• Title/Summary/Keyword: Bio-waste

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Study on vehicle application of biodegradable hydraulic oils from the point of tribological evaluation technology (Tribology 관점에서 생분해성 유압작동유 실적용 평가에 관한 연구)

  • Na ByungChul;Kim JinYong;Seo JoonHo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.367-371
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    • 2004
  • Bio-degradable hydraulic oil using polyolester base oil is formulated for the applications of heavy duty hydraulic machineries. It has proved quality and market price competitiveness by assessment of reliability test in vehicle manufacturer and specific vehicle related institute. Contribution of bio-degradable oil keep the working environment clean and increase export competitiveness in European market. Leakage or waste of mineral types of hydraulic oils in heavy duty machineries causes pollution of river, ocean, underground water. Drinkable-water pollution is serious problem in Europe. In some European countries, using bio-degradable hydraulic oils become an obligation in heavy duty machineries. New product of bio-degradable oils satisfy the European regulations(OECD 302B) and shows excellent performance in compare with European products.

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N3S-ligated Copper(II) Complex Catalyzed Selective Oxidation of Benzylic Alcohols to Aldehydes under Mild Reaction Conditions

  • Dharmalingam, Sivanesan;Koo, Eunhae;Yoon, Sungho;Park, Gyoosoon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.715-720
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    • 2014
  • A Cu(II) complex with an three nitrogens and one sulfur coordination environment was synthesized and characterized. Its redox potential was observed at 0.483 V vs. NHE, very similar to that of a Cu-containing fungal enzyme, galactose oxidase, which catalyzes the oxidation of alcohols to corresponding aldehydes with the concomitant reduction of molecular oxygen to water. The Cu(II) complex selectively oxidizes the benzylic alcohols using TEMPO/$O_2$ under mild reaction conditions to corresponding aldehydes without forming any over-oxidation product. Moreover, the catalyst can be recovered and reused multiple times for further oxidation reactions, thus minimizing the waste generation.

Sludge Thickening Performance of the Filtration Bio-reactor Equipped with Shadow Mask Filter Module (Shadow mask 여과 모듈을 이용한 슬러지 농축 특성)

  • Jung, Yong-Jun;Kwon, Koo-Ho;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.29-33
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    • 2005
  • In order to recycle the waste material and to develop the thickening unit of waste activated sludge from wastewater treatment facilities, the filtration bio-reactor equipped with a shadow mask filter module was employed for this work from which the operating properties and parameters were drawn. The sludge thickening and filtration unit is made of cylindrical acryl tank(12cm i.d. ${\times}$ 58cm height: working volume of 6L), where the flat-sheet type of shadow mask filter module(pore size: 220~250um, opening area: 34.8~39.6%) was installed and the effluent was withdrawn from the effluent port at the lowest point of the reactor, and the filtration was performed only by the hydraulic pressure. For evaluating the operating performance of this reactor, some parameters such as the solid-liquid separation of different biomass concentrations, the water quality of filtrate, the aeration cleaning time and the cleaning effect were investigated. Depending on the MLSS concentrations, the different time to withdraw 3L of filtrate was required in which the longer filtration time was necessary for the higher MLSS concentrations caused by the thicker formation of cake layer: 40 minutes for 5,000 mg/L, 70 minutes for 10,000 mg/L and 100 minutes for 15,000 mg/L, where the concentrations of SS were 8.9, 6.7 and 6.5 mg/L, respectively. Under the same operating conditions (the intensity of aeration cleaning: 80 L/min, MLSS: 10,000 mg/L), the proper aeration cleaning time was revealed 30 seconds, and the stable formation of cake layer was in the range of 10 to 15 minutes. Therefore, the shadow mask considered as a waste material can be of use as a filter material for the sludge thickening system.

Studies on the Selection of Microorganism for Food Wastes and Optimization of Fermentation Process (음식물찌꺼기 소멸효율 재고를 위한 발효균 및 발효 공정 최적화 연구)

  • Kim, Young-Kwon;Hong, Myung-Pyo;Kim, Myung-Jin;Hong, Suk-Il;Park, Myung-Suk;Kim, Jong-Suk;Chang, Ho-Geun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.2
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    • pp.95-112
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    • 1998
  • For the effective disposal of organic food wastes, we seleted 4 strains of microorganism from 186 microbial candidate via enzyme activity test, salt tolerance, food decomposition rate, stability and safety of strains. The identity of these 4 strains are as follows : Fungi is Rhizopus sp., yeasts are Galactomyces sp., Pichia sp. and Hyphopichia sp., In the 50L fermenter scale, we tested various fermenting factor for the optimization of conditions of food waste decomposition using 4 selected strains. The optimum fomenting conditions were as follows : BIO-CHIP Volume 25-30 L, BIO CHIP size 2.0-6.0mm, air flow 200-280L/min, mixing intensity 2-4rpm, temperature $30-45^{\circ}C$. In these fermenting conditions, the efficiency of decomposition(rate of weight loss of food wastes) were 93%. Also the quality of fermenting output were assayed at the basis of fertilizer, and the results were as good as general compost.

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Proteome analysis of chickens fed with tissue culture medium waste after harvest of Korean wild ginseng (산삼 배양액을 급여한 육계에서 근육의 프로테옴 분석)

  • Seol, Jae-Won;Hwang, In Ho;Chae, Joon-Seok;Kang, Hyung-Sub;Ryu, Kyeong-Seon;Kang, Chun-Seong;Park, Sang-Youel
    • Korean Journal of Veterinary Research
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    • v.45 no.2
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    • pp.155-161
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    • 2005
  • Proteomics is a useful approach to know protein expression, post-translational modification and protein function. We investigated the protein expression pattern and identity in chickens fed with the tissue culture medium waste after harvest of Korean wild ginseng (TCM-KWG) (Panax ginseng). Two groups (n=60/group) of day old broiler chickens were administered with 0 (control) and 0.8% (treatment) TCM-KWG through drinking water. After 5 weeks, we examined the protein expression pattern of fibularis longus and superficial pectoral muscle by Two-dimensional electrophoresis analysis. Interestingly, TCM-KWG treatment significantly increased five spot's density, and markedly reduced five spot's density in the muscles. We identified 10 proteins (desmin, myosin light chain 1, heat shock 25 kDa protein, collapsin response mediator protein-2A, alpha enolase, vimentin, actin alpha 1, my023 protein, pyruvate kinase and troponin T) by the matrix-assisted laser desorption ionization time of flight (MALDI-TOF).

Triboelectric Nanogenerator based on Mandarin Peel Powder (감귤 과피 분말 기반 마찰전기 나노발전기 제작)

  • Kim, Woo Joong;Kim, Soo Wan;Park, Sung Hyun;Doh, Yang Hoi;Yang, Young Jin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.5
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    • pp.9-15
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    • 2022
  • Discarded bio-wastes, such as seeds and rinds, cause environmental problems. Multiple studies have recycled bio-wastes as eco-friendly energy sources to solve these problems. This study uses bio-waste to fabricate a mandarin peel powder based triboelectric nanogenerator (MPP-TENG). The MPP-TENG is based on the contact separation mode. It generates an open-circuit voltage and short-circuit current of 156V and 2µA, respectively. In addition, MPP-TENG shows stable operation over continuous 3000s without any deviation in output. Also, the device exhibits maximum power density of 5.3㎼/cm2 when connected to a resistance of 100MΩ. In an energy storage capacity test for 1000s, the MPP-TENG stores an energy of 171.6µJ in a 4.7µF capacitor. The MPP-TENG can power 9 blue LEDs and 54 green lettering LEDs. These results confirm that the MPP-TENG can provide a new avenue for eco-friendly energy harvesting device fabrication.

Biological Hydrogen Production from Mixed Organic Waste of Food and Activated Sludge by Pre-treatment (음식물쓰레기와 전처리한 폐활성슬러지의 혼합비율에 따른 생물학적 수소생산)

  • Lee, Jun-Cheol;Kim, Jae-Hyung;Choi, Kwang-Keun;Pak, Dae-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.1044-1050
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    • 2007
  • In this study, Bio-hydrogen is produced from organic waste mixtures containing food waste and waste activated sludge (WAS). The effects of different operational factor on hydrogen production, including various solubilization methods for pretreatments of WAS, pH and different ratios of food waste and WAS, were investigated. The highest hydrogen production values are obtained as 4.3 mL $H_2/g$ $VS_{consumed}$ in the case of applying the mixed pre-treatments of alkali and ultrasonic. The pH value in bio-reactor increased from 4 to 8 after the ultrasonic treatment with alkali and the hydrogen yield touched its highest value in the pH range of 5.0 to 5.5. Similarly, the hydrogen production reached the level of 13.8 mL $H_2/g$ $VS_{consumed}$ using the same pre-treatment method from the mixture of food waste and WAS. The ratio of 2 : 1 produced a maximum amount of hydrogen of 5.0 L $H_2/L/d$. The amount of volatile fatty acids(VFAs) including acetate, propionate and butyrate, were also varied considerably. Propionate decreased consistently with rising of hydrogen while butyrate comparing to acetate relatively increased in the effluent.

Effect of Food Waste Compost on Crop Productivity and Soil Chemical Properties under Rice and Pepper Cultivation

  • Lee, Chang Hoon;Ko, Byong-Gu;Kim, Myung-Sook;Park, Seong-Jin;Yun, Sun-Gang;Oh, Taek-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.682-688
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    • 2016
  • Food waste has recognized one of useful sources for potentially agricultural application to supply organic matter and nutrients in arable soil. However, there was little information on application of food waste compost related to the maturity and NaCl content in arable soil. This study evaluated the effect of food waste compost application on yield and fertility in soil under flooding and upland condition. The yields in rice and pepper cultivation decreased with increasing the rate of food waste compost application in soil (p<0.05). Maximum yields of rice ($49.0g\;plant^{-1}$) and pepper ($204g\;plant^{-1}$) were shown at 10 and $30Mg\;ha^{-1}$ of food waste compost application, respectively. The N, P, and K contents in grain and plant residues increased by the application of food waste compost, there was no difference on Na/K ratio in plant tissue among the treatments. Application of food waste compost resulted in the increase of pH, EC, TC, available P contents in soil after crop harvest, especially, which was shown the increase of the CEC and exchangeable sodium percentage (ESP) contents in irrespective of water condition. In conclusion, application of food waste compost in soil was effective on the supply of the organic matter and nutrient. However, it might need caution to apply food waste compost for sustainable productivity in arable soil because of potential Na accumulation.

Characteristics of Bio-oil by Pyrolysis with Pig Feces (돈분을 이용한 열분해공정 바이오오일의 특성)

  • Kun, Zhu;Choi, Hong L.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.4
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    • pp.57-63
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    • 2008
  • The characteristics of the bio-oil produced by the pyrolysis process with pig feces was investigated in this paper. The continuous auger-type reactor produced bio-oil was maintained at the temperature range of 400 to $600^{\circ}C$, which was higher than a typical that in a conventional pyrolysis system. The pig feces was used as the feedstock. The bio-oil and its compositions were characterized by water analysis, heating values, elemental analysis, bio-oil compounds, by Gas Chromatography/Mass Spectrometry (GC/MS), and functional group by $^1H$ NMR spectroscopy. It was found that the maximum bio-oil yields of 21% w.t. was achieved at $550^{\circ}C$. This result suggested that this auger reactor might be a potential technology for livestock waste treatment to produce bio-oil because it is able to be improved to reach higher efficiency of bio-oil production in further study. The pyrolysis system reported herein had low heat transfer into the feedstock in the auger reactor so that it needs improve the heat conduction rate of the system in further study.

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Hydrodeoxygenation of Spent Coffee Bio-oil from Fast Pyrolysis using HZSM-5 and Dolomite Catalysts

  • Park, Jeong Woo;Ly, Hoang Vu;Linh, Le Manh;Tran, Quoc Khanh;Kim, Seung-Soo;Kim, Jinsoo
    • Clean Technology
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    • v.25 no.2
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    • pp.168-176
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    • 2019
  • Spent coffee is one of biomass sources to be converted into bio-oil. However, the bio-oil should be further upgraded to achieve a higher quality bio-oil because of its high oxygen content. Deoxygenation under hydrotreating using different catalysts (catalytic hydrodeoxygenation; HDO) is considered as one of the promising methods for upgrading bio-oil from pyrolysis by removal of O-containing groups. In this study, the HDO of spent coffee bio-oil, which was collected from fast pyrolysis of spent coffee ($460^{\circ}C$, $2.0{\times}U_{mf}$), was carried out in an autoclave. The product yields were 72.16 ~ 96.76 wt% of bio-oil, 0 ~ 18.59 wt% of char, and 3.24 ~ 9.25 wt% of gas obtained in 30 min at temperatures between $250^{\circ}C$ and $350^{\circ}C$ and pressure in the range of 3 to 9 bar. The highest yield of bio-oil of 97.13% was achieved at $250^{\circ}C$ and 3 bar, with high selectivity of D-Allose. The carbon number distribution of the bio-oil was analyzed based on the concept of simulated distillation. The $C_{12}{\sim}C_{14}$ fraction increased from 22.98 wt% to 27.30 wt%, whereas the $C_{19}{\sim}C_{26}$ fraction decreased from 24.74 wt% to 17.18 wt% with increasing reaction time. Bio-oil yields were slightly decreased when the HZSM-5 catalyst and dolomite were used. The selectivity of CO was increased at the HZSM-5 catalyst and decreased at the dolomite.