• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 1999년도 제1회 학술대회논문집(KIASC 1st conference 99)
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• pp.22-25
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• 1999

A well oriented Bi-2212 superconductor thick films were fabricated by screen printing with a Cu-free Bi-Sr-Ca-Cu-O powder on a copper plate and heat-treating at 820- $880^{\circ}C$for several minute in low oxygen pressure or are. At minute in low oxygen pressure of air. At , the printing layer partially melted by reaction between the Cu-free precursor by reaction between the Cu-free$870^{\circ}C$ precursor and CuO of the oxidizing copper plate. It is believed that the solid phase is Bi : Sr : Ca : Cu = 2 : 2 : 0 : 1. It is likely that the Bi-2212 superconducting phase is formed at Bi-2212 superconducting phase is formed at Bi-free phase/liquid interface by nucleation and grows.

• E2M - 전기 전자와 첨단 소재
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• 제9권7호
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• pp.680-689
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• 1996

SrCaCuO와 BiPbCuO 화합물로 이루어진 이중층시료가 만들어 졌으며, 소결과정에서 나타나는 확산과 입자간의 상호작용으로 108K의 임계온도를 나타내었다. 이 시료는 820.deg. C에서 0-210 시간동안 소결되었다. 초전도체의 생성, 성장메카니즘과 임계온도의 관계가 연구되었으며, 최적조건은 820.deg. C에서 210시간 소결하고 SrCaCuO와 BiPbCuO의 도포비가 1:0.6인 시편에서 나타났다. 또한 이중층시료에서 가장 좋은 조성비는 S $r_{2}$C $a_{2}$C $u_{2}$ $O_{x}$와 B $i_{1.9}$P $b_{0.5}$C $u_{3}$ $O_{y}$ 이었다.다.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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• pp.300-304
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• 1999

To tap the feasibility of exploiting the 2$^{nd}$ phases as flux-pinning centers in the (Bi,Pb)$_2Sr_2Ca_2CuO_{10}$ superconductor, the size and the distribution of the precipitates have been controlled by changing reaction temperature and time, oxygen partial pressure Po$_2$ and annealing condition. Various annealing heat treatments were also conducted on the as-received 61 filament Bi-2223 tapes with Bi$_{1.8}Pb_{0.4}Sr_2Ca_{2.2}Cu_3O_8$ starting composition and annealed specimen were analyzed with XRD, SEM, EDS and TEM.. The grain size of (Ca,Sr)$_2$(BiPb)O$_4$ or Bi$_{0.5}Pb_3Sr_2Ca_2CuO_{\delta}$ was controllable by optimizing the heat treatment condition and critical current density (J$_c$) showed dependence on the size of the 2$^{nd}$ phases.

• 한국전기전자재료학회논문지
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• 제16권5호
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• pp.429-434
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• 2003

The magnetic field sensor was fabricated with superconducting ceramics of BiPbSrCaCuO system. The sensor at liquid nitrogen temperature showed the increase of electrical resistance by applying magnetic field. Actually, the voltage drop across the sensor was changed from zero to a value more than 100 $\mu\textrm{V}$ by the applied magnetic field. The change of electrical resistance depended on magnetic field. The sensitivity of this sensor was 2.9 $\Omega$/T. The sensing limit was about 1.5${\times}$10$\^$-5/ T. The increase of electrical resistance by the magnetic field was ascribed to a modification of the Josephson junctions due to the penetrating magnetic flux into the superconducting material. Considering the observed properties of the superconductor with trapped magnetic flux, a magnetic sensor was fabricated to detect simultaneously both the intensity and the direction of the magnetic field.

• 한국전기전자재료학회논문지
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• 제17권7호
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• pp.788-792
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• 2004

The Electromagnetic properties in BiPbSrCaCuO superconductor was studied. In the measurement of current-voltage characteristics, a voltage across the superconducting sample was observed on applying an external magnetic field. The voltage continues to appear the removal of the magnetic field. The appearance of the voltage is ascribed to the trapping of magnetic flux. Depanding on the direction of appied magnetic flux less than $2.5\times{10}^-5$ T, the voltage in the magnetized sample increases or decreases. It is considered that mechanism of voltage occurrence can be explained by applying filament model.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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• pp.64-69
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• 1992

Bi-Sr-Ca-Cu-O superconducting system have the low and high Tc phases. In order to get the superconductor above crtitical temperature 100K, we added with Pb and sintered for a long time about 200 hrs. In this study, the influence of superconducting characteristics on the Bi(Pb)SrCaCuO system characteristics on the Bi(Pb)SrCaCuO system dopped Sb was investigate too. Adding Sb of 0.1 mol, the sintering time is short than that dopped Pb only. We could get the critical temperature 102 K at sintered for 24 hrs and 109 K for 210 hrs.

• 한국전기전자재료학회논문지
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• 제13권4호
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• pp.349-358
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• 2000

Fabrication and Characterization of Bi$_{2}$/Sr$_{2}$/CaCu$_{2}$/O$_{8}$(Bi2212) superconductor thick films were fabricated successfully on C tapes by liquid reaction between Cu-free precursors of Bi$_{x}$/SrCaO/$_{y}$(x=1.2-2) and Cu tapes. Cu-free Bi-Sr-Ca-O powder mixtures were screen-printed on Cu tapes and heat-treated at 850-87$0^{\circ}C$ for several minutes in air oxygen nitrogen and low oxygen pressure. In order to obtain the optimum heat-treatment condition we studied the effect of the precursor composition the printing thickness and the heat-treatment atmosphere on the superconducting properties of Bi2212 films and the reaction mechanism. Microstructures and phases of thick films were analyzed by films and the reaction mechanism. Microstructures and phases of thick films were analyzed by optical microscope and XRD. The electric properties of superonducting films were examined by the four probe method. At heat-treatment temperature the thick films were in a partially molten state by liquid reaction between CuO of the oxidized copper tape and the precursors which were printed on Cu tapes. During the heat-treatment procedure Bi2212 superconducting particle nucleate and grow in preferred orientations.ons.s.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권4호
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• pp.209-212
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• 2006

The electromagnetic effect observed in a BiSrCaCuO superconductor was studied. The electromagnetic properties of a $Ag_2O$ doped BiSrCaCuO superconductor and an undoped superconductor were evaluated to investigate the contribution of the pinning effect. It was confirmed experimentally that a large amount of magnetic flux was trapped in the $Ag_2O$ doped BiSrCaCuO than that in the undoped one, indicating that the pinning centers of magnetic flux are related closely to the occurrence mechanism of magnetic phenomena. It was considered that by adding $Ag_2O$, the area where normal conduction takes place increases and the magnetic flux penetrating through the sample increases. It also was considered that $Ag_2O$ acts to increase pinning centers of magnetic flux.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2007년 추계학술발표대회 개요집
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• pp.282-284
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• 2007

The superconductor characteristics of BSCCO spray films by Heat treatment was studied. $Bi_2Sr_2CaCu_2O_x$(Bi-2212) is high-Tc superconductor(HTS) coatings have been prepared by Heat treatment. Where high current carrying capabilities are required and therefore thick film and bulk material are called for, the Bi2Sr2Ca1Cu2O8-d(Bi-2212)compound has evoleved as one of the most promising. and the Bi-2212 HTS coating layer is synthesized through the peritectic reaction between Sr-Ca-Cu oxide coating layer and Bi-Cu oxide coating layer by partial melting process. The superconducting characteristics depends on the spray distance which was related to the spray particle melt. The Bi-2212 HTS layer consists of the whisker growth and secondary phase in 2212 layer were observed.

• 대한전기학회논문지
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• 제41권7호
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• pp.766-772
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• 1992

Bi-Sr-Ca-Cu-O superconducting system has both the low and high Tc phases. We added Pb and sintered for 200hrs. in OS12T atmosphere in order to get the superconductor above critical temperature 100K. Superconducting properties of the Bi(Pb)SrCaCuO system doped Sb were also investigated. When Sb of 0.1mol is added, the sintering time becomes shorter than that doped Pb only. We could get the critical temperature 102K at the samples sintered for 24hrs. and 109K for 210hrs.