• Applied Chemistry for Engineering
• /
• v.29 no.6
• /
• pp.635-644
• /
• 2018

Lithium ion batteries have been broadly used in various applications to our daily life such as portable electronics, electric vehicles and grid-scale energy storage devices. Significant efforts have recently been made on developing electrode materials for lithium ion batteries that meet commercial needs of the high energy density, light weight and low cost. In this review, we summarize the principles and recent research advances in cathode and anode materials for lithium ion batteries, and particularly emphasize electrode material designs and advanced characterization techniques.

• Applied Chemistry for Engineering
• /
• v.34 no.4
• /
• pp.365-382
• /
• 2023

A lithium metal anode with high energy density has the potential to revolutionize the field of energy storage systems (ESS) and electric vehicles (EVs) that utilize rechargeable lithium-based batteries. However, the formation of lithium dendrites during cycling reduces the performance of the battery while posing a significant safety risk. In this review, we discuss various strategies for achieving dendrite-free lithium metal anodes, including electrode surface modification, the use of electrolyte additives, and the implementation of protective layers. We analyze the advantages and limitations of each strategy, and provide a critical evaluation of the current state of the art. We also highlight the challenges and opportunities for further research and development in this field. This review aims to provide a comprehensive overview of the different approaches to achieving dendrite-free lithium metal anodes, and to guide future research toward the development of safer and more efficient lithium metal anodes.

• Proceedings of the KIPE Conference
• /
• 2020.08a
• /
• pp.49-51
• /
• 2020

본 논문에서는 전기자동차 급속 충전 시 배터리 팩의 온도 모사를 위한 열 모델링 기법을 제안한다. 배터리 등가 회로 모델을 기반으로 배터리 팩 내부 발열량을 계산하고, 배터리 열 모델 구성을 위한 파라미터 추출 실험 방안을 제안하다. 또한, 전기자동차 방열 시스템의 영향 등으로 인한 발열량 변화를 실시간으로 보정하여 온도 모사 정확도를 개선한다. 열 모델링 기법의 유효성 검증을 위하여 전기자동차용 배터리 팩 기반의 시뮬레이션 및 실험을 진행한다.

• Electronics and Telecommunications Trends
• /
• v.38 no.6
• /
• pp.128-136
• /
• 2023

Lithium accounts for only 0.0017% of the earth crust, and it is produced in geographically limited regions such as South America, the United States, and China. Since the first half of 2017, the price of lithium has been continuously increasing, and with the rapid adoption of electric vehicles, lithium resources are expected to be depleted in the near future. In addition, economic blocs worldwide face intensifying scenarios such as competition for technological supremacy and protectionism of domestic industries. Consequently, Korea is deepening its dependence on China for core materials and is vulnerable to the influence of the United States Inflation Reduction Act. We analyze post-lithium secondary battery technologies that rely on more earth-abundant elements to replace lithium, whose production is limited to specific regions. Specifically, we focus on the technological status and issues of sodium-ion, zinc-air, and redox-flow batteries. In addition, research trends in post-lithium secondary batteries are examined. Post-lithium secondary batteries seem promising for large-capacity energy storage systems while reducing the costs of raw materials compared with existing lithium-based technologies.

• Transactions of the Korean hydrogen and new energy society
• /
• v.28 no.3
• /
• pp.287-294
• /
• 2017

EVs manufacturers typically target a range of 300 km on a fully charged battery. Many studies have been conducted to improve these disadvantages. As a results, the mileage of EVs is expected to increase significantly. However, as the distance traveled by EVs increases, current test method (SCT) have many difficulties. The biggest problem is that it takes a lot of time to test an EVs and greatly increases the error rate during the test period. In order to solve these problems, this paper discusses the fuel economy test method of EVs for energy efficiency and mileage. The comparison of test methods was achieved by chassis dynamometer test about EVs. These review of test methods are intended to both improve testing efficiency and provide a practical testing methodology that can be easily adapted to accommodate future testing enhancements. In conclusion, the results of MCT mode and SCT mode comparison show similar results within 3 %, confirming that the test method is appropriate. Also, as the CSCM distance becomes shorter in the MCT mode, the mileage becomes longer and the fuel economy becomes lower. As a result, the error from the SCT test results is expected to increase. In order to minimize the error of SCT measurement fuel economy, it is recommended to maximize the CSCM driving distance. However, since the timing of the EOT is not clearly known, it is reasonable to define the allowable range of the CSCE to be within 20 % of the MCT total mileage.

• Journal of Communications and Networks
• /
• v.14 no.6
• /
• pp.662-671
• /
• 2012

Plug-in hybrid electric vehicles (PHEVs) will be widely used in future transportation systems to reduce oil fuel consumption. Therefore, the electrical energy demand will be increased due to the charging of a large number of vehicles. Without intelligent control strategies, the charging process can easily overload the electricity grid at peak hours. In this paper, we consider a smart charging and discharging process for multiple PHEVs in a building's garage to optimize the energy consumption profile of the building. We formulate a centralized optimization problem in which the building controller or planner aims to minimize the square Euclidean distance between the instantaneous energy demand and the average demand of the building by controlling the charging and discharging schedules of PHEVs (or 'users'). The PHEVs' batteries will be charged during low-demand periods and discharged during high-demand periods in order to reduce the peak load of the building. In a decentralized system, we design an energy cost-sharing model and apply a non-cooperative approach to formulate an energy charging and discharging scheduling game, in which the players are the users, their strategies are the battery charging and discharging schedules, and the utility function of each user is defined as the negative total energy payment to the building. Based on the game theory setup, we also propose a distributed algorithm in which each PHEV independently selects its best strategy to maximize the utility function. The PHEVs update the building planner with their energy charging and discharging schedules. We also show that the PHEV owners will have an incentive to participate in the energy charging and discharging game. Simulation results verify that the proposed distributed algorithm will minimize the peak load and the total energy cost simultaneously.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2012.05a
• /
• pp.73-73
• /
• 2012

Modern technology-driven society largely relies on hybrid electric vehicles or electric vehicles for eco-friendly transportation and the use of high technology devices. Lithium rechargeable batteries are the most promising power sources because of its high energy density but still have a challenge. Graphite is the most widely used anode material in the field of lithium rechargeable batteries due to its many advantages such as good cyclic performances, and high charge/discharge efficiency in the initial cycle. However, it has an important safety issue associated with the dendritic lithium growth on the anode surface at high charging current because the conventional graphite approaches almost 0 V vs $Li/Li^+$ at the end of lithium insertion. Therefore, a fundamental solution is to use an electrochemical redox couple with higher equilibrium potentials, which suppresses lithium metal formation on the anode surface. Among the candidates, $Li_4Ti_5O_{12}$ is a very interesting intercalation compound with safe operation, high rate capability, no volume change, and excellent cycleability. But the insulating character of $Li_4Ti_5O_{12}$ has raised concerns about its electrochemical performance. The initial insulating character associated with Ti4+ in $Li_4Ti_5O_{12}$ limits the electronic transfer between particles and to the external circuit, thereby worsening its high rate performance. In order to overcome these weak points, several alternative synthetic methods are highly required. Hence, in this presentation, novel ways using a synergetic strategy based on 1D architecture and surface coating will be introduced to enhance the kinetic property of Ti-based electrode. In addition, first-principle calculation will prove its significance to design Ti-based electrode for the most optimized electrochemical performance.

• Journal of Electrical Engineering and Technology
• /
• v.13 no.1
• /
• pp.143-151
• /
• 2018

In this paper, a novel hybrid configuration combining a phase-shift full-bridge (PSFB) and a half-bridge resonant LLC converter is proposed for the On-Board Charger of Electric Vehicles (EVs). In the proposed converter, the PSFB converter shares the lagging-leg switches with half-bridge resonant converter to achieve the wide ZVS range for the switches and to improve the efficiency. The output voltage is modulated by the effective-duty-cycle of the PSFB converter. The proposed converter employs an active reset circuit composed of an active switch and a diode for the transformer which makes it possible to achieve zero circulating current and the soft switching characteristic of the primary switches and rectifier diodes regardless of the load, thereby making the converter highly efficient and eliminating the reverse recovery problem of the diodes. In addition an optimal power sharing strategy is proposed to meet the specification of the charger and to optimize the efficiency of the converter. The operation principle the proposed converter and design considerations for high efficiency are presented. A 6.6 kW prototype converter is fabricated and tested to evaluate its performance at different conditions. The peak efficiency achieved with the proposed converter is 97.7%.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.13 no.3
• /
• pp.35-40
• /
• 2005

In the present study, the influence of operating conditions on fuel economy for hybrid electric vehicle was analyzed. In order to accomplish this, vehicle speed, engine speed, battery current and voltage, SOC (state of charge),motor speed and torque, generator speed and torque, engine coolant temperature etc. were measured in real time. The tests were carried out under different driving cycles which are urban and highway cycles, KOREA CITY cycle and on-road driving, and also under various operating conditions such as different initial SOC, with or without regenerative braking etc.. Generally, conventional gasoline engines show a poor fuel economy at stop and go driving, because braking energy is wasted and the engine is operated in low thermal efficiency regions. However, in case of hybrid vehicles, higher fuel economy can be obtained because of utilizing the maximum thermal efficiency regions of engine, idling stop of engine, and regenerative braking etc..

• Transactions of the Korean Society of Automotive Engineers
• /
• v.21 no.6
• /
• pp.31-39
• /
• 2013

A virtual chassis platform for Fuel Cell Hybrid Electric Vehicles(FCHEV) has been developed, and a virtual platform similar to the actual system has been composed. In addition, major components such as a motor, fuel cell and battery for the virtual platform have been constructed by using a mathematical formulation. The FCHEV virtual platform using a detailed model based on the mathematical formula is capable of simulating various conditions according to changes of the control logic and component modules to evaluate performance, considering the vehicle dynamic characteristics. Usability of the mathematical model has been verified by comparative simulations according to the motor current control variation. In addition, reliability of the developed virtual chassis platform has been verified by simulating its fuel consumption with the UDDS(Urban Dynamometer Driving Schedule) FTP-72 velocity profile.