• Title/Summary/Keyword: Bio stability

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Emulsification of the Mixture of Catalytic Pyrolysis Oil Obtained under Methane and Nitrogen Environment in Diesel Using Span 80 and Atlox 4916 as Surfactants

  • Farooq, Abid;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.357-360
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    • 2021
  • Emulsions were prepared using a mixture of bio-oil obtained from the pyrolysis of sawdust in an N2 environment and Quercus mongolica in a CH4 environment for both non-catalytic and catalytic cases. Both prepared emulsions were examined by measuring the physical stability and Fourier transform infrared spectroscopy. The emulsion with HLB 5.8 (Span 80 and Atlox 4916) for the ratio of bio-oil (B-oil and C-oil): surfactant: diesel = 10% : 3% : 87% showed stability for 15 days. Combining oils produced in N2 and CH4 environments could be a potential solution for generating high-quality emulsions with a high heating value.

Effect of Alkyl Ketene Dimer(AKD) on Red Algae Reinforced Biocomposites (AKD 처리한 홍조류섬유 보강 바이오복합재료의 특성)

  • Lee, Min-Woo;Park, Dong-Hui;Seo, Yung-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.2
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    • pp.66-71
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    • 2011
  • Biocomposites were fabricated with biodegradable polymers and natural fibers. Biocomposites have benefits of low cost, low density, and biodegradability over inorganic fiber composite, and give comparable strength properties. Hydrophobic polymer used for sizing in paper industry, AKD (Akenyl Keten Dimer), was applied to natural fibers, red algae fibers (RAF) in this study, to make fiber surfaces more compatible to hydrophobic nature of matrix polymers. Composites with RAF, kenaf, glass fibers, and carbon fibers have been fabricated by a compression molding method and their thermo-mechanical properties have been studied. Also, the thermal dimensional stability test was done from at 30 to $100^{\circ}C$. The storage moduli and the thermo-mechanical stabilities of polypropylene and poly lactic acid based biocomposites were improved by reinforcing with the RAF and much more with AKD treated fibers. Dimensional stability of biocomposite was also markedly improved by AKD pretrement on RAF.

Comparison of the Stability of Poly-γ-Glutamate Hydrogels Prepared by UV and γ-Ray Irradiation

  • Park, Sang-Joon;Uyama, Hiroshi;Kwak, Mi-Sun;Sung, Moon-Hee
    • Journal of Microbiology and Biotechnology
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    • v.29 no.7
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    • pp.1078-1082
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    • 2019
  • Poly-${\gamma}$-glutamate (${\gamma}$-PGA) has various applications due to its desirable characteristics in terms of safety and biodegradability. Previous studies have been conducted on ${\gamma}$-PGA hydrogels produced by ${\gamma}$-ray irradiation, but these hydrogels have proved unstable in solutions. This study was conducted to enable the ${\gamma}$-PGA hydrogel to maintain a stable form in solutions. The ${\gamma}$-PGA mixture for UV-irradiation was prepared with a cross-linker (N,N,N-trimethyl-3-[(2-methylacryloyl)amino]propan-1-aminium). Both ${\gamma}$-PGA hydrogels' characteristics, including stability in solutions, were examined. The UV-irradiated ${\gamma}$-PGA hydrogel maintained a stable form during the nine weeks of the study, but the ${\gamma}$-ray irradiated hydrogel dissolved after one week.

Enhanced Stability of Tyrosine Phenol-Lyase from Symbiobacterium toebii by DNA Shuffling

  • Kim, Jin-Ho;Song, Jae-Jun;Kim, Bong-Gyun;Sung, Moon-Hee;Lee, Sang-Chul
    • Journal of Microbiology and Biotechnology
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    • v.14 no.1
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    • pp.153-157
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    • 2004
  • Tyrosine phenol-lyase (TPL) is a useful enzyme for the synthesis of pharmaceutical aromatic amino acids. In the current study, sequential DNA shuffling and screening were used to enhance the stability of TPL. Twenty-thousand mutants were screened, and several improved variants were isolated. One variant named A13V, in which the $13^{th}$ amino acid alanine was substituted by valine, exhibited a higher temperature and denaturant stability than the wild-type TPL. The purified mutant TPL, A13V, retained about 60% of its activity at $76^\circ{C}$, whereas the activity of the wild-type TPL decreased to less than 20% at the same temperature. Plus, A13V exhibited about 50% activity with 3 M urea, while the wild-type TPL lost almost all its catalytic activity, indicating an increased denaturant tolerance in the mutant A13V. It is speculated that the substitution of Val for the Ala in the $\beta$-strand of the N-terminal arm was responsible for the heightened stabilization, and that the current results will contribute to further research on the structural stability of TPL.

Study on the Performance and Emission Characteristics of a DI Diesel Engine Operated with LPG / Bio-diesel Blended Fuel (LPG/바이오디젤 혼합연료를 사용하는 직접분사식 디젤엔진의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Oh, Seung-Mook;Choi, Young;Kang, Kern-Yong
    • Journal of the Korean Institute of Gas
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    • v.14 no.1
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    • pp.8-14
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    • 2010
  • In this study, we experimentally investigated a compression ignition engine operated with Bio-diesel blended LPG fuel. In particular, the performance, emissions characteristics (including total hydrocarbon, carbon monoxide, nitrogen oxides, and carbon dioxides emissions), and combustion stability of a CI engine fueled with Bio-diesel blended LPG fuel were examined at 1500 rpm. The percentage of Bio-diesel in the fuel blend ranged from 20-60%. The results showed that stable engine operation was possible for a wide range of engine loads up to 40% Bio-diesel by mass. When the Bio-diesel content was increased, leading to a decrease in the lower heating value of the blended fuel, the cetane value increased, resulting in a advanced start of heat release. Exhaust emission measurements showed that THC and CO emissions were increased when using the blended fuel at low engine speeds due to partial burn from over-mixing. NOx emission was emitted less at lower loads and more at higher loads.

Electrospun Poly(Ether Sulfone) Membranes Impregnated with Nafion for High-Temperature Polymer Electrolyte Membrane Fuel Cells

  • Lee, Hong Yeon;Hwang, Hyung Kwon;Lee, Jin Goo;Jeon, Yukwon;Park, Dae-Hwan;Kim, Jong Hak;Shul, Yong-Gun
    • Journal of the Korean Electrochemical Society
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    • v.19 no.1
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    • pp.9-13
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    • 2016
  • Electrospun poly(ether sulfone) (PES) membrane impregnated with Nafion (PES-N) have been developed for high-temperature polymer-electrolyte membrane fuel cell (HT-PEMFC). The PES-N obtains highly thermal stability up to $430^{\circ}C$, which is higher than that of the commercial Nafion 212. The PES-N membrane shows a good proton conductivity of about $10^{-2}S\;cm^{-1}$ in a temperature range from $75^{\circ}C$ to $120^{\circ}C$. The membrane-electrode assembly (MEA) with the PES-N membrane exhibits a current density of $1.697A\;cm^{-2}$ at $75^{\circ}C$, and $0.813A\;cm^{-2}$ at $110^{\circ}C$ when the applied voltage is 0.6 V, whereas the MEA with the Nafion 212 membrane shows the current density of $0.647Acm^{-2}$ at $110^{\circ}C$. The results suggest that the PES-N can be a good candidate for a polymer electrolyte membrane of the HT-PEMFC.

Finite Element Analysis Approach for the Stress of Digging Part of Garlic Harvesters (유한요소해석을 이용한 마늘 수확기 굴취부의 응력분석)

  • Kim, Kyu-Bong;Lee, Myung-Hee;Kim, Dae-Cheol;Cho, Yongjin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.11
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    • pp.78-86
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    • 2020
  • A stress analysis was performed to verify the stability of the digging part of a garlic harvester. A finite element analysis was performed to examine the distribution and concentrated loads on the digging part of the blade and contact plate. Moreover, the stability and maximum deformation of the digging part were determined. Under a distributed load, the maximum principal stress, total deformation, and minimum safety factor ranged from 64-128 MPa, 0.35-0.70 mm, and 2.9-5.7, respectively. The analysis results for the distribution load indicated that the maximum stress occurred at the center of the blade. In contrast, under the concentrated load, the maximum principal stress, total deformation, and minimum safety factor ranged from 66-247 MPa, 0.35-0.79 mm, 1.48-5.53, respectively. The analysis results for the concentrated load indicated that stress and deformation were larger toward the edge and center, respectively.

Physical Properties of Agro-Flour Filled Aliphatic Thermoplastic Polyester Bio-Composites

  • Eom, Young Geun;Kim, Hee Soo;Yang, Han Seung;Kim, Hyun Joong
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.3
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    • pp.71-78
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    • 2004
  • The purpose of this study was to investigate the water absorption and thickness swelling of biocomposites at room temperature. These properties of bio-composites mainly depend on the ability of the agro-flour to absorb water through hydrogen bonding between water and the hydroxyl groups of the holocellulose and lignin in the cell wall. As the content of agro-flour increased, the water absorption and thickness swelling of the bio-composites increased. The effects of agro-flour content and rice husk flour (RHF) particle size on the water absorption and thickness swelling of the bio-composites were evaluated. In general, wood-based materials showed significantly higher water absorption and thickness swelling than the bio-composites. This might be attributed to the ability of the polybutylene succinate (PBS) hydrophobic polymer to prohibit the water absorption and thickness swelling of the bio-composites, Therefore, the use of agro-flour filled PBS bio-composites, which exhibit improved dimensional stability in comparison with wood-based materials, is recommended.

The Effect of Temperature on the Stability of Bioluminescence from Immobilized Photobacterium phosphoreum (저장 온도에 따른 고정화 Photobacterium phosphoreum의 Bioluminescence 안정성의 변화)

  • 김현숙;이은수;정성제;유승오;전억한
    • KSBB Journal
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    • v.14 no.1
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    • pp.91-95
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    • 1999
  • The objective of this work was to improve bioluminescence stability of Photobacterium phosphoreum when it stored in view of developing continuous on-line monitoring system for pullutants. Long-term experiments were made to determine the effect of immobilization and storage temperature on the maintenance and stability of bioluminescence from luminescent bacteria. The immobilized cells of P. phosphoreum were compared with free cells in terms of maintenance of bioluminescence at room temperature. The bioluminescence of cells immobilized showed higher bioluminescence intensity that free and strontium bioluminescence stability was investigated with free and immobilized cells stored at $20^{\circ}C,\; 4^{\circ}C,\; -20^{\circ}C\;and\;-70^{\circ}C$for 20 days. Both free and immobilized cells stored at $4^{\circ}C$ emitted a stable bioluminescence while the bioluminescence markedly decreased with those stored at $20^{\circ}C,\;-20^{\circ}C\;and\; -70^{\circ}C$.

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Photocrosslinking of Polyester by UV irradiation (자외선 조사에 의한 폴리에스터의 광가교)

  • Yun, Deuk-Won;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.7-7
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    • 2011
  • Poly(ethylene terephthalate)(PET) is one of the most widely used materials in textile industry. It can have a low cost, silk-like handle, and excellent mechanical properties. Low thermal stability of PET had been a common problem limiting its high temperature application. The polyester have been known to have the disadvantage of degradation under ionized irradiation compared to crosslikable polymers such as polyethylene, polypropylene and polystylene. To improve thermal stability of PET, the PET films were photocrosslinked by UV irradiation. A hydrogen-abstractable photoinitiator was used to photocrosslink of PET by continuous UV irradiation. Photoinitiator addition increased the gel fraction. The photocrosslinking was attributed to the recombination of PET radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of the PET polymer chains by the added photoinitiator. Also the crosslinked PET showed higher thermal stability and mechanical strength with increasing UV energy. Polyester type films such as poly(ethylene naphthalate)(PEN) and poly(butylene terephthalte)(PBT) were also increased the gel fraction and improved thermal stability and mechanical properties by UV irradiation.

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