Effects of Plasticizer to Radioresistance and Electrical Conductivity of Irradiated Polyvinylchlorde

방사선(放射線)으로 조사(照射)된 Polyvinylchloride의 내방사성(耐放射性) 전기전도도(電氣傳導度)에 가소제(可塑劑)가 미치는 영향(影響)

In order to investigate corelation between contents of dioctylphthalate in polyvinylchloride blent dibutyl tin dilaulate with dibutyl tin maleate as stabilizer and the behaviors of radiation resistance as well as electrical conductivity on irradiated specimens, several observations were carried out. A characteristic peak observed in the range of $1,540-1,640cm^{-1}$ on infrared spectra shows such a sensitive response to radiation as the intensity decreases with increasing doses and that this tendency strongly depressed in the presence of plasticizer. It is seemingly attributed for origin of the peak to the existence of RCOO- ion resulting from dissociation of stabilizere, further the depressive effect of decreasing peak intensity influenced by radiation seems to be caused by resonance absorption in benzen ring being a consistituent of plasticizer. It is also suggestive to be use the peak behavior influenced by radiation as a criterion for the evaluation of radiation resistance of PVC. Further the results obtained from electrical conductivity measurement also exhibit reasonable characteristics explainable with views used for the interpretation of the peak behavior mentioned previousely.

유기석계(有機錫系) 안정제(安定劑)를 포함하고 있는 polyvinylchloride (PVC)의 내방사성(耐放射性)은 가소제(可塑劑)로서 첨가된 dioctylphthalate(DOP)의 양의 증가와 더부러 증가하며 이와 같은 내방사성(耐放射性)의 평가는 시료의 IR 특성 상에서 안정제의 해이(解離)에 기인(起因)하고 있는 $1,540{\sim}1,640cm^{-1}$에서의 흡수대가 선량과 더부러 변화하는 거동으로 살필 수 있다. 가소화된 PVC에서의 내방사성의 증가는 DOP 분자구조의 일부를 형성하는 benzen 환(環)에서 방사 에너지가 공명흡수 되기 때문이라 사료(思料)되며 이와 같은 견해(見解)는 방사선량에 대한 도전율변화특성(導電率變化特性)의 고찰 결과와도 잘 일치 한다. 실용적면(實用的面)에서 $0{\sim}100Mrad$ 사이의 선량에 대한 충분(充分)한 내방사성(耐放射性)을 얻기 위하여는 30phr 전후의 DOP 첨가량이 필요하다.