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Synthesis of Garnet in the Ca-Ce-Gd-Zr-Fe-O System (Ca-Gd-Ce-Zr-Fe-O계에서의 석류석 합성 연구)

  • Chae Soo-Chun;Jang Young-Nam;Bae In-Kook;Yudintsev S.V.
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.187-196
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    • 2005
  • Structural sites which cations can occupy in garnet structure are centers of the tetrahedron, octahedron, and distorted cube sharing edges with the tetrahedron and octahedron. Among them, the size of cation occuping at tetrahedral site (the center of tetrahedron) is closely related with the size of a unit cell of garnet. Accordingly, garnet containing iron with relative large ionic radii in tetrahedral site can be considered as a promising matrix for the immobilization of the elements with large ionic radii, such as actinides in radioactive wastes. We synthesized several garnets with the batch composition of $Ca_{1.5}GdCe_{0.5}ZrFeFe_3O_{12}$, and studied their properties and phase relations under various conditions. Mixed samples were fabricated in a pellet form under a pressure of $200{\~}400{\cal}kg/{\cal}cm^2$ and were sintered in the temperature range of $1100\~1400^{\circ}C$ in air and under oxygen atmospheres. Phase identification and chemical analysis of synthesized samples were conducted by XRD and SEM/EDS. In results, garnet was obtained as the main phase at $1300^{\circ}C$, an optimum condition in this system, even though some minor phases like perovskite and unknown phase were included. The compositions of garnet and perovskite synthesized from the batch composition of $Ca_{1.5}GdCe_{0.5}ZrFeFe_3O_{12}$ were ranged $[Ca_{l.2-1.8}Gd_{0.9-1.4}Ce_{0.3-0.5}]^{VIII}[Zr_{0.8-1.3}Fe_{0.7-1.2}]^{VI}[Fe_{2.9-3.1}]^{IV}O_{12}$ and $Ca_{0.1-0.5}Gd_{0.0-0.8}Ce_{0.1-0.5}\;Zr_{0.0-0.2}Fe_{0.9-1.1}O_3$, respectively. Ca content was exceeded and Ce content was depleted in the 8-coordinated site, comparing to the initial batch composition. This phenomena was closely related to the content of Zr and Fe in the 6-coordinated site.

A Study on the Estimation of Object's Dimension based on the Vision System Model of Extended Kalman filtering (확장칼만 필터링의 비젼시스템 모델을 이용한 물체 치수 측정에 관한 연구)

  • Jang, W.S.;Ahn, H.C.;Kim, K.S.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.2
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    • pp.110-116
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    • 2005
  • It is very important to reduce the computational processing time for the application of the vision system in real time such as inspection, the determination of object's dimension and welding etc, because the vision system model involves a lot of measurement data acquired by CCD camera. Also, a lot of computation time is required in estimating the parameters in the vision system model if the iterative batch estimation method such as Newton Raphson is used. Thus, the effective computation method such as the Extended Kalman Filtering(EKF) is required to solve the above problems. The EKF has much advantages in that it takes explicitly into account the measurement uncertainties, and is a simple and efficient recursive procedures. Thus, this study is to develop the EKF algorithm to compute the parameters in the vision system model in real time. This vision system model involves the six parameters to account for the cameras inner and outer parameters. Also the EKF is applied to estimate the object's dimension. Finally, practicality of the estimation scheme of the vision system based on the EKF is verified experimently by performing the estimation of object's dimension.

Flotation for Improving Grade of Domestic Fine Coal (국내산(國內産) 미립(微粒) 석탄(石炭)의 품위향상(品位向上)을 위한 부유선별(浮遊選別) 연구(硏究))

  • Han, Oh-Hyung;Kim, Min-Gyu;Kim, Byoung-Gon
    • Resources Recycling
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    • v.22 no.6
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    • pp.64-72
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    • 2013
  • The purpose of this study is to confirm the possibility of obtaining high grade coal from 57.39% of fixed carbon fine coal. Also, the mineralogical, physical/chemical and liberation characteristics are to be identified to decrease in ash amount, during the pre-processing of clean coal technology. In this study, batch flotation and CPT column flotation proper for the processing of fine particles were used with the variation in kinds and quantity of frother, collector and depressant. Also air flow rate and feeding rates were examined. As a result of batch flotation using 20% of pulp density DMU 101 collector(100 mL/ton), AF65 frother(300 mL/ton), sodium metaphosphate depressant (1 kg/ton), 67.57% of ash rejection and 70.90% of combustible recovery were obtained. The result of CPT column flotation was 85.59% of ash rejection and 88.97% of combustible recovery under the conditions of 5% of pulp density, DMU-101 collector (100 mL/ton), AF65 frother(10 L/ton), SMP depressant(1 kg/ton), wash water(100 mL/min.) and air flow rate(1,200 mL/min.).

Preparation of Seaweed Calcium Microparticles by Wet-grinding Process and their Particle Size Distribution Analysis (초미세습식분쇄공정의 공정변수에 따른 해조칼슘의 입자크기 분석)

  • Han, Min-Woo;Youn, Kwang-Sup
    • Food Engineering Progress
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    • v.13 no.4
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    • pp.269-274
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    • 2009
  • The main objective of this study was to establish optimum condition of wet grinding process for manufacturing microparticulated seaweed calcium. Process parameters such as concentration of forming agent, rotor speed, bead size, feed rate, and grinding time were adapted during wet-grinding of seaweed calcium. The particle size range of the raw seaweed calcium was 10-20 $\mu$m. The calcium particles were reduced to under 1 $\mu$m as nano scale after grinding. Gum arabic was suitable for forming agent and 5%(w/v) concentration was the most effective in grinding efficiency. A wet-grinding process operated at 4,000 rpm rotor speed, 0,4 mm bead size, and 0.4 L/hr feeding rate, respectively, produced less than 600 mm(>>90%)-sized particles. In batch systems, 8 cycles of grinding showed higher efficiency, but 20 min of grinding time in continuous processing was more efficient to reduce particle size than the batch processing. Based on the result, the optimum conditions of the wet grinding process were established: operation time of 20 minutes, rotor speed of 4,000 rpm, bead size of 0.4 mm, feed rate of 40 mL/min and 30% mixing ration with water. The size of the resulting ultra fine calcium particles ranged between 40 and 660 mm.

Implementation of AI-based Object Recognition Model for Improving Driving Safety of Electric Mobility Aids (전동 이동 보조기기 주행 안전성 향상을 위한 AI기반 객체 인식 모델의 구현)

  • Je-Seung Woo;Sun-Gi Hong;Jun-Mo Park
    • Journal of the Institute of Convergence Signal Processing
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    • v.23 no.3
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    • pp.166-172
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    • 2022
  • In this study, we photograph driving obstacle objects such as crosswalks, side spheres, manholes, braille blocks, partial ramps, temporary safety barriers, stairs, and inclined curb that hinder or cause inconvenience to the movement of the vulnerable using electric mobility aids. We develop an optimal AI model that classifies photographed objects and automatically recognizes them, and implement an algorithm that can efficiently determine obstacles in front of electric mobility aids. In order to enable object detection to be AI learning with high probability, the labeling form is labeled as a polygon form when building a dataset. It was developed using a Mask R-CNN model in Detectron2 framework that can detect objects labeled in the form of polygons. Image acquisition was conducted by dividing it into two groups: the general public and the transportation weak, and image information obtained in two areas of the test bed was secured. As for the parameter setting of the Mask R-CNN learning result, it was confirmed that the model learned with IMAGES_PER_BATCH: 2, BASE_LEARNING_RATE 0.001, MAX_ITERATION: 10,000 showed the highest performance at 68.532, so that the user can quickly and accurately recognize driving risks and obstacles.

Implementation of AI-based Object Recognition Model for Improving Driving Safety of Electric Mobility Aids (객체 인식 모델과 지면 투영기법을 활용한 영상 내 다중 객체의 위치 보정 알고리즘 구현)

  • Dong-Seok Park;Sun-Gi Hong;Jun-Mo Park
    • Journal of the Institute of Convergence Signal Processing
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    • v.24 no.2
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    • pp.119-125
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    • 2023
  • In this study, we photograph driving obstacle objects such as crosswalks, side spheres, manholes, braille blocks, partial ramps, temporary safety barriers, stairs, and inclined curb that hinder or cause inconvenience to the movement of the vulnerable using electric mobility aids. We develop an optimal AI model that classifies photographed objects and automatically recognizes them, and implement an algorithm that can efficiently determine obstacles in front of electric mobility aids. In order to enable object detection to be AI learning with high probability, the labeling form is labeled as a polygon form when building a dataset. It was developed using a Mask R-CNN model in Detectron2 framework that can detect objects labeled in the form of polygons. Image acquisition was conducted by dividing it into two groups: the general public and the transportation weak, and image information obtained in two areas of the test bed was secured. As for the parameter setting of the Mask R-CNN learning result, it was confirmed that the model learned with IMAGES_PER_BATCH: 2, BASE_LEARNING_RATE 0.001, MAX_ITERATION: 10,000 showed the highest performance at 68.532, so that the user can quickly and accurately recognize driving risks and obstacles.

Fermentative Hydrogen Production from the Pretreated Food-Processing Waste and Sewage Sludge using Chemical/Ultra-Sonication (두부제조폐기물과 하수슬러지의 화학/초음파 전처리에 의한 가용화 및 혐기발효 수소생산)

  • Kim, Mi-Sun;Lee, Dong-Yeol;Kim, Dong-Hun;Kim, Ok-Sun;Lim, So-Yung
    • Journal of Hydrogen and New Energy
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    • v.21 no.6
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    • pp.580-586
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    • 2010
  • Acid and alkali pretreatments were applied to tofu processing waste (TPW) to increase the solubility of ingredients in TPW. Pretreatment at 1.0% of HCl and 2.5% of NaOH condition resulted in the increase of SCOD concentration from 3.2 g COD/L to 27 g COD/L and 33 g COD/L, respectively. The acid and alkali-pretreated TPW was studied for its fermentative $H_2$ production capacity in batch mode using a thermophillic mixed culture. Alkali pretreatment on presence of 2.5% NaOH exhibited more soluble portion released compared to acid pretreatment using HCl, however the $H_2$ production from acid pretreated TPW was better than alkali-pretreated TPW probably due to the sodium inhibition on microbial activity. In addition, sewage sludge was externally added to the acid-pretreated (1.0% HCl) TPW by 20% (on volume basis). Average H2 production rate was increased from 31 to 78 ml/L-broth/hr, and it was attributed to the high buffer capacity and abundant nutrients especially divalent cation in sewage sludge.

XML-based Variable Data Publishing System with Dynamic Editing and Formatting Function (동적 편집과 포맷팅 기능을 갖는 XML 기반의 가변 데이터 출판 시스템)

  • Lim, Kwang-Taeg
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.11
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    • pp.4583-4591
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    • 2010
  • Existing XML-based variable data publishing, in which a user has to manually prepare and edit template rules, is rather difficult for general users to create documents. Especially when processing large variable XML documents such as manuals or technical documents, fast document formatting is required to provide fast response speed for editing, which the existing batch processing cannot provide. This paper proposes a variable data publishing system with dynamic editing and formatting function, which support fast formatting upon user's request for large volume documents as well as for template editing through interaction by displaying the result of template-based variable documents on WYSIWYG screen. Proposed system can be effectively used for creating customized documents with many variable data that can be changed according to individual characteristics such as individual, company or area; source documents, template documents and formatted documents adopt XML, XSLT and XPath standards suggested by W3C, which facilitates extension to web document processing system.

Optimization of Post-Processing for Subsequence Matching in Time-Series Databases (시계열 데이터베이스에서 서브시퀀스 매칭을 위한 후처리 과정의 최적화)

  • Kim, Sang-Uk
    • The KIPS Transactions:PartD
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    • v.9D no.4
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    • pp.555-560
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    • 2002
  • Subsequence matching, which consists of index searching and post-processing steps, is an operation that finds those subsequences whose changing patterns are similar to that of a given query sequence from a time-series database. This paper discusses optimization of post-processing for subsequence matching. The common problem occurred in post-processing of previous methods is to compare the candidate subsequence with the query sequence for discarding false alarms whenever each candidate subsequence appears during index searching. This makes a sequence containing candidate subsequences to be accessed multiple times from disk, and also have a candidate subsequence to be compared with the query sequence multiple times. These redundancies cause the performance of subsequence matching to degrade seriously. In this paper, we propose a new optimal method for resolving the problem. The proposed method stores ail the candidate subsequences returned by index searching into a binary search tree, and performs post-processing in a batch fashion after finishing the index searching. By this method, we are able to completely eliminate the redundancies mentioned above. For verifying the performance improvement effect of the proposed method, we perform extensive experiments using a real-life stock data set. The results reveal that the proposed method achieves 55 times to 156 times speedup over the previous methods.

Dewatering Filtrate Treatment with Center Well Depth of Secondary Clarifier in Small Sewage Treatment Plant (소규모하수처리시설의 이차침전조 내통길이 변화를 통한 탈수여액의 처리)

  • Choi, Jung-Su;Kim, Hyun-Gu;Lee, Dong-Ho;Joo, Hyun-Jong
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.694-702
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    • 2013
  • The purpose of this study is to evaluate a de-watering filtrate treatment and the possibility of securing biological treatment capacity by changing the structure of the secondary clarifier. Accordingly, the column test was conducted to determine the effect of polymer in the de-watering filtrate on sludge sedimentation. Also, the characteristics of de-watering filtrate processing was evaluated through batch test and continuous processing operation. The results showed that sludge settling velocity increased with higher polymer concentration, and that effluent SS concentration was found to decrease. Regarding processing characteristics of de-watering filtrate, the removal efficiency of TSS and TBOD5 increased as the length of secondary clarifier was longer. Also, comparing injections into anoxic tank and secondary clarifier, de-watering filtrate by continuous infusion treatment process showed stability in both conditions. Therefore, by modifying the structure of secondary clarifier, efficient processing of de-watering filtrate is expected to be possible and processing capacity of small sewage treatment plants is considered to be improved.