• Title/Summary/Keyword: Batch process

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A Study on the Treatment of Wastewater from Ion Removal Process for Purifying Electrocoat Paint in the Bath by Use of Reverse Osmosis (역삼투압을 이용한 전착도료 정제공정폐수처리에 관한 연구)

  • 김진성
    • Membrane Journal
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    • v.8 no.2
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    • pp.77-85
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    • 1998
  • To treat effectively EDIR (electrodeposition ion removal) wastewater in terms of CO$_{Mn}$ 1,500~2,000 ppm generated from aluminum painting process, a RO (reverse osmosis) process was designed and installed to recover and reuse the concentrated solvent sent back to the electrocodeposition tank while the permeate reused as rinse water. A RO system in which three polyamide-spiral wound modules ($102\Phi \times 1,016L$ mm) connnected in series had been running to treat 20 m$^3$ in waste volume in 3 days batch operation at the condition of system recovery of 30 %, applied pressure 11.5 $kg_f/cm^2$ and room temperature. During 42 hours continuous operation leading to 5-fold decrease in waste volume, nearly constant permeation flux of 390 l/m$^2$-hr was maintained and the permeate with average CO$_{Mn}$, 300 ppm was obtained which could be used for washing the remaining paint solution in ion-exchange tower instead of demineralized water. Also COD$_{Mn}$ rejection as a function of running time was observed to be in the range of 78~87 % and the observed solvent rejections for ethyl cellusolve, buthyl cellusolve and n-butanol were 79 %, 87 % and 70 %, respectively.

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Institutional Research for the Introduction of Construction Management at Risk in the Public Sector (시공책임형 CM의 국내 공공부문 도입을 위한 제도적 기반 수립 연구)

  • Park, Jiho;Kim, Kyungrai;Bae, Byungyun
    • Korean Journal of Construction Engineering and Management
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    • v.22 no.4
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    • pp.20-28
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    • 2021
  • The Domestic Construction Industry is in the process of changing from a one-sided production method centered on the contractor to a production method in which the order and the contractor can collaborate. Depending on the delivery method, the bid/success method, the contract method, and the degree of business involvement of the order may also vary. In this thesis, in order to introduce 'Construction Management at Risk' suitable for the domestic environment, domestic and foreign institutional analysis, bid process analysis, contract fulfillment and management analysis, post management analysis, and related laws and regulations for legalization In order to suggest a plan for the efficient operation of the system, a system and case analysis of domestic and international construction responsibility type construction project management was conducted. 'Construction Responsible Construction Project Management' defined in the Framework Act on the Construction Industry is divided into the main contract transfer contract, which is a service contract performing pre-con work, and the main contract, which is construction project management and construction contract. Therefore 'Construction Management at Risk' should be regarded as one of the ordering methods rather than a successful bid system, as in the case of overseas, and legalization as a bidding system equivalent to design/construction batch bid and technology proposal is necessary for introduction. In order to introduce 'Construction Management at Risk' suitable for the domestic environment, domestic and foreign institutional analysis, bidding process analysis, contract fulfillment and management analysis, and follow-up management analysis are conducted. A method for efficient operation was suggested so that it can be applied in the domestic market while maintaining the original merits of this system.

FinBERT Fine-Tuning for Sentiment Analysis: Exploring the Effectiveness of Datasets and Hyperparameters (감성 분석을 위한 FinBERT 미세 조정: 데이터 세트와 하이퍼파라미터의 효과성 탐구)

  • Jae Heon Kim;Hui Do Jung;Beakcheol Jang
    • Journal of Internet Computing and Services
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    • v.24 no.4
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    • pp.127-135
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    • 2023
  • This research paper explores the application of FinBERT, a variational BERT-based model pre-trained on financial domain, for sentiment analysis in the financial domain while focusing on the process of identifying suitable training data and hyperparameters. Our goal is to offer a comprehensive guide on effectively utilizing the FinBERT model for accurate sentiment analysis by employing various datasets and fine-tuning hyperparameters. We outline the architecture and workflow of the proposed approach for fine-tuning the FinBERT model in this study, emphasizing the performance of various datasets and hyperparameters for sentiment analysis tasks. Additionally, we verify the reliability of GPT-3 as a suitable annotator by using it for sentiment labeling tasks. Our results show that the fine-tuned FinBERT model excels across a range of datasets and that the optimal combination is a learning rate of 5e-5 and a batch size of 64, which perform consistently well across all datasets. Furthermore, based on the significant performance improvement of the FinBERT model with our Twitter data in general domain compared to our news data in general domain, we also express uncertainty about the model being further pre-trained only on financial news data. We simplify the complex process of determining the optimal approach to the FinBERT model and provide guidelines for selecting additional training datasets and hyperparameters within the fine-tuning process of financial sentiment analysis models.

A Study on Adsorption and Desorption of As(III) and As(V) on Soil using a Column (칼럼을 이용한 토양에서 As(III)와 As(V)의 흡착 및 탈착에 관한 연구)

  • Kim, Myoung-Jin;Kim, Tae-Suk
    • Journal of Soil and Groundwater Environment
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    • v.13 no.1
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    • pp.52-59
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    • 2008
  • Adsorption is a major process causing the accumulation of arsenic onto soil. Therefore, further understanding of the adsorption/desorption characteristics of arsenic species on soil is essential for predicting their fate and preparing appropriate remediation strategy to remove arsenic from soil. In this study, the column adsorption/desorption experiment has been performed with As(III) and As(V) on soil. Experiment with As(III) was conducted under reducing condition, whereas that with As(V) was under oxidizing condition. Most of As(III) was remained on the oxidation state during the experiment. The results showed that the adsorption/desorption rate of As(III) was higher than that of As(V). Adsorption and desorption of arsenic species were not completely reversible in the column experiment. It was also found that As(V) in the column experiment was adsorbed more rapidly on soil than in the batch experiment.

Preparation of Alginate Microspheres Using Membrane Emulsification Method (막유화법에 의한 알지네이트 Microsphere의 제조)

  • Youm Kyung Ho;Choi Yong Han;Dianne E. Wiley
    • Membrane Journal
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    • v.14 no.3
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    • pp.218-229
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    • 2004
  • We prepared monodispersed calcium alginate microspheres by controlling various conditions of emulsification procedure using a lab-scale batch type membrane emulsification system equipped with SPG (Shirasu porous glass) tubular membranes. We determined the effects of process parameters of membrane emulsification (ratio of dispersed phase to continuous phase, alginate concentration, emulsifier concentration, type and concentration of stabilizer, transmembrane pressure, concentration of crosslinking agent, stirring speed and membrane pore size) on the mean size and size distribution of alginate microspheres. The increase of the ratio of dispersed phase to continuous phase, transmembrane pressure and alginate concentration led to the increase in the mean size of alginate microspheres. On the contrary, the increase in emulsifier concentration, stirring speed of the continuous phase and concentration of the crosslinking agent caused the reduction of the mean size of microspheres. Through controlling these parameters, monodisperse alginate microspheres with about $6{\mu}{\textrm{m}}$ of the mean size and 1.1 of the size distribution value were finally prepared in case of the using SPC membrane with the pore size of $2.9{\mu}{\textrm{m}}$.

Study on Characteristics and Preparation of Binderless ZSM-5 Granules for Adsorption of Xylene Isomers (Binderless ZSM-5 성형체의 합성 및 자일렌 이성체의 흡착 특성에 관한 연구)

  • Yun, Hyo-Sang;Hong, Ji-Sook;Suh, Jeong-Kwon;Shin, Chae-Ho
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.417-423
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    • 2010
  • In this study, an effective method to prepare granular binderless ZSM-5 which is as efficient p-xylene separatory adsorbent was explored. Colloidal silica sol 30 wt% solution as an inorganic binder and microcrystalline cellulose as an organic additive were added to ZSM-5 powder ($SiO_2/Al_2O_3$ = 50). Adsorbent with enough strength (0.721 kgf), high crystallinity (94.6%) and high BET specific surface area ($379.2m^2$/g) was obtained by calcination, binderless treatment, ${NH_4}^+$ ion exchange, and activation after spherical granulation process. A batch type adsorption experiment was proceeded with solutions comprising 3 xylene isomers by 1 : 1 : 1 weight ratio to evaluate adsorption characteristics of prepared absorbent. As a result, the obtained binderless ZSM-5 granule showed a higher selective adsorption performance for para-xylene than that of commercial adsorbent.

A Study of Ozonation Characteristics of Bis(2-chloroethyl) Ether (Bis(2-chloroethyl) Ether (BCEE)의 오존산화 특성에 관한 연구)

  • Lee, Cheal-Gyu;Kim, Moon-Chan
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.610-615
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    • 2010
  • In this study ozonation of bis(2-chloroethyl) ether (BCEE) in aqueous solution was performed in a laboratory scale batch reacter. The ozonation process of BCEE was carried out by bubbling ozone at the bottom of reactor containing the BCEE solution. Ozonation was almost complete after 80 min with an ozone concentration of $50{\pm}10mg/L$. Ozonation treatment efficiencies of BCEE were evaluated in terms of $BOD_5$, $COD_{Cr}$, and TOC. In the ozonation of BCEE a 62.79% decrease of the $COD_{Cr}$ and a 57.25% decrease of the TOC lead to biodegradable by-products ($BOD_5/COD_{Cr}$ = 0.39). The results of this research show that wastewaters containing non-biodegradable compounds, such as BCEE can be successfully treated by ozonation followed by bio-treatment. The pseudo first-order rate constants of the ozonation was $2.00{\times}10^{-4}sec^{-1}$ and the activation energy was $10.02kcal{\cdot}mol^{-1}$ at $30^{\circ}C$.

Development and Characterization of Translucent Opal Glass for Diffuser of LED Lighting (LED 조명용 반투명 유백유리 Diffuser 조성 개발 및 특성)

  • Ku, Hyun-Woo;Lim, Tae-Young;Hwang, Jonghee;Kim, Jin-Ho;Lee, Mi-Jai;Shin, Dong Wook
    • Korean Journal of Materials Research
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    • v.22 no.12
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    • pp.650-657
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    • 2012
  • For the purpose of improving the durability problem, translucent opal glass was fabricated as a substitute for the polycarbonate diffuser of LED lighting. Calcium phosphate was used as an opacifier of opal glass and melted in an electric furnace. The opaque effect was identified according to the change of the cooling procedure. As results, translucent opal glass was obtained by the melting of a batch with a composition of 3.8% calcium phosphate at $1550^{\circ}C$ for 2 hrs and then the cooling of the material in the furnace. For the cooling condition of the glass sample, HTCG (High Temperature Cooled Glass) was found to have better optical properties than LTAG (Low Temperature Annealed Glass). It had excellent optical properties for a diffuser of LED lighting, with no dazzling from direct light due to its high haze value of over 99% and low parallel transmittance value of under 1%. For the thermal properties, it had an expressed thermal expansion coefficient of $5.7{\times}10^{-6}/^{\circ}C$ and a softening point of $876^{\circ}C$; it also had good thermal properties such as good thermal shock resistance and was easy to apply to the general manufacturing process in the forming of glass tubes and bulbs. Therefore, it is concluded that this translucent opal glass can be used as a glass diffuser material for LED lighting with high heat resistance and high durability; this material is suitable as a substitute for polycarbonate diffusers.

Fatty Acid Methyl Ester (FAME) Technology for Diagnosing Nocardia Foaming in Activated Sludge (활성슬러지내 Nocardia 거품현상 진단을 위한 Fatty Acid Methyl Ester (FAME) 기술)

  • Lee, Jae Woo;Kim, Il Kyu;Lee, Seok Hun;Ahn, Kyu-Hong;Cha, Daniel K.
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.480-485
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    • 2004
  • Fatty acid methyl ester (FAME) technology was evaluated as a monitoring tool for quantification of Nocardia amarae causing a nuisance foaming problem in activated sludge process. The identified signature peak was 19:1 alcohol as a reliable unique peak to N. amarae. Chemostat study revealed that the distribution and quantity of fatty acid peaks were dependent on the growth stage of Nocardia. The FAME results were similar for two relatively high dilution rates; however, the amounts of signature peaks extracted from the 4 and 6 day cultures were significantly higher. This dependence of signature peaks on the physiological state of the organism may be a useful information to assess the health of microbial populations in activated sludge. A laboratory scale batch foaming potential experiment provided a critical foaming level depending on Nocardia population. This critical Nocardia level determined in this study was in terms of either the threshold filament intersections number or the threshold signature FAME amount. The threshold peak area of signature FAME (19:1 alcohol) and corresponding filament counts were 430PA/mg VSS and $1.45{\times}10^6$ intersections/g VSS, respectively. The threshold signature FAME level could be effectively applied as a criterion for diagnosing foam occurrence in activated sludge system.

Differentiation in Nitrogen-Converting Activity and Microbial Community Structure between Granular Size Fractions in a Continuous Autotrophic Nitrogen Removal Reactor

  • Qian, Feiyue;Chen, Xi;Wang, Jianfang;Shen, Yaoliang;Gao, Junjun;Mei, Juan
    • Journal of Microbiology and Biotechnology
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    • v.27 no.10
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    • pp.1798-1807
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    • 2017
  • The differentiations in nitrogen-converting activity and microbial community structure between granular size fractions in a continuous completely autotrophic nitrogen removal over nitrite (CANON) reactor, having a superior specific nitrogen removal rate of $0.24g/(g\;VSS{\cdot}h)$, were investigated by batch tests and high-throughput pyrosequencing analysis, respectively. Results revealed that a high dissolved oxygen concentration (>1.8 mg/l) could result in efficient nitrite accumulation with small granules (0.2-0.6 mm in diameter), because aerobic ammonium-oxidizing bacteria (genus Nitrosomonas) predominated therein. Meanwhile, intermediate size granules (1.4-2.0 mm in diameter) showed the highest nitrogen removal activity of $40.4mg/(g\;VSS{\cdot}h)$ under sufficient oxygen supply, corresponding to the relative abundance ratio of aerobic to anaerobic ammonium-oxidizing bacteria (genus Candidatus Kuenenia) of 5.7. Additionally, a dual substrate competition for oxygen and nitrite would be considered as the main mechanism for repression of nitrite-oxidizing bacteria, and the few Nitrospira spp. did not remarkably affect the overall performance of the reactor. Because all the granular size fractions could accomplish the CANON process independently under oxygen limiting conditions, maintaining a diversity of granular size would facilitate the stability of the suspended growth CANON system.