• 제목/요약/키워드: Available $P_2O_5$

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밭토양(土壤)에서 삼요소(三要素) 장기연용(長期連用)에 의(依)한 대맥(大麥) 수량(收量) 및 토양(土壤)의 이화학적(理化學的) 성질변화(性質變化) (Changes in Barely Yield and Soil Physcio-Chemical Properties Affected by Long-Term Fertilization to the Upland Soil)

  • 김창배;박노권;박선도;최대웅
    • 한국토양비료학회지
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    • 제26권1호
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    • pp.20-24
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    • 1993
  • 밭토양(土壤)에서 비료(肥料)의 장기(長期) 연용(連用)이 대맥(大麥)의 생육(生育) 및 수량(收量)에 미치는 영향(影響)을 구명(究明)코자 미사질(微砂質) 식양토(埴壤土)인 우평통(牛坪統)에 무비(無肥), P.K, N.K, N.P 및 N.P.K구(區)를 처리(處理)하여 1975~1990년(年)까지 16년간(年間)의 년차간(年次間) 수량변화(收量變化), 16년차(年次) 수확기(收穫期) 식물체(植物體) 부위별(部位別) 양분흡수량(養分吸收量) 및 토양성질(土壤性質) 변화(變化)를 조사(調査)한 결과(結果)는 다음과 같다. 1. 삼요소(三要素) 대조구(對照區)에 비(比)하여 각요소(各要素) 결제구(缺除區)의 수량감수정도(收量減收程度)는 P.K$P_2O_5$와 $K_2O$ 흡수량(吸收量)이 전처리중(全處理中) 가장 적었고 특(特)히 N와 $K_2O$의 흡수이용률(吸收利用率)은 부(負)의 수치(數値)를 보였다. 4. 시험후(試驗後) 토양분석결과(土壤分析結果) N.K 처리구(處理區)에서 토양(土壤) pH가 매우 낮았고, 또한 토양중(土壤中) $P_2O_5$, Ca, Mg 함량(含量)은 매우 적었으며, 16년간(年間) 평균토양중(平均土壤中) 인산(燐酸) 및 고토함량(苦土含量)과 대맥수량(大麥收量)과는 정(正)의 상관(相關)을 보였으나, 16년차(年次) 시험(試驗) 후(後) 토양중(土壤中) $NO_3-N$ 함량(含量)은 매우많은 반면(反面) 식물체(植物體) 질소(窒素) 및 기타(其他) 성분(成分) 흡수량(吸收量)은 매우 적었다.

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Assessing Changes in Selected Soil Chemical Properties of Rice Paddy Fields in Gyeongbuk Province

  • Park, Sang-Jo;Park, Jun-Hong;Won, Jong-Gun;Seo, Dong-Hwan;Lee, Suk-Hee
    • 한국토양비료학회지
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    • 제50권3호
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    • pp.150-161
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    • 2017
  • This study was conducted with the data of monitoring on soil chemical properties of rice paddy soils in Gyeongbuk Province. The selected soil chemical properties were analyzed every 4 year from 1999 to 2015. The soil pH measured in 2015 was higher than pH 6.0, which was 0.3-0.4 pH unit higher than data until 2007 survey year. The mean content of organic matter was greater than $24g\;kg^{-1}$ since 2003, but 35% of soil samples remained below the recommended level ($20-30g\;kg^{-1}$) in 2015. The mean concentration of available phosphate was maintained at $40mg\;kg^{-1}$ higher than the upper recommendation level ($80-120mg\;kg^{-1}$), and more than 40% of paddy soils tested were found to have less than the recommendation level during the survey period. The exchangeable K concentration ranged from 0.25 to $0.39cmol_c\;kg^{-1}$. Exchangeable Ca showed an average at the optimum range ($5.0-6.0cmol_c\;kg^{-1}$) during the monitoring period. Exchangeable Mg decreased linearly ($0.02cmol_c\;kg^{-1}\;year^{-1}$) from $1.55cmol_c\;kg^{-1}$ as of 1999 to below the lower level of the recommendation range ($1.5-2.0cmol_c\;kg^{-1}$). The amount of available $SiO_2$ was increased significantly from 2011 to over the recommendation level (${\geq}157mg\;kg^{-1}$). It was revealed that the soil chemical properties of rice paddy fields was influenced by topology, soil texture, type and region as result of principal component analysis or cluster analysis. Therefore, an assessment on chemical properties of rice paddy soils should be performed to consider various soil physical conditions and agronomic practices such as fertilization, cropping system, and so on. Because of the high variability of nutrient levels across Gyeongbuk Province, nutrient management based on soil fertility test is required by respective farm land unit.

A Novel Acid-Base Catalyzed Sol-Gel Synthesis of Highly Active Mesoporous TiO2 Photocatalysts

  • Khan, Romana;Kim, Sun-Woo;Kim, Tae-Jeong;Lee, Hyo-Sun
    • Bulletin of the Korean Chemical Society
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    • 제28권11호
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    • pp.1951-1957
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    • 2007
  • A new synthetic strategy based on the acid-base catalyzed sol-gel method was developed for the preparation of a series of mesoporous TiO2 nanoparticles. A key feature of the method involves a gradual change in pH (0.8- 9) during the sol-gel transition, which guarantees easy introduction of mesoporosity without relying on the well-established sonochemical or template approach. In addition, this method leads to the exclusive formation of the anatase phase stable enough to the calcination temperature up to 600 oC. The physicochemical properties of the particles in the series were characterized by various spectroscopic and analytical techniques such as wide-angle XRD, SAXRD, BET surface area, FE-SEM, TEM, FT-IR, TGA, and XPS. The photocatalytic efficiency of these materials was investigated for the oxidation of toluene under UV-irradiation. All but T-ad in the series exhibited high photocatalytic activity pushing the reaction into completion within 3 h. The reaction followed the first order kinetics, and the rate reaches as high as 3.9 × 10?2/min which exceeds the one with the commercially available Degussa P-25 by a factor of 3.2. When comparison is made among the catalysts, the reactivity increases with increase in the calcination temperature which in turn increases the crystallinity of the anatase phase, thus revealing the following rate orders: T-3 < T-4 < T-5 < T-6.

광역친환경농업단지의 경축순환자원 양분관리 (Management of Recycled Nutrient Resources using Livestock Waste in Large-Scale Environment-Friendly Agricultural Complex)

  • 문영훈;안병구;정성수
    • 한국토양비료학회지
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    • 제45권2호
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    • pp.177-184
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    • 2012
  • 광역친환경농업단지의 경축순환자원 활용실태를 파악하기 위해 전북 완주군 고산광역친환경농업단지의 토양특성과 축분퇴비 소요량 등을 조사하였다. 주요작물 재배면적은 2,353 ha (벼 1,398 ha, 감 189 ha 등)이며 이 가운데 친환경 참여면적은 402.9 ha이고, 주요 축종사육은 한우 21,077, 젖소 1,099, 돼지 32,993마리 등 총 58,955 마리이었다. 경축자원화센터에 유입되는 분뇨는 한우, 돼지 각각 6,000 마리, 닭 200,000 마리 참여로 일일 32 Mg이고, 퇴비생산량은 연간 9,600톤이며, 비료성분은 T-N 1.4%, $P_2O_5$ 2.7%, $K_2O$ 2.1%, MgO 0.9%, CaO 2.5% 이었다. 친환경농업단지 내에서 소모되는 퇴비량은 6,588 Mg이었다. 친환경농업단지의 토양화학성분은 논의 경우 pH는 78.1%, 밭 58.2%, 과수원 60.3%, 비가림시설 재배지 62.1%가 적정범위였다. 유기물은 논의 경우 41.7%, 밭 46.5%, 과수원 40.5%, 비가림시설재배지 81.4%가 과잉으로 나타났다. 유효인산은 밭토양을 제외하고 64.9~91.7%가 과잉으로 나타났으며, 치환성 $K^+$, $Ca^{2+}$, $Mg^{2+}$은 과수원과 비가림시설재배지에서 53.2~70.2%가 과잉인 것으로 나타났다. 비가림시설 재배지의 토양화학성은 2년차 이후에 증가폭이 컸으며, 모든 농경지의 중금속 함량은 토양오염우려기준을 초과한 경우는 없었다. 친환경농업단지의 미생물분포는 일반농경지 보다 높았고, 호기성균의 경우 친환경농업단지의 밭과 과수원토양에서 가장 높았다.

Comparison of Livestock Manure Compost and Chemical Fertilizer Application in Distribution of P Fractions at Reclaimed Land Soils

  • Moon, Tae-Il;Yoon, Young-Man
    • 한국토양비료학회지
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    • 제49권4호
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    • pp.327-334
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    • 2016
  • In order to compare phosphorus (P) behavior of livestock manure compost (LMC) and chemical fertilizer (CF) applied to the sea-reclaimed land soils, incubation experiments were conducted for five weeks. Four soils differing textural classes, sandy loam and clay loam, and electric conductivity (EC) value, high and low, were applied with CF and LMC. LMC was applied at the level of 0, 1, 2, and 3% on the soil weight basis and CF was applied at the same levels of P as LMC. The results showed that increase of P application rate of CF and LMC led to linearly increase available $P_2O_5$ and $0.01M\;CaCl_2$ extractable P contents regardless of soil texture and EC. However, 0.01M $CaCl_2$ extractable P from soil applied with CF was significantly higher than with LMC. Correlation analysis between $0.01M-CaCl_2$ extractable P and fractionated P by different extraction methods showed that $0.01M-CaCl_2$ extractable P positively correlated with KCl-P (soluble and exchangeable P) and HCl-P (Ca and Mg bound P). However, NaOH-P (Fe and Al bound P and organic P) and residual P was adverse. The amount of NaOH-P significantly influenced to the amount of 0.01M $CaCl_2$ extractable P of CF and LMC in the soils. The application of LMC at sandy loam soil could be carried out in the consideration of nutrient leaching and crop uptake.

통일계(統一系) 수도품종(水稻品種)에 대(対)한 답토양별(畓土壤別) 인산(燐酸) 및 가리시비적량(加里施肥適量) (Determination of the Optimum Rates of P and K Fertilizer Application for Tong-il Line Rices in Different Paddy Soils)

  • 이춘수;허범량;류인수;박천서;고미석
    • 한국토양비료학회지
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    • 제15권2호
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    • pp.101-109
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    • 1982
  • 농가포장에서 실시한 '76~'79년의 비료 시험성적으로부터 수도의 통일계 품종에 대한 인산 및 칼리의 시비효과와 시비적량을 토양의 물리적 특성을 달리하는 답유형별로 검토하였으며, 이 중 '77년의 시험성적을 집중적으로 분석하여 토양화학 검정치에 따른 시비적량의 산출기준을 설정하였는 바, 그 결과를 요약하면 다음과 같다. 1. 답유형별로 산출한 인산의 시비적량 6.6-11.4kg/10a범위에서 미숙답>보통답>사질답>염해답${\fallingdotseq}$습답의 순이었고, 칼리의 시비적량은 7.0-11.3kg/10a범위에서 미숙답>습답>사질답>보통답${\fallingdotseq}$염해답의 순이었다. 2. 답유형별로 산출된 적정시비량은 사용하였을 때 각각의 무요소구에 대한 증수효과는 인산의 경우 3.5-7.5%, 칼리의 경우 2.2-91%의 범위에서 답유형별로 차이가 있었다. 인산의 효과는 미숙답에서, 칼리의 효과는 습답에서 가장 컸으며, 염해답에서는 인산과 칼리의 효과가 모두 비교적 높았다. 3. 답토양의 필지별 화학성분 검정치와 상대수량 지수의 관계에서 시비효과의 한계점인 토양중 유효인산의 임계함량은 보통답 약 100ppm, 사질답 약 200ppm이었고, 치환성 칼리 염기비(K/Ca+Mg${\times}100$)임계점은 보통답 약 8, 사질답 8이상이며, 습답에서는 나타나지 않았다. 4. 토양검정치(x)에 따른 시비적량(y) 산출식은 인산에 있어서는 보통답 y=11.270-0.048x, 사질답 y=13.383-0.061x이고 칼리에 있어서는 보통답 y=9.526-0.569x, 사질답 y=11.727-1.004x, 습답 y=12.574-0.558x이었다.

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한국 밭토양 화학성 변동 평가 (Status and Changes in Chemical Properties of Upland Soil from 2001 to 2017 in Korea)

  • 김이현;공명석;이은진;이태구;정구복
    • 한국환경농학회지
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    • 제38권3호
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    • pp.213-218
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    • 2019
  • BACKGROUND: Monitoring of the dynamic changes of chemical properties in agricultural land is very important for agricultural sustainability. Chemical properties of agricultural soils in Korea have been investigated at four-year interval in the order of paddy, plastic film house, upland, and orchard soils since 1999. METHODS AND RESULTS: Total 8,160 topsoil samples were taken from the upland in 2001, 2005, 2009, 2013, and 2017, respectively. Soil chemical properties such as pH, electrical conductivity (EC), organic matter (OM), available phosphate (Avail. $P_2O_5$), and exchangeable (Exch.) cations (K, Ca, and Mg) were analyzed. Soil pH and Exch. Ca contents have increased since 2001. Average concentration of Avail. $P_2O_5$ increased from $547mg\;kg^{-1}$ in 2001 to $657mg\;kg^{-1}$ in 2017. Average concentration of Exch. Ca in 2017 was higher than the upper limit of its optimal range for upland cultivation. Excess and deficiency of chemical properties of upland soils comply with soil analysis and fertilizer prescription. CONCLUSION: We concluded that excessive nutrient in upland needed to be properly managed with soil test.

원주지역 산지초지의 연간 생초수량과 버려진 초지의 식생천이에 관한 연구 (Annual Flesh Weight Yield of Oversowing Grassland and Vegetation Succession of Abandoned Grassland in Wonju area)

  • 이성규
    • 한국초지조사료학회지
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    • 제17권3호
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    • pp.257-264
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    • 1997
  • This study was conducted to assess present situiatioq of oversowing grassland yield and vegetational succession of abondoned since 6 years passed grassland in Wonju. The highest annual h s h weight yield was 28ton/ ha and the lowest was I lton/ha and the grass rate of investigated oversowing grasslands were range from 19.5% to 9lS%. The soil properties of abandoned oversowing grassland, such as soil pH content of organic matter, available phosphorus, exchangeable potasium, calcium, and magnesium were 5.7, 3.88%, 3lppm, O.lme1100g 4.9meI 100g and 2.3me/100g, respectively. The floristic composition of abandoned grassland were composed 26 species of vascular plants. The dominant species based on SDR, of grassland were Miscanthus sinensis var. purpurascens(56.32%). Artemisia feddei(48.62%) and Dactylis glomerata(43.85%). The biological spectra showed the H-$D_1$-$R_5$-e type.

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서울시 도시농업지역 토양의 이화학적 특성 및 중금속 함량 (Properties and Heavy Metal Contents of Urban Agricultural Soils in Seoul)

  • 김혁수;김영남;김진원;김계훈
    • 한국토양비료학회지
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    • 제44권6호
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    • pp.1048-1051
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    • 2011
  • This study was carried out to find out properties and total and phytoavailable contents of heavy metals (Cd, Pb, Cu, Zn) in 21 urban agricultural soils in Seoul. The investigated urban soils showed $pH_{(1:5)}$ 6.89, $EC_{(1:5)}$ $0.14dS\;m^{-1}$, organic mater 2.22%, available $P_2O_5$ $139mg\;kg^{-1}$, cation exchange capacity (CEC) $11.36cmol_c\;kg^{-1}$, total nitrogen 0.15% and exchangeable Ca, Mg, K and Na were 6.71, 1.44, 1.06 and $0.30cmol^+\;kg^{-1}$, respectively. Total heavy metal concentrations in urban agricultural soils were lower than those of the warning levels in the area 1 according to the Soil Environmental Conservation Act of Korea. Phytoavailable-Cu, -Pb, and -Zn concentrations of the samples showed 0.02-0.28, N.D-0.09, $0.01-0.43mg\;kg^{-1}$, respectively.

침엽수와 활엽수 산림에서 산불 후 토양화학적 및 토양미생물학적 특성 변화 (Changes of Chemical and Microbial Properties of Soils after Forest Fires in Coniferous and Deciduous Forests)

  • 김종갑;오기철
    • The Korean Journal of Ecology
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    • 제24권1호
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    • pp.1-7
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    • 2001
  • 침엽수림과 활엽수림의 산불지역에서 토양환경의 회복과정을 살펴보기 위해, 산불발생 후 시간이 경과함에 따른 토양화학적 성질과 토양미생물 변화를 조사하였다. 활엽수림인 삼신봉 지역 산화지에서의 산불직후 토양의 화학적 성질은 pH 5.8, 유기물량 7.42%, 전질소량 0.37%, 유효인산량 28.5 mg/kg, 치환성양이온인 $K^{+}$이 1.3 me/100g, $Ca^{++}$이 13.3 me/100g, $Mg^{++}$이 2.2 me/100g로 나타났으나 시간이 경과할수록 감소하는 경향이었으며, 비산화지에서는 시간 경과에 따른 변화폭이 적었다. 침엽수림인 촛대산 산불지역에서 산불직후 토양의 화학적 성질은 pH 5.3, 유기물량 6.42%, 전질소량 0.25%, 유효인산량 24.4 mg/kg, 치환성양이온인 $K^{+}$이 0.7 me/100g, $Ca^{++}$이 3.7 me/100g, $Mg^{++}$이 2.1 me/100g로 각각 나타났으며, 시간이 경과할수록 역시 감소하는 경향 이었다. 활엽수림 인 삼신봉 산불지역의 토양미생물은 호기성균 291$\times$$10^4$ CFU균, 방선균 523$\times$$10^4$ CFU균, 진균 691$\times$$10^4$ CFU균으로 진균의 개체수가 비교적 높게 나타났으며, 비산불지역에서는 호기성균 160$\times$$10^4$ CFU균, 방선균 745$\times$$10^4$ CFU균, 진균 594$\times$$10^4$ CFU균으로 방선균의 개체수가 높게 나타났다. 침엽수림인 촛대산 산불지역에서는 호기성균 350$\times$$10^4$ CFU균, 방선균 434$\times$$10^4$ CFU균, 진균 676$\times$$10^4$ CFU균으로 진균의 개체수가 비교적 높게 나타났으며, 비산불지역에서는 호기성균 328$\times$$10^4$ CFU균, 방선균 319$\times$$10^4$ CFU균, 진균 461$\times$$10^4$ CFU균으로 진균의 개체수가 높게 나타났다. 토양미생물은 호기성균, 방선균, 진균 모두 비산불지역 보다 산불지역에서 많이 나타났다. 본 조사지역에서 호기성균은 활엽수림보다 침엽수림에서 많게 나타났으며, 방선균과 진균은 침엽수림보다 활엽수림에서 많이 나타났다.

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