• 한국물환경학회지
• /
• 제35권2호
• /
• pp.165-180
• /
• 2019

Water quality data of 81 lakes in Korea, 2013 ~ 2017 were analyzed. Most water quality parameters showed left-skewed distribution, while dissolved oxygen showed normal distribution. pH and dissolved oxygen showed a positive correlation with organic matter and nutrients, which appeared to be a nonsense correlation mediated by the algae. The ratio of $BOD_5$ and $COD_{Mn}$ to CBOD was 21 % and 52 % in the freshwater lakes, respectively. TOC concentration appeared to be underestimated by the UV digestion method, when salinity exceeds $700{\mu}S\;cm^{-1}$. In terms of nitrogen/phosphorus ratio, the limiting factor for algal growth seemed to be phosphorus in most of the lakes. Chlorophyll ${\alpha}$ increased acutely with decrease of N/P ratio. However, it seemed to be a nonsense correlation mediated by phosphorus concentration, since the N/P ratio depended on phosphorus. The N/P ratio of brackish lakes was lower than that of the freshwater, at the same concentration of phosphorus. It is worth examining denitrification that occurs, in bottom layer and sediment, during saline stratification. $Chl.{\alpha}$ concentration decreased in the form of a power function with increase of mean depth. The primary reason is that deep lakes are mainly at the less-disturbed upstream. However, it is necessary to investigate the effect of sediment, on water quality in shallow lakes. Light attenuation in the upper layer, was dominated by tripton (non-algal suspended solids) absorption/scattering (average relative contribution of 39 %), followed by CDOM (colored dissolved organic matter) (average 37 %) and $Chl.{\alpha}$ (average 21 %).

• 유기물자원화
• /
• 제14권2호
• /
• pp.63-70
• /
• 2006

본 연구에서는 폐기물매립지의 안정화 정도를 용이하게 평가하기 위하여 매립폐기물의 분해정도를 수치화 할 수 있는 매립지의 안정화 지수 개발을 목적으로 하였다. 안정화 지수를 개발하기 위하여 50개소의 사용종료 매립지를 대상으로 침출수 수질, 매립가스 조성, 매립폐기물의 물리화학적 특성 자료를 수집하여 이들의 매립연령별 환경특성을 고찰하였다. 그리고 이들 환경지표중 폐기물매립지의 안정화와 상관도가 높은세부 환경지표로서 침출수의 BOD/CODcr, 발생가스중의 $CH_4$농도, 매립폐기물의 C/N가 안정화 지표로 선정하였다. 각 지표에 대한 매립연령별 추세선을 이용하여 지수화한 결과 매립지 안정화 지수로 다음과 같은 식을 얻을 수 있었다. $$I_{LS}=S_L+S_G+S_W$$ $$S_L=-\{4.892+16.587{\cdot}ln[BOD/COD_{Cr]\}$$ $$S_G=53.872-12.782{\cdot}ln[CH_4]$$ $$S_W=79.382-20.013{\cdot}ln[C/N]$$ (단, $S_L$, $S_G$, and $S_W$는 각각 33.3점이 최대값이다.) 여기서, $I_{LS}$ : 매립지 안정화 지수 $S_L$ : 침출수의 안정화 점수 $S_G$ : 매립가스의 안정화 점수 $S_W$ : 폐기물의 안정화 점수.

• 한국환경과학회지
• /
• 제25권11호
• /
• pp.1493-1498
• /
• 2016

The efficiencies of Gang-Byeon sewage treatment facilities, which are based on GPS-X modelling, were analysed and used to design recycle water treatment processes. The effluent of an aeration tank contained total kjeldahl nitrogen (TKN) of 1.8 mg/L with both C-1 and C-2 conditions, confirming that most ammonia nitrogen ($NH_3{^+}-N$) was converted to nitrate nitrogen ($NO_3{^-}-N$). The concentrations of $NH_3{^+}-N$ and $NO_3{^-}-N$ were found to be 222.5 and 227.2 mg/L, respectively, with C-1 conditions and 212.2 and 80.4 mg/L with C-2 conditions. Although C-2 conditions with higher organic matter yielded a slightly higher nitrogen removal efficiency, sufficient denitrification was not observed to meet the discharge standards. For the total nitrogen (T-N) removal efficiency, the final effluent concentrations of T-N were 293.8 mg/L with biochemical oxygen demand (BOD) of 2,500 mg/L, being about 1.5 times lower than that (445.3 mg/L) with BOD of 2,000 mg/L. Therefore, an external carbon source to increase the C/N ratio was required to get sufficient denitrification. During the winter period with temperature less than $10^{\circ}C$, the denitrification efficiency was dropped rapidly even with a high TKN concentration (1,500 mg/L). This indicates that unit reactors (anoxic/aerobic tanks) for winter need to be installed to increase the hydraulic retention time. Thus, to enhance nitrification and denitrification efficiencies, flexible operations with seasons are recommended for nitrification/anoxic/denitrification tanks.

• 환경위생공학
• /
• 제15권3호
• /
• pp.50-56
• /
• 2000

In this study, sewage were treated with operating Two-step Aeration System and conventional activated sludge process together in a condition. At the same HRT 8hr of Two-step Aeration System and Activated Sludge Process, BOD treatment efficiency of 1st sedimentation basin effluent 36.9% by Two-step Aeration system was 12.3% higher than 24.65 by Activated Sludge Process and the COD treatment efficiency 39.8% by two-step Aeration System was 11.6.3% higher than 28.2% by Activated Sludge Process. BOD and COD treatment efficiencies of 2nd sedimentation basin effluent were 88.1% and 85.6% Two-step Aeration System and were 83.8% and 82.3% Activated Sludge Process. In the first treatment, as BOD was relatively removed a lot, F/M ratio 0.17, $0.21{\cdot}BOD/kg{\cdot}MLSS.d$ was maintained by Activated Sludge Process. Therefore it was proved that organic matter treatment efficiency by Two-step Aeration System os Higher than by Activated Sludge Process in a aeration time 8hr. $NH_4^{+}-N$ treatment efficiencies were 55.5% by Two-step Aeration System and 39.75 by Activated sludge Process. $NO_3^{-}-N$ concentration in 2nd. sedimentation basin effluent were 3.33% by Two-step Aeration System and 2.36% by Activated Sludge Process. From this result, Two-step Aeration System was proved more advantageous treatment process for nitrification than Activated Sludge Process. The fluctuation range of BOD, COD and SS concentration in 2nd sedimentation basin effluent $16~33mg/{\ell}$, $15~23mg/{\ell}$ and $14~22mg/{\ell}$ by Two-step Aeration System was smaller than $16~57mg/{\ell}$, $15~25mg/{\ell}$ by Activated sludge Process. Overall the fluctuation range in 2nd sediment basin effluent by was smaller than by Activated Sludge Process. As a result, it is possible for this Two-step Aeration with no facility investment and a little of operation condition change in a conventional sewage treatment plant to get stability and nitrification of treatment water quality.

• 한국물환경학회지
• /
• 제37권1호
• /
• pp.20-31
• /
• 2021

In this study, an analysis of the characteristics of organic matter and nitrogenous oxygen demand (NOD) of 17 sewage effluent and wastewater treatments was conducted. High CODMn and carbonaceous biological oxygen demand (CBOD) concentrations were observed in the livestock treatment plants (LTP), wastewater treatment plants(WTP), and night soil treatment plants (NTP), but the highest NOD concentration and contribution rates of NOD to BOD5 were found in sewage treatment plants (STP). There was no significant difference in the CBOD/CODMn ratio for each of the six pollution source groups, but the LTPs, WTPs, and NTPs all showed relatively high CODMn concentrations in their effluent samples, indicating that they are facilities which discharge large amounts of refractory organic matter. The seasonal change of NOD in all facilities' effluent was found to be larger than the seasonal change of CBOD, and data results also revealed an elevation of NOD and NH3-N concentration from December to February, when the water temperature was low. There was no significant difference in NH3-N concentration in relation to pollution source group (p=0.08, one-way ANOVA), but the STP, which had a high NOD contribution rate to BOD5 of 48%, showed a high correlation between BOD5 and NOD (r2=0.95, p<0.0001). These results suggest that the effect of NOD on BOD5 is an important factor to be considered when analyzing STP effluent.

• 한국물환경학회지
• /
• 제28권1호
• /
• pp.63-70
• /
• 2012

This study was carried out to investigate change in influent concentration of domestic wastewater flowed from a newly constructed separate sewer system (SSS) and biological nutrients removal efficiency of a full scale Air-vent sequential batch reactor (SBR, $600m^3/d$). The average concentration of $BOD_5$, SS, T-N and T-P from SSS were 246.5 mg/L, 231.6 mg/L, 42.974 mg/L, 5.360 mg/L, respectively which corresponds to 2.2times, 1.2times, 1.8times and 2.1times higher than those from the conventional combined sewer system (CSS). The removal efficiency of $BOD_5$, SS, T-N, and T-P for the Air-vent SBR operated with influent from SSS averaged 99.1%, 99.0%, 91.2%, and 93.5%, respectively. Especially the respective nitrogen and phosphorus removal was 15% greater than that of the SBR operated with influent from CSS. Simultaneous nitrification and denitrification (SND) was observed in an aerobic reactor(II) as a result of DO concentration gradient developed along the depth by the Air-vent system. In order to achieve T-N removal greater than 90%, the C/N ratio should be over 6.0 and the difference between $BOD_5$ loading and nitrogen loading rate be over 100 kg/day (0.130 kg $T-N/m^3{\cdot}d$). Even with high influent T-P concentration of 5.360 mg/L from SSS (compared with 2.465 mg/L from CSS) T-P removal achieved 93.5% which was 15.5% higher than that of the SBR with influent from CSS. This is probably due to high influent $BOD_5$ concentration from SSS that could provide soluble carbon source to release phosphorus at anaerobic condition. In order to achieve T-P removal greater than 90%, the difference between $BOD_5$ loading and phosphorus loading rate should be over 100 kg /day (0.130 kg $T-N/m^3{\cdot}d$).

• 한국환경과학회지
• /
• 제8권5호
• /
• pp.617-623
• /
• 1999

This study was carried out to obtain the optimal operating parameter on organic matters and nutrient removal of mixed wastewater which was composed of sewage and stable wastewater using SBR. A laboratory scale SBR was operated with An/Ae(Anaerobic/Aerobic) ratio of 3/3, 2/4 and 4/2(3.5/2.5) at organic loading rate of 0.14 to 0.27 kgBOD/$m^3$/d. TCOD/SCOD ratio of mixed wastewater was 3, so the important operating factor depended upon the resolving the particulate parts of wastewater. Conclusions of this study were as follows: 1) For mixed wastewater, BOD and COD removal efficiencies were 93-96% and 85-89%, respectively. It was not related to each organic loading rate, whereas depended on An/Ae ratio. During Anarobic period, the amount of SCOD consumption was very little, because ICOD in influent was converted to SCOD by hydrolysis of insoluble matter. 2) T-N removal efficiencies of mixed wastewater were 55-62% for Exp. 1, 66-76% for Exp. 2, and 67-81% for Exp. 3, respectively. It was found that nitrification rate was increased according to organic concentration in influent increased. Therefore, the nitrification rate seemed to be achieved by heterotrophs. During anoxic period, denitrification rate depended on SCOD concentration in aerobic period and thus, was not resulted by endogenous denitrification. However, the amount of denitrification during anaerobic period were 3.5-14.1 mg/cycle, and that of BOD consumed were 10-40 mg/cycle. 3) For P removal of mixed wastewater, EBPR appeared only Mode 3($3^＊$). It was found that the time in which ICOD was converted to VFA should be sufficient. For mode 3 in each Exp., P removal efficiencies were 74, 87, and 81%, respectively. But for 45-48 of COD/TP ratio in influent, P concentration in effluent was over 1 mg/L. It was caused to a large amount of ICOD in influent. However, as P concnetration in influent was increased, the amounts of P release and uptake were increased linearly.

• 한국환경보건학회지
• /
• 제36권6호
• /
• pp.502-509
• /
• 2010

In this study, the (phosphorous removal) the characteristics of phosphorous removal due to (the iron compound precipitated) iron compound precipitation by iron electrolysis in (the anoxic. oxic process) anoxic and oxic processes (equipped with the) in an iron precipitation device were analyzed. During the device operation period, the average concentration of BOD, T-N, and T-P were 219.9 mg/l, 54.6 mg/l and 6.71 mg/l, respectively. The BOD/$COD_{Cr}$ ratio was 0.74, and the BOD/T-N and BOD/T-P ratios were 4.0 and 32.8, respectively. The removal rate of (the organic matters) organic matter (BOD and $COD_{Cr}$) was very high at 91.6% or higher, and that of nitrogen was 80.5%. The phosphorous concentration (of the final) in the treated water was 0.43 mg/l (0.05-0.74 mg/l) on average, and the removal efficiency was high at 90.8%. The soluble T-P concentrations in (an) the anoxic reactor, oxic reactor (II) and final treated water were 1.99 mg/l, 0.79 mg/l and 0.43 mg/l, respectively, which indicated that the phosphorous concentration in the treated water was very low. Regardless of the changes in the concentrations of (organic matters) organic matter, nitrogen and phosphorous in the influent, the quality of the treated water was relatively stable and high. The removal rate of T-P somewhat increased with the increase in the F/M ratio in the influent, and it also linearly increased in proportion to the T-P loading rate in the influent. In the treatment process used in this study, phosphorous was removed (using) by the precipitated iron oxide. Therefore, the consumption of organic (matters) matter for biological phosphorus removal was minimized and (most of the organic matters were) was mostly used as the organic carbon source for the denitrification in the anoxic reactor. This (can be an economic) treatment process (without the need for the supply of additional organic matters) is economic and does not require the supply of additional organic matter.

• 상하수도학회지
• /
• 제11권4호
• /
• pp.63-70
• /
• 1997

The objectives of this study were to find out the optimum treatment conditions for removing nitrogen in a synthetic wastewater by using microorganisms immobilized with PVA-Freezing method. The samples used as influents to the laboratory scale treatment units were a synthetic wastewater. The experiments in this study were mainly directed to collect the data of nitrogen and organic matter removal efficiencies for the different hydraulic and internal recycle rates conditions, temperature and influent C/N ratios. The removal efficiencies of nitrogen and organic matters were investigated for the operating conditions of HRT 2~12hours, internal recycle rates 50~400%, temperatures $15{\sim}30^{\circ}C$ and C/N ratios 2.5~7.5. The adequate internal recycle rate for removing T-N and $BOD_5$ in the synthetic wastewater was found to be about 300% at the temperature of $30^{\circ}C$ when the ratio of carbon contents to the nitrogen (C/N) in the influent was around 5.5. Under these conditions, the final effluent concentrations of T-N and $BOD_5$ were 8.7 and 8.4 mg/l, respectively.

• 대한환경공학회지
• /
• 제38권9호
• /
• pp.469-475
• /
• 2016

본 연구는 실제 운영되는 수산물 가공 산업폐수의 immersed MBR (iMBR)공정을 이용한 폐수처리시설 운영 결과에 대한 실증적 고찰을 수행한 것이다. 수산물 가공 산업의 특성상 일별, 월별 유량 변동이 심하여 유량조정조의 설계 및 운전방법이 중요하며, 유량조정조 교반시 포기식 교반을 적용하면 산발효 방지를 통하여 후속 응집/부상 공정의 약품비 절감이 가능하다. 동 현장은 유량조정조, 가압부상조, iMBR을 거쳐 방류하며, 이때 가압부상조를 거쳐 iMBR로 유입되는 BOD, $COD_{Mn}$, SS, T-N, T-P의 농도는 2,291 mg/L, 530 mg/L, 38 mg/L, 256.8 mg/L, 13.5 mg/L으로 나타났다. 수산물 가공 폐수와 같이 고농도의 염이 함유된 폐수의 생물학적 처리는 슬러지의 침강성과 관계없는 침지식 중공사막을 이용한 iMBR 공법을 적용하는것이 바람직한 것으로 나타났다. iMBR 공정의 주요 에너지 소모 요인인 공기세정에 대한 운영 값의 검토 결과 SADm값이 $0.31m^3/hr{\cdot}m^2$ membrane area이었으며, SADp값은 $26.5m^3/hr{\cdot}m^3$ permeate으로 상용화된 평막 대비 월등히 에너지 효율이 우수한 것으로 나타났다. 무산소, 혐기, 호기 탈기조로 구성된 침지식 중공사막이 결합된 iMBR 공정에서 막오염 지표인 Normalized TMP와 온도, MLSS 등을 비교 분석한 결과 F/M비가 0.08~0.10 gBOD/gMLSS에서 임계 F/M 값을 나타냈다. 생물반응조에서의 BOD, $COD_{Mn}$, SS, T-N, T-P의 처리수질은 각각 1.8 mg/L, 11.0 mg/L, 1.1 mg/L, 11.0 mg/L, 0.24 mg/L으로 운전되었으며, 제거율은 99.9%, 97.9%, 96.3%, 95.7%, 97.8%으로 나타났다.