• 제목/요약/키워드: Biomass-derived

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궐련형 담배 바이오매스 기반의 슈퍼커패시터용 탄소의 제조 및 응용 (Preparation of Heated Tobacco Biomass-derived Carbon Material for Supercapacitor Application)

  • 김지원;제갈석;김동현;윤창민
    • 유기물자원화
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    • 제30권2호
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    • pp.5-15
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    • 2022
  • 본 연구에서는 궐련형 담배의 담뱃잎 바이오매스 폐기물을 수거하여 슈퍼커패시터용 활물질로 제조 및 응용하였다. 수거한 담뱃잎 폐기물을 질소 환경에서 다양한 온도(800/850/950℃)로 탄화하였으며, 탄소/산소 성분비(C/O ratio) 분석을 통해 850℃에서 가장 우수한 품질의 탄소 물질이 제조되었음을 확인하였다. 추가적으로 담뱃잎 기반의 탄소 물질에 폴리피롤(Polypyrrole)을 저온중합법을 통해 코팅하여 전기화학적 성능을 향상시켰다. 탄소 물질(CTL-850)과 폴리피롤을 코팅한 탄소 물질(CTL-850/PPy)을 기반으로 한 전극의 전기화학적 성능을 측정한 결과, -1.0-0.0V와 0.0-1.0V의 전위창에서 각각 100.2F g-1@1 A g-1과 155.3F g-1@1 A g-1의 우수한 비정전용량(Specific capacitance)를 나타내었다. 두 개의 전극을 활용하여 비대칭형 슈퍼커패시터 소자(Asymmetric supercapacitor device)를 제작하였으며, 제조한 비대칭형 CTL-850//CTL-850/PPy 소자는 2.0V의 구동전압 범위와 비정전용량(31.1F g-1@1 A g-1)을 가지고 있음을 확인하였다. 또한, 제조한 슈퍼커패시터 소자의 방전을 통해 1.8V의 Red Led를 점등할 수 있음을 확인하였다. 본 연구 결과를 통해 바이오매스를 우수한 성능의 친환경 에너지 저장매체로 활용하는 후속 연구에 대한 방향성을 제시할 수 있을 것으로 판단된다.

The Importance of Intertidal Benthic Autotrophs to the Kwangyang Bay (Korea) Food Webs: ${\delta}^{13}$C analysis

  • Kim, Jong-Bin;Kim, Jeong-Bae;Lee, Pil-Yong;Hong, Jae-Sang;Kang, Chang-Keun
    • Journal of the korean society of oceanography
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    • 제36권4호
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    • pp.109-123
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    • 2001
  • The importance of phytoplankton, benthic vegetation, vascular marsh plants (primarly Phragmites communis and Salix gracilstyla) and riverine particulates inputs to the coastal bay food web was studied in Kwangyang Bay, Korea using stable carbon isotope ratios. Vascular marsh plants (${\delta}^{13}$C=-27.4${\pm}$0.8%o) and riverine particulates (-26.0${\pm}$0.8%o) were isotopically distinct from phytoplankton (-20.7${\pm}$0.8%o), microphytobenthos (-14.2${\pm}$0.6%o) and seagrass (8.8%o). The ${\delta}^{13}$C values of consumers in the study site ranged from -20.2 to -11.3olo suggesting the assimilation of carbon derived from both phytoplankton and benthic vegetation (including algae and seagrass), The relative importance of both pelagic and benthic origins of food sources was likely to vary depending on feeding habit of the consumers. The isotopic difference between pelagic and benthic consumers indicated that plankton-derived carbon was used mostly by pelagic consumers, but the carbon derived from intertidal benthic vegetation was incorporated into food webs through benthic consumers. The ${\delta}^{13}$C values of consumers in the present study differed noticeably from published values of the phytoplankton-based ecosystem, particularly in the $^{13}$C enrichment of benthic grazers, deposit-feeders and demersal feeders of fishes. This tendency of the $^{13}$C enrichment was also found in suspension-feeding bivalves. Taking the biomasses of benthic vegetation into consideration, benthic microalgae was likely to account for the consumer $^{13}$C enrichment. Role of terrestrially derived riverine carbon was limited to the riverine system and was not evident within the bay systems. Phragmites, despite their important biomass, appeared to be of little importance as consumer diet.

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Waste coffee grounds-derived nanoporous carbon nanosheets for supercapacitors

  • Park, Min Hong;Yun, Young Soo;Cho, Se Youn;Kim, Na Rae;Jin, Hyoung-Joon
    • Carbon letters
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    • 제19권
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    • pp.66-71
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    • 2016
  • The development of nanostructured functional materials derived from biomass and/or waste is of growing importance for creating sustainable energy-storage systems. In this study, nanoporous carbonaceous materials containing numerous heteroatoms were fabricated from waste coffee grounds using a top-down process via simple heating with KOH. The nanoporous carbon nanosheets exhibited notable material properties such as high specific surface area (1960.1 m2 g−1), numerous redox-active heteroatoms (16.1 at% oxygen, 2.7 at% nitrogen, and 1.6 at% sulfur), and high aspect ratios (>100). These unique properties led to good electrochemical performance as supercapacitor electrodes. A specific capacitance of ~438.5 F g−1 was achieved at a scan rate of 2 mV s−1, and a capacitance of 176 F g−1 was maintained at a fast scan rate of 100 mV s−1. Furthermore, cyclic stability was achieved for over 2000 cycles.

Enhancement of Growth and Secondary Metabolite Biosynthesis: Effect of Elicitors Derived from Plants and Insects

  • Jeong Gwi-Taek;Park Don-Hee
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제10권1호
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    • pp.73-77
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    • 2005
  • Plant-derived natural products have been and will continue to be valuable sources. Elicitors have been employed to modify cell metabolism in order to enhance the productivity of useful metabolites in plant cell/tissue cultures. In this study, several elicitors were used to improve the productivity of useful metabolites and to reduce culture time for archiving high concentration in P. ginseng hairy root cultures. The addition of chitosan, chitosan oligosaccharide and alginate oligosaccharide to the culture of P. ginseng hairy roots caused growth to be inhibited with the increase in elicitor concentration. The usage of the chitosan elicitor and D-glucosamine caused a slight decrease in hairy root growth, whereas total ginseng saponin accumulated slightly with the increase in elicitor concentration. When gel beads were added to the culture medium at the initial period, hairy root growth was enhanced. The maximum growth was 1.35 times higher than that of the control at $1\%$ (w/v). Total ginseng saponin content decreased due to the addition of alginate beads. This would result in consistent diffusion of lower levels of calcium ions during the culture period that promotes biomass growth.

Production of Arachidonic Acid by Mortierella Fungi

  • Higashiyama, Kenichi;Fujikawa, Shigeaki;Park, Enoch Y.;Shimizu , Sakazu
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제7권5호
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    • pp.252-262
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    • 2002
  • The growing interest in the application of arachidonic acid (ARA) in various fields of health and dietary requirements has elicited much attention on the industrial production of ARA-containing oil by the cultivation of Mortierella fungi. For the industrial production of ARA, various studies, such as isolation of a high-potential strain and optimization of culture conditions, have been conducted. Studies including the investigation of morphology are important because ARA is accumulated in the mycelia, and thus cultivation with high biomass concentration is essential for obtaining a high ARA yield. Combining the results derived from various studies, a high ARA yield was attained in an industrial fermentor. These ARA production techniques are applicable to the production of other polyunsaturated fatty acids (PUFAs), and will contribute to the improvement of fermentation technology especially in the field of fungal cultivation.

생물 고분자를 이용한 중금속 제거에 대한 고찰 (Review on Heavy Metal Removal Using Biopolymer)

  • 전충
    • 유기물자원화
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    • 제16권2호
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    • pp.38-46
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    • 2008
  • 미생물의 세포벽을 구성하는 많은 생물고분자들이 금속이온의 흡착과 이온교환에 주된 역할을 한다는 사실이 연구자들에 의하여 보고되어져왔다. 미생물로부터 유도되어지는 생물고분자들은 이온교환수지나 킬레이팅 수지와 같은 합성 고부나들이 상업적인 흡착제로서 널리 사용되고 있지만, 산업적인 적용에서 다양한 금속 이온들을 회수하기 위한 생물 흡착제로서 유용하다. 이 연구에서는 금속을 제거하는데 유용하고 상업적인 생물고분자들이 소개되어질 것이다.

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역 유동층 생물막 반응기에서의 생물막 탈착에 관한 연구 (A Study on Biofilm Detachment in an IFBBR)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제3권3호
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    • pp.263-271
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    • 1994
  • A detachment of biofilm was investigated in an inverse fluidized bed biofilm reactor(IFRBR). The biofilm thickness, 5 and the bioparticle density, Pm were decreased by the increase of Reynolds number, Re and the decrease of biomass concentration, h. The correlations were expressed as $\delta$=6l.6+16.33$b_c$-0.004Re and Ppd=0.3+0.027$b_c$- 2.93x$l0^{-5}$ no by multiple linear regression analysis method. Specific substrate removal rate, q was derived by F/M ratio and biofilm thickness as q=0.44.+0.82F/M-5.Ix10$-4^{$\delta$}$. Specific biofilm detachment rate, bds was influenced by FIM ratio and Reynolds number as $b_{ds}$=-0.26+0.26F/M+ 2.17$\times$$10^{-4}$Re. Specific biofilm deachment rate in an IFBBR was higher than that in a FBRR(fluidized bed biofilm reactor) because of the friction between air bubble and the bioparticles.

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고도처리 효율 향상을 위한 통계적 접근 (Improvement of Operating Efficiency on Advanced Wastewater Plant Using Statistical Approach)

  • 문경숙;민경섭;김승민;이찬형
    • 한국환경과학회지
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    • 제17권4호
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    • pp.405-412
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    • 2008
  • Statistical analysis technique was applied to operating parameters and removal efficiency data sets obtained from advanced wastewater treatment plant during 1 year. Through factor analysis three factors derived varimax rotation were selected each plant. Three components explained 96%, 87% of the total variance of the process, respectively. The components on $A_2O$ Plant were identified in the following order : 1) Shortening the SRT during high-flow period, 2) Keeping biomass high on winter 3) factor was related to DO. On DNR plant, we defined them as follows: factor 1, Prolonged the SRT during high-flow period; factor 2 was related to sludge return; factor 3, Influent BOD during low-DO period. This technique was believed to assist operators in identifying priorities to improve operation efficiency.

Interpretation of tropical tropospheric ozone derivation from TOMS

  • Na Suomi;Kim Jae-Hwan
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2005년도 Proceedings of ISRS 2005
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    • pp.366-369
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    • 2005
  • A persistent maximum over the southern tropical Atlantic in the latitudinal tropospheric ozone distribution from the CCD method is seen in the latitudinal tropospheric ozone distribution from the TOMS-Pacific method. The tropical Atlantic paradox exists in the results of both the CCD and TOMS-Pacific methods. During the northern burning season, the latitudinal distributions in the tropospheric ozone derived from the TOMS-SAGE and TOMS-Sonde methods show higher tropospheric ozone over the northern tropical Atlantic than the southern Atlantic due to a stronger gradient in stratospheric ozone relative to that from the CCD and TOMS-Pacific methods.

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Calibration and Validation of the Estimated Chlorophyll a Derived from KOMPSAT/OSMI Data and Fisheries Application in the East China Sea

  • Suh Young-Sang
    • 한국환경과학회지
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    • 제14권10호
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    • pp.911-917
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    • 2005
  • A comparison between the estimated chlorophyll a from OSMI, the SeaWiFS and the chlorophyll a measured from the research cruises of National Fisheries Research and Development Institute was made. The updated empirical algorithm for calibrating and validating of the estimated chlorophyll a in the East China Sea was formulated by relationship between the estimated chlorophyll a and the field one. The relationship between the chlorophyll a and the band ratio(nLw490/555) was still highest in the OSMI data after launching of KOMPSAT satellite. The distributions of OSMI chlorophyll a were compared with those of sea surface temperature, zooplankton biomass, and catch amounts of the Pacific mackerel in the East China Sea. In case of the relationships in specially winter seasons of 2002 and 2004, the zooplankton and the fish were totally depended on the distributions of SST than those of chlorophyll a.