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One-step microwave synthesis of magnetic biochars with sorption properties

  • Zubrik, Anton;Matik, Marek;Lovas, Michal;Stefusova, Katarina;Dankova, Zuzana;Hredzak, Slavomir;Vaclavikova, Miroslava;Bendek, Frantisek;Briancin, Jaroslav;Machala, Libor;Pechousek, Jiri
    • Carbon letters
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    • v.26
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    • pp.31-42
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    • 2018
  • Adsorption is one of the best methods for wastewater purification. The fact that water quality is continuously decreasing requires the development of novel, effective and cost available adsorbents. Herein, a simple procedure for the preparation of a magnetic adsorbent from agricultural waste biomass and ferrofluid has been introduced. Specifically, ferrofluid mixed with wheat straw was directly pyrolyzed either by microwave irradiation (900 W, 30 min) or by conventional heating ($550^{\circ}C$, 90 min). Magnetic biochars were characterized by X-ray powder diffraction, $M{\ddot{o}}ssbauer$ spectroscopy, textural analysis and tested as adsorbents of As(V) oxyanion and cationic methylene blue, respectively. Results showed that microwave pyrolysis produced char with high adsorption capacity of As(V) ($Q_m=25.6mg\;g^{-1}$ at pH 4), whereas conventional pyrolysis was not so effective. In comparison to conventional pyrolysis, one-step microwave pyrolysis produced a material with expressive microporosity, having a nine times higher value of specific surface area as well as total pore volume. We assumed that sorption properties are also caused by several iron-bearing composites identified by $M{\ddot{o}}ssbauer$ spectroscopy ([super] paramagnetic $Fe_2O_3$, ${\alpha}-Fe$, non-stoichiometric $Fe_3C$, ${\gamma}-Fe_2O_3$, ${\gamma}-Fe$) transformed from nano-maghemite presented in the ferrofluid. Methylene blue was also more easily removed by magnetic biochar prepared by microwaves ($Q_m=144.9mg\;g^{-1}$ at pH 10.9) compared to using conventional techniques.

Changing C-N Interactions in the Forest Floor under Chronic N Deposition: Implications for Forest C Sequestration

  • Park, Ji-Hyung
    • Journal of Ecology and Environment
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    • v.31 no.3
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    • pp.167-176
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    • 2008
  • Atmospheric N deposition has far-reaching impacts on forest ecosystems, including on-site impacts such as soil acidification, fertilization, and nutrient imbalances, and off-site environmental impacts such as nitrate leaching and nitrous oxide emission. Although chronic N deposition has been believed to lead to forest N saturation, recent evidence suggests that N retention capacity, particularly in the forest floor, can be surprisingly high even under high N deposition. This review aims to provide an overview of N retention processes in the forest floor and the implications of changing C-N interactions for C sequestration. The fate of available N in forest soils has been explained by the competitive balance between tree roots, soil heterotrophs, and nitrifiers. However, high rates of N retention have been observed in numerous N addition experiments without noticeable increases in tree growth and soil respiration. Alternative hypotheses have been proposed to explain the gap between the input and loss of N in N-enriched, C-limited systems, including abiotic immobilization and mycorrhizal assimilation, both of which do not require additional C sources to incorporate N in soil N pools. Different fates of N in the forest floor have different implications for C sequestration. N-induced tree growth can enhance C accumulation in tree biomass as observed across temperate regions. C loss from forests can amount to or outweigh C gain in N-saturated, declining forests, while another type of 'C-N decoupling' can have positive or neutral effects on soil C sequestration through hampered organic matter decomposition or abiotic N immobilization, respectively.

Investments on Pro-poor Development Projects on Goats: Ensuring Success for Improved Livelihoods

  • Devendra, C.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.1
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    • pp.1-18
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    • 2013
  • The elements that determine the success of development projects on goats and the prerequisites for ensuring this are discussed in the context of the bewildering diversity of goat genetic resources, production systems, multifunctionality, and opportunities for responding to constraints for productivity enhancement. Key determinants for the success of pro-poor projects are the imperatives of realistic project design, resolution of priorities and positive impacts to increase investments and spur agricultural growth, and appropriate policy. Throughout the developing world, there exist 97% of the total world population of 921 million goats across all agroecological zones (AEZs), including 570 breeds and 64% share of the breeds. They occupy a very important biological and socioeconomic niche in farming systems making significant multifunctional contributions especially to food, nutrition and financial security, stability of farm households, and survival of the poor in the rural areas. Definitions are given of successful and failed projects. The analyses highlighted in successful projects the value of strong participatory efforts with farmers and climate change. Climate change effects on goats are inevitable and are mediated through heat stress, type of AEZ, water availability, quantity and quality of the available feed resources and type of production system. Within the prevailing production systems, improved integrated tree crops - ruminant systems are underestimated and are an important pathway to enhance C sequestration. Key development strategies and opportunities for research and development (R and D) are enormous, and include inter alia defining a policy framework, resolution of priority constraints using systems perspectives and community-based participatory activities, application of yield-enhancing technologies, intensification, scaling up, and impacts. The priority for development concerns the rainfed areas with large concentrations of ruminants in which goats, with a capacity to cope with heat tolerance, can be the entry point for development. Networks and networking are very important for the diffusion of information and can add value to R and D. Well formulated projects with clear priority setting and participatory R and D ensure success and the realisation of food security, improved livelihoods and self-reliance in the future.

Biosorption and Desorption of Pb by Using Sargassum sagamianum (해조류, Sargassum sagamianum을 이용한 Pb 흡착 및 탈착)

  • Seo, Geun-Hak;An, Gap-Hwan;Gong, In-Su
    • KSBB Journal
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    • v.14 no.5
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    • pp.611-615
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    • 1999
  • Biosorption of Pb was evaluated for Sargassum sagamianum. An adsorption equilibrium was reached in about 1 hr. The uptake capacity of Pb was 224.5 mg Pb/G biomass. The adsorption parameters for Pb were determined according to Langmuir and Frueundlich model. With increasing pH, more negative sites are becoming available for adsorption of Pb. When Ca and Mg concentration increases in Pb solution, Pb was selectively adsorbed. The Pb adsorbed by S. sagamianu could be desorbed by desorption process and the efficiency from 0.1M HCl, 0.1M HNO$_3$and 0.1M EDTA was above 95%. S. Sagamianum was reused 6 times and the total uptake was 736.8 mg Pb/g biomass.

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Cyclic Seismic Testing of Full-Scale Column-Tree Type Steel Moment Connections (반복재하 실물대 실험에 의한 컬럼-트리(Column-Tree) 형식 철골 모멘트 접합부의 내진거동 연구)

  • Lee, Cheol Ho;Park, Jong Won
    • Journal of Korean Society of Steel Construction
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    • v.10 no.4 s.37
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    • pp.629-639
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    • 1998
  • This paper summarizes the results of full-scale cyclic seismic performance tests on three column-tree type steel moment connections. Each test specimen consisted of a $H-600{\times}200$ beam and a $H-400{\times}400$ column of SS41 (SS400). Key parameter included was column PZ (panel zone) strength relative to beam strength. The seismic performance of specimen with stronger PZ tended to be inferior. Total plastic rotations available in the specimens ranged from 1.8 to 3.0 (% rad). The limited test results in this study seem to support the speculation that permitting PZ yielding shall be more beneficial to enhancing total plastic rotation capacity of the moment connection. Beam flange fracture across the heat affected zone and divot-type pullout of the column flange were observed in the tests. A conceptual mechanical model consistent with observed test results was also sought.

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Adsorption of selected endocrine disrupting compounds (EDCs)/pharmaceutical active compounds (PhACs) onto granular activated carbon (GAC) : effect of single and multiple solutes (EDCs/PhACs의 단일,복합 조건에서의 GAC에 대한 흡착 연구)

  • Jung, Chanil;Son, Jooyoung;Yoon, Yeomin;Oh, Jeill
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.2
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    • pp.235-248
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    • 2014
  • The widespread occurrence of dissolved endocrine disrupting compounds(EDCs) and pharmaceutical active compounds(PhACs) in water sources is of concern due to their adverse effects. To remove these chemicals, adsorption of EDCs/PhACs on granular activated carbon(GAC) was investigated, and bisphenol A, carbamazepine, diclofenac, ibuprofen, and sulfamethoxazole were selected as commonly occurring EDCs/PhACs in the aquatic environment. Various adsorption isotherms were applied to evaluate compatability with each adsorption in the condition of single-solute. Removal difference between individual and competitive adsorption were investigated from the physicochemical properties of each adsorbate. Hydrophobicity interaction was the main adsorption mechanism in the single-solute adsorption with order of maximum adsorption capacity as bisphenol A > carbamazepine > sulfamethoxazole > diclofenac > ibuprofen, while both hydrophobicity and molecular size play significant roles in competitive adsorption. Adsorption kinetic was also controled by hydrophobicity of each adsorbate resulting in higher hydrophobicity allowed faster adsorption on available adsorption site on GAC. EDCs/PhACs adsorption on GAC was determined as an endothermic reaction resulting in better adsorption at higher temperature ($40^{\circ}C$) than lower temperature ($10^{\circ}C$).

Distributed Data Management based on t-(v,k,1) Combinatorial Design (t-(v,k,1) 조합 디자인 기반의 데이터 분산 관리 방식)

  • Song, You-Jin;Park, Kwang-Yong;Kang, Yeon-Jung
    • The KIPS Transactions:PartC
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    • v.17C no.5
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    • pp.399-406
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    • 2010
  • Many problems are arisen due to the weakness in the security and invasion to privacy by malicious attacker or internal users while various data services are available in ubiquitous network environment. The matter of controlling security for various contents and large capacity of data has appeared as an important issue to solve this problem. The allocation methods of Ito, Saito and Nishizeki based on traditional polynomial require all shares to restore the secret information shared. On the contrary, the secret information can be restored if the shares beyond the threshold value is collected. In addition, it has the effect of distributed DBMS operation which distributes and restores the data, especially the flexibility in realization by using parameters t,v,k in combinatorial design which has regularity in DB server and share selection. This paper discuss the construction of new share allocation method and data distribution/storage management with the application of matrix structure of t-(v,k,1) design for allocating share when using secret sharing in management scheme to solve the matter of allocating share.

Synthesis of Kaolinitic Clay Mineral from Amorphous Alumino-Silicate by Hydrothermal Process (비정질 Alumino-Silicate로부터 수열반응에 의한 Kaolinite질 인공점토의 합성에 관한 연구)

  • 김남일;박계혁;정창주
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1076-1086
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    • 1994
  • This study covers synthetic effect of the various hydrothermal treatments on formation of artificially made kaolinite mineral. The hydrothermal treatment includes the temperature treatment with time duration, addition of seeds, particle size of the starting material used, pH variation and the different types of organic acids. A colloidal silica and alumina sol which are commercially available are used for this study. A colloidal silica and alumina sol are mixed by the atomic ratio of Al/Si = 1, based on the theoretical kaolinite composition and calcined at $600^{\circ}C$ for 8 hours duration. It was found that the kaolinitic clay mineral was well developed; thereby, the different patterns of crystalline mineral are appeared. Spherical type as a crystal form was distinctively formed at the temperature of 20$0^{\circ}C$ to 25$0^{\circ}C$ with short duration time, while platy type as a crystal was highly yielded at 300~35$0^{\circ}C$. Moreover, by adding more than 20 wt% of seed as the natural kaolinitic clay to the starting material is widely distributed and developed when 2 ${\mu}{\textrm}{m}$ or less particle size of the starting material is used; also, when they are heat-treated at the temperature of 25$0^{\circ}C$ with 5 hours duration. With respect of the effect of pH variation on formation of the synthetic kaolinite minerals, the crystalline minerals are highly yielded at less than pH 2 and gradually diminished at more than pH9. Regarding to the effect of different acids on development of the kaolinite mineral, the organic acids with high chelating capacity produces good formation of crystalline minerals; whereas, amine radical-(NH2) is not an effective agent to generate the crystalline minerals.

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Proposed STAR Procedure of Incheon International Airport Considering Safety and Efficiency (인천공항 도착항공기의 안전 및 효율 향상을 위한 표준접근절차 수정방안 연구)

  • Chang, Jaeho
    • Journal of Advanced Navigation Technology
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    • v.20 no.4
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    • pp.292-297
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    • 2016
  • Since continuous descent operations (CDO) is one of several tools available to aircraft operators and air navigation service providers (ANSPs) to increase safety, flight predictability, and airspace capacity while reducing noise, controller-pilot communications, fuel burn and emissions, widespread implementation of CDO would result in significant reductions in the environmental impact and aircraft operation costs in south korea as well. After analyzing each procedure from standard terminal arrival routes used for the Incheon international airport, it can be noticed that one of the procedures has a relatively high altitude constraint at initial approach fix than others, which lead the pilots to use unnecessary drag device in certain situations. Therefore we came to a conclusion that some arrival procedures need to be revised, so unnecessary procedure required during approach can be minimized, thereby reducing fuel consumption, noise and emissions compared to current approach procedures. And it is going to increase the safety margin significantly during approach phase due to reduced workload.

Implementation of Wireless Network Design Tool for TD-SCDMA (TD-SCDMA 무선망 설계 Tool 의 구현 방법론)

  • Jeon, Hyun-Cheol;Ryu, Jae-Hyun;Park, Sang-Jin;Kim, Jung-Chul;Ihm, Jong-Tae
    • 한국정보통신설비학회:학술대회논문집
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    • 2007.08a
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    • pp.247-250
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    • 2007
  • There are three main kinds of service standards for 3G(Third-Generation) wireless communication as WCDMA, CDMA2000 and TD-SCDMA(Time Division-Synchronous Code Division Multiple Access). Compare with WCDMA and CDMA2000, TD-SCDMA system has distinguished technical characters. It is a TDD(Time Division Duplexing) based technology and deploys several advanced but in some respects complex technologies such as smart antenna, joint-detection and baton-handoff, etc. Therefore to analyze and design TD-SCDMA wireless network, it needs more efficient and systematic simulation tool. General simulation tool has so many analysis functions including path loss prediction, capacity and coverage analysis. For more suitable for TD-SCDMA, new additional technologies have to be implemented in simulation tool. Especially as the wireless network highly advancing focused on data service, it more needs to research and develop on the reliability of the simulation tool. In this paper, to give the concrete process and skill about how to implement TD-SCDMA simulation tool, we define the kinds of simulation tool and list basic analysis functions available for TD-SCDMA network design at first. And then we explain how to consider the effects of new technologies of TD-SCDMA and give the solutions about theses considerations.

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