• Korean Journal of Materials Research
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• v.19 no.3
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• pp.163-168
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• 2009

$Eu^{3+}$-doped $Y_2O_3$ red phosphor was synthesized in a flux method using the chemicals $Y_2O_3,\;Eu_2O_3,\;H_3BO_3$ and $BaCl_2{\cdot}2H_2O$. The effect of a flux addition on the preparation of $Y_2O_3:Eu_{3+}$ red phosphor used as a cold cathode fluorescence lamp was investigated. $H_3BO_3$ and $BaCl_2{\cdot}2H_2O$ fluxes were used due to their different melting points. The crystallinity, thermal properties, morphology, and emission characteristics were measured using XRD, TG-DTA, SEM, and a photo-excited spectrometer. Under UV excitation of 254 nm, $Eu_2O_3$ 3.7 mol% doped $Y_2O_3$ exhibited a strong narrow-band red emission, peaking at 612 nm. From this result, the phosphor synthesized by firing $Y_2O_3$ with 3.7 mol% of $Eu_2O_3$, 0.25 mol% of $H_3BO_3$ and 0.5 mol% of $BaCl_2{\cdot}2H_2O$ fluxes at $1400^{\circ}C$ for 2 hours had a larger particle size of $4{\mu}m$ on average compared to the phosphor of the $H_3BO_3$ flux alone. In addition, a phosphor synthesized by the two fluxes together had a rounder corner shape, which led to the maximum emission intensity.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.5
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• pp.277-284
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• 2015

In order to analyze the contamination level of sediment samples taken from Chusori and Chudong areas in Daechung Reservoir, the particle size and concentrations of organics and nutrients were analyzed and phosphorus fractionation analysis was conducted. The average fraction of silt-sized particles was 92% in the sediments taken from Chudong area and Chusori area at the site adjacent to main current, which was higher than that from the upper Chusori area. The concentrations of total phosphorus in the sediments at Chusori and Chudong area were 999 (${\pm}98$) and 1,123 (${\pm}119$) mg/kg sediment, respectively. The fractions of autochthonous phosphorus, which can be readily eluted by change of environmental conditions, were much higher than those of allochthonous phosphorus, indicating the internal load can contribute the eutrophication in these areas. The concentrations of total nitrogen were over 5,600 mg/kg sediment in all samples, which is the guideline of Contamination Assessment of River and Lake Sediments of the Ministry of Environment, indicating the contamination level of total nitrogen is serious in the sediments. It is concluded that the countermeasures to manage the quality of sediments are required to improve the water quality in the Daechung Reservoir.

• Journal of the Korean Society of Food Science and Nutrition
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• v.31 no.2
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• pp.236-240
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• 2002

Characteristics of ostrich egg shell and optimal ashing conditions for preparation of calcium lactate were investigated. Average weight, girth, and length of ostrich egg shell with membrane (OESM) were 255.17 g, 39.50 cm, and 15.20 cm, respectively. Ostrich egg shell without membrane (OES) contained 0.35% moisture, 40.98% Ca as a maior mineral, 2.43% protein, and 235.0 mg/100 g of amino acids. Optimal ashing times for preparation of white-colored ashing powder from OES were 12 hr at $700^{\circ}C$, 80 min at 80$0^{\circ}C$, and 15 min at 90$0^{\circ}C$, respectively. These ashing conditions resulted in ashing powder with yields of 54.5~54.6% and color values of 97.26 ~97.51 for $L^{*}$, -0.30~-0.34 for $a^{*}$, and 0.63~0.98 for $b^{*}$. Ashing powders, from three different particle size ranges of OES, did not show significant differences in yield.eld.d.

• Journal of Korean Society of Forest Science
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• v.76 no.1
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• pp.17-26
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• 1987

To develop the rehabilitation measures for rockily denuded forest lands which are widely distributed in Seoul metropolitan area, erosional characteristics of denudation should, first of all, be evaluated and analysed. As a fundamental study for developing such technical measures, the rockily denuded lands were classified into 6 types according to denudation features of the mountain land, and also movements of stone debris-and-sand on rock-exposed hillslopes were measured and analysed. The 6 basic types of denudation features include a) natural rock-outcrop-exposed land, b) stone debris-and-sand scattered land, c) stone debris-and-sand deposited land, d) coarse sand producing bare land susceptible to weathering and erosion, e) dwarfed pine growing land, and f) torrential valley susceptible to the debris slides. In the stone debris-and-sand scattered hillslopes (type b), average amount of moved-down debris reached to about 3.9 ton/ha/yr due to surface washing and slidings. In the particle size distribution of the moved-down debris, it amounts to about 25% of 10-25mm, about 15% of 5-10mm, about 24% of 2-5mm, and about 36% of less than 2mm in diameter class, respectively. The detailed experimental studies should be accomplished further more about the denudation processes including weathering, erosion and debris slides on rock-exposed hillslopes.

• Journal of the Korean Ceramic Society
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• v.38 no.11
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• pp.1008-1014
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• 2001

Nanosize YIG powders added by Cerium which is exellent element in magneto-optical effect were synthesized by Sol-Gel method using Ethylene Glycol solvent. In 120 to 150 minute reaction time, stable sol solution which showed no change in viscosity, pH, and aging time was obtained. Monolithic YIG was synthesized at 80$0^{\circ}C$ with DTA and XRD measurement and its lattice parameter had a tendency to increase from 12.3921 $\AA$. Increasing annealing temperature from 80$0^{\circ}C$ to 105$0^{\circ}C$, average particle size was in the range of 40 nm to 330 nm. Saturation magnetization (M$_{s}$) value was increased from 18.37 to 21.25 emu/g due to enhancement of YIG crystallity and decreasing of orthoferrite phase. On the other hand, coercivity (H$_{c}$) value increased up to 90$0^{\circ}C$ and then decreased above 90$0^{\circ}C$. With increasing Ce addition, coercivity was almost not changed but saturation magnetization value was maximum at Ce 0.1 mol% and then decreased because of increasing a orthoferrite amount. Also, curie temperature (T$_{c}$) of YIG were not changed with Ce addition.ion.

• Korean Journal of Materials Research
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• v.8 no.10
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• pp.918-924
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• 1998

This study has been carried out to investigate the effect of reaction milling time on the synthesis of Ti- TiC p powder synthesised from the elemental titanium and activated carbon by reaction milling(RM), and the effect of vacu­u urn hot pressing temperature and TiC volume fraction on microstructural and mechanical properties of Ti- TiC com­p posite $\infty$ns이idated by vacuum hot pressing(VHP).T The elemental powders of titanium and activated carbon can be converted into Ti- TiC composite powders by reac­t tion milling for about 300hours, and were the average grain size of the as- milled powders has been measured to be a about $5\mu\textrm{m}$. The relative density of Ti- TiC VHPed above $1000^{\circ}C$ during Ihr is about 98% and the mechanical properties o of In- situ Ti- TiC composites are improved by TiC particle dispersed uniformly on titanium matrix. In order to investi­g gate thermal stability of Ti- TiC composite, after annealing at $600^{\circ}C$ for 80hrs micro- Vickers hardness have been per­f formed, and the values have been shown little changed as compared with those before annealing. The compact has b been tested on high temperature compressive test at $700^{\circ}C$ and has showed a high temperature compressive strength of 330MPa in a Ti- 20vol% TiC.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.2
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• pp.82-89
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• 2009

According to the great city development and the rapid growth of redevelopment project, waste concrete emission has been increased. Waste concrete powder is one of the by-product originated from the recycling of the waste concrete. The more making high quality recycled aggregate to use aggregate for concrete, the more waste concrete powder is producted relatively. Therefore, to realize the total recycling of waste concrete, development of recycling technology for waste concrete powder need very much. This technical note present the discharged process and the various properties of waste concrete powder. As the results, on the average, the maximum particle-size of waste concrete powder is less than $600{\mu}m$, and oven-dry density is less than $2.5g/cm^3$. And waste concrete powder contains more than 50% of $SiO_2$, 30% of CaO and 10% of $Al_2O_3$. Thus qualities of waste concrete powder is lower than those of high quality raw material for concrete. However, if it is processed by grading to the purpose, it will be used as resource of raw materials for construction field.

• Journal of the Microelectronics and Packaging Society
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• v.23 no.3
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• pp.51-56
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• 2016

To fabricate a copper (Cu)-based fine conductive filler having antioxidation property, submicron silver (Ag)-coated Cu particles were fabricated and their antioxidation property was evaluated. After synthesizing the Cu particles of $0.705{\mu}m$ in average diameter by a wet-reduction process, Ag-coated Cu particles were fabricated by successive Ag plating using ethylene grycol solvent. Main process parameters in the Ag plating were the concentration of reductant (ascorbic acid), the injection rate of Ag precursor solution, and the stirring rate in mixed solution. Thus, Ag plating characteristics and the formation of separate fine pure Ag phase were observed with different combinations of process parameters. As a result, formation of the separate pure Ag phase and aggregation between Ag-coated Cu particles could be suppressed by optimization of the process parameters. The Ag-coated Cu particles which were fabricated using optimal conditions showed slight aggregation, but excellent antioxidation property. For example, the particles indicated the weight gain not exceeding 0.1% until $225^{\circ}C$ when they were heated in air at the rate of $10^{\circ}C/min$ and no weight gain until 75 min when they were heated in air at $150^{\circ}C$.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.9 no.2
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• pp.63-71
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• 2011

A large volume of uranium electrokinetic leachate has been generated during the electrokinetic decontamination to remove uranium from contaminated soil. The treatment technology for the reuse of the uranium leachate was developed. The concentration of uranium in the generated uranium leachate was 180 ppm and concentrations of Mg(II), K(I), Fe(II), and Al(III) ions ranged from 20 ppm to 1,210 ppm. The treatment process for uranium leachate consisted mainly of mixing and cohesion, precipitation, concentration, and filtration. In order to obtain the pH=11 of a precipitate solution, the calcium hydroxide needs to be 3.0g/100ml and the sodium hydroxide needed to be 2.7g/100ml. The results of several precipitation experiments showed that a mixture of NaOH+0.2g alum+0.15g magnetite was an optimal precipitant for filtration. The average particle size of precipitate with NaOH+alum+0.15g magnetite was $600\;{\mu}m$. Because the total value of metal concentrations in supernatant at pH=9 was the smallest, sodium hydroxide should be added with 0.2g alum and 0.15g magnetite for pH=9 of leachate.

• Applied Chemistry for Engineering
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• v.3 no.3
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• pp.527-534
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• 1992

Raney nickel was used as catalyst in the hydrogen electrode for an alkaline fuel cell. The hydrogen electrode manufactured with the Raney nickel catalyst which was sintered at $700^{\circ}C$ was found to have the highest electrode performance. Using the Raney nickel powder of average particle size $90{\AA}$ for the electrode, the current density which had been measured was $450mA/cm^2$ at $80^{\circ}C$ using 6N KOH solution as an electrolyte. The effects of PTFE addition were investigated with CO-chemisorption, polarization curves and Tafel slope. CO-chemisorption had shown the optimum value when the Raney nickel was mixed with 5wt% of PTFE, but from the current density and Tafel slope at porous Raney nickel electrode, the appropriate value of PTFE addition was 10wt%. Recommendable Ni and Al portion for Raney nickel was 60 : 40 and loading amount was $0.25g/cm^2$. Also the influence of pressing pressure for manufacturing catalytic layer and for junction with gas diffusion layer was examined. The morphology of catalyst surface was investigated with SEM. The influence of reactivation time and heat-treatment temperature were also studied.