• Title/Summary/Keyword: Bi-phase

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A Microstructural and Electrical Properties of $WO_3$-Doped ZnO Varistors ($WO_3$가 첨가된 ZNO 바리스터의 미세구조적, 전기적 특성)

  • 정순철;박춘현;남춘우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.275-279
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    • 1998
  • The influence of $WO_3$ (0.5-4.0mol%) on the microstructural and electrical properties of ZnO varistors was investigated. The major part of a tungsten segregated to the nodal point. SEM, EDAX, and XRD analysis revealed that three phase, such as W-rich phase, Bi-rich phase, and spinel phase, coexist at the nodal point. The average grain size increased in the range of 15.5-29.9pm with increasing $WO_3$ content. This may be probably attributed to liquid phase formed by $WO_3$, $WO_3$ acted as promotion additive of grain growth. As $WO_3$ content increase, the varistor voltage greatly decreased in the range 186.82-35.87V/mm due to the increase of grain growth. The barrier height decreased in the range 1.93-0.42eV with increasing $WO_3$content.

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The Effect of Relatively Low Lead Contents on the Phase Formation and Jc values of Bi-2223/Ag Tapes

  • Jiang, C.H.;Yoo, J.M.;Ko, J.W.;Kim, H.D.;Chung, H.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.17-20
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    • 2002
  • The effects of relatively low lead content (0.2~0.3) on the 2223 phase formation and transport property of Bi-2223/Ag tapes have been investigated. The results show that lead contents have great impact on the phase assemblage of precursors, subsequently, on the phase formation and transport property of silver sheathed BSCCO-2223 tapes. Powders containing Pb=0.25 and Pb=0.3 resulted in the nearly identical $J_c$ values in fully processed tapes, but leaded to significant difference on the phase formation process. For the case of Pb=0.2, both low conversion fraction of 2212 to 2223 and low $J_c$ value were obtained in final reacted tape, which was probably due to lack of enough liquid phase to facilitate the phase transformation.

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Fabrication of Superconducting Thick Film by Spray Pyrolysis Method (Spray Pyrolysis에 의한 초전도 합성)

  • Lee, Sang-Heon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.1
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    • pp.120-122
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    • 2010
  • In this paper the effect of constituent content on superconductivity and phase in BiPbSrCaCuO system was reported. The zero resistance temperature reaches as high as 100k when dophant Sb was decreased dramatically with increasing Sb content in BiPbSrCaCuO system while the corresponding phase was changed fundamentally.

Role of the $Bi_2O_3\;in\;SrBi_2TaNbO_9/Bi_2O_3/SrBi_2TaNbO_9$ Heterostructure and Low Temperature Annealing Property

  • Park, Yoon-Beak;Jang, Se-Myeong;Kim, Ju-Hyung;Lee, Jeon-Kook;Park, Jong-Wan
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.276-279
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    • 2000
  • Ferroelectric properties of $SrBi_2TaNbO_9$ (SBTN) thin films were changed by the amount of Bi content in SBTN. We suggested that the addition of excess Bi into the films could be accomplished by heat-treating $SBTN/Bi_2O_3/SBTN$ heterostructure fabricated by r.f. magnetron sputtering method. Excess Bi composition was controlled by the thickness of the sandwiched $Bi_2O_3$ from 0 to $400\;\AA$. When the SBTN thin films were inserted by $400\;{\AA}\;Bi_2O_3$ layer, $Bi_2Pt$ phase was formed as a second phase in SBTN films, resulting in poor ferroelectric properties. The onset temperature for hysteresis loop can be reduced by heat treating $SBTN/Bi_2O_3/SBTN$ heterostructure. The films with $SBTN/Bi_2O_3(100\;{\AA})/SBTN$ hetero-structure followed by annealing at $650^{\circ}C$ for 30 min show 2Pr and Ec of $5.66\;{\mu}C/\textrm{cm}^2$ and 54 kV/cm, respectively.

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Phase Transformation Behavior of Bi2O3-ZnO-Nb2O5 Ceramics sintered at low Temperature

  • Shiao, Fu-Thang;Ke, Han-Chou;Lee, Ying-Chieh
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1232-1233
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    • 2006
  • To co-fire with commercial LTCC (Low Temperature Co-fired Ceramic) materials at $850^{\circ}C{\sim}880^{\circ}C$, different contents of $B_2O_3$ were added to the $Bi_2O_3-ZnO-Nb_2O_5$ (BZN) ceramics. According to the test results, the cubic phase of BZN was transformed into orthorhombic in all the test materials. $BiNbO_4$ phase was formed in test materials with $2{\sim}5wt%$ of $B_2O_3$ addition. The phase transformation of cubic BZN was controlled during the synthesis process with excess ZnO content. The Cubic and orthorhombic phases of BZN could coexist and be sintered densely at $850^{\circ}C/2hr$.

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Topology optimization of variable thickness Reissner-Mindlin plate using multiple in-plane bi-directional functionally graded materials

  • Nam G. Luu;Thanh T. Banh;Dongkyu Lee
    • Steel and Composite Structures
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    • v.48 no.5
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    • pp.583-597
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    • 2023
  • This paper introduces a novel approach to multi-material topology optimization (MTO) targeting in-plane bi-directional functionally graded (IBFG) non-uniform thickness Reissner-Mindlin plates, employing an alternative active phase approach. The mathematical formulation integrates a first shear deformation theory (FSDT) to address compliance minimization as the objective function. Through an alternating active-phase algorithm in conjunction with the block Gauss-Seidel method, the study transforms a multi-phase topology optimization challenge with multi-volume fraction constraints into multiple binary phase sub-problems, each with a single volume fraction constraint. The investigation focuses on IBFG materials that incorporate adequate local bulk and shear moduli to enhance the precision of material interactions. Furthermore, the well-established mixed interpolation of tensorial components 4-node elements (MITC4) is harnessed to tackle shear-locking issues inherent in thin plate models. The study meticulously presents detailed mathematical formulations for IBFG plates in the MTO framework, underscored by numerous numerical examples demonstrating the method's efficiency and reliability.

Growth and Characteristics of YIG, Bi:YIG, TbBi:YIG Single Crystal Thick Films (YIG, Bi:YIG, TbBi:YIG 단결정 후막의 성장과 특성)

  • 윤석규;김근영;김명진;이형만;김회경;윤대호
    • Journal of the Korean Ceramic Society
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    • v.40 no.7
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    • pp.672-676
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    • 2003
  • The single crystalline thick films of Y$_3$Fe$\sub$5/O$\sub$12/(YIG), Y$_3$Fe$\sub$5/O$\sub$12/(Bi:YIG), (TbBi)$_3$(FeAlGa)$\sub$5/O$\sub$12/ (TbBi:YIG) were grown on (GdCa)$_3$(GaMgZr)$\sub$5/O$\sub$12/ (SGGG) by Liquid Phase Epitaxy (LPE). The change of lattice mismatch, Bi concentration, characteristic of magnetic and surface morphology were investigated in the thick film growth as a function of species and amount of chemical element, while substrate rotation speed, supercooling and growth time were kept constant. It was observed that the lattice constant of garnet single crystalline thick films of TbBi:YIG (12.500 ${\AA}$) is closed to the one of the substrate (12.496 ${\AA}$). Besides magnetic field of saturation exhibits excellent results (150 Oe).

Crystal Structure and Microstructure Variation of Nonstoichiometric Bi1±xFeO3±δ and Ti-doped BiFeO3 Ceramics under Various Sintering Conditions (비화학양론적 Bi1±xFeO3±δ와 Ti가 첨가된 BiFeO3의 소결조건에 따른 결정구조와 미세구조 변화)

  • Bae, Jihee;Kim, Jun Chan;Kim, Myong-Ho;Lee, Soonil
    • Korean Journal of Materials Research
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    • v.30 no.2
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    • pp.61-67
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    • 2020
  • BiFeO3 with perovskite structure is a well-known material that has both ferroelectric and antiferromagnetic properties called multiferroics. However, leaky electrical properties and difficulty of controlling stoichiometry due to Bi volatility and difficulty of obtaining high relative density due to high dependency on the ceramic process are issues for BiFeO3 applications. In this work we investigated the sintering behavior of samples with different stoichiometries and sintering conditions. To understand the optimum sintering conditions, nonstoichiometric Bi1±xFeO3±δ ceramics and Ti-doped Bi1.03Fe1-4x/3TixO3 ceramics were synthesized by a conventional solid-state route. Dense single phase BiFeO3 ceramics were successfully fabricated using a two-step sintering and quenching process. The effects of Bi volatility on microstructure were determined by Bi-excess and Ti doping. Bi-excess increased grain size, and Ti doping increased sintering temperature and decreased grain size. It should be noted that Ti-doping suppressed Bi volatility and stabilized the BiFeO3 phase.

Effects of Ag on the Characteristics of Sn43Bi57Agx(wt%) Lead-free Solder for Photovoltaic Ribbon (태양광 리본용 Sn43Bi57Agx(wt%) 무연 솔더의 특성에 미치는 Ag의 영향)

  • Jeong, Joo-Hyeon;Cho, Tae-Sik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.119-125
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    • 2017
  • We have studied the effects of Ag on the characteristics of $Sn_{43}Bi_{57}Ag_x$(wt%) lead-free solders for photovoltaic ribbon. Ag atoms in the solder formed an alloy phase of Ag3Sn after reacting with some part of Sn atoms, while they did not react with Bi atoms, but decreased the mean size of Bi solid phase and the thickness of solder. When Ag atoms of 3.0 wt% was added to eutectic $Sn_{43}Bi_{57}$(wt%) solder, it showed the optimally useful results that the peel strength of photovoltaic ribbon greatly increased and the sheet resistance of the solder decreased. In the meanwhile, the eutectic $Sn_{43}Bi_{57}$(wt%) solder showed a low melting temperature of $138.9^{\circ}C$, and showed a very similar result regardless of the added amount of Ag atoms.