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A study of NOx performance for Cu-chabazite SCR catalysts by Sulfur poisoning and desulfation (Cu-Chabazite SCR Catalysts의 황 피독 및 탈황에 의한 NOx 저감 성능에 관한 연구)

  • Nam, Jeong-Gil
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.855-861
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    • 2013
  • Small-pore Cu-chabazite SCR catalysts with high NOx conversion at low temperatures are of interest for marine diesel engines with exhaust temperatures in the range of 150 to $300^{\circ}C$. Unfortunately, fuels for marine diesel engines can contain a high level of sulfur of up to 1.5% by volume, which corresponds to a $SO_2$ level of 500 ppm in the exhaust gases for an engine operating with an A/F ratio of 50:1. This high level of $SO_2$ in the exhaust may have detrimental effects on the NOx performance of the Cu-chabazite SCR catalysts. In the present study, a bench-flow reactor is used to investigate the effects of sulfur poisoning on the NOx performance of Cu-chabazite SCR catalysts. The SCR catalysts were exposed to simulated diesel exhaust gas stream consisted of 500 ppm $SO_2$, 5% $CO_2$, 14% $O_2$, 5% $H_2O$ with $N_2$ as the balance gas at 150, 200, 250 and $300^{\circ}C$ for 2 hours at a GHSV of 30,000 $h^{-1}$. After sulfur poisoning the low-temperature NOx performance of the SCR catalyst is evaluated over a temperature range of 150-$300^{\circ}C$ to determine the extent of the catalyst deactivation. Desulfation is also carried out at 600 and $700^{\circ}C$ for 30 minutes to determine whether it is possible to recover the NOx performance of the sulfur-poisoned SCR Catalysts.

Thermophilic Biohydrogen Production from Glucose with a Long-term Operation of CSTR (CSTR의 장기운전을 통한 포도당으로부터의 고온 수소생산)

  • Ahn, Yeong-Hee;Oh, You-Kwan;Park, Sung-Hoon
    • KSBB Journal
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    • v.20 no.6
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    • pp.425-430
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    • 2005
  • Thermophilic $H_2$ was produced for 1 year using a bench-scale continuous stirred tank reactor(CSTR). The CSTR was inoculated with anaerobically digested sludge after heat treatment and fed with a glucose-based medium. The reactor showed relatively short start-up period(30 days) and high maximal $H_2$ yield(2.4 mol $H_2/mol$ glucose). Keeping pH 5.0 or less suppressed methanogenic activity. Bacteria affiliated with Thermoanaerobacterium thermosaccharolyticum kept being dominant from approximately 40 days as determined by DGGE. Environmental perturbation(pH or temperature) caused the decrease of biomass concentration in the reactor and the instability of reactor performance, $H_2$ production rate and $H_2$ yield. The unstable performance was accompanied with high concentration of lactate in the effluent. Taken together, the poor recovery of CSTR after perturbations could be partly explained by low biomass concentration and/or metabolic shift of the major population in the CSTR.

Status of soils in reclaimed land (개간지(開墾地) 토양(土壤)에 대(對)한 현황(現況) 조사(調査))

  • Shin, Chun Soo;Rhee, Gyeong Soo;Kim, Jong Deog;Shin, Yong Hwa
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.3
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    • pp.137-140
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    • 1974
  • The present-state survey was carried out on reclaimed land of entire country to grasp the farming conditions, soil characteristics and productivities. The results was summarized as follows: 1) Among farmers participating in reclamation, small farmers, which hold land under cultivation less than 1 ha occupied 42 percent of total farmers; while big farmers, hold more than 3 ha, occupied only 11.1 percent. 2) The land use of reclaimed land by reclaimed year had such big variation that mulberry land was decreasing, however, grass land markedly increased. 3) Soils less than 15 percent slope in reclaimed land occupied 68.7 percent of total reclaimed land, and steep sloping land was reclaimed through bench-terraced method, while gently sloping land, through non terraced one. 4) The chemical properties of reclaimed land was very poor, except for phosphate, all element after 10 years of reclamation was under levels of land of cultivation. 5) Amount of fertilizer application to reclaimed land was under that of recommendation. 6) The yield of reclaimed land was 30 to 86 percent of average of land under cultivation.

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Biological Phosphorus Release and Uptake on Nitrate Loadings in Anoxic Condition of SBR process (SBR 공정의 무산소조건에서 질산염농도에 따른 생물학적 인의 방출 및 흡수 특성)

  • Lee, Hee-Ja;Kim, Kwang-Soo;Cho, Yang-Seok;Kim, I-Tae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.1164-1168
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    • 2007
  • 질소 및 인 동시제거 공정 중 대표적인 연속회분식반응조(Sequencing Batch reactor: SBR)는 비교적 간편한 운전방법과 저렴한 건설비, 유입수의 부하변동에 큰 영향을 받지 않는 소규모 하수처리에 적합한 공정으로 알려져 있다. 또한 SBR 공정은 기존 활성슬러지 공법에 비해 적은 부지로 많은 양의 폐수를 처리할 수 있고 유입수 수질 및 유량변동에 따라 다양한 운전주기를 변화할 수 있으며, 유기물 제거뿐만 아니라 반응조의 변형에 의해 영양염류의 제거가 가능한 장점이 있다. 본 연구에서는 bench scale SBR 실험을 통하여 질산염의 탈질속도 및 용해성 인의 흡수와 방출속도를 측정하고, SBR 공정의 무산소조건에서 인흡수 및 탈질을 동시에 수행하는 DPB 존재의 가능성을 파악하고자 하였다. 연구결과 무산소조건에서 S-P의 방출과 흡수가 동시에 진행되었으며, 무산소조건에서 S-P의 방출속도는 $0.08{\sim}0.94\;kgS-P/kgMLSS{\cdot}d$, 흡수속도는 $0.012{\sim}0.1\;kgS-P/kgMLSS{\cdot}d$를 나타내었다. 무산소조에서 S-P의 방출 및 흡수가 진행되는 동안 탈질과정도 함께 진행되었으며, 각각의 F/M비에서 탈질속도를 측정한 결과 F/M비 $0.44\;kgCOD/kgMLSS{\cdot}d$에서는 최대 $0.16\;kgNO_3^-N/kgMLSS{\cdot}d$의 탈질속도를 나타내었다. S-P이 방출되지 않는 경우와 방출되는 경우의 비탈질속도를 비교한 결과 S-P이 방출되지 않는 경우의 비탈질속도가 S-P이 방출되는 경우의 비탈질속도보다 높았다. 이렇게 S-P이 방출되는 경우의 비탈질속도가 더 낮은 이유는 무산소 조건에서 탈질과 S-P의 방출 및 흡수가 동시에 일어나는 경우 S-P의 방출에 관여하는 미생물과 탈질에 관여하는 미생물간의 경쟁반응 때문으로 판단된다.응답법의 적용이 가능함을 보였고, 이는 보다 복잡한 관망에서의 천이류 해석이 가능함을 시사한다.$경상도지리지$\lrcorner$(慶尙道地理志)에는 상주가 8곳으로 1/3의 자기 생산을 담당하고 있었다. $\ulcorner$경상도지리지$\lrcorner$(慶尙道地理志)에는 $\ulcorner$세종실록$\lrcorner$(世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와 동년대에 동일한 목적으로 찬술되었음을 알 수 있다. $\ulcorner$경상도실록지리지$\lrcorner$(慶尙道實錄地理志)에는 $\ulcorner$세종실록$\lrcorner$(世宗實錄) $\ulcorner$지리지$\lrcorner$(地理志)와의 비교를 해보면 상 중 하품의 통합 9개소가 삭제되어 있고, $\ulcorner$동국여지승람$\lrcorner$(東國與地勝覽) 에서는 자기소와 도기소의 위치가 완전히 삭제되어 있다. 이러한 현상은 첫째, 15세기 중엽 경제적 태평과 함께 백자의 수요 생산이 증가하자 군신의 변별(辨別)과 사치를 이유로 강력하게 규제하여 백자의 확대와 발전에 걸림돌이 되었다. 둘째, 동기(銅器)의 대체품으로 자기를 만들어 충당해야할 강제성 당위성 상실로 인한 자기수요 감소를 초래하였을 것으로 사료된다. 셋째, 경기도 광주에서 백자관요가 운영되었으므로 지방인 상주지역에도 더 이상 백자를 조달받을 필요가 없이, 일반 지방관아와 서민들의 일상용기 생산으로 전락하여 소규모화 되었을 것이라고 사료된다.장 운동기능을 향상시키는 유효성분의 보강 등이 필요하다는 점도 알 수 있었다.더불어 산화물질 해독에 관여하는 다른 유전자

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Development of Korean Geoid Model and Verification of its Precision (우리나라 지오이드 모델 구축 및 정밀도 검증)

  • Lee, Jisun;Kwon, Jay Hyoun;Baek, Kyeong Min;Moon, Jiyeong
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.30 no.5
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    • pp.493-500
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    • 2012
  • The previous geoid model developed in early 2000s shows 14cm level of precision due to the problems on distribution, and quality of the land gravity and GPS/Leveling data. From 2007, the new land and airborne gravity data as well as GPS/Leveling data having high quality and regular distribution has been obtained. In 2011, a new gravimetric geoid model has been constructed with precision of 5.29cm which was improved about 27% comparing to the previous model. However, much more land gravity data has been collected at the control point, bench marks and triangulation points since 2010. Also, GPS/Leveling data having 10km spacing over whole country has been obtained through the project which is for the construction of new control points. In this study, new gravimetric geoid has been calculated based on the all available gravity data up to present. The geoid height shows the range from 18.05m to 32.70m over whole country and its precision is 5.76cm. The degree of fit and precision of hybrid geoid model are 3.60cm and 4.06cm, respectively. At the end, 3.35cm of the relative precision in 15km baseline has been calculated to confirm its practical usage. Especially, it has been founded that regional bias occurred at the Kangwon and coastal area due to problems on the leveling data. Also, some inland points show inconsistent large difference which needs to be verified by analyzing the unified control points results.

Simultaneous Removal of Nitrogen and Phosphorus Leached from Farming Feed by the Marine Bacteria, Bacillus sp. CK-10 and Bacillus CK-13, Isolated from Shrimp Farming Pond (새우양식장에서 분리한 해양세균 Bacillus sp. CK-10과 Bacillus sp. CK-13에 의한 양식사료에 포함된 질소와 인의 동시제거)

  • Chun Jae-Woo;Ma Chae-Woo;Kahng Hyung-Yeel;Oh Kye-Heon
    • Microbiology and Biotechnology Letters
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    • v.33 no.2
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    • pp.136-141
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    • 2005
  • A bench-scale feasibility study was conducted with solid farming feed to evaluate a treatment process for microbiological removal of nitrogen (N) and phosphorus (P). Strains, Bacillus sp. CK-10 and Bacillus sp. CK-13, were originally isolated from water samples of shrimp farming pond. Simultaneous removal of N/P in marine media was monitored in the co-cultures, CK-10 and CK-13. As the results, $400\;{\mu}M\;NH^{+}_4$ and $400\;{\mu}M\;NO^{-}_2$ were eliminated within 12 hours and $NO^{-}_3$ within 36 hours, and $500\;{\mu}M\;PO^{-3}_4$ was completely disappeared within 36 hours from the media. Cultures of CK-10 and CK-13 were applied for removal of N/P leached from shrimp farming fred. HPAEC-PAD system was used to analyze sugars in farming feed, resulting in resolution of various sugars including glucose, galactose, galatosamine, mannose, and fucose. $0.2\%$ (w/v) Pulp densities of the farming feed contained approximately $33.3\;{\mu}M\;NH^{+}_4,\;12.9\;{\mu}M\;NO^{-}_2.\;81.5\;{\mu}M\;NO^{-}_3\;and\;248\;{\mu}M\;PO^{-3}_4$ which could dissolved within 72 hours of leaching in aqueous solution followed by bacterial removal. Complete bacterial removal of N/P was achieved within 84 hours at $0.2\%$ of the feed in co-cultures, whereas single cultures removed to incompletion of N/P during the incubation period. This work demonstrated that test cultures, CK-10 and CK-13 showed effective removal of N/P derived from shrimp farming feed.

The Effect of Kinesio Taping on Muscle Strength Improvement, Blood Fatigue Factors, Muscle Fatigue and Damage Index (Kinesio taping이 근력, 혈중 피로물질 및 근 손상 물질 농도변화에 미치는 영향)

  • Lee, Min-Sun;Paik, Il-Young;Kwak, Yi-Sub;No, Hee-Tae;Jin, Hwa-Eun
    • Journal of Life Science
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    • v.20 no.6
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    • pp.870-876
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    • 2010
  • The purpose of this study was to examine the effect of kinesio taping on muscle strength and changes of muscle fatigue and damage. 10 male subjects participated in 1-RM and isometric cybex muscle strength tests with and without taping application. Muscle strength (bench press, leg press) and extension (knee, shoulder) strength were significantly increased after taping, but there was no significant difference in flexion (knee, shoulder) strength. The concentration of fatigue factors (ammonia, phosphorous), muscle damage index substances (CK, LDH), IGF-I and creatinine were reduced after taping, but there were no significant differences.

Characteristics of Glucose Oxidase Reaction of Onion Juice (양파 착즙액과 포도당 산화효소의 반응 특성)

  • Choi, Bong-Young;Lee, Eun-Mi;Kim, Young-Ran;Kim, Hyun-Jong;Chung, Bong-Woo
    • Korean Journal of Food Science and Technology
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    • v.35 no.3
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    • pp.417-422
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    • 2003
  • The onions are considered to be a favorable functional source of beverage because they contain much sugar and various nutrients, and they are juicy vegetable. Recently, consumers have a new trend to take functional foods with health benefits. To meet this need, this study was the basic research to establish a manufacturing process of functional onion beverage by glucose oxidase. Glucose oxidase catalyzes reaction of glucose oxidation and makes generation of gluconic acid. Kinetics of the reaction was also investigated, and maximum glucose consumption rate $(V_{max})$ of $26.1{\times}10^{-2}\;g/L{\cdot}min$ and $K_m$ of 5.84 g/L were obtained. Optimum conditions were obtained when the glucose oxidase catalyzed reaction was carried out at temperature of $25^{\circ}C$, agitation rate of 450 rpm and aeration rate of 4 vvm in a 2.5 L jar fermentor. Finally, the enzyme reactor was 10-times scaled up and a similar glucose oxidation performance was achieved in the scaled-up reactor.

Stripping of Ion-Implanted Photoresist Using Cosolvent-Modified Supercritical Carbon Dioxide (공용매로 변형된 초임계 이산화탄소를 이용한 이온 주입 포토레지스트 세정)

  • Jung, In-Il;Kim, Ju-Won;Lee, Sang-Yun;Kim, Woo-Sik;Ryu, Jong-Hoon;Lim, Gio-Bin
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.27-32
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    • 2005
  • We propose an effective and environmentally friendly dry stripping method using a supercritical carbon dioxide ($SCCO_2$) system modified by a single and multiple cosolvents to remove ion-implanted photoresist and residue from a wafer surface at three different temperatures (97, 148, $200^{\circ}C$) and pressures (200, 300, 400 bar). After high dose of ion implantation the photoresist was not easily removed by using pure $SCCO_2$, but swollen. The $SCCO_2$ system modified by single cosolvents and multiple cosolvents mixed with aprotic solvents could not effectively remove the heavy organics, but swell them. However, the $SCCO_2$ system modified with multiple cosolvent (5%, v/v) composed of DMSO and DIW showed high removal efficiency for ion-implanted photoresists at $97^{\circ}C$ and 200 bar for 30 min (about 80%). In this study it has been shown that the dry stripping method using $SCCO_2$ system modified with multiple cosolvents could replace either plasma ashing or acid and solvent wet bench method and dramatically reduce accompanied chemical usage and disposal.

Drying Characteristic of High Moisture Coal using a Flash Dryer (기류건조기를 이용한 고수분 석탄의 건조 특성)

  • Kim, Sang Do;Lee, Si Hyun;Rhim, Young Joon;Choi, Ho Kyung;Lim, Jeong Hwan;Chun, Dong Hyuk;Yoo, Ji Ho
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.106-111
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    • 2012
  • Drying characteristic of high moisture coal using a 5 kg/hr bench scale flash dryer was investigated. Moisture content and heating value of raw coal as received basis were 29.74 wt% and 4,270 kcal/kg, respectively. Gas inlet temperature and gas inlet flow rate were $400{\sim}600^{\circ}C$ and 10~20 m/sec, respectively. The raw coal was ground and classified to the particle size range of $100{\sim}2,000{\mu}m$. The moisture removal rate of raw coal was dramatically increased with increasing gas inlet temperature and decreasing gas inlet flow rate. The heating value of dried coal was increased to 5,100~5,900 kcal/kg. To examine the chemical change on the surface of high moisture coal during flash drying process, FT-IR spectral analysis was carried out. As a result, major changes in hydroxyl, carboxyl and carbonyl peak was confirmed.