• Title/Summary/Keyword: B-doped

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Preparation and Nonlinear Optical Properties of CuCl-doped Nonlinear Optical Glasses : III. Bimodal Distribution of CuCl Nanocrystals and Temperature Dependent Optical Absorption Spectra (CuCl 미립자가 분산된 비선형 광학유리의 제조와 비선형 광특성: III. CuCl 반도체 미립자의 Bimodal 분포 특성과 온도에 따른 광흡수도)

  • 윤영권;한원택
    • Journal of the Korean Ceramic Society
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    • v.34 no.4
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    • pp.436-442
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    • 1997
  • The bimodal distribution of CuCl nano-crystals precipitated in alumino-borosilicate glass matrix (30SiO2-45B2O3-7.5Al2O3-7.5Na2O-7.5CaO-2.5GeO2(mole %)) was investigated by TEM and the temperature dependent optical spectroscopy. Two types of CuCl particles with different size were observed by TEM and it was confirmed by the splitting of Z3 absorption peak at low temperature and the occurrence of deflection point in the optical spectra with temperature.

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Effects of Morphology on Energy transfer and Device performance in Phosphorescent Dye Doped Polymer Light Emitting Devices

  • Noh, Yong-Young;Lee, Chang-Lyoul;Kim, Jang-Joo;Yase, Kiyoshi
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.98-101
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    • 2002
  • The effect of morphology on energy transfer and device performance in phosphorescent dye doped polymer light emitting diodes is reported. We selected two host polymers (PVK and PFHP) which have nearly the same potential for the energy transfer to Ir(ppy)$_3$. The PFHP:Ir(ppy)$_3$ film showed b-micron size aggregation, whereas the PVK:Ir(ppy)$_3$ film showed homogeneous and smooth images. As a result, energy transfer is efficient with high emission efficiency in PVK:Ir(ppy)$_3$ whereas little energy transfer and low quantum efficiency are obtained in PFHP:Ir(ppy)$_3$.

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Photocatalytic Degradation Characteristics of Organic Compound by Boron-doped TiO2 Catalysts

  • Nam, Chang-Mo
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.6
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    • pp.649-656
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    • 2010
  • Boron-doped $TiO_2$ photocatalysts were synthesized by a modified sol-gel method and their photocatalytic activities were performed and compared with those of pure synthetic and commercial $TiO_2$ catalysts under UV or visible light conditions. Pure $TiO_2$ itself exhibited very negligible photocatalytic performance under visible light conditions in the aspects of toluene decomposition reactions, although significant decomposition potential was observed as expected with UV light conditions. However, boron doping over $TiO_2$ significantly improved photocatalytic activity particularly under visible conditions, where over 95% degradation of toluene was achieved with 1wt% $B-TiO_2$ within 2 hrs. All the decomposition reactions seemed to follow pseudo first-order kinetics. The effects of boron-doping and its characteristics are further discussed through the kinetic studies and comparison of results.

Magnetic Properties and Cation Distribution of Phosphorous-Doped $Co-{\gamma}-{Fe_2} {O_3}$ Particles

  • Na, J.G.;Han, D.H.
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.51-54
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    • 1996
  • The effects of additional P-doping on the magnetic properties, thermal stability and cation distribution of Co-doped ${\gamma}-{Fe_2} {O_3}$have been investigated by means of magnetic annealing and measurements with vibration sample magnetometer and torque magnetometer. It is found that the P-doping promotes the coercivity and its magnetic-thermal stability, which may be attributed to increase of the cubic magneto-crystalline anisotropy constant, $K_1$ and the activation energy, E, for cation rearrangement, respectively. The cation distribution of P and Co-substituted iron oxide was calculated from the variation of the saturation magnetization with P-doping on the basis of the Neel model. It was found that the most of P ions in the iron oxides occupied the B-site of spinel lattice.

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In situ cavity loss measurements of a mode-locked erbium-doped fiber ring laser by thed relaxation oscillation frequency method

  • Jhon, Young-Min;Kim, Bong-Kyu;Kim, Dong-Hwan;Kim, Myong-Wook;Kim, Sang-Kuk;Choi, Sang-Sam
    • Journal of the Optical Society of Korea
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    • v.4 no.1
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    • pp.11-13
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    • 2000
  • We experimentally measured the cold cavity loss of a mode-locked erbium-doped fiber ring laser in situ by using the relaxation oscillation frequency method. The relaxation oscillation frequency is measured for various pumping powers and the data is fitted by the least squares method with a theoretical curve of parameters including the cavity loss. We obtained a cavity loss of 15.3$\pm$0.5 dB which was found to agree with the results of direct transmission loss measurements.

Characterization of conducting aluminium doped zinc oxide (ZnO:Al) thin films deposited on polymer substrates (폴리머 기판위에 증착된 ZnO:Al 전도막의 특성연구)

  • Koo, Hong-Mo;Kim, Se-Hyun;Park, Jong-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.535-538
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    • 2004
  • Zinc Oxide (ZnO) films have attracted considerable attention for transparent conducting films, because of their high conductivity, good optical transmittance from UV to near IR as well as a low-cost fabrication. To increase the conductivity of ZnO, doping of group III elements (Al, Ga, In and B) has been carried out. Transparent conducting films have been applied for optoelectric devices, the development of the transparent conducting thin films on flexible light-weight substrates are required. In this research, the transparent conducting ZnO thin films doped with Aluminum (Al) on polymer substrates were deposited by the RF magnetron suputtering method, and the structural, optical and electrical properties were investigated.

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Comparative Experimental Analysis of Thermal Characteristics of Ytterbium-Doped Phosphosilicate and Aluminosilicate Fibers

  • Lee, Seungjong;Vazquez-Zuniga, Luis A.;Lee, Dongyoung;Kim, Hyuntai;Sahu, Jayanta K.;Jeong, Yoonchan
    • Journal of the Optical Society of Korea
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    • v.17 no.2
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    • pp.182-187
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    • 2013
  • We present a comparative experimental analysis of the thermal spectroscopic characteristics of a phosphosilicate (P)-based ytterbium-doped fiber (YDF) against an aluminosilicate (Al)-based YDF in the temperature range of 25 to $150^{\circ}C$. We also characterize the fibers as gain media in a cladding-pumped amplifier configuration. While both fibers exhibit comparable trends in their thermal characteristics, there are noticeable distinctions in the fluorescence lifetime reduction rate and the spectral dependence of the transition cross-sections. The P- and Al-based YDFs present thermal lifetime reduction rates of $0.012%/^{\circ}C$ and $0.026%/^{\circ}C$, respectively. In particular, in the spectral region at ~940 nm, the absorption cross-section of the P-based YDF undergoes significantly less thermal change compared to that of the Al-YDF. In the cladding-pumped amplifier configuration operating at a total gain of 10 dB, the Al-based YDF generally performs betters than the P-based YDF in the temperature range of 25 to $75^{\circ}C$. However, it is highlighted that in the high temperature range of over $75^{\circ}C$, the latter shows a less gain reduction rate than the former, thereby yielding higher relative output power by 3.3% for a 1060-nm signal, for example.

Synthesis and Characterization of V2O - Doped Karrooite Brown Pigments (V2O5가 고용된 Karrooite계의 Brown색 안료합성과 특성)

  • Kim, Gum-Sun;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.48 no.4
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    • pp.303-306
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    • 2011
  • [ $V_2O_5$ ]doped Karrooite pigments were synthesized by the solid state method to get stabilized brown pigment in oxidation and reduction atmosphere. Optimum substitution condition and limited dopant with $V_2O_5$ for Karrooite pigment was investigated. With calcination at $1250^{\circ}C{\sim}1400^{\circ}C$, compositions were designed varying $V_2O_5$ molar ratio by increasing 0.02mole to the formula $Mg_1-xTi_2-xM_{2x}O_5$(x = 0.01~0.09 mole). Synthesized pigments were analyzed by XRD, Raman spectroscopy and UV-vis. When $V_2O_5$ was doped from 0.01 to 0.05 mole, single phase of Karrooite was observed at temperature $1300^{\circ}C$ and soaking time 4h by Raman spectroscopy. However, it was found that excess $VO_2$ peak appeared with 0.07 and 0.09 mole of $V_2O_5$ doped to $MgTi_2O_5$. This result indicated that the maximum limit of solid solution is 0.05 mole $V_2O_5$. Karrooite pigments were applied as a ceramic pigment to achieve brown colors in lime magnesia glaze and lime barium graze at both of oxidation and reduction atmosphere. CIE color coordinates are $L^*$ = 40.34, $a^*$ = 9.94, $b^*$ = 21.40 in lime magnesia glaze.

Thickness Dependance of Al-doped ZnO Thin Film on Polymer Substrate (폴리머 기판상의 Al-doped ZnO 박막의 두께에 따른 특성 변화)

  • Kim, B.S.;Kim, E.K.;Kang, H.I.;Lee, K.I.;Lee, T.Y.;Song, J.T.
    • Journal of the Korean Vacuum Society
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    • v.16 no.2
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    • pp.105-109
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    • 2007
  • In this paper, we fabricated TCO (transparent conductive oxide) electrode on flexible substrate in order to study effects of electrical and optical properties according to Al-doped ZnO(AZO) film thickness. The thickness of film was from 100 nm to 500 nm and was controlled by changing deposition time. We used High Resolution X-ray Diffractometer (HR-XRD) to analyze crystal structure and UV-visible spectrophotometer to measure property of optical transmittance, respectively. The surface images are obtained by using ESEM (Environment Scanning Electron Microscopy). In this experiment, all the AZO films deposited on flexible substrate show high transmittance over 90% and especially in the films with 400 nm and 500 nm thickness, the resistivity ($4.5{\times}10^{-3}\;{\Omega}-cm$) and optical bandgap energy (3.61 eV) are superior to the other films.

The study of the characteristic of n-ZnO:In/p-Si(111) heterostructure using Pulsed Laser Deposition (PLD법으로 증착된 n-ZnO:In/p-Si(111) 이종접합구조의 특성연구)

  • Jang, B.L.;Lee, J.Y.;Lee, J.H.;Kim, J.J.;Kim, H.S.;Lee, D.W.;Lee, W.J.;Cho, H.K.;Lee, H.S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.355-356
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    • 2008
  • In this work, ZnO films doped with different contents of Indium (0.1at.%, 0.3at.%, 0.6at.%, respectively) were deposited on Si (111) substrate that has 1~20 $\Omega$cm by pulsed laser deposition (PLD) at $600^{\circ}C$ for 30min. The thickness of the films are about 250 nm. The structural, optical and electrical properties of the films were investigated using X-ray Diffraction (XRD), Atomic force microscope (AFM), Photoluminescence (PL) and Hall measurement. It has been found that RMS of the films is decreased and grain size is increased with increasing the contents of doped Indium. The results of the Photoluminescence properties were indicated that the films have UV emission about 380nm and shows a little red shitf with increasing contents of doped indium. The result of the Hall measurement shows that the concentration and resisitivity in doped ZnO are as changing as one order, respectively ${\sim}10^{18}/cm^2$, ${\sim}10^{-2}cm{\Omega}cm$.

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