• 제목/요약/키워드: Barrier energy

검색결과 825건 처리시간 0.027초

Study on Reactive Non-thermal Plasma Process combined with Metal Oxide Catalyst for Removal of Dilute Trichloroethylene

  • Han Sang-Bo;Oda Tetsuji;Park Jae-Youn;Park Sang-Hyun;Koh Hee-Seok
    • 한국전기전자재료학회논문지
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    • 제19권3호
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    • pp.292-300
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    • 2006
  • In order to improve energy efficiency in the dilute trichloroethylene removal using the nonthermal plasma process, the barrier discharge treatment combined with manganese dioxide was experimentally studied. Reaction kinetics in this process was studied on the basis of final byproducts distribution. Decomposition efficiency was improved to about $99\;\%$ at the specific energy of 40 J/L with passing through manganese dioxide. C=C ${\pi}$ bond cleavage of TCE substances gave DCAC, which has the single bond of C-C through oxidation reaction during the barrier discharge plasma treatment. Those DCAC were broken easily in the subsequent catalytic reaction due to the weak bonding energy about $3{\sim}4\;eV$ compared with the double bonding energy in TCE molecules. Oxidation byproducts of DCAC and TCAA from TCE decomposition are generated from the barrier discharge plasma treatment and catalytic surface chemical reaction, respectively. Complete oxidation of TCE into COx is required to about 400 J/L, but $CO_2$ selectivity remains about $60\;\%$.

건축물의 창틀과 벽체 사이 열교 차단을 위한 단열공법 개발 (Development on Thermal Bridge Barrier Between Window Frame and Wall)

  • 박철용;김웅회;이상희
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 추계 학술논문 발표대회
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    • pp.10-11
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    • 2018
  • Internal Insulation system is applied to the most apartment building in Korea. However due to the importance of building energy enhanced the interest of the exernal insulation system. The extermal insulation system has better thermal performance because the thermal bridge through the structure are rarely formed. But the thermal bridge around the window decrease the thermal performance of the envelope system. Therefore the technology for reducing the thermal bridge around window improves energy efficiency of the building. In order to this it is necessary to minimize the thermal bridge around window of building. In this study it is aimed to minimize the thermal bridge around the window of building. It was confirmed that the use of thermal bridge barrier imporved the heat transfer rate by 64% or more and the condensation reduction phenomenon by 42% or more compared with the exist technology. These thermal bridge barrier will be used as the main technology to improve the energy efficiency of building.

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산화그래핀이 함유된 폴리이미드 나노복합막의 기체차단성 평가 및 활용 (Graphene Oxide/Polyimide Nanocomposites for Gas Barrier Applications)

  • 유병민;이민용;박호범
    • 멤브레인
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    • 제27권2호
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    • pp.154-166
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    • 2017
  • 식품 포장, 전자 기기 등에 활용되고 있는 고분자 기반 기체 차단성 필름은 경량성, 낮은 제조 원가, 높은 가공성으로 인하여 많은 주목을 받고 있다. 특히 전자기기에 활용되기 위하여, 기체 차단 필름은 매우 높은 수준의 기체 차단성을 요구받고 있다. 하지만 현재 수준의 고분자 기반 기체 차단 필름은 다른 소재와 비교하여 상대적으로 높은 수준의 기체 투과유량을 보이고 있다. 따라서 기존의 고분자 필름이 가지고 있는 장점을 유지하면서 더 높은 수준의 기체 차단성을 부여하기 위한 요구가 증대되고 있다. 최근 그래핀 소재는 기체 차단을 위한 2차원 소재로서 각광받고 있다. 그러나 그래핀 소재의 낮은 가공성과 어려운 대면적화 문제 때문에 산화그래핀이 그 대안으로서 떠오르고 있다. 산화그래핀은 높은 종횡비를 가지는 2차원 층상구조의 그래핀에 산소관능기를 함유한 형태로서, 수용성 혹은 극성 용매에 잘 분산되는 성질을 가지며, 따라서 대량 생산에 용이한 특성을 가지고 있다. 본 연구에서는, 산화그래핀이 함유된 폴리이미드 나노복합막을 제조하였다. 폴리이미드는 현재 널리 이용되고 있는 기체 차단성 고분자 중의 하나로서 높은 기계적 강도, 열적 안정성 및 내화학성을 가지고 있다. 본 연구를 통하여 산화그래핀이 함유된 폴리이미드 나노복합막이 기체 차단성을 가지고 있음을 확인하였다. 더 나아가, Triton X-100이나 sodium deoxycholate (SDC) 등의 계면활성제를 나노복합막에 도입함으로써 산화그래핀의 고분자 매트릭스 내에서의 분산성을 향상시켜 기체 차단성을 높이고자 하였다. 그 결과로서, Triton X-100이 도입된 나노복합막이 예상치와 유사한, 향상된 기체 차단성을 보임을 확인하였다. 본 연구를 기반으로 고분자 기반 나노복합막의 기체 차단성 분야로의 활용성이 증대될 것으로 기대한다.

Oxygen Barrier Coating with Carbon Interlayer on Polypropylene

  • 김성진;송은경;조경식;윤태경;문명운;이광렬
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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    • pp.210-210
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    • 2012
  • Gas barrier coating from dense thin film deposition has been one of the important applications such as food-packaging and organic display. Especially for food-packaging, plastic container has been widely used due to its low price and high through-put in mass production. However, the plastic container with low surface energy like polypropylene (PP) has been limited to apply gas barrier coating. That is because a gas barrier coating could not adhere to PP due to its too low surface energy and high porosity of PP. In this research, we applied carbon coating consisting of Si and O as an interlayer between silicon oxide (SiOx) and PP. A carbon layer was found to provide better adhesion, which was experimentally proved by oxygen transmission rate (OTR) and SEM images. However, we also found that there is a limitation in the maximum thickness of a carbon layer and SiOx film due to their high stress level. For this conflict, we obtain the optimal thickness of a carbon layer and SiOx film showing optimal gas barrier property.

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Analysis of Energy Flow and Barrier Rib Height Effect using Ray-Optics Incorporated Three-dimensional PDP Cell Simulation

  • Chung, Woo-Joon;Jeong, Dong-Cheol;Whang, Ki-Woon;Park, Jae-Hyeung;Lee, Byoung-Ho
    • Journal of Information Display
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    • 제2권4호
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    • pp.46-51
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    • 2001
  • Using ray-optics code incorporated with three-dimensional PDP cell simulation, we have analysed the energy flow in the PDP cell from the electric power input to the visible light output. Also, the visible light output profile and viewing angle distribution were obtained. We applied our code to the analysis of the barrier rib height effect on the visible light luminance and efficiency of the sustaining discharge. Although cells with higher barrier rib generate more VUV photons, less ratio of visible photons are emitted toward front panel due to the shadow effect. Thus, there exists optimal barrier rib height giving the highest visible luminance and efficiency. This kind of code can be a powerful tool in designing cell geometry.

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Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • 제15권3호
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

표면방사율에 따른 복사단열시스템의 열관류성능 평가 연구 (Evaluation of U-value for Radiant Barrier Systems in Relation to Surface Emissivity)

  • 김기세;이동규;윤종호;송인춘
    • 태양에너지
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    • 제20권3호
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    • pp.39-50
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    • 2000
  • Radiant barrier systems(RES) constructed with low emissivity materials bounded by an open air space can be used to reduce the net radiation transfer between two surfaces. To analyze the heat transfer characteristics of the radiant barrier systems which consist of a single-glass and radiation barriers, a simple theoretical model based on energy balances was suggested. And the model was validated by means of the experimental results. Using a guarded hot box, the temperatures of layers in selected RES and energy use for each cases were measured. The results show that the model well explained the heat transfer characteristics of those RES. Also, the heat transfer coefficient correlations considering natural and forced convection heat transfer ware suggested. It is found that the heat transfer efficiency of a RBS with aluminium surface improved up to 66.6% over that of a single glazing system.

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Analysis of Electrical Properties of Ti/Pt/Au Schottky Contacts on (n)GaAs Formed by Electron Beam Deposition and RF Sputtering

  • Sehgal, B-K;Balakrishnan, V-R;R Gulati;Tewari, S-P
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제3권1호
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    • pp.1-12
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    • 2003
  • This paper describes a study on the abnormal behavior of the electrical characteristics of the (n)GaAs/Ti/Pt/Au Schottky contacts prepared by the two techniques of electron beam deposition and rf sputtering and after an annealing treatment. The samples were characterized by I-V and C-V measurements carried out over the temperature range of 150 - 350 K both in the as prepared state and after a 300 C, 30 min. anneal step. The variation of ideality factor with forward bias, the variation of ideality factor and barrier height with temperature and the difference between the capacitance barrier and current barrier show the presence of a thin interfacial oxide layer along with barrier height inhomogenieties at the metal/semiconductor interface. This barrier height inhomogeneity model also explains the lower barrier height for the sputtered samples to be due to the presence of low barrier height patches produced because of high plasma energy. After the annealing step the contacts prepared by electron beam have the highest typical current barrier height of 0.85 eV and capacitance barrier height of 0.86 eV whereas those prepared by sputtering (at the highest power studied) have the lowest typical current barrier height of 0.67 eV and capacitance barrier height of 0.78 eV.

Vertical Diffusion of Ammonia Into Amorphous Ice Sturcture

  • 김영순;문의성;강헌
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.280-280
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    • 2012
  • We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

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Hydrodynamic performance of a vertical slotted breakwater

  • George, Arun;Cho, Il Hyoung
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제12권1호
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    • pp.468-478
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    • 2020
  • The wave interaction problem with a vertical slotted breakwater, consisting of impermeable upper, lower parts and a permeable middle part, has been studied theoretically. An analytical model was presented for the estimation of reflection and transmission of monochromatic waves by a slotted breakwater. The far-field solution of the wave scattering involving nonlinear porous boundary condition was obtained using eigenfunction expansion method. The empirical formula for drag coefficient in the near-field, representing energy dissipation across the slotted barrier, was determined by curve fitting of the numerical solutions of 2-D channel flow using CFD code StarCCM+. The theoretical model was validated with laboratory experiments for various configurations of a slotted barrier. It showed that the developed analytical model can correctly predict the energy dissipation caused by turbulent eddies due to sudden contraction and expansion of a slotted barrier. The present paper provides a synergetic approach of the analytical and numerical modelling with minimum CPU time, for better estimation of the hydrodynamic performance of slotted breakwater.