• Journal of the Korean Geographical Society
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• v.41 no.4 s.115
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• pp.418-434
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• 2006

The study was investigated to runoff characteristics of non-point pollutants according to rainfall in Kokseong river watershed. The result of which is as follows : First of all, major reason which affect the formation of water quality of Kokseong River is judged to be caused by non-point pollution source which flows out from farmland and residential area. Flow of rainfall effluent in the downstream in which direct flow components of urban district and combined sewer overflows of farmland was intervened faster than that in the upstream reacted more promptly. Generation of pollutants by non-point source shows increasing trend in general in accordance with the increase in the intensity of rainfall but it was affected by SS, BOD, COD and T-P in the upstream part whereas BOD, COD and T-N were significantly affected by beginning period of rainfall in the downstream. EMC in the downstream increased approximately 3-315 times as compared to upstream, particularly the discharge of SS5 and T-P were extremely increased. While surface flow out of rainfall effluent in the upstream was only 4.7%, the surface flow in the downstream took up as much as 29%, which was major reason for the increase of EMC. From the above contents, we can see that the change in water quality according to the increase and decrease of effluent at the time of rainfall showed very complex pattern depending on the type of land use, and it is judged that the most important thing for the administration of non-point pollution source is to come up with the solution for the reduction of effluent at the beginning.

• Journal of Wetlands Research
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• v.23 no.3
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• pp.242-251
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• 2021

Surface water pollution is a serious environmental problem in developing countries, like India, due to the unregulated discharge of untreated wastewater. To overcome this, the constructed wetlands (CWs) have been proven to be an efficient technology for wastewater treatment. In this study, different existing and experimental facilities were reviewed to be able to determine the current status of constructed wetlands in India. Based on the collected data from published literature, industrial wastewater contained the highest average chemical oxygen demand (COD), biochemical oxygen demand (BOD). In terms of total nitrogen (TN), Total phosphorous (TP), the lowest concentration was found on domestic wastewater. Vertical flow constructed wetlands (VFCW) and Horizontal flow constructed wetland (HFCW) were more effective in removing TSS, BOD, TP in domestic and industrial wastewater, whereas hybrid constructed wetlands (HCW) showed the highest removal for COD. The use of constructed wetlands as advanced wastewater treatment facilities in India yielded better water quality. The treatment of wastewater using constructed wetlands also enabled further reuse of wastewater for irrigation and other agricultural purposes. Overall, this study can be beneficial in evaluating and promoting the use of constructed wetlands in India.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.4
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• pp.414-419
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• 2005

This study was performed to compare the treatment efficiencies of two media, newly developed Bio-rock and conventional gravel, in soil clothing contact oxidation process. The composition of synthetic wastewater were $COD_{Cr}$ $150{\sim}370\;mg/L$, $BOD_5$ $150{\sim}270\;mg/L$, T-N $20{\sim}60\;mg/L$, T-P $5{\sim}25\;mg/L$, pH 7 and 2 mL/L of trace element solution. The experiment using two reactors was comparatively conducted for the flow rate of 40 L/d for 13 months, respectively. Initially Bio-rock reactor was increased to pH 12 due to $Ca(OH)_2$ with hydration of cement, but gravel reactor was dropped to pH 4 due to the degradation of organic material and nitrification. This significant pH variation deteriorated the growth and activity of microorganism. But the high pH of Bio-rock seems favorite to ammonia stripping and precipitation of phosphate. Such pH variation of Bio-rock and gravel reactors were finally stabilized to pH 8 and pH 6, respectively. The removal efficiencies of organic compounds from Bio-rock reactor were 96% of $COD_{Cr}$, 98% of $BOD_5$, 80% of T-N and 85% of T-P which stably coping against variation of influent concentration. But those of gravel reactor were 96% of $COD_{Cr}$, 96% of $BOD_5$, 42% of T-N and 40% of T-P, respectively. The Bio-rock was 2 times higher than T-N and T-P in treatment efficiency. And electron-microscopic examination showed that Bio-rock was more favorable to microbial adherence than gravel. The microbial populations were $5.2{\times}10^6\;CFU/mL$ of Bio-rock reactor compared to $2.6{\times}10^6\;CFU/mL$ in gravel reactor. In result Bio-rock was favor to microbial adherence and high treatment efficiency in spite of variation of influent concentration which had the advantages in saving running time and reducing site requirement.

• Journal of the Korean Association of Geographic Information Studies
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• v.6 no.4
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• pp.85-98
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• 2003

There has recently been an increasing interest of the watershed management as a solution to a wide range of problems related water environment, therefore this study attempted to construct the environment information system to monitor the Geumho River watershed, and to evaluate the impacts of the watershed characteristics on stream water quality. A detailed GIS database to analyze the environmental characteristics at the subwatershed units, including 1:25,000 scale topographical maps, detailed soil maps, land use, 10m-resolution DEMs, roads, streams, vegetation index(NDVI) calculated from Landsat TM imagery, rainfall, and soil loss using RUSLE, is compiled for the study area. The set of variables representing watershed urbanization or industrialization, residential and commercial landuse, industrial landuse, and road area have significantly negative(-) relationship with water quality variables(BOD, COD, SS, T-N, T-P). On the other hand, watershed indicators related to natural environmental conditions, forest cover and vegetation index(NDVI) in each subwatershed were significantly positive(+) relationship with water quality. Three other variables, agricultural landuse, amount of fertilizer and pesticides, and potential soil loss, were not significant in explaining the correlations between watershed environment and stream water quality.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.3
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• pp.89-98
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• 1987

Analyzed by using finite element method was 2-dimensional pollutant transtport phenomenon considering longitudinal and lateral direction in river. The Galerkin's finite element method based on linear interpolation is used and triangle is adopted as an element. In a number of model test attempts it has been demonstrated that the results calculated by the model are in good agreement with analytical solutions in a simplified channel where there is a known solution available. Actual application of the model is attempted along the 9km reach of the Han River considering the influx of the Tan Cheon and the Joongryang Cheon. The resultant 2-dimensional BOD concentrations profile in the reach is exhibiting more realistically the field situations than conventional 1-dimensional models are.

• Journal of Korean Society on Water Environment
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• v.22 no.6
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• pp.1123-1129
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• 2006

Pyrene of natural and anthropogenic sources is one of the toxic, mutagenic polycyclic aromatic hydrocarbons (PAHs) listed as priority pollutants. The objectives of this research are to break down pyrene by using ozonation, identify the intermediates and byproducts of pyrene, and test the biodegradability of intermediates and byproducts of pyrene in the aqueous phase. Since pyrene is non-polar, hexane was chosen as a solvent to effectively dissolve pyrene. Pyrene solutions were treated with ozone, as it has high oxidation capacity and electrophilic characteristic. After different ozonation pretreatment times (2, 3, and 10 minutes), intermediates of pyrene in the form of yellowish solid were collected from the hexane solution using a centrifuge. They were identified by gas chromatography/mass spectrometer (GC/MS). $BOD_5$, COD, and E-coli toxicity tests have been performed to assess the ozonation products.

• Journal of Wetlands Research
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• v.18 no.3
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• pp.226-231
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• 2016

Land Generated Waste Load Unit(LGWLU) estimation based on land use data is required to understand the impact of land use on water quality. The method of estimating LGWLU based on the monitoring data requires a lot of time and manpower. In this study, we propose a method of land pollution unit load estimation based on land use data with LP optimization. Optimization is the process to obtain the best possible optimal solution in a given condition. This study carried out optimization by using excel solver in Microsoft Excel. This study derived LGWLU of BOD, T-N, T-P in Gongju-Si and Seocheon-Gun by using the 2012 land use map made by ministry of environment based on 2010 satellite image. This study about LGWLU estimation is expected to be able to determine more clearly the water pollution caused by land use changes.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.8
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• pp.767-773
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• 2010

In recent years, there has been considerable concern over the release of methyl tert-butyl ether (MTBE), a gasoline additive, into the aquifers used as potable water sources. MTBE readily dissolves in water and has entered the environment via gasoline spills and leaking storage tanks. In this study air stripping and ozonation of MTBE in aqueous solution were performed in a laboratory scale batch reacter. The mass transfer rate (N) was evaluated and a values about $1.24{\times}10^{-6}\;mol{\cdot}sec^{-1}$ was found. In the ozonation of MTBE a 8.3% decrease of the COD and a 6.5% decrease of the TOC lead to BOD/COD = 0.03. The peudo first-order rate constants of the ozonation of MTBE was $3.75{\times}10^{-5}\;sec^{-1}$. The resulting Ea of 4.80 kcal；mol-1 was observed for molecular ozone reactions.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.373-378
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• 2021

The study aimed to develop a high-power enzymatic electrode for a wearable fuel cell that generates electricity utilizing lactate present in a sweat as fuel. Anode was fabricated by immobilizing lactate oxidase (LOx) on flexible carbon paper. As the lactate concentration in the electrolyte solution increased, the amount of current generated by catalysis of lactate oxidase increased. The immobilized LOx generated 1.5-times greater oxidation current density in the presence of gold nanoparticles than carbon paper only. Bilirubin oxidase (BOD)-immobilized cathode generated a larger amount of reduction current in the electrolyte saturated with oxygen than purged with nitrogen. A fuel cell composed of two electrodes was fabricated and cell voltage was measured under different discharge current. At the discharge current density of 66.7 ㎂/cm², the cell voltage was 0.5±0.0 V leading to maximum cell power density of 33.8±2.5 ㎼/cm².

• Journal of environmental and Sanitary engineering
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• v.12 no.2
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• pp.29-35
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• 1997

Phenol, often discharged from petroleum and fine chemical industries is potential carcinogen and was classified into priority pollutant by EPA in USA. It causes serious environmental and health problem if discharged to the environment such as soil or aquifer. The removal efficiency of phenol and COD using Fenton treatment(Hydrogen Peroxide and Ferrous Sulfate) was observed and biodegradability (BOD$_{5}$/COD$_{cr}$) of reaction products were also examined. When 50 mg/l of phenol was treated by Fenton's Reagent(50 mg/l of hydrogen peroxide and 900 mg/l of ferrous sulfate), the removal efficiency of phenol and COD was 100% and 80% respectively in 10 minutes, which suggested this method can be used as actual phenol removal process. The initial biodegradability of 500 mg/l phenol solution was 0.7 but decreased as hydrogen peroxide was increased.