• Title/Summary/Keyword: Bituminous

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Sorption of Heavy Metals from the Wastewater by the Artificial Zeolite (인공 제올라이트에 의한 폐수중 중금속 흡착)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Lee, Sang-Bok;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.61-66
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    • 1998
  • An artificial zeolite was synthesized from bituminous coal fly ash by thermo-alkali treatment, $100{\pm}3^{\circ}C$ and 3.5 N NaOH solution for 24 hours, to develope new useful material in waste water treatment system. The artificial zeolite had much higher cation exchange capacity, $299cmol^+\;kg^{-1}$ and lower concentration of extractable heavy metals than bituminous coal fly ash. The higher the temperature and the longer the shaking time, the more Zn, Cu, Cd and Pb were sorbed chemically by the artificial zeolite. Shaking artificial zeolite and wastewater at $35^{\circ}C$ for 9 hours, the amount of sorbed heavy metals were $123.5g\;kg^{-1}$ for Zn, $164.7g\;kg^{-1}$ for Cu, $184.4g\;kg^{-1}$ for Cd and $350.6g\;kg^{-1}$ for Pb, respectively.

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Investigation on the Leaching Potential of Water-Soluble Metals from Bottom Ashes in Coal-fired Power Plants (화력발전소 바닥재의 수용성 금속이온 용출가능성 조사)

  • Seo, Hyosik;Koh, Dong-Chan;Choi, Hanna
    • Journal of Soil and Groundwater Environment
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    • v.27 no.1
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    • pp.39-49
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    • 2022
  • Bottom ash generated from thermal power plants is mainly disposed in landfills, from which metals may be leached by infiltrating water. To evaluate the effect of metals in leachate on soil and groundwater, we characterized bottom ash generated from burning cokes, bituminous coal, the mixture of bituminous coal and wood pellets, and charcoal powder. The bottom ash of charcoal powder had a relatively large particle size, and its wood texture was well-preserved from SEM observation. The bottom ash of charcoal powder and wood pellets had relatively high K concentration from total element analysis. The eluates of the bottom ash samples had appreciable concentrations of Ca, Al, Fe, SO4, and NO3, but they were not a significant throughout the batch test. Therefore, it is considered that there is low possibility of soil and groundwater contamination due to leaching of metal ions and anions from these bottom ash in landfills. To estimate the trend of various trace elements, long-term monitoring and additional analysis need to be performed while considering the site conditions, because they readily adsorb on soil and aquifer substances.

Effect of Fly ash Application on the Yield of Rice and Silicate Availability in Paddy Soil (Fly ash 시용(施用)이 수도(水稻)의 수량(收量)과 논 토양(土壤)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響))

  • Kim, Yong-Woong;Yun, Chong-Hee;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.275-283
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    • 1994
  • The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

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The Logistics Process Analysis of Coal Market (석탄류의 물류 프로세스 분석)

  • Kim, Kyoung-Tae;Kwon, Yong-Jang;Kim, Young-Joo;Lee, Suk
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.3299-3305
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    • 2011
  • Railroad is considered a representative echo-friendly mode, but there are many civil complaints due to dusts arising in the process of bulk cargo transportation. The freight station which is handling coal are slowly decreasing because of civil complaints. Generally gondolas and hopper cars kinds of freight cars have a role to carry coal such as anthracite and bituminous coal. The railroad competitiveness in the field of bulk cargo transportation is diminishing because there are cost increase and dust emission in the process of transshipment. In this study, we analysed the logistics process of bulk cargo transportation in the point of railroad and we could draw the problems from the logistics process. The results could be used to study various alternatives to improve the process of coal transportation.

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Modeling of Coking Process in a Coke Oven (코크스 공정에서의 열유동 현상 모델링)

  • Yang, Kwang-Heok;Yang, Won;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1184-1189
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    • 2004
  • Coking process is the thermal decomposition of bituminous coal with final temperature of about $900^{\circ}C$ Because coke plays important roles in ironmaking process in a blast furnace it's essential for developing modeling of coke oven. In this study, An unsteady 2-dimesional model is proposed to simulate coking process in a coke oven. In this model, gas and solid phase are assumed homogeneous continnum and solid bed is assumed as porous media . The model contains governing equations for the solid phase and the gas phase. Complicated phenomena such as swelling, softening, resolidification and shrinkage are neglected and mass loss by drying and devolatilization is reflected by generation of internal pores. Drying, devolatilization, heat transfer and generation of internal pores are also reflected in source terms. Calulated results are compared with experimental data

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Behavior of Sulfur-containing Compounds in High Temperature Pyrolysis of Coals (석탄의 고온열분해시 황화합물의 거동 연구)

  • 정봉진
    • Journal of Energy Engineering
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    • v.11 no.3
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    • pp.269-275
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    • 2002
  • Experimental studies are carried out to find the behavior of sulfur compounds which are evolved during high temperature pyrolysis of coals at the smelting reduction process for iron ore. Three kinds of bituminous coals, such as Hunter & Mt. Thorley (Australia), and Ensham (South Africa) are used. And forms of sulfur compound and their amounts are analyzed at the temperature ranges of 800~110$0^{\circ}C$. Then H$_2$S is the major gas, but CS$_2$ and COS are minor gases. Sulfur compounds in three coals are distributed into the volatiles (gas & tar) and coal char as the ratio of approximately 50%:50%, respectively.

Investigation of Aging Effect on Rheological Properties of Asphalt Binder in RAP Contained Mixture Design Process

  • Park, Kyung-Won;Rhee, Suk-Keun;Yoo, Ju-Yeol
    • 한국도로학회:학술대회논문집
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    • 2006.10a
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    • pp.105-114
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    • 2006
  • There are several methods determining an appropriate performance grade of virgin binder, which is re(erred as design binder, in RAP contained bituminous mixture design process. However, difficulties have been experienced in utilizing the methods in the field application in Korea, because SHRP binder test, the key tests to determine a design binder, requires well-trained personnel, high price equipment, and time consuming process. Thus, the study investigated the relationship among the binder aging level, RAP contents, and rheologica1 properties of binder. The study results provide mix designer with a simple method in selecting an appropriate grade of virgin binder.

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A Study on the Optimization of Fuel Allocation for the Management of Sulfur Dioxide Pollution (亞黃酸가스 汚染度 管理를 위한 燃料配分의 最適化에 관한 硏究)

  • 安徹;金丁勖
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.1
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    • pp.103-110
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    • 1986
  • Since sulfur dioxide is released from the oxidation of sulfur in fuel, the level of $SO_2$ in industrial areas can be effectively managed by optimizing the allocation of fuels: the fuel should be allocated to each industries so as to achieve the air quality goal in the area with minimum fuel cost. The solution for this can be by solved using linear programming technique incorporated with the Gaussian dispersion equation. When this method was applied in Ulsan Industrial Complex, 39.3% of fuel expense could be saved compared with the present uniform fuel policy. With this method, bituminous coal generally was allocated to big emission sources such as power plants or to industries sparsely located in remote areas, and LPG or low-sulfur oils to small or medium-size sources in dense indurstrial aras. However, the particulates emission will increase with this policy, because it maximizes the use of coal within the limit to achieve the air quality goal in the area.

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유한요소법을 이용한 현수애자의 응력 해석

  • 금영탁;박관흠;유영면;이종원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.3
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    • pp.367-372
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    • 1985
  • 본 연구에서는 Heuer는 원추형 애자의 해석을 ANSYS프그램을 사용하여 시도하 였으나 시멘트와 자기간의 접촉문제를 다루지 않았고, Iwama와 Kito는 이에 대한 언급 이 없이 유한요소법에 의한 자기내부의 응력분포 결과와 실험식과를 개략적으로 비교 하였다. Fig. 1은 현수애자의 외관과 단면도이다. 철재의 핀(Pin)과 캡(cap), 자 기, 철재와 자기를 접착시키는 시멘트(cement), 접촉면의 불균일 상태를 보상시키는 역청(bituminous layer), 그리고 시멘트와 자기간의 사층(sand band)으로 구성되어 있 는 현수애자의 핀의 하단에서 송전선 무게의 하중이 가해지고 캡의 홈으로 다른 애자 가 연결되어 송전탑에 부착된다. 본 해석에서는 핀의 하단에 정적으로 사용하중이 가해진다고 가정하였다.

Studies on the clinker formed in thermal power plants (화력발전소에서 생성된 크링커에 대한 연구)

  • Park, Hyun-Joo;Nam, Chang-Hyun;Yun, Yeo-Chan;Lee, Tae-Won
    • Journal of the Korean Society of Combustion
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    • v.8 no.2
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    • pp.34-40
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    • 2003
  • Analyses for concentration, surface phenomena, and crystal structure were performed to identify the causes of clinker formation in three type of pulverized coal fired boilers. Some clinkers had partially molten surface and more CaO and $Fe_2O_3$ as compared with fly ash, and the major crystalline phases identified in the clinker were mullite and quartz. Clinkers were formed in high temperature zone of the boiler according to the identification of mullite by XRD. Free $SiO_2$ in sand combined with K, Na and Ca in limestone served as a fluxing agent to form clinkers in a circulating bed boiler.

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