• Title/Summary/Keyword: Average Grain

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Varistor Properties and Aging Behavior of ZnO-V2O5-MnO2-Co3O4-La2O3 Ceramics Modified with Various Additives (Cr, Nb, Dy, Bi)

  • Nahm, Choon-Woo;Lee, Sun-Kwon;Heo, Jae-Seok;Lee, Don-Gyu;Park, Jong-Hyuk;Cho, Han-Goo
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.4
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    • pp.193-198
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    • 2013
  • The effects of additives (Cr, Nb, Dy, and Bi) on microstructure, electrical properties, dielectric characteristics, and aging behavior of $ZnO-V_2O_5-MnO_2-Co_3O_4-La_2O_3$ (ZVMCL) ceramics were systematically investigated. The phase formed in common for all ZVMCL ceramics modified with various additives consisted of ZnO grain as a main phase, and $Zn_3(VO_4)_2$ and $ZnV_2O_4$ as the secondary phases. The sintered density and average grain size were in the range of $5.4-5.54g/cm^3$ and $3.7-5.1{\mu}m$, respectively. The ZVMCL ceramics modified with Cr exhibited the highest breakdown field (6,386 V/cm) and the ZVMCL ceramics modified with Nb exhibited the lowest breakdown field (3,517 V/cm). All additives enhanced the nonlinear coefficient (${\alpha}$), by a small or large margin, in particular, additives such as Bi and Nb noticeably increased the nonlinear coefficient, with ${\alpha}=25.5$ and ${\alpha}=23$, respectively. However, on the whole, all additives did not improve the stability against a DC stress, compared with ZVMCL ceramics.

Dielectrical and Pyroelectrical Properties of $Pb(Zn_{1/3}Nb_{2/3})O_3-Pb(Zr_xTi_{1-x})O_3$ Compound Ceramics ($Pb(Zn_{1/3}Nb_{2/3})O_3-Pb(Zr_xTi_{1-x})O_3$세라믹의 유전 및 초전 특성)

  • 이성갑;조현무
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.796-801
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    • 2001
  • Ferroelectric 0.05PZN-xPZT(90/10)-(0.95-x)PZT(10/90) (x=0.65, 0.85) specimens were fabricated by the solid-state reaction method, and especially PZT(90/10) and PZT(10/90) powders were derived by the sol-gel method. All specimens showed a uniform ferroelectric grain without the presence of the pyrocholre phase. Average grain size increased with an increased in sintering temperature, the values for the x=0.65 and x=0.85 specimens sintered at 125$0^{\circ}C$ were 14.4$\mu$m and 9.8$\mu$m, respectively. The dielectric constant and dielectric loss of the x=0.65 specimen sintered at 125$0^{\circ}C$ were 1247. 2.06%, respectively. The coercive field and the remanent polarization of x=0.65 and x=0.85 specimens sintered at 125$0^{\circ}C$ were 8.5kV/cm, 13$\mu$C/$\textrm{cm}^2$ and 17.2kV/cm, 28 $\mu$C/$\textrm{cm}^2$, respectively. The pyroelectric coefficient of the x=0.65 and x=0.85 specimens sintered at 125$0^{\circ}C$ were 5.64$\times$10$^{-8}$ C/$\textrm{cm}^2$K and 2.76$\times$10$^{-8}$ C/$\textrm{cm}^2$K, respectively.

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Effect of Annealing Temperature and Alloying Elements on the Mechanical Properties of Fe-Mn-C TWIP Steels (Fe-Mn-C계 TWIP강의 재질특성에 미치는 소둔온도와 첨가원소의 영향)

  • Jung, Jong-Ku;Kim, Nam-Kyu;Yeon, Yeo-Sun;Kim, Hyun-Ho;Lee, Oh-Yeon
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.385-391
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    • 2010
  • Twinning-induced plasticity (TWIP) steels have attracted great attention due to their excellent mechanical properties of high tensile strength (over 800MPa) and high ductility (over 50%), which result from the high strain hardening due to the mechanical twin formation during plastic deformation. The purpose of this study is to investigate the effect of annealing temperature and alloying elements on the mechanical properties of Fe-18Mn-0.6C TWIP steel. In 1.5%Al TWIP steel with 0.123%Ti content, the average recrystallized grain size was reduced to 2.5 ${\mu}m$ by cold rolling and annealing at $800^{\circ}C$ for 5 min, because of the pinning effect of the fine TiC carbides on grain coarsening. The tensile strength was decreased and the ductility was improved with the increase of the annealing temperature. However, a reversion of hardness and yield strength happened between $750^{\circ}C$ and $800^{\circ}C$ due to TiC and $M_3C$ type precipitation. 0.56% Ni added TWIP steel exhibited relatively lower yield strength, because Ni precipitates were not formed during the annealing process. When this specimen was annealed at $800^{\circ}C$ for 5min, the tensile strength and elongation were revealed at 1096MPa and 61.8%, respectively.

Manufacturing of Cu-Zn-Al shape memory alloy using spark plasma sintering (SPS법을 이용한 CuZnAl계 형상기억합금의 제조)

  • 박노진;이인성;조경식;김성진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.4
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    • pp.172-177
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    • 2002
  • The CuZnAl alloys have some advantages against other shape memory alloys, such as the widely variable transformation temperature, the low cost and easy fabrication. The alloys have been produced mostly by metallurgical methods. Thereby a tendency to large grain sizes is observed, which causes brittle properties of the materials. In order to avoid these deficiencies a special powder metallurgical process, SPS(spark plasma sintering), is applied in the present investigation. The starting materials were the pure (99.9 %) Cu, Zn and Al element powders with different particle size. The relatively fine grained and homogeneous Cu-24.78Zn-9.11Al (at.%) and Cu-13.22Zn-17.24Al (at.%) shape memory alloys were obtained using the powders with size of 75-150 $\mu$m. The average grain size is about 70 $\mu$m and the phases at room temperature are the austenitic and martensitic phase respectively.

A Study on Knit Flare Skirts of Hem for 3D Virtual Clothing System - Focused on the Angle of Flare Skirt - (가상착의 시스템을 통한 니트 플레어스커트의 드레이프 형상에 관한 연구 - 각도에 따른 플레어스커트를 중심으로 -)

  • Ki, Hee-Sook
    • Journal of the Korea Fashion and Costume Design Association
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    • v.15 no.2
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    • pp.77-89
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    • 2013
  • This study investigated the formation of silhouette and hemline shape of knit flare skirts according to the properties of knit material through virtual clothing with a 3D virtual clothing system called i-Designer of Technoa, thus building a database of the property data of knit material to reduce the number of sample making steps repeated and implemented several times in the process of clothes making. The results would help to estimate a silhouette in advance, offer assistance to the development of original knit wear, and explore ways to provide basic data for the development of the knit industry of the nation. The investigator made 12 kinds of experimental clothes to the angles(width of skirt: $90^{\circ}$ and $180^{\circ}$), gauge(7G, 12G, and 15G), and grain directions(wale and bias direction) of experimental clothes for virtual clothing. The dynamic characteristics of knit skirt samples according to each gauge were measured with the KES-FB system. Draper shapes were analyzed with the sectional shape data of hemline based on i-Designer. As for the measurements of the sectional shape of hemline and the formation of silhouette, the number of nodes, the average height of node mountains and valleys, and the hemline width right and left and before and after increased at the angle of $180^{\circ}$ than $90^{\circ}$. As gauges multiplied, the number of nodes, and silhouette angle dropping. When considering grain directions, the number of nodes and silhouette index increased in the wale direction at the angle of $90^{\circ}$ with the number of nodes and silhouette angle increasing in the wale direction at the angle of $180^{\circ}$.

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A Study on Settling Properties of Cohesive Sediments in Shihwa Lake (시화호 점착성 퇴적물의 침강 특성에 관한 연구)

  • LEE YOUNG-JAE;LEE SANG-HWA;HWANG KYU-NAM;RYU HONG-RYUL
    • Journal of Ocean Engineering and Technology
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    • v.19 no.4 s.65
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    • pp.42-48
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    • 2005
  • The sediment of Shihwa Lake contains an abundant quantity of cohesive sediments. The transport processes of the cohesive sediments are complex and difficult to predict, quantitatively. The cohesive sediments are the primary reason for the pollution of the environment and water quality in the coastal region. In this study, a column test has been performed. In order to quantify the settling velocities of sediment from Shihwa Lake, an experiment was conducted using a specially designed 1.8m tall settling column. A series of settling tests and physico-chemical property tests on Shihwa Lake cohesive sediments has been conducted to investigate the correlation between settling properties and their physico-chemical properties, which are represented as grain size distribution, mineralogical composition, and percentage oj organic contents. Experimental results of physico-chemical property tests show that Shihwa Lake sediments are relatively large in average grain $size(74\mu m)$ contain very small organic $material(6\%)$, and are dominantly composed of Quarts, which has relatively low cohesion. Thus, Shihwa Lake sediments might be specified as those whose settling properties are more influenced by gravity than cohesion. It is concluded that the magnitude of settling velocities of muddy sediments can be quite different, regionally, and it implies that field or laboratory experiments for settling velocity measurement should be preceded over the numerical modeling of muddy sediment transport, in order to obtain the reliable prediction results for a given specific site.

Effect of Variation in Particle Size of WC and Co Powder on the Properties of WC-Co Alloys (WC와 Co원료 입자크기 변화에 따른 WC-Co계 초경합금의 특성 변화)

  • Chung, Tai-Joo;Ahn, Sun-Yong;Paek, Yeong-Kyeun
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.171-177
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    • 2005
  • The effect of variation in particle size of WC and Co powder on the properties of WC-Co alloys was investigated. WC and Co powders having different particle sizes were used in the fabrication of $WC-10\;wt\%$Co composites. High hardness and low fracture toughness alloy was obtained with the decrease in WC particle size regardless of Co particle size. It was newly found in this investigation that the initial particle size of Co as well as WC had a great role in the microstructure and properties of WC-Co hard materials. The average grain size and fracture toughness of WC-Co alloys using same WC powder size increased and their hardness decreased with the use of relatively finer Co binder.

Analysis of An Anomalous Hump Phenomenon in Low-temperature Poly-Si Thin Film Transistors (저온 다결정 실리콘 박막 트랜지스터의 비정상적인 Hump 현상 분석)

  • Kim, Yu-Mi;Jeong, Kwang-Seok;Yun, Ho-Jin;Yang, Seung-Dong;Lee, Sang-Youl;Lee, Hi-Deok;Lee, Ga-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.11
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    • pp.900-904
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    • 2011
  • In this paper, we investigated an anomalous hump phenomenon under the positive bias stress in p-type LTPS TFTs. The devices with inferior electrical performance also show larger hump phenomenon. which can be explained by the sub-channel induced from trapped electrons under thinner gate oxide region. We can confirm that the devices with larger hump have larger interface trap density ($D_{it}$) and grain boundary trap density ($N_{trap}$) extracted by low-high frequency capacitance method and Levinson-Proano method, respectively. From the C-V with I-V transfer characteristics, the trapped electrons causing hump seem to be generated particularly from the S/D and gate overlapped region. Based on these analysis, the major cause of an anomalous hump phenomenon under the positive bias stress in p-type poly-Si TFTs is explained by the GIDL occurring in the S/D and gate overlapped region and the traps existing in the channel edge region where the gate oxide becomes thinner, which can be inferred by the fact that the magnitude of the hump is dependent on the average trap densities.

Electron beam weldability of titanium alloy (타이타늄합금의 전자빔용접성)

  • Lee, Chae-Hun;Yun, Jong-Won;Park, No-Gwang
    • Laser Solutions
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    • v.10 no.4
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    • pp.13-17
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    • 2007
  • Electron beam weldability was investigated for 1mm thick cold rolled sheets of commercially pure grade titanium and Ti-6Al-4V alloy. Accelerating voltage of 40kV, beam current of 6mA, and weld speed of 0.8m/min was used and focal position of focused electron beam was just on the surface of workpiece. Microstructure of weld metal, the heat affected zone and base metal was observed using optical microscope. Vickers hardness was measured across the welds and the transverse tensile test was carried out. Hydroformability test was also carried out for the butt welded coupons of commercially pure grade titanium. For the electron beam welded C P Ti, the average grain size was equiaxed $\alpha(15{\sim}25{\mu}m)$ for base metal, coarse equiaxed $\alpha(80{\sim}200{\mu}m)$ for weld metal and annealed and enlarged grain($40{\sim}120{\mu}m$) for the HAZ. The vickers hardness of C P Ti was $180{\sim}200Hv$ for base metal, and $160{\sim}180Hv$ for the weld metal and the HAZ. For the electron beam welded Ti-6Al-4V alloy, the vickers hardness was 360Hv for the base metal, abd $400{\sim}425Hv$ for the weld metal and the HAZ. All the failure occurred at the base metal, when the transverse weld tensile test was carried out for both electron beam welded C P Ti and Ti-6Al-4V alloy. The formability of electron beam welded C P Ti was decreased compared with that of C P Ti base alloy.

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Effects of Yittrium and Manganese on the PTCR Barium Titanate Synthesized by Ultrasonic Spray Pyrolysis (초음파 분무 열분해법으로 합성한 PTCR Barium Titanate에 미치는 Y와 Mn의 효과)

  • 김복희;이정형;윤연현;최의석;정웅기
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1169-1177
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    • 1995
  • Barium nitrate and yittrium nitrate were dissolved into distilled water. Titaium hydroxide precipitated from titanium chloride with NH4OH was dissolved into nitric acid. Each aqueous solution was mixed for 12 hr in the composition of Ba1-xYxTiO3 (x=0.1∼0.6) and the concentration of mixed solution was 0.1 mol/ι. The mixed solution was sprayed with an ultrasonic atomizer and carried into an electric furnace which was kept at 900∼1000$^{\circ}C$ and pyrolyzed. Pyrolyzed powders were collected on the glass filter with vacuum pump. Aqueous Mn solutiion was added into the synthesized powders, mixed with ultrasonic vibration and sintered at 1300∼1400$^{\circ}C$. Synthesized powders were characterized with SEM, XRD, DT-TGA, and BET. Microsture and resistivity of sintered body were investigated with SEM and multimeter. The results of this experiment were as follows; 1) Yittrium dooped BaTiO3 powders were synthesized above 950$^{\circ}C$. 2) The average particle sizes of powders from BET specific surface area and SEM were 0.045$\mu\textrm{m}$, 0.046$\mu\textrm{m}$ respectively. The particle size distribution was narrow in the range of 0.1∼1.0$\mu\textrm{m}$ from SEM. 3) Room temperature resistivity and pmax/pmin of 0.4 mol% Y doped specimen which was sintered at 1375$^{\circ}C$ were 102∼3 (Ω$.$cm) and 102∼3 respectively. 4) Room temperature resistivity and pmax/pmin of 0.4 mol% Y and 0.04 at% Mn added specimen which was sintered at 1375$^{\circ}C$ were 102∼3 (Ω$.$cm) and 106∼7 respectively. 5) Grain growth was inhibited with addition of Y2O3 and enhanced in addition of Mn by 0.05 atm%.

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