• Title/Summary/Keyword: Base Potential

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Effect of Substrate on Electroless Co-Base Deposited Films (무전해 코발트계 석출막에 미치는 기판의 영향)

  • Han, Chang-Suk;Chun, Chang-Hwan;Han, Seung-Oh
    • Korean Journal of Materials Research
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    • v.19 no.6
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    • pp.319-324
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    • 2009
  • The deposition behavior and structural and magnetic properties of electroless Co-B and Co-Fe-B deposits, as well as the amorphous ribbon substrates, were investigated. These Co-based alloy deposits exhibited characteristic polycrystalline structures and surface morphology and magnetic properties that were dependent on the type of amorphous substrates. The catalytic activity sequence of the amorphous ribbon electrodes for anodic oxidation of DMAB was estimated from the current density-potential curve in the anodic partial electrolytic bath that did not contain the metal ions. Both the deposition rate and potential in the initial region were obtained in order of the catalytic activity, depending on the alloy compositions of the substrates. The deposition rate linearly varied against the deposition time. The initial deposition potential may have also determined the structural and magnetic properties of the deposit based on the thickness of ${\mu}m$ order. Furthermore, a basic study of the electroless deposition processes on an amorphous ribbon substrate has been carried out in connection with the structural and magnetic properties of the deposits.

Interference effect by electric utilities at electric resistivity Survey of fill dam (필댐의 전기비저항 탐사시 전기매체에 의한 영향 분석 연구)

  • Kim, Jae-Hong;Shin, Dong-Hoon;Im, En-Sang
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1037-1040
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    • 2009
  • Using much most electricity electric resistivity survey by nondestructiveness inquiry enforcement design of country base equipment business and facilities preservation administration dimension electric resistivity survey sends and cause much effects in survey believability by electricity medium of survey personality survey contiguity that grasp base special quality by potential difference flowing current artificially in base. Is item that enforce in most in-suite although when make electric resistivity survey until present, electricity medium or effect research by electricity origination was gone much. There is shortcoming that must be difficult to know correct underground utilities establishment state in-suite in this research and do comparison examination running parallel drilling investigation to heighten believability of electric resistivity survey. Did to dam that censure data that regulate grading from construction and is censure construction which can know correctly interior base situation comparatively to electricity medium of interior and electricity eruption won of contiguity and base condition (base rock).

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Acid-Base Bifunctional Metal-Organic Frameworks: Green Synthesis and Application in One-Pot Glucose to 5-HMF Conversion

  • Zhang, Yunlei;Jin, Pei;Meng, Minjia;Gao, Lin;Liu, Meng;Yan, Yongsheng
    • Nano
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    • v.13 no.11
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    • pp.1850132.1-1850132.14
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    • 2018
  • The direct synthesis of metal-organic frameworks (MOFs) with acidic and basic active sites is challenging due to the introduction of functional groups by post-functionalization method often jeopardize the framework integrity. Herein, we report the direct synthesis of acid-base bifunctional MOFs with tuning acid-base strength. Employing modulated hydrothermal (MHT) approach, microporous MOFs named $UiO-66-NH_2$ was prepared. Through the ring-opening reaction of 1,3-propanesultone with amino group, $UiO-66-NH_2-SO_3H-type$ catalysts can be obtained. The synthesized catalysts were well characterized and their catalytic performances were evaluated in one-pot glucose to 5-HMF conversion. Results revealed the acid-base bi-functional catalyst possessed high activity and excellent stability. This work provides a general and economically viable approach for the large-scale synthesis of acid-base bi-functional MOFs for their potential use in catalysis field.

Coagulation of Cationic Rosin Emulsion and its Effect on Ink Receptivity of Coating Layer (양이온성 로진 에멀션의 응결현상이 도공층의 잉크흡수성에 미치는 영향)

  • 박철웅;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.74-83
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    • 1998
  • The phenomenon of decrease in sizing efficiency when the stock temperature is increased is well recognized as summer sizing, and this is believed to be caused by uneven distribution of sizing agents on paper surface most often incurred by coagulation of sizing agents. When unevenly sized paper is used as coating base stock, nonuniform consolidation of the coating layer may result, which, in turn, causes uneven distribution of binder on coating surface. This causes nonuniform ink absorption to produce print mottle. In this study the effects of simple or polymeric electrolytes, storage temperature and time on the coagulation of cationic dispersed rosin size were investigated using a turbidity measurement method which was verified to correlate well with the particle size of rosin emulsion or its coagulates. Handsheets sized with rosin dispersions coagulated under various conditions were prepared and their sizing degree and coated paper properties including gloss and ink density were examined. The relationship between the sizing nonuniformity of coated papers and its ink absorption property was evaluated. Turbidity of rosin emulsion increased as the storage temperature and time were increased. Addition of simple or polymeric electrolytes caused reduction in $zeta$ -potential of the rosin dispersion and accelerated the coagulation tendency substantially. Reversion of the $zeta$ -potential of rosin dispersion, however, did not occur when coagulation was induced with simple electrolytes. On the other hand, addition of an anionic polyelectrolyte reversed the $zeta$ -potential of the flocculated rosin dispersion. This indicated that electrical double layer compaction and bridging flocculation were coagulation mechanisms for simple and polymeric electrolytes, respectively. Sizing degree decreased as coagulation of rosin was increased. Paper gloss, ink gloss and ink density were increased when sizing degree of base stock was increased most probably due to prevention of base paper swelling and increased binder migration to coating surface. This suggested that uneven printing ink density occurred when uneven sizing development was induced by coagulation of rosin particles.

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Effect of pH and Buffering Potential of Important Domestic Woods on the Gelation Time of Urea-Formaldehyde Resin (주요국산재의 pH 및 Buffering Potential이 요소수지접착제의 Gel시간에 미치는 영향)

  • 권진헌;한태형;류경산
    • Journal of the Korea Furniture Society
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    • v.10 no.1
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    • pp.43-49
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    • 1999
  • The pH and buffering potential for water extract of seven hardwoods and three softwoods were determined. The pH values ranged from 3.81 to 5.51 for hardwoods and 4.08 to 5.49 for softwoods. The gelation time for a urea-formaldehyde resin for each woods was determined and found to be a range of one minute thirty seven seconds to two minutes thirty nine seconds. Results shows that gelation time of a urea-formaldehyde resin was directly correlated to the pH and inversely correlated with acid buffering potential for seven hardwoods and three softwoods aqueous extracts

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Potential-based Reinforcement Learning Combined with Case-based Decision Theory (사례 기반 결정 이론을 융합한 포텐셜 기반 강화 학습)

  • Kim, Eun-Sun;Chang, Hyeong-Soo
    • Journal of KIISE:Computing Practices and Letters
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    • v.15 no.12
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    • pp.978-982
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    • 2009
  • This paper proposes a potential-based reinforcement learning, called "RLs-CBDT", which combines multiple RL agents and case-base decision theory designed for decision making in uncertain environment as an expert knowledge in RL. We empirically show that RLs-CBDT converges to an optimal policy faster than pre-existing RL algorithms through a Tetris experiment.

Activity Coefficients and Coulombic Correction Factor for Surface Complexation Modeling

  • Rhee, In-Hyoung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.146-155
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    • 2002
  • Surface complexation models employ mass law equations to describe the reaction of surface functional groups with ions in the solution and also Gouy-Chapman theory to consider the electrostatic effects in the surface reactions. In current surface complexation models, however, the coulombic factors used are not wholly consistent with the Gouy-Chapman model of the surface. This study was to provide the derivation of the coulombic term usually employed and then a revised coulombic term completely consistent with Gouy-Chapman Theory. The electrical potential energy. zF${\psi}$, in current surface complexation models is not consistent with the Gouy-Chapman theory with the potential gradient close to the charged surface but with the Donnan model with the uniform potential. Even though the new coulombic factor yielded lower surface potential, it provided worse fits for acid-base titration data of the goethite suspensions.

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The New Challenges for the Republic of Korea Navy and the Development of Maritime Task Flotilla's Force Development (한국해군의 새로운 도전과 기동전단의 발전 방향)

  • Kim, Duk-ki
    • Strategy21
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    • s.39
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    • pp.163-197
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    • 2016
  • The completion of Jeju Naval Base on February 2016 made the Republic of Korea Navy(ROKN) review the size and role of the Maritime Task Flotilla(MTF). The new strategic environment for the 12st century and the new challenges require the Navy to counter North Korea's provocations and prevent potential enemy's threat. The Navy is also required to take part in the variety of international roles and missions commensurated with Korea's global status to maximize the national interest. Despite these changes, Korea's military construction concept is still unable to break away from the old paradigm of the North Korean threat largely centered. In order to develop the current MTF into the Task Group with the construction of Jeju Naval Base, the Navy must newly not only establish new force development plan and fleet management concepts but also go to persuade and convince policy decision makers. To this end, the following efforts should be promoted. First, the ROK Navy steps up efforts in order to share with the Task Group's vision and strategy. The Navy should also provide the size and structure as well as the missions and roles of the Task Group to react to new maritime security environment. Second, the Navy analyse the MTF's ability and what is required and necessary to perform its duty. After that, it must set out the direction of the Task Group's force development. Third, the current missions and roles of the MTF should be re-established to respond various threats. Finally, accommodating of new technology to the MTF should intensify its strengths. The ROK Navy has a mixed force structure consisting of three fixed- base fleets and a MTF. The fixed base fleet has a passive force to defend and protect its own sea areas, but the MTF should actively not only counter North Korea's threats, including ballistic missiles, but also fight potential threats and takes international missions as a primary task force. However, the MTF has a limited capability to accomplish given missions and long-range operations, and thus, the ROK Navy is strongly required to construct the Task Group.

Analogical Reasoning in Construction of Quadratic Curves (이차곡선의 작도 활동에서 나타난 유추적 사고)

  • Heo, Nam Gu
    • Journal of Educational Research in Mathematics
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    • v.27 no.1
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    • pp.51-67
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    • 2017
  • Analogical reasoning is a mathematically useful way of thinking. By analogy reasoning, students can improve problem solving, inductive reasoning, heuristic methods and creativity. The purpose of this study is to analyze the analogical reasoning of preservice mathematics teachers while constructing quadratic curves defined by eccentricity. To do this, we produced tasks and 28 preservice mathematics teachers solved. The result findings are as follows. First, students could not solve a target problem because of the absence of the mathematical knowledge of the base problem. Second, although student could solve a base problem, students could not solve a target problem because of the absence of the mathematical knowledge of the target problem which corresponded the mathematical knowledge of the base problem. Third, the various solutions of the base problem helped the students solve the target problem. Fourth, students used an algebraic method to construct a quadratic curve. Fifth, the analysis method and potential similarity helped the students solve the target problem.

Morphological study of porous aromatic schiff bases as a highly effective carbon dioxide storages

  • Rehab Hammoda;Naser Shaalan;Mohammed H. Al-Mashhadani;Dina S. Ahmed;Rahimi M. Yusop;Ali H. Jawad;Emad Yousif
    • Analytical Science and Technology
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    • v.36 no.5
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    • pp.236-249
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    • 2023
  • Carbon dioxide (CO2) capture and storage is a critical issue for mitigating climate change. Porous aromatic Schiff base complexes have emerged as a promising class of materials for CO2 capture due to their high surface area, porosity, and stability. In this study, we investigate the potential of Schiff base complexes as an effective media for CO2 storage. We review the synthesis and characterization of porous aromatic Schiff bases materials complexes and examine their CO2 sorption properties. We find that Schiff base complexes exhibit high CO2 adsorption capacity and selectivity, making them a promising candidate for use in carbon capture applications. Moreover, we investigate the effect of various parameters such as temperature, and pressure on the CO2 adsorption properties of Schiff base complexes. The Schiff bases possessed tiny Brunauer-Emmett-Teller surface areas (4.7-19.4 m2/g), typical pore diameters of 12.8-29.43 nm, and pore volumes ranging from 0.02-0.073 cm3/g. Overall, our results suggest that synthesized complexes have great potential as an effective media for CO2 storage, which could significantly reduce greenhouse gas emissions and contribute to mitigating climate change. The study provides valuable insights into the design of novel materials for CO2 capture and storage, which is a critical area of research for achieving a sustainable future.