• Journal of the Korean Chemical Society
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• v.25 no.3
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• pp.152-159
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• 1981

The rates of solvolysis for p-nitrobenzyl chloride have been measured by the electric conductivity method in aqueous ethanol from 0.0 to 0. 5 mole fraction of ethanol under various pressures up to 1200bar at 50 and $60{\circ}C$. The activation parameters, ${\Delta}V_\0^{\neq},\ {\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ are evaluated from the rate constants. The results indicated that ${\Delta}V_\0^{\neq}$ exhibits an extremum behaviors near 0.3 mole fraction of ethanol and ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ near 0.1 mole fraction of ethanol. This behaviors are discussed in terms of solvent structure variation and the pressure dependences of ${\Delta}H^{\neq},\ {\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ are also discussed individually. The signs of the pressure dependence of ${\Delta}H^{\neq}$${\Delta}S^{\neq}$ are shown to be consistent with those required by the Maxwell relationships for classical thermodynamic systems.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.2
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• pp.245-251
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• 2008

Although many studies have been carried out about binary gas mixtures with $SF_6$, few studies were presented about breakdown characteristics of $SF_6/CF_4$ mixtures. At present study the breakdown characteristics of $SF_6/CF_4$ mixtures in non-uniform field was performed. The experiments were carried out under AC voltage and standard lightning impulse(SLI) voltage. Breakdown characteristics were investigated for $SF_6/CF_4$ mixtures when AC voltages and standard lighting impulse voltage was applied in a needle-plane. The needle-plane electrode whose gap distance was 3 mm were used in a test chamber. $SF_6/CF_4$ mixtures contained from 0 to 100% $SF_6$ and the experimental gas pressure ranged from 0.1 to 0.5 MPa. The breakdown characteristics of $SF_6/CF_4$ mixtures in non-uniform field may be influenced by defects like needle-shaped protrusions. In case of slowly rising SLI voltage and AC voltage it is enhanced by corona-stabilization. This phenomena caused by the ion drift during streamer development and the resulting space-charge is investigated. In non-uniform field under negative SLI voltage the breakdown voltage was increase linearly but under positive SLI voltage the breakdown voltage increase non-linearly. The breakdown voltage in needle-plane electrode displayed N shape characteristics for increasing the content of $SF_6$ at AC voltage. $SF_6/CF_4$ mixture has good dielectric strength and arc-extinguishing properties than pure SF6. This paper presents experimental results on breakdown characteristics for various mixtures of $SF_6/CF_4$ at practical pressures. We could make an environment friendly gas insulation material with maintaining dielectric strength by combing $SF_6\;and\;CF_4$ which generates a lower lever of the global warming effect.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.2
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• pp.180-186
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• 2001

The condensation heat transfer coefficients of pure refrigerants R-22, R-134a, and a binary refrigerant mixture R-410A flowing in a small diameter tube were investigated. The experiment apparatus consists of a refrigerant loop and a water loop. The main components of the refrigerant loop consist of a variable-speed pump, a mass flowmeter, an evaporator, and a condenser(test section). The water loop consists of a variable-speed pump, an isothermal tank, and a flowmeter. The condenser is a counterflow heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus. The test section consists of smooth, horizontal copper tube of 3.38mm outer diameter and 1.77mm inner diameter. The length of test section is 1220mm. The refrigerant mass fluxes varied from 450 to 1050kg/(㎡$.$s) and the average inlet and outlet qualities were 0.05 and 0.95, respectively. The main results were summarized as follows ; in the case of single-phase flow, the heat transfer coefficients increase with increasing mass flux. The heat transfer coefficient of R-410A was higher than that of R-22 and R-134a, and the heat transfer for small diameter tubes were about 20% to 27% higher than those predicted by Gnielinski. In the case of two-phase flow, the heat transfer coefficients also increase with increasing mass flux and quality. The condensation heat transfer coefficient of R-410A was slightly higher than that of R-22 and R-134a. Most of correlations proposed in the large diameter tube showed significant deviations with experimental data except for the ranges of low quality and low mass flux.

• Journal of Broadcast Engineering
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• v.16 no.3
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• pp.542-551
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• 2011

Recently an extension to DMB-AF (Digital Multimedia Broadcasting Application Format) standard was proposed in [1] without sufficient validation for industrial application due to incomplete implementation. The extended DMB-AF can include stereoscopic video and stereoscopic images for interactive service data, i.e., MPEG-4 BIFS data, in addition to the existing 2D video and 2D images for BIFS services. The contents in the extended DMB-AF can provide a temporal mixture of 2D/3D video presentations possibly with or without 2D/3D images for BIFS services. In this paper we developed DMB-AF player software that can play the extended DMB-AF files and authored several test files for its verification. As a result, we introduced a new method for indicating dependencies of 3D media tracks to improve the extension in [1] and validated the extended DMB-AF with the improvement.

• KSBB Journal
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• v.23 no.2
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• pp.135-141
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• 2008

SMB (simulated moving bed) chromatography is a very useful utility for the separation of binary system. We simulated the separation of L-arabinose and L-ribose from the mixture by using lab-scale 4(1-1-1-1)-zone SMB chromatography. Preliminary experiments of PIM (pulse input method) were performed to measure adsorption isotherms of L-ribose and L-arabinose in $NH_2$ HPLC column, and experimental and simulated results from ASPEN chromatography were compared. To find the most suitable separation condition in SMB, we carried out a simulation in $m_2-m_3$ plane base on the triangle theory and calculated operating parameters (flow rate of four zone, switching time and feed concentration and so on) using ASPEN chromatography under the conditions of linear isotherms obtained from PIM.

• Journal of the Korean Chemical Society
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• v.43 no.5
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• pp.527-534
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• 1999

Solvolyses of para-substituted cinnamoyl chlorides in aqueous binary mixtures of acetone, ethanol, methanol were investigated at 25.0$^{\circ}C$. These data were interpreted using the Grunwald-Winstein relationship, Hammett equation, and quantum mechanical model. Grunwald-Winstein plots of the first-order rate constants for para-substituted cinnamoyl chlorides with $Y_{CI}$ showed marked dispersions into three separate curves for the three aqueous mixtures with a large m vaIue for aqueous alcohol solvents. This study has shown that the potential energy surface and quanturm mechanical model predict transition state variation correctly for $S_N1$ like $S_N2$ reaction mechanism of para-substituted cinnamoyl chlorides.

• Korean Journal of Remote Sensing
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• v.36 no.1
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• pp.29-39
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• 2020

Forest fire is a critical disaster that causes massive destruction of forest ecosystem and economic loss. Hence, accurate estimation of the burned area is important for evaluation of the degree of damage and for preparing baseline data for recovery. Since most of the area size damaged by wildfires in Korea is less than 1 ha, it is necessary to use satellite or drone images with a resolution of less than 10m for detecting the damage area. This paper aims to detect wildfire-damaged area from a Kompsat-3 image using the indices such as NDVI (normalized difference vegetation index) and FBI (fire burn index) and to examine the classification characteristics according to the methods such as Otsu thresholding and ISODATA(iterative self-organizing data analysis technique). To mitigate the salt-and-pepper phenomenon of the pixel-based classification, a gaussian filter was applied to the images of NDVI and FBI. Otsu thresholding and ISODATA could distinguish the burned forest from normal forest appropriately, and the salt-and-pepper phenomenon at the boundaries of burned forest was reduced by the gaussian filter. The result from ISODATA with gaussian filter using NDVI was closest to the official record of damage area (56.9 ha) published by the Korea Forest Service. Unlike Otsu thresholding for binary classification,since the ISODATA categorizes the images into multiple classes such as(1)severely burned area, (2) moderately burned area, (3) mixture of burned and unburned areas, and (4) unburned area, the characteristics of the boundaries consisting of burned and normal forests can be better expressed. It is expected that our approach can be utilized for the high-resolution images obtained from other satellites and drones.

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.822-827
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• 1999

The specific capacitance characteristics which were of the electric double layer capacitors(ELDC) made of phenol based activated carbon fiber(ACF) electrodes and organic electrolytes has been investigated with respect to different specific surface area of electrodes and different kinds of organic electrolytes. Throughout charge-discharge cell tests, it has been found that larger surface area and larger pore diameter of electrodes contribute to increase the specific capacitance. Binary mixture of organic solvent with propylene cabonate(PC) and tetrahydrofuran(THF) for 1 M-$LiClO_4$ electrolyte has a higher specific capacitance than single solvent of PC or mixed solvent with PC and diethyl cabonate(DEC). Also, even though 1 M-tetraethylamonium perchlorate(TEAPC) of organic electrolyte shows higher specific capacitance, it has longer charge time because of its lower ion mobility.

• Fire Science and Engineering
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• v.27 no.5
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• pp.64-69
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• 2013

The autoignition temperatures (AITs) of solvent mixture was important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs and ignition delay time for n-propanol and formic acid system by using ASTM E659 apparatus. The AITs of n-Propanol and Formic acid which constituted binary system were $435^{\circ}C$ and $498^{\circ}C$, respectively. The experimental AITs of n-propanol and formic acid system were a good agreement with the calculated AITs by the proposed equations with a few A.A.D. (average absolute deviation). And n- Propanol and formic acid system was shown the minimum autoignition temperature behavior (MAITB).

• Fire Science and Engineering
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• v.13 no.1
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• pp.11-19
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• 1999

The flash point is generally used as a hazardous index of fire and explosion of a flammable liquid. A classification of the flash points is important for the safe handling of flammable liquids such as solvent mixtures. The flash points of pure substances and solvent mixtures can be c calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and a activity coefficient models. In this study, experimentally determined lower and upper flash points w were compared with the calculated values by using Raoult's law and van Laar equation. The flash points of pure substances were in agreement with the calculated values by vapor pressure and e explosive limits. Also, the lower flash points of M.E.K(methylethylketone)-toluene system were i in agreement with the predicted values by Raoult’s law, and the upper flash points were in a agreement with the predicted values by van Laar equation. By means of this methodology, it is possible to evaluate reliability of expermental data of the flash points of the flammable mixtures.