• Title/Summary/Keyword: Basic catalyst

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Study on the Development of Super-High-Early-Strength Mortar Using the Hardening catalyst and High early strength cement (조강시멘트를 사용한 초조강 모르타르 개발에 관한 연구)

  • Cho, In-Sung;Hur, Yeon-Ok;Min, Tae-Beom;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.217-219
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    • 2012
  • In this study, the experiment was conducted in the level of mortar as one of the basic studies on pre-cast concrete which acceleration curing is not done. This study has the purpose to develop the strength of mortar into 20MPa within 6 hours in the condition of room temperature using admixtures which can accelerate C3S hydration reaction. In this experiment, W/C was fixed into 20%, PCE which can stimulate C3S was used as an accelerating admixture. From the results of this experiment, maximum content of accelerating admixture was 1%. Also, as more than 20MPa was measured through 6-hour compressive strength, it can be known that strength can be developed without steam-curing.

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A Study on the Virtual Reality-based Museums : Exhibition Characteristics and Possibilities of Utilization (가상현실 기반 박물관의 전시특성 및 활용 가능성 연구 -세컨드라이프 내 박물관을 중심으로)

  • Son, Hee-Joo;Choi, Jin-Won
    • 한국HCI학회:학술대회논문집
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    • 2009.02a
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    • pp.862-867
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    • 2009
  • The development of internet has changed the realm of life from off-line to on-line, causing not only the overall change in society but also urgently demanding change in the basic concept of museum. Virtual Museums have appeared in line with such changes, and they utilize space regardless of real time and space unlike the traditional museums that collected and preserved works for exhibition in physical space thereby playing a role of catalyst for exhibition in virtual space and for direct exchange with the public. Through relevant literatures and case studies, the present research particularly investigated the exhibition characteristics of virtual reality-based museums out of all types of cyber museum, in an effort to make a comparison with those of offline museums, and eventually to suggest a direction of virtual reality museums that would be established in the future and to consider the possibilities of utilizing them.

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Functional Gold Nanoparticles (기능성 금 나노입자)

  • Lee, Jun-Wung
    • Journal of the Korea Institute of Military Science and Technology
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    • v.12 no.6
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    • pp.739-749
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    • 2009
  • Ever since gold was found, this element has fascinated human beings. It is stable in air, and is illuminating for several thousands years without changing its colors. Nanoparticles are the basic nanommaterials, and, particularly gold nanoparticles show unique properties which are not shown in bulk states. Scientists are trying to apply these new properties to catalysts, bioscience, optics, etc. Judging from the current research activities, one can envisage that gold nanoparticles can play a major role in opening a new era in diagnoses and treatment of diseases like cancers. However to apply the nanoparticles one must modify the surface of the nanoparticles in order to give the materials certain functionalities. It certainly is worth to review the current research status and challenges in the area of functional gold nanoparticles.

Effect of Chemical Modification of Carbon Supports on Electrochemical Activities for Pt-Ru Catalysts of Fuel Cells (탄소지지체의 화학적 변형에 따른 연료전지용 백금-루테늄 촉매의 전기화학적 활성의 영향)

  • Kim, Byung-Ju;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.94.1-94.1
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    • 2011
  • In this work, ordered mesoporous carbons (OMCs) were prepared by the conventional templating method using mesoporous silica (SBA-15) for Pt-Ru catalyst supports in fuel cells. The influence of surface modification on carbon supports on the electrochemical activities of Pt-Ru/OMCs was investigated with different pH. The neutral-treated OMCs (N-OMCs), base-treated OMCs (B-OMCs), and acid-treated OMCs (A-OMCs) were prepared by treating OMCs with 2 M $C_6H_6$, 2 M KOH, and 2 M $H_3PO_4$, respectively. The surface characteristic of the carbon supports were determined X-ray photoelectron spectroscopy (XPS). The electrochemical activities of the Pt-Ru catalysts had been enhanced when the OMCs supports were treated by basic or neutral agents, while the electrochemical activities had been decayed for the A-OMCs supported Pt-Ru.

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Synthesis of N,N-Dimethylacetamide from Carbonylation of Trimethylamine by Rhodium(I) Complex Under Anhydrous Condition

  • Hong, Jang-Hwan
    • Journal of Integrative Natural Science
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    • v.8 no.4
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    • pp.235-243
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    • 2015
  • Rhodium(I)-complex of $[Rh(CO)_2I_2{^-}]$ catalyzed carbonylation of anhydrous-trimethylamine in the presence of methyl iodide to give DMAC (N,N-dimethylacetamide) in no solvent. The catalyst had been reused 20 times, the analyses and distillation of collected products showed that the yields of DMAC, MAA (N-methylacetamide), and DMF (N,N-dimethylformamide) were 82.3%, 12.6%, and 4.4%. The conversion rate of trimethylamine was 99 % and the selectivity of DMAC was 82.3% with TON (Turnover Number) of 700. Stepwise procedure of inner-sphere reductive elimination for the formation of DMAC was suggested instead of acyl iodide intermediate.

Instruction Using Scaffolding for Language Learner Students in Solving Mathematical Word Problems

  • Noh, Jihwa;Warren, Jennifer;Huh, Nan;Ko, Ho Kyong
    • Research in Mathematical Education
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    • v.17 no.3
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    • pp.169-180
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    • 2013
  • Communicating about mathematics is an essential component in learning mathematics and is a key standard for successful learning in a mathematics classroom using stories and storytelling as a catalyst to mathematics instruction. This, however, can make learning math for students with language deficiencies since they are working toward mastering both basic language proficiency as well as the specialized language needed for mathematics. This is a particular concern because the number of students of multicultural families is rapidly increasing. In this paper, we discuss the challenges and complexities of language-deficient students learning math in a classroom where communication is a key standard for successful learning, and suggest implications for teaching, by presenting an USA elementrny teacher's scaffolding to make reading and solving word problems less intimidating for her language learner students as well as native speaking students.

High Aspect Single Crystalline Au Nanowire Electrode with an Atomically Smooth (111) Surface

  • Gang, Mi-Jeong;Gang, Ho-Seok;Gwak, Ju-Hyeon;Kim, Bong-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.210-210
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    • 2011
  • Ultrasmall electodes are of great importance for basic electrochemical study and applications. We fabricated single crystal (111) Au nanowire (NW) by growth mechanism on substrate without any catalyst. Consequently, these high aspect NW combined with tungsten microwire and the electrodes having NW tip on their end were obtained. These single crystal Au (111) NWs were characterized by electron microscope and electrochemical analysis. We show that precise electrochemical measurement could be possible on these NW electrode by obtaining underpotential deposition (UPD) and ferricyanide CV profiles on the electrode. The immersed depth of electrode into solution was controlled in micrometer scale by piezo-driven manipulator.

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Nano Catalysts for Proton Exchange Membrane Fuel Cells

  • Kim, Su-Gil;Hwang, Seung-Jun;Im, Ji-Eun;Yu, Seong-Jong;Lee, Seung-Cheol;Im, Tae-Hun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.71.1-71.1
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    • 2012
  • Proton Exchange Membrane Fuel Cells (PEMFCs) have been of great interest particularly in the automobile industries because of their high energy density and low pollutant emission. However, some of the issues such as, the necessarily high contents of Pt catalysts and their slow kinetics of cathode oxygen reduction reaction remain as obstacles in the commercialization of the PEMFC. In this presentation, after brief explanation on basic principles of PEMFC and its application to FC vehicles, recent researches to improve the activity and durability of Pt-based nano catalysts toward oxygen reduction will be introduced. It covers size and shape control of Pt nano particle, binary and ternary Pt-M alloys, novel core-shell nano structures of Pt, and a little bit about non-Pt catalysts. Strategies and methodologies for design and synthesis of novel catalysts will also be included.

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Dehydrogenative Polymerization of Hydrosilanes to Silicon Polymers

  • Kim, Myoung-Hee;Lee, Jun;Mo, Soo-Yong;Kim, Jong-Hyun;Woo, Hee-Gweon
    • Journal of Integrative Natural Science
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    • v.3 no.2
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    • pp.61-71
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    • 2010
  • Hydrosilanes possessing reactive Si-H bond are used in synthesizing various types of polysilanes by dehydrocoupling under the influence of various organometallic promoters. Catalytic Si-Si/Si-O coupling of hydrosilanes with hydrosilanes, alcohols, and lactones to silicon-based polymers are described in this article as selective examples of our recent research developments. These silicon-containing polymers can be used as a precursor to prepare useful functional materials for fabricating electronic devices.

Efficient Ring Opening Reaction of Epoxides with Oxygen Nucleophiles Catalyzed by Quaternary Onium Salt

  • Kim, Jin Won;Cho, Dae Won;Park, Gyoosoon;Kim, Sung Hong;Ra, Choon Sup
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2286-2290
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    • 2013
  • Ring opening reactions of epoxides with oxygen nucleophiles catalyzed by a variety of quaternary onium salt, such as ammonium or phosphonium salt were explored. The results showed that tetrabutylphosphonium bromide (TBPB) among salts serves as the most efficient catalyst for this process and that expoxide ring opening reactions with a variety of oxygen nucleophiles including carboxyic acid and phenol, promoted using this salt, lead to generate readily purifiable products in excellent yields.