• Korean Journal of Materials Research
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• v.31 no.11
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• pp.614-618
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• 2021

As the size of market for electric vehicles and energy storage systems grows, the demand for lithium-ion batteries (LIBs) is increasing. Currently, commercial LIBs are fabricated with liquid electrolytes, which have some safety issues such as low chemical stability, which can cause ignition of fire. As a substitute for liquid electrolytes, solid electrolytes are now being extensively studied. However, solid electrolytes have disadvantages of low ionic conductivity and high resistance at interface between electrode and electrolyte. In this study, Li₇La₃Zr₂O₁₂ (LLZO), one of the best ion conducting materials among oxide based solid electrolytes, is fabricated through RF-sputtering and various electrochemical properties are analyzed. Moreover, the electrochemical properties of LLZO are found to significantly improve with co-sputtered Li₂O. An all-solid thin film battery is fabricated by introducing a thin film solid electrolyte and an Li₄Ti₅O₁₂ (LTO) cathode; resulting electrochemical properties are also analyzed. The LLZO/Li₂O (60W) sample shows a very good performance in ionic conductivity of 7.3×10^-8 S/cm, with improvement in c-rate and stable cycle performance.

• Journal of the Korean Electrochemical Society
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• v.27 no.2
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• pp.55-72
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• 2024

Secondary batteries are used as an essential renewable energy source in our lives, such as electric vehicles and energy storage systems (ESS), as an alternative to fossil fuels due to global warming. However, cases of battery fires and explosions have been reported due to thermal runaway in secondary batteries due to various causes such as overdischarge, high-speed charging and discharging, and external short circuit, and great efforts are being made to find solutions suitable for each cause. In particular, as cases presumed to be caused by the overcharging process have been reported, this review will examine the chemical reactions of secondary batteries that can occur during the overcharging process and discuss risk investigation methods to check and prevent them.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.4
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• pp.39-48
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• 2020

Since the fire accident of ESS (energy storage system) occurred at Gochang KEPCO Power Testing Center in August 2017, 29 fire cases with significant property losses have occurred in Korea. Although the cause of fire accidents have not been identified precisely, it should be considered battery and PCS (power conditioning system) as well as unbalance issues in the distribution system. In particular, circulating currents in a neutral line of a grid-connected transformer, which can affect a magnetized current, may have a negative effect on the ESS with unintentional core saturation and surge voltages at the secondary side of the transformer. Therefore, this paper proposes the modeling of the distribution system, which was composed of a substation, grid-connected transformer, and customer loads using PSCAD/EMTDC S/W, to analyze the phenomena of circulating current and surge voltages of the transformer with unbalanced currents in the distribution system. This paper presents a countermeasure for a circulating current with the installation of NGR (neutral grounding resistor) in grid-connected transformer. From the simulation results, it is clear that exceeding the circulating current and surge voltage at the secondary side of the transformer can be one of the causes of fire accidents.

• Journal of the Korean Society of Safety
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• v.28 no.4
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• pp.38-42
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• 2013

This study performed the quantitative distribution analysis of created voids to an insulator when applying general flame and DC short-circuit current to 2.5 $mm^2$ HIV (600 V Grade Heat-Resistant Polyvinyl Chloride Insulated Wires). The diameter of cross-section of HIV normal product and the radius of conductor were measured to be 3.3 mm and 1.8 mm. The exterior of HIV exposed to general flame showed severe carbonization and its interior exhibited voids created by dechlorination reaction. This study observed the characteristics that, when the shortcircuit current applied for 2 seconds from a DC 12 V lead battery, the conductor and neighboring insulator were melted, causing the insulator adhering to the conductor. On average, 87 voids were created on 10 mm of the HIV. The average diameter of voids was 0.25 mm. In addition, it was found that, when the short-circuit current applied for 4 seconds, the interior of insulator in contact with conductor severely carbonized and showed exfoliation phenomenon. On average, 47 voids were created, with more voids at the bottom. The average diameter of voids was 0.20 mm. When the short-circuit current for 6 seconds, most parts of upper part of conductor was carbonized, 20 voids were created. The average diameter of voids was measured to be 0.24 mm. It could be seen that the created voids received little influence by the type of energy source and the number of created voids was reduced as the energy supply time increased.

• Journal of the Korean Society of Safety
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• v.24 no.4
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• pp.28-33
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• 2009

This study examined the mounting status of cigar lighter receptacles for vehicles and analyzed the tracking phenomenon that occurs when foreign material entered a cigar lighter receptacle to obtain data for the analysis of accident investigation. Regardless of the vehicle's output, cigar lighter receptacles are mounted in a vehicle horizontally, vertically, or at tilting or inclined angle. The tilting type cigar lighter receptacle is much easier to use but current leakage resulting from foreign materials (coffee, beverages, water, etc.) falling into the cigar lighter receptacle may cause a fire to start. This study used a vehicle battery (DC 12V) as a power supply for the tracking test and configured its circuit in the same way as that of an electrical device in a vehicle. The tracking phenomenon that occurred in the standby mode of the vehicle exhibited a fine flame and an irregular occurrence of smoke. While this tracking phenomenon was occurring, the leakage current and the reaching distance of the flame were measured to be approximately 930mA and $20{\sim}50cm$, respectively. It is thought that the resultant flame may ignite toluene, dust, cigarettes, etc. It was observed that as the tracking progressed, the internal metal socket melted and a hole was created, the surface of which was also severely carbonized. In addition, the electrical resistance of the carbonized conductive path was measured to be approximately $30{\Omega}$. It is thought that this much resistance may cause local heating when leakage current flows and could ignite any nearby flammable material.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.9 no.3
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• pp.901-920
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• 2015

Wireless Sensor Networks (WSNs) are widely used in geographically isolated applications like military border area monitoring, battle field surveillance, forest fire detection systems, etc. Uninterrupted power supply is not possible in isolated locations and hence sensor nodes live on their own battery power. Localization of sensor nodes in isolated locations is important to identify the location of event for further actions. Existing localization algorithms consume more energy at sensor nodes for computation and communication thereby reduce the lifetime of entire WSNs. Existing approaches also suffer with less localization coverage and localization accuracy. The objective of the proposed work is to increase the lifetime of WSNs while increasing the localization coverage and localization accuracy. A novel intelligent unmanned aerial vehicle anchor node (IUAN) is proposed to reduce the communication cost at sensor nodes during localization. Further, the localization computation cost is reduced at each sensor node by the proposed intelligent arc selection (IAS) algorithm. IUANs construct the location-distance messages (LDMs) for sensor nodes deployed in isolated locations and reach the Control Station (CS). Further, the CS aggregates the LDMs from different IUANs and computes the position of sensor nodes using IAS algorithm. The life time of WSN is analyzed in this paper to prove the efficiency of the proposed localization approach. The proposed localization approach considerably extends the lifetime of WSNs, localization coverage and localization accuracy in isolated environments.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.330-336
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• 2012

FCEV uses 250 ~ 450 V instead of using 12 V battery. High voltage vehicle can cause electric shock, fire and explosion accident. Therefore, it has potential factors that can cause hazard of safety for users. United states of America and Europe legislate regulations such as ECE R100, FMVSS 305 for regulating electrical safety during driving or after collision. The company manufacturing high voltage components must do advanced R&D about Method for improving and confirming the safety of high voltage. We develop the specific hardware components of high voltage wiring system for the power train system and power supply system of Hyundai Motors FCEV. This paper shows test method of insulative performance for securing the electrical safety of high voltage components such as power cable, connectors and buss-bar, and proposals the guide line value for human safety of FCEV according to the test result of our development components.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.17 no.8
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• pp.2209-2221
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• 2023

As the supply of electric vehicles increases, research on wireless charging methods for convenience has been increasing. Because the electric vehicle wireless transmission device is installed on the ground and the electric vehicle battery is installed on the floor of the vehicle, the transmission and reception antennas are approximately 15-30 cm away, and thus strong magnetic fields are exposed during wireless charging. When a metallic foreign object is placed in the magnetic field area, an eddy current is induced to the metallic foreign object, and heat is generated, creating danger of fire and burns. Therefore, this study proposes a method to detect metallic foreign objects in the magnetic field area of a wireless electric vehicle charging system. An active detection-only coil array was used, and an LC resonance circuit was constructed for the frequency of the supply power signal. When a metallic foreign object is inserted into the charging zone, the characteristics of the resonance circuit are broken, and the magnitude and phase of the voltage signal at both ends of the capacitor are changed. It was confirmed that the proposed method has about 1.5 times more change than the method of comparing the voltage magnitude at one node.

• Corrosion Science and Technology
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• v.23 no.4
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• pp.334-342
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• 2024

The need for efficient and sustainable energy storage solutions has emerged due to a rapidly increasing energy demand and growing concerns about environmental issues. Among various energy storage methods, lithium secondary batteries are widely used in a variety of electronic devices such as smartphones, laptops, electric vehicles, and large-scale power storage systems due to their high energy density, long lifespan, and cost competitiveness. Recently, all-solid-state batteries (ASSBs) have attracted great attention because they can reduce the risk of fire associated with liquid electrolytes. Additionally, using high-capacity alternative anodes and cathodes in ASSBs can enhance energy density. However, ASSBs that use solid electrolytes experience a degradation in their electrochemical performances due to resistance at solid-solid interfaces. These interfaces can also result in poor physical contact and the presence of products formed from chemical and electrochemical reactions. Solving this interface problem is a critical issue for the commercialization of ASSBs. This review summarizes interfacial reactions between the cathode and solid electrolyte, along with research aimed at improving these interactions. Future development directions in this field are also discussed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.10
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• pp.598-602
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• 2018

This study examined the characteristics of the waste catalyst used in the petroleum refinery operations. The total pore volume, specific surface area, and average pore size of the spent catalyst used in the petroleum refinery operations were 3.96cc/g, 13.81m2/g, and 1.15A, respectively. The weight loss observed in the range from $25^{\circ}C-700^{\circ}C$ for the spent catalysts using TG and DTA was approximately 23 wt. %. EDS analysis of the waste catalyst sample showed that the five major components were vanadium, nickel, manganese, iron, and copper. The extraction system is attractive for liquid-liquid extraction. In this study, Cynex 272 was used to extract vanadium from waste catalyst. The electrochemical characteristics of the extracted vanadium solution were measured by cyclic voltammetry (CV). As a result, an oxidation / reduction peak appeared, indicating the potential of an electrolytic solution.