• 제목/요약/키워드: Barium titanates

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Modeling the Relationship between Process Parameters and Bulk Density of Barium Titanates

  • Park, Sang Eun;Kim, Hong In;Kim, Jeoung Han;Reddy, N.S.
    • 한국분말재료학회지
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    • 제26권5호
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    • pp.369-374
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    • 2019
  • The properties of powder metallurgy products are related to their densities. In the present work, we demonstrate a method to apply artificial neural networks (ANNs) trained on experimental data to predict the bulk density of barium titanates. The density is modeled as a function of pressure, press rate, heating rate, sintering temperature, and soaking time using the ANN method. The model predictions with the training and testing data result in a high coefficient of correlation (R2 = 0.95 and Pearson's r = 0.97) and low average error. Moreover, a graphical user interface for the model is developed on the basis of the transformed weights of the optimally trained model. It facilitates the prediction of an infinite combination of process parameters with reasonable accuracy. Sensitivity analysis performed on the ANN model aids the identification of the impact of process parameters on the density of barium titanates.

$Sb_2O_3$첨가량에 의한 Barium-Titanates의 전기적 성질 (Electrical Properties of Barium-Titanates with addition $Sb_2O_3$)

  • 박창엽;왕진석;김현재
    • 대한전자공학회논문지
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    • 제14권1호
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    • pp.5-14
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    • 1977
  • 공기중의 열처리에 의하여 상온에서 낮은 저항을 갖는 PTC 써미스터를 제작했다. 재현성을 높이기 위해 BaTiO3에 Al2O3, SiO2 및 TiO2를 첨가 했으며, 불순물로서 Sb2O3를 첨가했다. 시편은 공기 중에서 1,200℃∼1,380℃로서 가열되었으며, Sb2O3첨가량에 대한 저항관계를 조사했다. 이 시편들은 공기중의 열처리에서도 재현성이 좋았다. 연구된 시편은 3.75mole% Al2O3, 1.25mole% SiO2, 2.25mole% TiO2 및 0.16∼0.25wt% Sb2O3를 BaTiO3에 첨가하여 만들었으며 저항값은 14∼300ohm이었다.

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Dimethyl oxalate에 의한 barium titanyl oxalate의 균일 침전에 미치는 화학적 인자와 이들이 티탄산 바륨의 특성에 미치는 영향 (Chemical Factors on the Homogeneous Precipitation of Barium Titanyl Oxalate by Dimethyl Oxalate and Their Effects on the Charateristics of Barium Titanate)

  • 류경열;허우영;이철
    • 분석과학
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    • 제12권3호
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    • pp.230-234
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    • 1999
  • $Ba^{2+}$$Ti^{4+}$이 함유된 염산용액에서 dimethyl oxalate(DMO)가 열분해되면 barium titanyl oxalate(BTO)가 균일 생성되었다. 일정량의 hydroxy propyl cellulose(HPC)를 분산제로 사용하였고 120min의 숙성시간에서 생성된 BTO의 전 침전물을 회수하였다. 반응온도, 염화이온의 농도, $[DMO]_0/([Ba^{2+}]_0+[Ti^{4+}]_0)$의 초기 농도비, 그리고 가한 HPC가 BTO입자의 형태, 화학적 회수율, 그리고 그들의 선구물질로부터 형성된 티탄산 바륨의 특성에 영향을 미침을 알았다.

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Nb이 첨가된 $BaTiO_3$ 세라믹스의 복소 임피던스 해석 (Complex Impedance Analysis of Nb-Doped Barium Titanate Ceramics)

  • 조경호;남효덕;이희영
    • 한국세라믹학회지
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    • 제31권9호
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    • pp.1012-1220
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    • 1994
  • BaTiO3 ceramics doped with 0.1 to 4.0 mol% Nb2O5 were prepared by conventional solid stage sintering process, so as to investigate the effect of the amount of Nb2O5 on the dielectric properties and complex impedance patterns of barium titanates. From the measurement of capacitance, we found that the dielectric constant of BaTiO3 samples with 1 mol% or more Nb2O5 remained approximately constant around room temperature with values higher than 2500. In this paper, the effect of impurity content as well as temperature on complex impedance patterns was discussed in detail. In particular, the grain and grain boundary behavior of samples which showed PTCR characteristics was discussed in terms of measuring temperature.

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섬유상 분말로 제조된 배향성을 가진 $BaTiO_3$ 세라믹 (Oriented Barium Titanate Ceramics Made from Fiber State Powder)

  • 서용교;야나기다히로아끼
    • 한국세라믹학회지
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    • 제30권12호
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    • pp.1066-1070
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    • 1993
  • When looked upon as a polycrystalline, ceramics have two basic differences from a single crystal. One is that there exist grain boundaries, the other is that the crystal axes of each small crystal are arranged in random directions. But the crystal axes fo small crystals which compose ceramics may be made to have the tendency of being arranged in a specific direction. This is called that the crystal axes are oriented. The degree of the direction arrangement of the crystal axes is called orientation. In order to orient the crystal axes effectively, the fiberous barium titanates were made through KDC method and the ion exchange method. And then they were arranged through pressing, doctor blade, and syringe. As the result of Lotgering evaluation, the sample oriented through syringe showed the highest orientation. After sintering, though the most particles that had been fiberous shaped became global shape viewed through SEM, the orientation of the crystals was reinforced by means of sintering.

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정저항요업체의 제조와 전기적 성질 (Preparation and Electrical Properties of PTCR Ceramic Materials)

  • 정형진;윤상옥
    • 한국세라믹학회지
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    • 제22권2호
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    • pp.11-16
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    • 1985
  • The semiconducting ceramics having positive temperature coefficient of resistivity in he family of 0.25mol% $Sb_2O_3$ doped barium titanates were prepared with AST ($4Al_2O_3$.$9SiO_2$.$3TiO_2$) and $MnO_2$ as additives and these electrical properties were investigated. The PTCR characteristic in these ceramic materials was improved by the addition of AST and $MnO_2$ because the addition of AST decreased the room temperature resistivity and controlled grin size due to the formation of a liquid phase during sintering and the addition of $MnO_2$ improved by forming acceptor level on the intergranular layer. On dependence on the switching time as switching temperature was increased the initial power and switching time increased.

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