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Sheet fabrication of Ni-WC anode for Molten Carbonate Fuel Cell by Tape Casting Method (테이프 캐스팅법에 의한 MCFC Anode용 Ni-WC 박판 제조)

  • Choe, Jin-Yeong;Jeong, Seong-Hoe;Jang, Geon-Ik
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.715-720
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    • 2000
  • By the mechanical alloying method. Ni-WC composite materials were prepared to improve the deformation-resistance for creep and sintering of Ni-anode at the operating temperature of $650^{\circ}C$. Mechanically alloyed powder w was initially fabricated by ball milling for 80hr, and then amorphization was occurred by the destruction of ordered crystals based on XRD analysis. In order to investigate the electrochemical performance and sheet characteristics of Ni-WC anode, tape casting process was adopted. Finally, the obtained sheet thickness of Ni- we after sintering at $1180^{\circ}C$ for 60 minutes in $H_2$ atmosphere was O.9mm and the average pore size was $3~5{\mu\textrm{m}}$ with porosities of 55%. The second phase was not observed in Ni- W matrix while W particles were finely and uniformly distributed in Ni matrix. This fine and uniform distributed W particles in Ni matrix are expected to enhance the mechanical properties of Ni anode through the dispersion and solid solution hardening mechanisms.

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Quantitative Analysis on the Damage of the Austenitic Stainless Steel under the Simultaneous Cavitation Bubble and Solid Particle Collapses (오스테나이트계 304 스테인리스강의 케비테이션 기포 및 고체 입자 동시 충격 손상의 정량적 고찰)

  • Hong, Sung-Mo;Park, Jin-Ju;Lee, Min-Ku;Rhee, Chang-Kyu
    • Korean Journal of Metals and Materials
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    • v.48 no.10
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    • pp.893-900
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    • 2010
  • In the present work, the impact loads and their effects on the surface damage under the simultaneous cavitation bubble and solid particle collapses in the sea water have been quantitatively investigated for the austenitic 304 stainless steel by using a vibratory cavitation test device. To do this, angular $SiO_2$ solid particles with an average size of $150{\mu}m$ were dispersed into the test liquid, and the measured impact amplitudes were converted into the impact loads by a steel ball drop test. The maximum impact load was determined to be 28.2 N in the absence of solid particles, but increased to 33.7 N in the presence of solid particles. In addition, the critical impact loads, $L_{crit}$, required to generate pits with sizes greater than $3{\mu}m$ were measured to be 19.6 N and 16.6 N, respectively, for the cavitation bubble collapse and solid particle collapse. As a result of the cavitation erosion test, the incubation time and erosion rate were 1.2 times lower and 1.5 times higher, respectively, by a solid particle collapse compared to those only by the cavitation bubble collapse, indicating a drastic decrease in a resistance to cavitation erosion by the solid particle collapse.

Mechanical Properties and Fabrication of Nanostructured Al2TiO5 Compound by Pulsed Current Activated Sintering (펄스전류 활성 소결에 의한 나노구조 Al2TiO5 화합물 제조 및 기계적 특성)

  • Kang, Hyun-Su;Park, Hyun-Kuk;Doh, Jung-Mann;Yoon, Jin-Kook;Park, Bang-Ju;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.11
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    • pp.817-822
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    • 2012
  • Nano powders of $Al_2O_3$ and $TiO_2$ compounds made by high energy ball milling were pulsed current activated sintered for studying their sintering behaviors and mechanical properties. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition of grain growth. Nano-structured $Al_2TiO_5$ with small amount of $Al_2O_3$ and$TiO_2$ was formed by sintering at $1300^{\circ}C$ for 5 minute, in which average grain size was about 96 nm. Hardness and fracture toughness of the nano-structured $Al_2TiO_5$ compound with a small amount of $Al_2O_3$ and$TiO_2$ were $602kg/mm^2$ and $2.6MPa{\cdot}m^{1/2}$, respectively.

Viator vitreocola gen. et sp. nov. (Stylonematophyceae), a new red alga on drift glass debris in Oregon and Washington, USA

  • Hansen, Gayle I.;West, John A.;Yoon, Hwan Su;Goodman, Christopher D.;Goer, Susan Loiseaux-de;Zuccarello, Giuseppe C.
    • ALGAE
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    • v.34 no.2
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    • pp.71-90
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    • 2019
  • A new encrusting red alga was found growing abundantly on glass debris items that drifted ashore along the coasts of Oregon and Washington. These included discarded fluorescent tubes, incandescent light bulbs, capped liquor bottles, and ball-shaped fishing-net floats. Field collections and unialgal cultures of the alga revealed that it consisted of two morphological phases: a young loosely aggregated turf and a mature consolidated mucilaginous crust. The turf phase consisted of a basal layer of globose cells that produced erect, rarely branched, uniseriate to multiseriate filaments up to $500{\mu}m$ long with closely spaced cells lacking pit-plugs. These filaments expanded in size from their bases to their tips and released single cells as spores. At maturity, a second phase of growth occurred that produced a consolidated crust, up to $370{\mu}m$ thick. It consisted of a basal layer of small, tightly appressed ellipsoidal-to-elongate cells that generated a mucilaginous perithallial matrix containing a second type of filament with irregularly spaced cells often undergoing binary division. At the matrix surface, the original filaments continued to grow and release spores but often also eroded. Individual cells, examined using confocal microscopy and SYBR Green staining, were found to contain a central nucleus, a single highly lobed peripheral chloroplast without a pyrenoid, and numerous chloroplast nucleoids. Morphological data from field and culture isolates and molecular data (rbcL, psbA, and SSU) show that this alga is a new genus and species which we name Viator vitreocola, "a traveller on glass."

The Effect of Exercising on a Stable and Unstable Surface on Young Female University Students' Arms (안정된 지지면과 불안정한 지지면에서의 운동이 20대 여대생의 팔에 미치는 영향)

  • Kim, Jwa-Jun;Park, Mi-Yeon;Shin, Ha-Lim;Lee, Eun-Kyung;Lee, Hyun-Joo;Hwang, Ryu-Kyung
    • PNF and Movement
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    • v.12 no.4
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    • pp.233-241
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    • 2014
  • Purpose: The purpose of this study is to investigate the effects of exercising on a stable and unstable surface for a period of six weeks on the arms of female university students in their twenties. Methods: The subjects consisted of 20 female university students. The experimental group consisted of ten individuals who exercised on an unstable surface, and the control group consisted of ten individuals who exercised on a stable surface. The exercise program was composed of aerobic exercises (i.e. Back and forth movements for clapping and raising cross with both arms) and muscle-strengthening exercises (i.e. Push-ups and raising arms). We measured the subjects before the experiment and after the exercise program using the following measurements tool: a ruler and T-scan plus. The same person measured changes in arm size with a ruler three times and calculated the average to minimize any errors in measurement. We controlled the subjects to measure the amount of arm muscle with a T-scan plus. Twelve hours before the measurements were taken subjects were not permitted to exercise, and four hours before the measurements were taken subjects were not permitted to eat anything. Results: The two groups had no significant difference, but each group felt the effect of the exercise program. Conclusion: There was no difference between the experimental group and the control group. However, it was determined that the exercise had a greater effect on an unstable surface than a stable surface.

Fabrication and Mechanical Properties of Nanostructured Al2O3-MgSiO3-SiO2 Composites Synthesized by Pulsed Current Activated Combustion of Mechanically Activated Powder (기계적 활성화된 분말로부터 펄스전류활성 연소합성에 의한 나노구조 Al2O3-MgSiO3-SiO2복합재료 제조 및 기계적 특성)

  • Shon, In-Jin;Kang, Hyun-Su;Doh, Jung-Mann;Yoon, Jin-Kook
    • Korean Journal of Metals and Materials
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    • v.49 no.7
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    • pp.565-569
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    • 2011
  • Nanopowders of MgO, $Al_2O_3$ and $SiO_2$ were made by high-energy ball milling. The fast sintering of nanostructured $Al_2O_3-MgSiO_3-SiO_2$ composites was investigated from mechanically activated powders of MgO, $Al_2O_3$ and $SiO_2$ by a pulsed-current activated sintering process. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties; in particular greater strength, hardness, excellent ductility and toughness. Highly dense nanostructured $Al_2O_3- MgSiO_3-SiO_2$ composites were produced with simultaneous application of 80 MPa and pulsed output current of 2800A within 2 minutes. The sintering behavior, grain size and mechanical properties of $Al_2O_3-MgSiO_3-SiO_2$ composites were investigated.

Mechanical Properties and Fabrication of Nanostructured Mg2SiO4-MgAl2O4 Composites by High-Frequency Induction Heated Combustion (기계적 활성화된 분말로부터 고주파유도 가열 연소합성에 의한 나노구조 Mg2SiO4-MgAl2O4 복합재료 제조 및 기계적 특성)

  • Shon, In-Jin;Kang, Hyun-Su;Hong, Kyung-Tae;Doh, Jung-Mann;Yoon, Jin-Kook
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.614-618
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    • 2011
  • Nanopowders of MgO, $Al_2O_3$ and $SiO_2$ were made by high energy ball milling. The rapid sintering of nanostructured $MgAl_2O_4-Mg_2SiO_4$ composites was investigated by a high-frequency induction heating sintering process. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition of grain growth. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties. As nanomaterials possess high strength, high hardness, excellent ductility and toughness, undoubtedly, more attention has been paid for the application of nanomaterials. Highly dense nanostructured $MgAl_2O_4-Mg_2SiO_4$ composites were produced with simultaneous application of 80MPa pressure and induced output current of total power capacity (15 kW) within 2min. The sintering behavior, gain size and mechanical properties of $MgAl_2O_4-Mg_2SiO_4$ composites were investigated.

Rapid Synthesis and Sintering of Nanostructured MgTiO3 Compound by High-Frequency Induction Heating (고주파 유도 가열에 의한 급속 나노구조 MgTiO3 화합물 합성 및 소결)

  • Kang, Hyun-Su;Doh, Jung-Mann;Yoon, Jin-Kook;Park, Bang-Ju;Shon, In-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.12
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    • pp.891-896
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    • 2012
  • Nanopowders of MgO and $TiO_2$ were made by high energy ball milling. The rapid synthesis and sintering of the nanostructured $MgTiO_3$ compound was investigated by the high-frequency induction heated sintering process. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition grain growth. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties. As nanomaterials possess high strength, high hardness, excellent ductility and toughness, undoubtedly, more attention has been paid for the application of nanomaterials. A highly dense nanostructured $MgTiO_3$ compound was produced with simultaneous application of 80 MPa pressure and induced current within 2 min. The sintering behavior, gain size and mechanical properties of $MgTiO_3$ compound were investigated.

Mechanical Property Evaluation of WC-Co-Mo2C Hard Materials by a Spark Plasma Sintering Process (방전플라즈마 소결 공정을 이용한 WC-Co-Mo2C 소재의 기계적 특성평가)

  • Kim, Ju-Hun;Park, Hyun-Kuk
    • Korean Journal of Materials Research
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    • v.31 no.7
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    • pp.392-396
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    • 2021
  • Expensive PCBN or ceramic cutting tools are used for processing of difficult-to-cut materials such as Ti and Ni alloy materials. These tools have the problem of breaking easily due to their high hardness but low fracture toughness. To solve these problems, cutting tools that form various coating layers are used in low-cost WC-Co hard material tools, and research on various tool materials is being conducted. In this study, binderless-WC, WC-6 wt%Co, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are densified using horizontal ball milled WC-Co, WC-Co-Mo2C powders, and spark plasma sintering process (SPS process). Each SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are almost completely dense, with relative density of up to 99.5 % after the simultaneous application of pressure of 60 MPa and almost no significant change in grain size. The average grain sizes of WC for Binderless-WC, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are about 0.37, 0.6, 0.54, and 0.43 ㎛, respectively. Mechanical properties, microstructure, and phase analysis of SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo2C, and WC-6 wt%Co-2.5 wt% Mo2C hard materials are investigated.

Investigation of Changes in Structural Characteristics and Chemical Composition after Heat Treatment Process of JIS-SUJ2 Bearing Steel (JIS-SUJ2 베어링강의 열처리 이후 표면 및 심부에서 나타나는 구조적, 화학적 물성 변화)

  • Donghee Lee;Kyun Taek Cho;Hyeonmin Yim;Seung-Hwan Oh;Tae Bum Kim;Woo-Byoung Kim
    • Korean Journal of Materials Research
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    • v.33 no.12
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    • pp.558-564
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    • 2023
  • In this study, we designed and manufactured a large angular contact ball bearing (LACBB) with low deformation using JIS-SUJ2 steel and analyzed changes in its structural characteristics and chemical composition upon heat treatment. The bearing was produced by hot forging and heat treatment including a quenching and tempering (Q/T) process, and its properties were analyzed using 4 mm thick specimens. A difference in the size distribution of the carbide in the outer and inner parts of the bearing was observed and it was confirmed that large and non-uniform carbide was distributed in the inner part of the bearing. After heat treatment, the hardness value of the outer part increased from 13.4 HRC to 61 HRC and the inner part increased from 8.0 HRC to 59.7 HRC. As a result of X-ray diffraction (XRD) measurements, the volume fraction of the retained austenite contained in the outer part was calculated to be 3.5~4.8 % and the inner part was calculated to be 3.6~5.0 %. The surface chemical composition and the content of chemical bonds were quantified through X-ray photoelectron spectroscopy (XPS), and a decrease in C=C bonds and an increase in Fe-C bonds were confirmed.