• Journal of Electrochemical Science and Technology
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• v.13 no.3
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• pp.362-368
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• 2022

The application of polymer composite electrolyte in all-solid-state lithium-sulfur battery (ASSLSBs) can guarantee high energy density and improve the interface contact between electrolyte and electrode, which has a broader application prospect. However, the inherent insulation of the sulfur-cathode leads to a low electron/ion transfer rate. Carbon materials with high electronic conductivity and electrolyte materials with high ionic conductivity are usually selected to improve the electron/ion conduction of the composite cathode. In this work, PEO-LiTFSI-LLZO composite polymer electrolyte (CPE) with high ionic conductivity was prepared. The ionic conductivity was 1.16×10^-4 and 7.26×10^-4 S cm^-1 at 20 and 60℃, respectively. Meanwhile, the composite sulfur cathode was prepared with Sulfur, reduced graphene oxide and composite polymer electrolyte slurry (S-rGO-CPEs). In addition to improving the ion conductivity in the cathode, CPEs also replaces the role of binder. The influence of different contents of CPEs in the cathode material on the performance of the constructed battery was investigated. The results show that the electrochemical performance of the all-solid-state lithium-sulfur battery is the best when the content of the composite electrolyte in the cathode is 40%. Under the condition of 0.2C and 45℃, the charging and discharging capacity of the first cycle is 923 mAh g^-1, and the retention capacity is 653 mAh g^-1 after 50 cycles.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.12
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• pp.1150-1154
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• 2003

The voltage profile during discharge of the zinc air battery has very flat pattern until reach to end of discharge voltage. But, when zinc air battery is discharged by high current, the discharge voltage and energy becomes low. Therefore, we focused on effects of catalyst size to solve this problems by increasing active sites of oxygen reduction reaction. The size of catalyst was reduced from 27 to l${\mu}{\textrm}{m}$ and we examined average discharge voltage, capacity, energy, resistance and characteristics during GSM pulse discharge of zinc air battery with change of current density. And we also measured porosity of the cathode according to the ASTM. So we have got improvement of average discharge voltage and energy when catalyst was minimized and we have got optimum size of catalyst at 5${\mu}{\textrm}{m}$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.292-292
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• 2010

Bimodal Tram is driven by both engine and Lithium Polymer battery pack which consists with 168 cells of LPB(80Ah, 650Vdc). LPB pack is very frequently charged and discharged in driving. Temperature inside of LPB pack makes an great effect on both charging and discharging capacity which seem to be related with LPB internal resistance. LPB internal resistance is increasing or little decreasing with the decreased temperature under 10 - $20^{\circ}C$ and the increased temperature over $30^{\circ}C$ which is similar to the temperature characteristics of single LPB cell. This paper has analyzed the driving characteristics of LPB pack for bimodal tram is running with either battery mode or hybrid mode.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.5
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• pp.839-844
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• 2008

A novel state of health estimation method for hybrid electric vehicle lithium battery using sliding mode observer has been presented. A simple R-C circuit method has been used for the lithium battery modeling for the reduced calculation time and system resources due to the simple matrix operations. The modeling errors of simple model are compensated by the sliding mode observer. The design methodology for state of health estimation using dual sliding mode observer has been presented in step by step. The structure of the proposed system is simple and easy to implement, but it shows robust control property against modeling errors and temperature variations. The convergence of proposed observer system has been proved by the Lyapunov inequality equation and the performance of system has been verified by the sequence of urban dynamometer driving schedule test. The test results show the proposed observer system has superior tracking performance with reduced calculation time under the real driving environments.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1949-1950
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• 2008

Activation battery that are required to deliver short pulses to power, for instance, pyrotechnic devices required during jettison payload separation. Activation battery contains 24 Sony US18650 cells configured as 3 strings in parallel, with each string containing 8 series connected cells. This allows to meet voltage and capacity requirements specified for the mission. In this paper design description and specifications of Activation battery are presented. Qualification test flow and results are also shown to make sure the performance in the predicted space environment. Electrical performance was proven on real equipment load assembly.

• Journal of the Korean Electrochemical Society
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• v.11 no.1
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• pp.37-41
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• 2008

The effects of carbon-coated silicon anode on the electrochemical properties and structural change were investigated. The carbon-coated silicon powders have been prepared by thermal decomposition under argon/10wt% propylene mixed gas flow at $700^{\circ}C$. The surface and crystal structure of the synthesized materials were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy. Lithium cells with electrodes made from the uncoated and the carbon coated silicon anode were assembled and tested. The carbon-coated silicon particles merged together well after the insertion/extraction of lithium ions, and showed a relatively low irreversible capacity compared with the uncoated silicon particle.

• Journal of Electrical Engineering and Technology
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• v.8 no.2
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• pp.238-243
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• 2013

In this paper, a novel approach for optimized installation and operations of battery energy storage system (BESS) and electric double layer capacitor (EDLC) modules for the renewable energy based intermittent generation is presented for them to be connected with an electric power grid. In order to make use of not merely the high energy density of battery but also the high power density of EDLC modules, it is very useful to devise the hybrid system which combines BESS and EDLC modules. The proposed method adopts the linear programming to calculate the optimized capacity as well as the quadratic programming to transmit the optimal operational signals to BESS and EDLC modules. The efficiency of this methodology will be demonstrated in the experimental study with the real data of wind speed in Texas.

• The Transactions of the Korean Institute of Electrical Engineers A
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• v.48 no.3
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• pp.241-246
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• 1999

This paper describes the economic evaluation of battery energy storage system(BESS) for the domestic application. Application target is decided on conventional combined cycle of domestic and we analyzed economics that compared conventional combined cycle with power generation cost in development and the commercialized in case that establish it on utility and customer, urban and rural. The result shows that about the same conventional combined cycle of Anyang, Bundang and Pyungtak but more economical than seoincheon conventional combined cycle. And, in case of capacity enlargment and using the maintenance free battery more economical than conventional system.

• Carbon letters
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• v.27
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• pp.12-17
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• 2018

We fabricated a Li-S battery with post-treated carbon nanotube (CNT) films which offered better support for sulfur, and investigated the effect of the surface properties and pore structure of the post-treated CNT films on Li-S battery performance. Post-treatments, i.e., acid treatment, unzip process and cetyltrimethylammonium bromide (CTAB) treatment, effectively modified the surface properties and pore structure of the CNT film. The modified pore structure impacted the ability of the CNT films to accommodate the catholyte, resulting in an increase in initial discharge capacity.

• Proceedings of the KIPE Conference
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• 2001.07a
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• pp.308-311
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• 2001

Most of the battery charger for electric powered forklift truck are controlled by the method of 3-phased constant current and constant voltage. However, these chargers have several disadvantages like a large charger capacity, and a short battery life time. This paper presents a digital type battery charger based on multi-mode control adding a constant power control and several assistant controls in the conventional control. The whole control system is performed by a low cost one-chip micro-controller and completely digitize. So we can get a high precision control and a good reliability.