• 제목/요약/키워드: Benzen

검색결과 29건 처리시간 0.029초

플라즈마 중합법에 의한 유기 박막의 광학 특성에 관한 연구(I) (A Study on the Optical Properties of the Organic Thin Films by Plasma Polymerization)

  • 최충석;정윤;이덕출;박구범;박상현;박복기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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    • pp.26-29
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    • 1992
  • In this study, We made use of interelectrode capacitively coupled type plasma polymerization apparatus in order to make th organic optical thin films. We adopted in Benzen. Styrene, which have optical function in the organic world. It is manufactured polymerization thin films and examined optics properties by it respectively. We have known that the refractive index decreased as discharging power increased. At the middle wave length as 550[nm], the refractive index of Styrene is smaller than one of Benzen. Then, it is known that measured results are valid because the extinction coefficient(K) is about 10$\^$-4/ for variation of refractive index.

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방사선(放射線)으로 조사(照射)된 Polyvinylchloride의 내방사성(耐放射性) 전기전도도(電氣傳導度)에 가소제(可塑劑)가 미치는 영향(影響) (Effects of Plasticizer to Radioresistance and Electrical Conductivity of Irradiated Polyvinylchlorde)

  • 김봉흡
    • Journal of Radiation Protection and Research
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    • 제3권1호
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    • pp.23-28
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    • 1978
  • 유기석계(有機錫系) 안정제(安定劑)를 포함하고 있는 polyvinylchloride (PVC)의 내방사성(耐放射性)은 가소제(可塑劑)로서 첨가된 dioctylphthalate(DOP)의 양의 증가와 더부러 증가하며 이와 같은 내방사성(耐放射性)의 평가는 시료의 IR 특성 상에서 안정제의 해이(解離)에 기인(起因)하고 있는 $1,540{\sim}1,640cm^{-1}$에서의 흡수대가 선량과 더부러 변화하는 거동으로 살필 수 있다. 가소화된 PVC에서의 내방사성의 증가는 DOP 분자구조의 일부를 형성하는 benzen 환(環)에서 방사 에너지가 공명흡수 되기 때문이라 사료(思料)되며 이와 같은 견해(見解)는 방사선량에 대한 도전율변화특성(導電率變化特性)의 고찰 결과와도 잘 일치 한다. 실용적면(實用的面)에서 $0{\sim}100Mrad$ 사이의 선량에 대한 충분(充分)한 내방사성(耐放射性)을 얻기 위하여는 30phr 전후의 DOP 첨가량이 필요하다.

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BTEX 분석용 토양 숙련도 표준시료(PTMs) 개발에 관한 연구 (A Study on the Development of Soil-based PTMs for Analysis of BTEX)

  • 이민효;이군택;이법열;이원석;김금희;홍석영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권5호
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    • pp.15-25
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    • 2013
  • In this study, two kinds of soil-based proficiency testing materials (PTMs), NICE-012L and NICE-012R were prepared and certified for Benzen, Toluene, Etylbenzene and Xylene with evaluation of uncertainties. In order to analyse BTEX (Benzen Toluene Etylbenzene Xylene) for the candidate materials, GC/MS was used after pretreatment according to methods of soil analysis by Ministry of Environment. For the homogeneity test among bottles in terms of candidate materials, ISO 13528 and IUPAC Protocol were used and according to the result, both candidate materials showed sufficient homogeneity. Also, the stability test over the candidate materials was accessed according to the ISO Guide 35 by classifying short-term and long-term stability and the result showed that both candidate materials showed decent stability. The reference values of the two candidate materials depending on BTEX components were derived from the average of the 11 samples that were used for verification of the samples' homogeneity. Uncertainty of measurement was combined by uchar that was caused by a characteristic value, $u_{bb}$ that was caused by between-bottle homogeneity, and $u_{stab}$ that was caused by stability, and then combined uncertainty ($u_{PTM}$) was multiplied to the coverage factor (k) derived from the effective degree of freedom from each factor that leads to expanded uncertainty (U) in about 95% of confidence level. The proficiency testing materials developed through this study were supplied to National Institute of Environmental Research (NIER) and utilized as an external proficiency testing materials for evaluating analysis capacity of soil agencies with specialty in terms of soil analysis approved by Minister of Environment.

수용성 C-60을 이용한 양모섬유의 기능화 (Functionalization of Wool Fiber Using Water-Soluble C-60)

  • 전영실;권혁성;남성우;김인회
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2008년도 제38차 학술발표대회
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    • pp.77-79
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    • 2008
  • Polynitro fullerenes were synthesized by reaction C-60 in benzen solution with a mixture of NaNO$_2$ and HNO$_3$. Hydrolysis of polynitro fullerenes in aqueous NaOH gave the corresponding polyhydroxylated fullerenes. Sulfonation reaction was carried out in pyridine solution of ClSO$_3$H. Infrared spectra of the resultant fullerene derivatives showed the characteristic IR bands, corresponding to absorptions of O-H, N-O, and SO$_3$Na functions. Electric resistivity and thermal transmittance of wool fiber absorbed with the water-soluble C-60 were investigated. Thermal transmittances of wool fiber were increased with increasing water-soluble C-60 concentrations, but electric conductivity were decreased with raising water-soluble C-60 uptake values.

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Interlayer Engineering with Different Host Material Properties in Blue Phosphorescent Organic Light-Emitting Diodes

  • Lee, Jong-Hee;Lee, Jeong-Ik;Lee, Joo-Won;Chu, Hye-Yong
    • ETRI Journal
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    • 제33권1호
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    • pp.32-38
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    • 2011
  • We investigated the light-emitting performances of blue phosphorescent organic light-emitting diodes, known as PHOLEDs, by incorporating an N,N'-dicarbazolyl-3,5-benzen interlayer between the hole transporting layer and emitting layer (EML). We found that the effects of the introduced interlayer for triplet exciton confinement and hole/electron balance in the EML were exceptionally dependent on the host materials: 9-(4-tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole, 9-(4-tert-butylphenyl)-3,6-ditrityl-9H-carbazole, and 4,4'-bis-triphenylsilanyl-biphenyl. When an appropriate interlayer and host material were combined, the peak external quantum efficiency was greatly enhanced by over 21 times from 0.79% to 17.1%. Studies on the recombination zone using a series of host materials were also conducted.

플라즈마 중합법에 의한 유기 박막의 광학 특성에 관한 연구 (II) (A Study on the Optical Properties of the Organic Thin Films by Plasma Polymerization(II))

  • 최충석;정윤;이덕출;박구범;박상현;박복기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.875-878
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    • 1992
  • In this study, We made use of inter-electrode capacitively coupled type plasma polymerization apparatus in order to make the organic optical thin films. We adopted in Benzen. Vinyl-Pyridine and Styrene, which have optical function in the organic world and manufactured double later. It is examined optics properties by it respectively. At the middle wave length as 550[nm], the transmittance is double layer smaller than one of single layer. The refractive index with wave length is various from 1.55 to 1.65. Then, it is known that measured results are valid because the extinction coefficient(K) is about $10^{-4}$ for variation of refractive index.

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온도센서로서 액정잉크의 개발 (Development of thermo-sensor used liquid crystal-polymer composite films)

  • 남수용
    • 한국인쇄학회지
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    • 제16권1호
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    • pp.25-38
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    • 1998
  • The developing agent is the materials which first acts on silver grain and make it into metallic silver by reducing reaction. There are several types in developing agent, and according to Lumiere-Andresen principle, substitution product which has amino or hydroxyl group in benzen nucleus has a developing power, but all reduing substances are not in used. In the developing effect, not only the role of developing agent but also that of assistant materials are important. But in this work, we have studied effect, change by lith developing agent which require high contrast image. We made an developing experiment after having manufactured developing solution used hydroquinone and another developing agents like chlorohydroquinone, pyrocatechol and pyrogallol as developing agent. And we added that did in addition of diethanolamine and ascorbic acid, and then we examined the possibility of use.

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저온상태에서 NMR을 이용한 p-Fluorophenylthioxanthylium 양이온에 관한 연구 (Low Temperature NMR Study on p-Fluorophenylthioxanthylium Ions)

  • 안양수;신정휴
    • 대한화학회지
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    • 제26권3호
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    • pp.165-171
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    • 1982
  • 티오크잔틸이움 이온과 안트라센이움 이온은 동리평면성의 구조를 가진다. 그러므로 이 양이온들에서 양전하 중심부의 빈 $P_z$-궤도는 융합된 벤젠고리의${\pi}$-궤도와 겹쳐진다. 이 양이온들은 Huckel의 (4n + 2)${\pi}$ 법칙에 따라 방향족성을 가진다. 방향족성의 안정화에 황원자가 기여하는 것은 티오크잔틸이움 이온과 안트라센이움 이온의 ${^19F}$핵자기 공명의 화학적 이동의 비교로 평가되었다.

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