• Title/Summary/Keyword: B4

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Removal of Rhodamine B using Electrocoagulation Process (전기응집 공정을 이용한 Rhodamine B의 제거)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.12
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    • pp.1081-1088
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    • 2009
  • The performance of a electrocoagulation (EC) process was examined for the removal of Rhodamine B (RhB) using iron electrode. The effects of operational parameters such as electrode material (aluminum and iron), current density, NaCl dosage, intial pH and initial dye concentration on RhB removal efficiency were investigated. The optimum range for each of these operating variables were experimentally determined. The experimental results showed that the iron is superior to aluminum as sacrificial electrode material. The optimum time of electrolysis, current density, NaCl dosage and pH were 10 min, 1630 A/$m^2$, 4 g/L and neutral pH, respectively. Under these conditions, RhB was effectively removed (> 93.4%) and also more than 80% of COD was removed (> 88.9%) when the initial concentration of RhB was 230 mg/L. The electrical energy consumption in the above conditions for the color and COD of RhB removal were 10.3 and 10.8 kWh/kg RhB, respectively. The electrocoagulation process could be a promising technology to treat dye wastewater containing RhB.

Purification of a Mosquitocidal Toxic Protein from B. thuringiensis strain H9B by Immuno-Affinity Chromatography (Immuno-Affinity Chromatography에 의한 B. thuringiensis H9B 균주의 모기살충성 내독소 단백질의 정제)

  • 김광현;배수장;이광배
    • Journal of environmental and Sanitary engineering
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    • v.12 no.2
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    • pp.59-64
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    • 1997
  • For purification of a 70kDa toxic protein of mosquitocidal delta-endotoxin from B. thuringiensis strain H9B, immuno-affinity chromatography was performed. After separation of 70kDa toxic proteins from the delta-endotoxin of the strain H9B on SDS-PAGE, the 70kDa toxic protein was subcutaneously injected into rabbit for making a polyclonal antibody. A anti-70kDa toxic protein was purified by a column chromatography packed with protein A-sepharose 4B gels. The 70kDa toxic protein from delta-endotoxin of the strain H9B was also purified by an immuno-affinity chromatography packed with CNBr-activated sepharose 4B gels conjugated anti-70kDa toxic protein after elution with 1/10M citric acid-1/5M Na$_{2}$HPO$_{4}$ buffer(pH3.2) containing 0.5M NaCl. The 70kDa toxic protein was purified through only one step-separation system, was demonstrated by SDS-PAGE and immunoblot.

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Performance Analysis of M-ary Impulse Communications over AWGN Channels (AWGN 채널에서 M진 임펄스 통신의 성능 분석)

  • 김동호;백승선;문용규;강희조
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.05a
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    • pp.559-562
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    • 2002
  • 본 논문에서는 최근 제한적으로 사용이 승인된 UWB(초광대역: Ultra-Wideband) 통신을 AWGN 하에서 다중 접속을 고려하지 않은 단일 사용사일 경우로 가정시, M진 값이 변화함에 따른 에러율과 성능 개선 기법으로 BCH를 채용시의 에러율을 비교 분석하였다. 기존에 연구되어 오던 변조로 PAM(Pulse Amplitude Modulation)과 PPM(Pulse Position Modulation)방식을 비교하였으며 에러율 $10^{-6}$을 기준으로 M=2, 4일 경우 PAM이 PPM보다 약 E$_{b}$/N$_{o}$ =3~4[dB], M=8 이상의 경우 PPM이 약 E$_{b}$/N$_{o}$ =9[dB], M=16일 경우 약 E$_{b}$/N$_{o}$ =15[dB]정도 성능이 우수하였다. AWGN 채널 하에서 에러 정정 부호인 BCH(15,7)를 도입하였을 경우 에러율 $10^{-6}$을 기준으로 PAM방식은 약 E$_{b}$/N$_{o}$ 가 약 1[dB], PPM 방식은 M=2, 4일 경우 약 E$_{b}$/N$_{o}$ =1~1.5[dB]정도 개선되었다.

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Design of a Messaging System for B2B Workflow (B2B 워크플로우의 메시징 시스템 설계)

  • Suh, Chang-Kyo;Kim, Jeong-Sam;Lee, Hyung-Seok
    • Asia pacific journal of information systems
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    • v.11 no.1
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    • pp.117-137
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    • 2001
  • B2B(business-to-business) commerce has become the prime driver of contemporary electronic commerce. Under B2B commerce, corporations often must operate across organizational boundaries to share their business processes. Workflow management was proposed by Aalst(4, 5) to support several business partners that are involved in shared workflow processes in B2B commerce. We designed a messaging system for B2B workflow, where heterogeneous workflow management systems on each organization for trade were integrated. Based on Aalst's example in(4, 5), we analyzed B2B workflow by using class diagram, use case diagram, activity diagram, and statechart diagram of UML, and designed the messaging system, We also demonstrated a prototype system which was implemented by using Java API and XML. To compare with a holistic system such as EDI systems, the messaging system allows the business partners in B2B commerce to communicate with each other by dedicated messages and integrate each B2B interoperable workflow without any restrictions.

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Syntheses and Biological Activities of Potential Antifungal Allylamine Compounds (항진균 알릴아민 화합물의 합성과 활성평가)

  • Chung Byung-Ho;Cheon Seung-Hoon;Chung Soon-Young
    • YAKHAK HOEJI
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    • v.49 no.4
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    • pp.299-305
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    • 2005
  • Structure-activity relationship studies of allylamine type of antimycotics were carried out to evaluate the effect of naphthyl and methyl portion of naftifine. Compounds with 3,4-difluorophenyl (2a-5a), 4-hydroxyphenyl (2b-5b), 3-nitro­phenyl (2c-5c), 4-chlorobenzothiazoly (2d-5d) and 5-methylfurfural (2e-5e) instead of naphthyl group, and with hydrogen (3a-3e), methyl (4a-4e) and ethyl (5a-5e) in the place of methyl in naftifine were synthesized and tested for their in vitro anti-fungal activities against five different fungi. Fourteen compounds (3a, 4a, 5a, 3b, 4b, 5b, 3c, 4c, 5c, 3d, 4d, 3e, 4e and 5e) showed significant anti-fungal activities against T. mentagrophytes. (E)-N-(3-Phenyl-2-propenyl)-3,4-difluoro-ben­zenemethaneamine(3a), (E)_N_(3_phenyl_2_propenyl)_4_hydroxy_benzenemethaneamine(3b) and (E)-N-ethyl-N-(3-phenyl­2-propenyl)-3-nitro-benzenemethaneamine (5c) displayed moderate anti-fungal activities against all five different fungi.

The Enhancement of Cytochrome P-450 Mediated Aryl Hydroxylation of Bentazon in Rice Microsomes (벼에서 Bentazon 히드록시화반응에 관련된 Cytochrome P-450 활성(活性) 증진(增進)에 관한 연구(硏究))

  • Pyon, J.Y.;Balke, N.E.
    • Korean Journal of Weed Science
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    • v.17 no.1
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    • pp.59-65
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    • 1997
  • Bentazon 6-hydroxylase (B6H) and cinnamic acid 4-hydroxylase (CA4H) activities were determined in rice (Oryza sativa L.) microsomes to study methods of enhancing cytochrome P-450 mediated aryl hydroxylation of bentazon by hydoxylase inducing compounds. Pretreating rice seeds with 1,8-naphthalic anhydride at 0.5-2% and fenclorim at 5 and 10 ${\mu}M$ increased B6H and CA4H activities. Treatments of rice seedling with ethanol 2.5% enhanced B6H and CA4H activities, and with phenobarbital at 12 mM enhanced B6H activity, and CA4H activity was enhanced at 2 mM. B6H activity was synergistically enhanced by combined treatments of ethanol 2.5 or 5% and phenobarbital 8 or 12mM and also that of 1,8-naphthalic anhydride 0.5 or 1% and phenobarbital 8 or 12 mM, but CA4H activity was decreased by combined treatment. Five-day-old rice seedlings showed higher B6H and CA4H activities which decreased with seedling age.

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Synthesis of Resin Derivatives and Purification of Protein - Synthesis of p-Aminoanilinylsuccinyl-AH-Sepharose 4B and Purification of Protein in Pleurotus cornucopiae - (친화성 고분자 유도체의 합성 및 단백질의 분리정제에 관한 연구 - p-Aminoanilinylsuccinyl-AH-Sepharose 4B의 합성 및 흰느타리버섯 중 단백질의 정제 -)

  • Min, Tae-Jin;Kim, Yong-Rip;Park, Sang-Shin;Lee, Soo-Yong
    • The Korean Journal of Mycology
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    • v.17 no.3
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    • pp.105-113
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    • 1989
  • For selective purification of proteins in Pleurotus cornucopiae, affinity chromatography was performed by p-aminoanilinylsuccinyl-AH-Sepharose 4B gel synthesized by treating p-phenylene diamine with succinyl-AH-Sepharose 4B, which was prepared by treating AH-Sepharose 4B with succinic anhydride. The capacity of p-aminoanilinyl ligand group was 6.1 micromole per milliliter of gel. Total apparent molecular weight of the affinity proteins eluted from the synthesized gel was 167 KD, which were a protein complex of 130 KD and 37 KD. The contents of the nonpolar, polar, positively and/or negatively charged amino acids in the affinity protein were 44.57%, 24.75%, 21.25%, and 9.43%, respectively. Total apparent molecular weight of the affinity proteins eluted from the AH-Sepharose 4B gel was 95.2 KD, which were a protein complex of 61 KD, 31 KD and 3.2 KD. The contents of the nonpolar, positively and/or negatively charged amino acids in the affinity protein by AH-Sepharose 4B gel were 44.05%, 29.13%, and 12.91% respectively.

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Performance Improvement of B4 Inverters by Adding Compensation Voltage (보상전압 첨가를 통한 B4 인버터 성능향상)

  • Lee, Dong-Myung
    • The Transactions of the Korean Institute of Power Electronics
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    • v.18 no.1
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    • pp.110-116
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    • 2013
  • This paper proposes a current ripple reduction method to improve the control performance of B4 type inverter that is studied for cost-effective drive systems. B4 inverters employ only four switches and they have a center-tapped connection between the split dc-link capacitors and one phase of a three-phase motor or load. In the B4 topology, unbalanced three-phase voltages will be generated due to the dc-link voltage ripple. To solve this problem, this paper presents a voltage distortion compensation method that adjusts the voltage reference with the consideration of dc-link voltage ripple. The validity of the proposed method is verified by simulation and excremental results with an induction machine.

Synthesis and Cationic Polymerization of Vinyl Ethers Containing Oxynitrobenzylidenemalononitrile and Oxynitrobenzylidenecyanoacetate as the NLO-phores in the Side Chain

  • 이주연;김무용;안미라
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.567-572
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    • 1999
  • 5-Nitro-2-(2'-vinyloxyethoxy)benzylidenemalononitrile (2a), methyl 5-nitro-2-(2'-vinyloxyethoxy)benzylidenecyanoacetate (2b), 3-nitro-4-(2'-vinyloxyethoxy)benzylidenemalononitrile (4a), methyl 3-nitro-4-(2'-vinyloxyethoxy)benzylidenecyanoacetate (4b), 2-nitro-5-(2'-vinyloxyethoxy)benzylidenemalononitrile (6a), and methyl 2-nitro-5-(2'-vinyloxyetboxy)benzylidenecyanoacetate (6b) were prepared by the condensation of 5-nitro-2-(2'-vinyloxyethoxy)benzaldehyde (1), 3-nitro-4-(2'-vinyloxyethoxy)benzaldehyde (3), and 2-nitro-5-(2'-vinyloxyethoxy)benzaldehyde (5) with malononitrile or methyl cyanoacetate, respectively. Vinyl ether monomers 2a-b, 4a-b, and 6a-b were polymerized with boron trifluoride etherate as a cationic initiator to yield poly(vinyl ethers) 7-9 having oxynitrobenzylidenemalononitrile and oxynitrobenzylidenecyanoacetate, which is effective chromophore for second-order nonlinear optical applications. Polymers 7-9 were soluble in common organic solvents such as acetone and DMSO. Tg values of the resulting polymers were in the range of 67-83 ℃. Electrooptic coefficient (r33) of the poled polymer films were in the range of 15-27 pm/V at 633 nm. Polymers 7-9 showed a thermal stability up to 300 ℃ in TGA thermograms, which is acceptable for NLO device applications.

Activated Nitrites in Heterocyclic Synthesis: Syntheses of Thiazole, Pyrazole and 4H-l,4-Benzothiazine Derivatives

  • El-Taweel, Fathy Mohamed Abdel-Aziz;Hadi-Mashaly, Mohamed-Abdel;Ali-Elagamey, Abdel-Ghani
    • Archives of Pharmacal Research
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    • v.13 no.3
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    • pp.261-264
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    • 1990
  • 4-Arylazo-3-phenyl-5-aminopyrazoles (5a, b) and substituted hydroxythiazoles 8a, b were synthesized from the reaction of 4a, b with hydrazine hydrate and mercaptoacetic acid respectively. Compounds 5a, b and 8a, b were also obtained from coupling of 2a, b with 6 and 7, respectively. 4H-1, 4-Benzothiazine 11 was prepared from 1 and 10. The resaction of the diazonium salts 2a-c with diethyl 3-amino-2-cyanopenet-2-en-1, 5-dicarboxylate 12 was also reported.

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