K, and Mg. Glass occurred in a form of porous sphere and irregular pumace-like grain often fused with iron oxide spheres or other glass grains. Iron oxide spheres were fine intergrowth of fast-grown iron oxide crystals in the matrix of silicate glass. Chemical, microstructural, and mineralogical properties would guide successful rare metal recovery from coal ash.

• International Journal of Highway Engineering
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• v.7 no.2 s.24
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• pp.97-107
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• 2005

Since the purpose of wheel tracking test is to find out relative difference of mixture's rut resistance, the wheel is an important part in the test for obtaining a consistent output. This study is performed to examine efficiency of different wheel material, rubber and steel in wheel tracking test. The rubber was inserted as a ring on the outer face of the steel wheel, and thickness of rubber ring was 15mm and 7.5mm and 0mm (steel wheel without rubber), making the total outer diameter 200mm. The objective of this study was to select reliable wheel material type in wheel tracking test at $60^{\circ}C$ based on variance in output (rut depth and dynamic stability) and correlation with SD (deformation strength). The result of regression analysis of rut depth with Sd showed that $R^2$ values of wheel rubber thickness of 15mm, 7.5mm and 0mm were 0.7, 0.8 and over 0.9, respectively. In a case of steel wheel (0mm), the highest $R^2$ value was 0.9569. Therefore, the wheel without rubber ring was the best in output consistency level and coefficient of determination $(R^2)$ with deformation strength. Therefore, the steel wheel without rubber ring is suggested as the best choice for wheel tracking test of asphalt concrete.

• Korean Journal of Environmental Agriculture
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• v.19 no.5
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• pp.401-418
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• 2000

1. Production of the artificial zeolite from coal ash Coal fly ash is mainly composed of several oxides including $SiO_2$ and $Al_2O_3$ derived from inorganic compounds remained after burning. As minor components, $Fe_2O_3$ and oxides of Mg, Ca, P, Ti (trace) are also contained in the ash. These components are presented as glass form resulting from fusion in the process of the combustion of coal. In other word, coal ash may refer to a kind of aluminosilicate glass that is known to easily change to zeolite-like materials by hydrothermal reaction. Lots of hot seawater is disposing near thermal power plants after cooling turbine generator periodically. Using seawater in the hydrothermal reaction caused to produce low price artificial zeolite by reduction of sodium hydroxide consumption, heating energy and water cost. As coal ash were reacted hydrothermally, peaks of quartz and mullite in the ash were weakened and disappeared, and new Na-Pl peaks were appeared strengthily. Si-O-Si bonding of the bituminous coal ash was changed to Si-O-Al (and $Fe^{3+}$) bonding by the reaction. Therefore the produced Na-Pl type zeolite had high CEC of 276.7 $cmol^+{\cdot}kg^{-1}$ and well developed molecular sieve structure with low concentration of heavy metals. 2. Utilization of the artificial zeolite in agro-environment The artificial zeolite(1g) could remove 123.5 mg of zinc, 164.7 mg copper, 184.4 mg cadmium and 350.6 mg lead in the synthetic wastewater. The removability is higher 2.8 times in zinc, 3.3 times in copper, 4.7 times in cadmium and 4.8 times in lead than natural zeolite and charcoal powder. When the heavy metals were treated at the ratio of 150 $kg{\cdot}ha^{-1}$ to the rice plant, various growth inhibition were observed; brownish discoloration and death of leaf sheath, growth inhibition in culm length, number of panicles and grains, grain ripening and rice yield. But these growth inhibition was greatly alleviated by the application of artificial zeolite, therefore, rice yield increased $1.1{\sim}3.2$ times according to the metal kind. In addition, the concentration of heavy metals in the brown rice also lowered by $27{\sim}75%$. Artificial Granular Zeolites (AGZ) was developed for the purification of wastewater. Canon exchange capacity was 126.8 $cmol^+{\cdot}kg^{-1}$. AGZ had Na-Pl peaks mainly with some minor $C_3S$ peaks in X-ray diffractogram. In addition, AGZs had various pore structure that may be adhere the suspended solid and offer microbiological niche to decompose organic pollutants. AGZ could remove ammonium, orthophosphate and heavy metals simultaneously. Mixing ratio of artificial zeolite in AGZs was related positively with removal efficiency of $NH_4\;^+$ and negatively with that of $PO_4\;^{3-}$. Root growth of rice seedling was inhibited severely in the mine wastewater because of strong acidity and high concentration of heavy metals. As AGZ(1 kg) stayed in the wastewater(100L) for 4days, water quality turned into safely for agricultural usage and rice seedlings grew normally.

• Korean Journal of Environmental Agriculture
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• v.17 no.3
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• pp.189-194
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• 1998

In order to evaluate the residual effects of bituminous coal fly ash, gypsum, oyster shell as soil amendments, Chinese cabbage was cultivated on acidic sandy loam soils with low boron content. The soils were amended in the upper 15cm with amendments in previous year and the growth and qualities of plants were analyzed. Amendments treated one year before were, in metric tons per hectare, i) none(Check) ; ii) 80 fly ash(FA) ; iii) 4 shell(SH) ; iv) 56 fly ash + 24 gypsum (FG) ; v) 40 fly ash + 24 gypsum + 0.8 shell(FGS). Yield response in fresh weight of Chinese cabbage was in order of 834% for FGS > 780% for FG > 755% FA > 193% for SH plants. Reducing sugar, vitamin-C, and total nitrogen contents of leaves depending on treatments showed the same tendencies as that in yields, whereas crude fibre opposite to them. In particular, FA, FG, and FGS plants showed normal growth without both boron deficiency symptoms which appeared in Check and SH plants and possibilities of accumulation of heavy metals. In any soils treated with the above amendments, however, magnesium was insufficient.

• Journal of Energy Engineering
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• v.20 no.3
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• pp.191-199
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• 2011

The char burn-out and NOx emissions from sub-bituminous coal were investigated in drop tube furnace under $O_2/N_2$ and $O_2/CO_2$ environments with different $O_2$ concentrations of 12, 21 and 31%. Results show that the char burn-out rate is faster as $O_2$ concentration increases higher and char burn-out rate under $O_2/CO_2$ decreases due to the lower oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. NO concentration increases with increasing $O_2$ concentration, but declines at $O_2$ concentration of 31%. Meanwhile, NO emission indexes decreases monotonically with increasing $O_2$ concentration, which indicates that more NO reduction occurs with higher $O_2$ concentration probably due to greater HCN formation. For all conditions of $O_2$ concentration, the NO concentration under $O_2/N_2$ maintains higher than those of $O_2/CO_2$ due to presence of thermal NO.