• Journal of Electrochemical Science and Technology
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• v.13 no.1
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• pp.19-31
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• 2022

Lithium-ion battery development is one of the most active contemporary research areas, gaining more attention in recent times, following the increasing importance of energy storage technology. The galvanostatic intermittent titration technique (GITT) has become a crucial method among various electrochemical analyses for battery research. During one titration step in GITT, which consists of a constant current pulse followed by a relaxation period, transient and steady-state voltage changes were measured. It draws both thermodynamic and kinetic parameters. The diffusion coefficients of the lithium ion, open-circuit voltages, and overpotentials at various states of charge can be deduced by a series of titration steps. This mini-review details the theoretical and practical aspects of GITT analysis, from the measurement method to the derivation of the diffusivity equation for research cases according to the specific experimental purpose. This will shed light on a better understanding of electrochemical reactions and provide insight into the methods for improving lithium-ion battery performance.

• Carbon letters
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• v.8 no.3
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• pp.207-213
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• 2007

The properties and electrochemical characteristics of anode material using pitch-coated graphite residue compounds by heat-treatment at $600^{\circ}C$ for 1 hour were investigated. The distance of layers of pitch-coated graphite residual compounds was 3.3539 ${\AA}$, which was as same as that of graphite. Its electrochemical and charge discharge characteristics were tested according to different four types of carbon material, natural graphite, pitch-coated graphite, amorphous graphite and pitch-coated graphite residual compounds, respectively. So it was shown the best charge-discharge characteristics in all of the samples. For the electrochemical and charge-discharge characteristics, although pitch-coated graphite residual compounds had different carbon contents 70% and 80%, these two samples were shown good electrochemical and charge-discharge characteristics.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.11a
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• pp.421-424
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• 2000

We have examined the impedance characteristics and the rate characteristics of LPB. As results, the impedance of LPB decreased with increased pressing rate of electrodes, adding amounts of PVdF and VGCF. And the rate characteristics of LPB increased with the a increase of pressure-rate, PVdF and VGCF contents. The rate characteristics of LPB was improved by pressing of electrode and adding of VGCF content. And specific capacity of anode was increased with adding amounts of PVdF. Higher pressing rate of electrodes, higher adding amounts of PVdF and VGCF was necessitated good rate characteristics for lithium polymer battery.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.33 no.5
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• pp.411-417
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• 2020

In this study, we introduce a Na β"-alumina composite thick film as a solid electrolyte, to reduce the resistance of electrolyte for a Na/S battery. An alumina/zirconia composite material was used to enhance the mechanical properties of the electrolyte. A solid electrolyte of about 40 ㎛ thick was successfully fabricated through the conversion and tape-casting methods. In order to investigate the effect of the surface treatment process of the solid electrolyte on the battery performance, the electrolyte was polished by dry and wet processes, respectively, and then the Na/S batteries were prepared for analyzing the battery characteristics. The battery with the dry process performed much better than the battery made with the wet process. As a result, the battery manufactured by the dry process showed excellent performance. Therefore, it is confirmed that the surface treatment process of the solid electrolyte has an important effect on the battery capacity and coulombic efficiency, as well as the interface reaction.

• Journal of the Korean Society of Industry Convergence
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• v.23 no.3
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• pp.491-498
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• 2020

Recently, In the production line of batteries, charge and discharge tests are essential to verify battery characteristics. In this case, the battery charging uses a unidirectional AC/DC converter capable of output voltage and current control, and the discharge uses a resistive load. Since this method consumes energy during discharge, it must be replaced with a bi-directional AC/DC converter system capable of charging and discharging. Although it is difficult to replace the connected inverter part of the bi-directional AC/DC converter system due to the high cost, the spread of the solar-connected inverter rapidly increases as the current solar supply business is activated, and thereby the solar-connected type Inverter prices are plunging. If it can be used as a power converter for battery discharge without program modification of the solar-powered inverter, it will have competition. In this paper, propose a new battery discharge system using a combination of a photovoltaic DC/DC simulator and photovoltaic PCS using a battery to be used as a power converter for battery discharge without program modification of a low-cost photovoltaic inverter. In addition, propose an optimal solar characteristic curve for the stable operation of PCS. The validity of the proposed system was verified using a 500[W] class solar DC/DC simulator and a solar PCS prototype.

• Journal of Ocean Engineering and Technology
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• v.35 no.1
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• pp.1-12
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• 2021

As increasing the international community's awareness of greenhouse gas reduction, the demand for eco-friendly ship fuel has accelerated recently. The fundamental aim of this study is to develop a new type of fully electrified ferry for passengers and cars considering Korean domestic coastal environmental conditions. Several technical difficulties are encountered in applying a fully electric propulsion system based on removable battery systems into a ship due to limitations imposed by the batteries' size and capacity. This paper reviews and analyzes marine environment regulations strengthened recently, technology trends related to fully electric propulsion vessels in each country, and Korean domestic coastal environments. We propose a new fully electrified car ferry design with a displacement of 400 t applied in Korea. It is powered by removable battery systems pre-charged in a safe inland charging station. The mobile battery system is developed to enable roll-on and roll-off using wheels. The characteristics of the ship motion are analyzed based on the weight and location of the battery systems. We expect our battery systems to be applicable to larger ships in the future.

• Design & Manufacturing
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• v.17 no.1
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• pp.48-55
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• 2023

In this study, on the structure simulation for manufacturing a high strength/light weight 48V battery housing for a mild hybrid vehicle was conducted. Compression analysis was performed in accordance with the international safety standards(ECE R100) for existing battery housings. The effect of plastic materials on compressive strength was analyzed. Three models of truss, honeycomb and grid rib for the battery housing were designed and the strength characteristics of the proposed models were analyzed through nonlinear buckling analysis. The effects of the previous existing rib, double-sided grid rib, double-sided honeycomb rib and double-sided grid rib with a subtractive draft for the upper cover on the compressive strength in each axial direction were examined. It was confirmed that the truss rib reinforcement of the battery housing was very effective compared to the existing model and it was also confirmed that the rib of the upper cover had no significant effect. In the results of individual 3-axis compression analysis, the compression load in the lateral long axis direction was the least and this result was found to be very important to achieve the overall goal in designing the battery housing. To reduce the weight of the presented battery housing model, the cell molding method was applied. It was confirmed that it was very effective in reducing injection pressure, clamping force and weight.

• Smart Media Journal
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• v.12 no.11
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• pp.103-112
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• 2023

Recently, the need to prevent battery fires and accidents has emerged, as the use of lithium-ion batteries has increased. In order to prevent accidents, it is necessary to predict the state of health (SOH) and check the replacement timing of the battery with a lot of degradation. This paper proposes a model for predicting the degradation state of a battery by using four battery degradation indicators: maximum voltage arrival time, current change time, maximum temperature arrival time, and incremental capacity (IC) that can be obtained in the battery charging process, and LSTM using an attention mechanism. The performance of the proposed model was measured using the NASA battery data set, and the predictive performance was improved compared to that of the general LSTM model, especially in the SOH 90-70% section, which is close to the battery replacement cycle.

• Journal of Electrochemical Science and Technology
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• v.11 no.1
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• pp.1-13
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• 2020

As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (R_b), charge transfer reaction (R_ct), interface layer (R_SEI), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.786-790
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• 1998

K-GIC of the new carbon electrode to improve performance of carbon negative electrode in lithium ion secondary battery was prepated and its electrical characteristics were studied. Form this study, intercalated K quantity was increased in order of $2>3>1mole/{\ell}$ of KCl solution. And, for KCl solution of 1mole, the mole ratio of carbon and potassium was 156~388 carbon/potassium. The proper condition of K-GIC preparation was KCl solution of $1mole/{\ell}$, reaction temperature of $700^{\circ}C$, reaction time of 1 hour. From this condition, the intercalation and deintercalation behavior of lithium was very excellent. Also the reversibility was excellent.