• 대한치과보철학회지
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• 제27권2호
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• pp.261-270
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• 1989

Bend test is one of the methods comparing the physical properties of the clasp wires. The type of bend test used in this investigation was the cantilever loading of a wrought wire. The purpose of this study was to compare the flexibility of a number of commonly used clasp wires, in according to gauge, alloy and heat treatment, under specific condition of load and deflection. Seven noble and one base metal wires were tested under three conditions as follows: (1) as received, (2) quenched (placed in an over at $700^{\circ}C$ for ten minutes and immediately quenched in water at room temperature.), (3) oven cooled (quencned as described, then placed in an oven at $450^{\circ}C$ for two minutes and uniformly slowly cooled to $250^{\circ}C$ in thirty minutes.) The basic test specimen consists of a sample 25 mm in length and 19, 18 gauge in diameter (17 gauge also in two alloys), and the wire was loaded in the form of straight cantilever beams. Force at 0.25 mm (0.01 inch) and 0.5 mm (0.02 inch) deflections for all samples were recorded. The results were as follows ; 1. Ticonium was least flexible and No. 2 was most flexible in according to gauge, alloy and heat treatment. 2. In most of precious wrought wire, the flexibility was increased, but there was no statistically significant differences between as-received and softened condition. 3. There was no statistically differences between as-received and hardened condition. 4. For each alloy, there were statistically significant differences in flexibility due to clasp diameter.

• 한국결정성장학회지
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• 제23권2호
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• pp.114-118
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• 2013

최근 금속자원 재활용과 환경보호에 대한 기술적 필요성에 의해 구리(Cu)를 주성분으로 하는 동합금으로부터 니켈, 주석 등의 유가금속 분리/회수에 대한 관심이 높아지고 있다. 본 연구에서는 동합금에 포함된 유가금속들을 분리/회수하는 기초연구중 하나로서, 킬레이트 수지를 이용하여 동합금 제련시 발생하는 부산물에 포함되어 있는 대표적인 유가금속인 니켈(Ni)을 분리/추출할 수 있는 농축 공정의 가능성에 대해 검토하였다. 킬레이트 수지는 원자량이 높은 $Cu^{2+}$ 이온을 $Ni^{2+}$ 이온보다 선택적으로 흡수하였으며, 이러한 과정을 수차례 반복함으로써 실제 동합금 부산물 샘플의 $Ni^{2+}$ 및 $Cu^{2+}$ 이온을 농축할 수 있었으며, XRF 분석을 통하여 각각 70 % 및 99 %의 농도로 분리할 수 있음을 확인하였다.

• Journal of Welding and Joining
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• 제18권2호
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• pp.86-94
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• 2000

This study was performed to investigate types and formation mechanism of cracks in two Al alloy welds, A5083 and A7N01 spot-welded by pulse Nd : YAG laser, using SEM, EPMA and Micro-XRD. In the weld zone, three types of crack were observed : center line crack({TEX}$C_{C}${/TEX}), diagonal crack({TEX}$C_{D}${/TEX}), and U shape crack({TEX}$C_{U}${/TEX}). Also, HAZ crack({TEX}$C_{H}${/TEX}) was observed in the HAZ region, furthermore, mixing crack({TEX}$C_{M}${/TEX}) consisting of diagonal crack and HAZ crack was observed. White film was formed at th hot crack region in the fractured surface after it was immersed to 10% NaOH water. In the case of A5083 alloy, white films in {TEX}$C_{C}${/TEX} crack and {TEX}$C_{D}${/TEX} crack region were composed of low melting phases, {TEX}$Fe_{2}SiAl_{8}${/TEX} and eutectic phases, $Mg_2$Al$_3$ and $Mg_2$Si. Such films observed $CuAl_2$, {TEX}$Mg_{32}(Al,Zn)_{3}${/TEX}, MgZn$_2$, $Al_2$CuMg and $Mg_2$Si were observed in the whitely etched films near {TEX}$C_{C}${/TEX} crack and {TEX}$C_{D}${/TEX} crack regions. The formation of liquid films was due to the segregation of Mg, Si, Fe in the case of A5083 alloy and Zn, Mg, Cu, Sim in the case of A7N01 alloy, respectively. The {TEX}$C_{C}${/TEX} and {TEX}$C_{D}${/TEX} cracks were regarded as a result of the occurrence of tensile strain during the welding process. The formation of {TEX}$C_{M}${/TEX} crack is likely to be due to the presence of liquid film at the grain boundary near the fusion line in the base metal as well as in the weld fusion zone during solidification. The {TEX}$C_{U}${/TEX} crack is considered a result of the collapsed keyhole through incomplete closure during rapid solidification.

• 대한금속재료학회지
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• 제48권12호
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• pp.1056-1063
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• 2010

We present a new joining method for Pd-Cu membrane foils used as permeation tubes to collect $CO_2$. Since foils have poor mechanical strength, joining should be done at low temperatures to reduce residual stresses and without joining pressure. This contradicts the well known conditions for good contact between base materials that determines joint qualities. We selected Sn-Ag-Cu alloys that are highly reactive with Pd and Cu as a filler metal. As the filler melts at joining temperatures as low as $220{\sim}280^{\circ}C$, Pd and Cu are dissolved into the melt and react with the filler elements, which raises the melting temperature of the filler based on eutectic structures among the elements. Then, isothermal solidification progresses for the rest of the joining time. Intermetallic compounds (IMC) in the joints, one of the main factors for brittle joints, are inevitably formed. However, by optimizing both joining time and temperature, we balanced the wettability with IMC. Sealing test results confirmed that the joints are mechanically reliable during operation.

• 해양환경안전학회지
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• 제18권6호
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• pp.569-576
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• 2012

일반적으로 중성용액 하에서 알루미늄 합금은 부동태피막($Al_2O_3$나 $Al_2O_3{\cdot}3H_2O$)을 형성한다. 그러나, 해수 환경에서 염소이온이 표면에 생성된 부동태 피막을 파괴하여 부식이 발생하게 된다. 본 연구에서는 해수환경 하에서 부식 문제점을 해결하기 위해 Al-4.5%Mg-0.6%Mn 알루미늄 합금에 대하여 정전위 방식 기술을 적용하였다. 분극실험결과, 개로전위보다 귀한 전위에서는 활성 용해 반응이 나타났으며 개로전위 보다 비한 전위에서는 용존산소 환원에 의한 농도 분극과 활성화 분극이 관찰되었다. 정전위 실험결과, 농도 분극에서 활성화 분극으로 전환되는 전위부터 적용 시간이 증가할수록 전착물이 많이 생성되었으며, 부분적으로 전착물과 모재의 계면사이에서 틈부식이 관찰되었다. 전체적으로 정전위 양극분극실험시, 활성용해반응이 발생하여 정전위 방식 기술을 적용하기 어려운 반면, 정전위 음극분극 실험시 방식 전위인 농도분극 범위내에서 적용 시간을 고려하여 최적 방식 조건을 -1.1 V~-0.75 V로 규명하였다.

• 한국결정성장학회지
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• 제28권3호
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• pp.130-134
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• 2018

솔더(solder) 재료는 수 천년 이상 인류 문명과 함께해온 대표적인 금속 합금으로서 현재까지도 전자 패키징(electronic packaging) 및 표면 실장(SMT, surface mount technology) 분야의 핵심 소재로 사용되고 있다 그러나 최근 Ag 가격의 급격한 상승과 전자산업의 저가격화 전략으로 인해 솔더 재료에서의 Ag 함량의 감소가 지속적으로 요구되고 있다. 본 연구에서는 Sn-3.0Ag-0.5Cu, Sn-0.7Cu 및 Sn-0.3Ag-0.5Cu(weight%) 조성의 무연납 솔더바 샘플을 주조법으로 합금화 하였다. 제조한 Sn-3.0Ag-0.5Cu, Sn-0.7Cu 및 Sn-0.3Ag-0.5Cu 샘플에 대한 결정구조, 화학조성 및 미세구조를 XRD, XRF, 광학현미경, FE-SEM 및 EDS 분석을 이용하여 조사하였다. 분석결과, 제조된 샘플은 ${\beta}-Sn$, ${\varepsilon}-Ag_3Sn$ 및 ${\eta}-Cu_6Sn_5$ 결정으로 구성되어 있었을 확인할 수 있었다.

• 한국산학기술학회논문지
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• 제17권10호
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• pp.280-288
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• 2016

본 연구의 목적은 마찰교반용접을 마그네슘 합금에 응용하기에 앞서 형상이 다른 두 종류의 용접 툴을 마찰교반용접 시험에 적용 및 비교하여 마그네슘 합금 마찰교반용접에 더 적합한 용접 툴을 제안하였다. 용접 툴의 효과를 알아보기 위해서 용접조건 변수 중 이송속도는 200mm/min으로 고정하였고 회전속도를 400, 600, 800rpm으로 변화시키면서 용접부의 거동과 용접 툴 변화에 따른 효과를 평가 및 관찰하였다. 기계적 물성 평가를 위해 인장시험과 경도시험을 수행하였으며, 용접부 내 거동 및 결함의 유무를 확인하기 위하여 용접부에 수직인 방향의 횡단면을 광학현미경을 통해 관찰하였다. 용접 툴에 관계없이 회전속도가 400rpm일 때 결함이 관찰되었으며, 회전속도가 증가할수록 결함이 감소하는 경향을 보였다. 최종적으로 회전속도 800rpm에서 결함이 없는 용접부를 얻었다. 용접 툴 변화에 따른 기계적 물성 평가 결과 C type 용접 툴을 적용한 경우 보다 우수한 결과가 나타났다. 기계적 물성이 가장 우수한 용접조건은 회전속도 800rpm, 이송속도 200mm/min 이었고, 이때 용접부의 인장강도, 항복강도 그리고 연신율은 모재 대비 90.0%, 69.1%, 83.2% 수준으로 각각 나타났다.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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• pp.235-243
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• 2002

Ni-base superalloys are used extensively in industry, both in aeroengines and land based turbines. About 60% by weight of most modern gas turbine engine structural components are made of Ni-base superalloys. To satisfy practical demands, the efficiency of gas turbine engines has been steadily and systematically increased by design modifications to handle higher turbine inlet or firing temperatures. However, the increase in operating temperatures has lead to a decrease in the life of components and increase in costs of replacement. Moreover, around 80% of the large frame size industrial/utility gas turbines operating in the world today were installed in the mid-sixties to early seventies and are now 25 to 30 years old. Consequently, there are greater opportunities now to repair and refurbish the older models. Basically, there are two major factors influencing the weldability of the cast alloys: strain-age cracking and liquation cracking. Susceptibility to strain-age cracking is due to the total Ti plus AI content of the alloy; Liquation cracking is due either to the presence of low melting constituents or constitutional liquation of constituents. Though Rene 41 superalloy has 4.5wt.% total Ti and Al content and falls just below the safe limit proposed by Prager et al., controlled grain size and special heat treatments are needed to obtain crack-free welds. Varying heat treatments and filler materials were used in a laboratory study, then the actual welding of service parts was carried out to verity the possibility of crack-tree weld of components fabricated from Rene 41 superalloy. The microstructural observations indicated that there were two kinds of carbides in the FCC matrix. MC carbides were located along the grain boundaries, while M$_{23}$C$_{6}$ carbide was located both inter and intra granularly. Two kinds of filler materials, Rene 41 and Hastelloy X were used to gas tungsten arc weld a patch into the sheet metal, along with varying pre-weld heat treatments. The microstructure, hardness and tensile tests were determined. The service distressed parts were categorized into three classes: with large cracks, with medium cracks and with small or no visible cracks. No significant difference in microstructure among the specimens was observed. Specimens were cut from the corner and the straight edge of the patch repair, away from the corner. The only cracks present were found to be associated with inadequate surface preparation to remove oxidation. Guidelines for oxide removal and the welding procedures developed in the research enabled crack-free welds to be produced.d.

• 한국산학기술학회논문지
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• 제18권5호
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• pp.278-284
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• 2017

본 연구에서는 일정한 회전 속도에서 용접 속도를 제어하여 AZ61 마그네슘 합금에 적합한 입열량 조건을 도출하였다. 또한 산업적 측면에서는 더 빠른 용접 속도가 요구되기 때문에 용접 속도에 따른 효과를 연구하였다. 회전 속도 변수는 800rpm으로 일정하게 적용하였고, 용접 속도는 100 - 500mm/min 으로 변화시켜 용접부의 거동을 관찰 및 평가하였다. 기계적 물성 평가를 위하여 인장 및 경도 시험을 수행하였으며, 미세구조 관찰과 용접부의 건정성을 판단하기 위하여 광학현미경을 사용하였다. 용접 속도가 400mm/min 이상 적용되었을 때 용접부 내부에서 결함이 관찰되었다. 용접 속도가 증가할수록 교반부의 결정립 크기는 작아졌으며, 경도 또한 비례 증가하는 경향을 보였다. 회전속도 800rpm, 용접 속도 200mm/min과 300mm/min 일 때, 용접부 내 외부 적으로 결함이 없었으며, 우수한 기계적 물성이 기록되었다. 이때, 접합 효율은 각각 100.5%, 101.2%이었고, 최대인장강도가 모재의 강도와 유사하였다. 인장 시편의 파괴는 시편의 전진측과 교반부 사이에서 발생하였으며, 이는 횡단면부 경도 분포에서 경도가 일시적으로 감소하는 위치와 일치하였다.

• Journal of Welding and Joining
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• 제18권2호
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• pp.213-213
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• 2000

This study was performed to investigate types and formation mechanism of cracks in two Al alloy welds, A5083 and A7NO1 spot-welded by pulse Nd: YAG laser, using SEM, EPMA and Micro-XRD. In the weld zone, three types of crack were observed: center line crack($C_{C}$), diagonal crack($C_{D}$), and U shape crack($C_{U}$). Also, HAZ crack($C_{H}$), was observed in the HAZ region, furthermore, mixing crack($C_{M}$), consisting of diagonal crack and HAZ crack was observed.White film was formed at the hot crack region in the fractured surface after it was immersed to 10%NaOH water. In the case of A5083 alloy, white films in C crack and $C_D crack region were composed of low melting phases, Fe₂Si$Al_8$ and eutectic phases, Mg₂Al₃ and Mg₂Si. Such films observed near HAZ crack were also consist of eutectic Mg₂Al₃. In the case of A7N01 alloy, eutectic phases of CuAl₂, $Mg_{32}$ (Al,Zn) ₃, MgZn₂, Al₂CuMg and Mg₂Si were observed in the whitely etched films near $C_{C}$ crack and $C_{D}$ crack regions. The formation of liquid films was due to the segregation of Mg, Si, Fe in the case of A5083 alloy and Zn, Mg, Cu, Si in the case of A7N01 aooly, respectively.The $C_{D}$ and $C_{C}$ cracks were regarded as a result of the occurrence of tensile strain during the welding process. The formation of $C_{M}$ crack is likely to be due to the presence of liquid film at the grain boundary near the fusion line in the base metal as well as in the weld fusion zone during solidification. The $C_{U}$ crack is considered a result of the collapsed keyhole through incomplete closure during rapid solidification. (Received October 7, 1999)