• Title/Summary/Keyword: Battery Characteristics

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Synthesis and Characterization of Li-Graphite intercalation Compounds (리튬-흑연 층간 화합물의 합성 및 특성)

  • Oh, Won-Chun;Kim, Myung-Kun;Ko, Young-Shin
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.315-320
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    • 1994
  • Li-GICs as a high performance energy storager were synthesized as a function of the Li content by the admixture and add-pressure method. The characteristics of these prepared compounds have been determined from the studies by X-ray diffraction, UV-VIS spectrometry and CHN analysis. It follows from the results of X-ray diffraction that the lower-stage intercalation compounds are formed as the Li contents increase, however the mixed stages in these compounds are also observed. In the case of the $Li_{40wt%}$, the compound with the structure of stage 1 has been predominently, but the structure of only stage 1 is not obtained. The $d_{001}$ value of stage 1 was determined to be ca. $3.70{\AA}$. An analysis of spectrometric data shows that each of the compounds gives distingushible energy state spectra. It is seen from the spectra that the positions of $R_{min}$ values, with increase in the Li contents, are shifted in the region of higher energy state. Such a result can be attributed to the formation of stable stages. The results of CHN analysis allow us to find the mixing state related to chemical compositions of the intercalated compounds and the superiority to admixture and add-pressure method. From the results determined, it reveals that $Li_{10wt%}$-GIC and $Li_{20wt%}$-GIC can be utilized for an anode of rechargable battery.

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Multi-query Indexing Technique for Efficient Query Processing on Stream Data in Sensor Networks (센서 네트워크에서 스트림 데이터 질의의 효율적인 처리를 위한 다중 질의 색인 기법)

  • Lee, Min-Soo;Kim, Yearn-Jeong;Yoon, Hye-Jung
    • Journal of Korea Multimedia Society
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    • v.10 no.11
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    • pp.1367-1383
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    • 2007
  • A sensor network consists of a network of sensors that can perform computation and also communicate with each other through wireless communication. Some important characteristics of sensor networks are that the network should be self administered and the power efficiency should be greatly considered due to the fact that it uses battery power. In sensor networks, when large amounts of various stream data is produced and multiple queries need to be processed simultaneously, the power efficiency should be maximized. This work proposes a technique to create an index on multiple monitoring queries so that the multi-query processing performance could be increased and the memory and power could be efficiently used. The proposed SMILE tree modifies and combines the ideas of spatial indexing techniques such as k-d trees and R+-trees. The k-d tree can divide the dimensions at each level, while the R+-tree improves the R-tree by dividing the space into a hierarchical manner and reduces the overlapping areas. By applying the SMILE tree on multiple queries and using it on stream data in sensor networks, the response time for finding an indexed query takes in some cases 50% of the time taken for a linear search to find the query.

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Modeling, Preparation, and Elemental Doping of Li7La3Zr2O12 Garnet-Type Solid Electrolytes: A Review

  • Cao, Shiyu;Song, Shangbin;Xiang, Xing;Hu, Qing;Zhang, Chi;Xia, Ziwen;Xu, Yinghui;Zha, Wenping;Li, Junyang;Gonzale, Paulina Mercedes;Han, Young-Hwan;Chen, Fei
    • Journal of the Korean Ceramic Society
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    • v.56 no.2
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    • pp.111-129
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    • 2019
  • Recently, all-solid-state batteries (ASSBs) have attracted increasing interest owing to their higher energy density and safety. As the core material of ASSBs, the characteristics of the solid electrolyte largely determine the performance of the battery. Thus far, a variety of inorganic solid electrolytes have been studied, including the NASICON-type, LISICON-type, perovskite-type, garnet-type, glassy solid electrolyte, and so on. The garnet Li7La3Zr2O12 (LLZO) solid electrolyte is one of the most promising candidates because of its excellent comprehensively electrochemical performance. Both, experiments and theoretical calculations, show that cubic LLZO has high room-temperature ionic conductivity and good chemical stability while contacting with the lithium anode and most of the cathode materials. In this paper, the crystal structure, Li-ion transport mechanism, preparation method, and element doping of LLZO are introduced in detail based on the research progress in recent years. Then, the development prospects and challenges of LLZO as applied to ASSBs are discussed.

Preparation and Electrochemical Properties of Pr1-x (Sr, Ca)xCoO3 Cathode Materials for Zinc Air Batteries (아연공기전지용 Pr1-x (Sr, Ca)xCoO3 양극촉매 제조 및 전기화학적 특성)

  • Heo, Sang-Hun;Eom, Seung-Wook;Kim, Hyun-Soo
    • Journal of the Korean Electrochemical Society
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    • v.12 no.4
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    • pp.342-348
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    • 2009
  • Zn/Air secondary batteries are high energy density type and environment-friendly. Also, they have safer properties than batteries of other type by low manufacturing cost and using the electrolyte solution. But, they have a weak concerning large output discharge. Oxygen evolution reaction(OER) and oxgen reduction reaction(ORR) in aqueous solution make a result of a decrease of cell efficiency and life span. Therefore, to minimize the voltage drop from between OCV and charge/discharge voltage is key point. The problem should be solved through developing catalysts of high efficiency. In this study, we synthesized $Pr_{1-x}(Sr,\;Ca)_x\;CoO_3$ powders by citric method and then measured physical characteristics of each powder by XRD, SEM, TGA etc. We examined its electrochemical properties by the cathodic polarization, anodic polarization and cyclic voltammogram. We achieved results that new catalysts showed better performances than existing $La_{1-x}Sr_xCoO_3$, $La_{1-x}Ca_xCoO_3$, ect. catalysts prepared in our lab.

Economic and Environmental Assessment of a Renewable Stand-Alone Energy Supply System Using Multi-objective Optimization (다목적 최적화 기법을 이용한 신재생에너지 기반 자립 에너지공급 시스템 설계 및 평가)

  • Lee, Dohyun;Han, Seulki;Kim, Jiyong
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.332-340
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    • 2017
  • This study aims to propose a new optimization-based approach for design and analysis of the stand-alone hybrid energy supply system using renewable energy sources (RES). In the energy supply system, we include multiple energy production technologies such as Photovoltaics (PV), Wind turbine, and fossil-fuel-based AC generator along with different types of energy storage and conversion technologies such as battery and inverter. We then select six different regions of Korea to represent various characteristics of different RES potentials and demand profiles. We finally designed and analyzed the optimal RES stand-alone energy supply system in the selected regions using multiobjective optimization (MOOP) technique, which includes two objective functions: the minimum cost and the minimum $CO_2$ emission. In addition, we discussed the feasibility and expecting benefits of the systems by comparing to conventional systems of Korea. As a result, the region of the highest RES potential showed the possibility to remarkably reduce $CO_2$ emissions compared to the conventional system. Besides, the levelized cost of electricity (LCOE) of the RES-based energy system is identified to be slightly higher than conventional energy system: 0.35 and 0.46 $/kWh, respectively. However, the total life-cycle emission of $CO_2$ ($LCE_{CO2}$) can be reduced up to 470 g$CO_2$/kWh from 490 g$CO_2$/kWh of the conventional systems.

A Study on the Development of the Single Station Fixed Temperature Detector of Low Power Consumption for Residential Fire Prevention (주택화재 예방을 위한 저소비 전력형 단독경보형 정온식감지기 개발에 관한 연구)

  • Park, Se-Hwa;Cho, Jae-Cheol
    • Fire Science and Engineering
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    • v.24 no.6
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    • pp.61-68
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    • 2010
  • In this paper, a research and development result for the implementation of single station fixed temperature detector for residential fire prevention is described. The detector was developed for the certification in Japanese market because of very low domestic market situation. It is in the situation that there is no other regulation especially for residential detectors in Korea, Japanese case has been reviewed. Investigation of domestic legal circumstances and a comparative study for the test standard owned by KFI (Korea Institute of Fire Industry & Technology) and JFEII (Japan Fire Equipment Inspection Institute) respectively are also indicated. The detector alarms with a buzzer and an indicating LED. In the implementation ultra low power MCU(Micro Controller Unit) is applied to control the sleeping state and the monitoring state properly with low current consumption. To sense the temperature fast response thermistor is adopted in the design of fixed temperature residential detector. Automatic test function and alarm stop function are also considered in the design. The major factors which influence to current consumption are explained for the purpose of design reference. Main electronics circuit parts related to it's characteristics of the detector are described. It is explained that the measured current and experimental result of the battery discharge can be met over 10 years operation.

A Point-based Resource Distribution Scheme and Its Characteristics for Mobile P2P Streaming Service (모바일 P2P 스트리밍 서비스를 위한 포인트 기반 자원 배분 기법과 그 특성)

  • Kim, Yangjung;Chong, Ilyoung;Han, Chimoon
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.6
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    • pp.33-42
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    • 2013
  • In the early stage of P2P, the technology was limited to narrow usage of file sharing, but currently, P2P technology has become essential to maximize the efficiency between associated technologies without additional deployment of high costly infrastructure and also the burden of the server. Especially, P2P media streaming service is a highly attractive service to mobile users. which requires a higher quality in the mobile environment in accordance with the development of technology of wired network as well as better mobile terminals. However, P2P technology should consider the trade-off between 'peer selfishness' and QoE for providing fairness. The P2P system also try to maximize the resource utilization through an incentive mechanism for service differentiation and encourage peers to contribute continuously for improving the overall system performance. In this paper, we propose an point-based incentive mechanism based on peer's contribution level and energy availability for service differentiation. We also introduce that the proposed mechanism efficiently enhances the system performance as the peer with incentive using contribution and energy obtains more effective resource distribution.

Association of Bone Lead with Neurobehavioral Test Scores in Lead Workers (연작업자들에서 골중 연량이 신경행동학적 검사성적에 미치는 영향)

  • Lee, Sung-Soo;Kim, Nam-Soo;Kim, Hwa-Sung;Ahn, Kyu-Dong;Lee, Byung-Kook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.15 no.2
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    • pp.144-152
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    • 2005
  • To evaluate the effect of lead biomarkers including bone lead on neurobehavioral test in lead workers, 652 lead workers without any occupational exposure to organic solvent, mercury and arsenic were agreed to participate this study. For the control subjects 102 non-occupationally lead exposed blue collar workers in general manufacturing industries were also joined this study. All study subjects joined this study with written informed consent. The study variables of lead exposure were blood and patella lead. For the general characteristics of study subjects, standardized questionnaire regarding age, sex, past disease history, job duration, body mass index (BMI), drinking and smoking habit were provided. For the past history of neurotoxicity related diseases, all study subjects were interviewed by qualified occupational health physician. The results obtained were as follows: 1. Compared with controls without occupational lead exposure, lead exposed subjects had worse performance on all tests(p<0.05). 2. After adjustment for covariates (age, sex, job duration, education level, BMI, smoking and drinking status), the signs of the regression coefficients for blood lead were negative for 13 of the 14 tests. Blood lead was a significant predictor of poorer scores on 8 tests (simple reaction time(ms & root MSD), Trail-Making Test B, Digit Symbol Substitution, Purdue Pegboard assembly, Digit Span Test, Benton Visual Retention, and Purdue pegboard both hand). 3. After adjustment for covariates (age, sex, job duration, education level, BMI, smoking and drinking status), the signs of the regression coefficients for patella lead were negative for 12 of the 14 tests. Patella lead was a significant predictor of poorer scores on 8 tests (simple reaction time(ms). Purdue Pegboard assembly, Digit Span Test, Benton Visual Retention. Pursuit Aiming rest (no. of correct & no. of incorrect), Purdue pegboard non-dominant hand and both hand). With above results, blood lead and patella lead were associated with poorer performance of neurobehavioral tests. In addition, patella lead was confirmed to be better predictor of manual dexterity test in neurobehavioral test battery in lead workers

Energy-Efficient Data-Aware Routing Protocol for Wireless Sensor Networks (무선 센서 네트워크를 위한 에너지 효율적인 데이터 인지 라우팅 프로토콜)

  • Lee, Sung-Hyup;Kum, Dong-Won;Lee, Kang-Won;Cho, You-Ze
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.45 no.6
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    • pp.122-130
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    • 2008
  • In many applications of wireless sensor networks, sensed data can be classified either normal or urgent data according to its time criticalness. Normal data such as periodic monitoring is loss and delay tolerant, but urgent data such as fire alarm is time critical and should be transferred to a sink with reliable. In this paper, by exploiting these data characteristics, we propose a novel energy-efficient data-aware routing protocol for wireless sensor networks, which provides a high reliability for urgent data and energy efficiency for normal data. In the proposed scheme, in order to enhance network survivability and reliability for urgent data, each sensor node forwards only urgent data when its residual battery level is below than a threshold. Also, the proposed scheme uses different data delivery mechanisms depending on the data type. The normal data is delivered to the sink using a single-path-based data forwarding mechanism to improve the energy-efficiency. Meanwhile, the urgent data is transmitted to the sink using a directional flooding mechanism to guarantee high reliability. Simulation results demonstrate that the proposed scheme could significantly improve the network lifetime, along with high reliability for urgent data delivery.

Characteristics of Saturation and Circulating Current Based on Winding and Iron Core Structure of Grid-connected Transformer in Energy Storage System (ESS 연계용 변압기의 결선방식 및 철심구조에 따른 순환전류와 포화특성에 관한 연구)

  • Tae, Dong-Hyun;Lee, Hu-Dong;Kim, Ji-Myung;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.39-48
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    • 2020
  • Since the fire accident of ESS (energy storage system) occurred at Gochang KEPCO Power Testing Center in August 2017, 29 fire cases with significant property losses have occurred in Korea. Although the cause of fire accidents have not been identified precisely, it should be considered battery and PCS (power conditioning system) as well as unbalance issues in the distribution system. In particular, circulating currents in a neutral line of a grid-connected transformer, which can affect a magnetized current, may have a negative effect on the ESS with unintentional core saturation and surge voltages at the secondary side of the transformer. Therefore, this paper proposes the modeling of the distribution system, which was composed of a substation, grid-connected transformer, and customer loads using PSCAD/EMTDC S/W, to analyze the phenomena of circulating current and surge voltages of the transformer with unbalanced currents in the distribution system. This paper presents a countermeasure for a circulating current with the installation of NGR (neutral grounding resistor) in grid-connected transformer. From the simulation results, it is clear that exceeding the circulating current and surge voltage at the secondary side of the transformer can be one of the causes of fire accidents.